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Kelvin

The kelvin (symbol: K) is the of , defined by fixing the numerical value of the k at exactly $1.380\,649 \times 10^{-23} J K^{-1}, where the joule is the SI unit of energy. This definition, adopted in the 2019 revision of the (SI), establishes the kelvin as an with 0 K corresponding to —the theoretical lowest temperature at which the of a perfect reaches its minimum value and all thermal motion ceases. The unit is named after William Thomson, 1st Baron Kelvin (1824–1907), a physicist and engineer who first proposed an absolute temperature scale in 1848 to resolve inconsistencies in the theory. The kelvin scale aligns closely with the Celsius scale, differing only by a constant shift: a temperature interval of 1 K equals 1 °C, and the conversion is given by T(\text{K}) = t(°\text{C}) + 273.15, with the triple point of water measured at 273.16 K. Historically, the kelvin's magnitude was originally set by the triple point of water (0.01 K above the ice point) until the 2019 redefinition, which decoupled it from any physical artifact for greater precision and universality. This unit is fundamental in fields like physics, chemistry, and engineering, enabling precise measurements of phenomena such as blackbody radiation, ideal gas behavior, and quantum effects near absolute zero.

Definition and Fundamentals

Absolute Scale Characteristics

The kelvin, symbol K, is the base unit of the (SI) for . Prior to the 2019 revision of the SI, the kelvin was defined as exactly 1/273.16 of the thermodynamic temperature of the of , which served as a reproducible fixed point for calibration. Following the 26th General Conference on Weights and Measures in 2018, the kelvin was redefined by fixing the numerical value of the k to exactly $1.380649 \times 10^{-23} when expressed in the unit J K^{-1}, where the joule is defined in terms of the hertz and second. This redefinition maintains the triple point of water at exactly 273.16 K while linking the unit directly to a fundamental , ensuring long-term stability independent of material artifacts. The Kelvin scale is an absolute thermodynamic scale, with its zero point at , defined as 0 K—the theoretical lower limit of temperature at which the thermal motion of particles in a perfect crystalline substance reaches its minimum, approaching complete rest. Unlike empirical interval scales such as the , which allow negative values relative to an arbitrary zero, the Kelvin scale prohibits negative temperatures and exhibits additivity for temperature intervals, enabling consistent measurement of differences regardless of the reference point. This absolute nature ensures that thermodynamic T, expressed in kelvins, behaves as an invariant under reversible processes, preserving its value across equilibrium transformations. A key application of the Kelvin scale arises in fundamental thermodynamic relations, such as the , which relates P, volume V, n, and T through PV = nRT, where R is the gas constant. Here, T in kelvins directly scales with the average of gas particles, proportional to kT per degree of freedom, underscoring the scale's connection to microscopic distributions. The relation to the scale is given by T (in K) = t (in °C) + 273.15, facilitating practical conversions without altering the absolute properties.

Conversion to Other Temperature Scales

The Kelvin scale is an absolute temperature scale, allowing straightforward conversions to other scales like and through defined offsets and ratios. To convert from Kelvin to , subtract 273.15 from the Kelvin value, as the scale is shifted by this exact amount relative to Kelvin: T(°C) = T(K) - 273.15 This offset arises because the of , where solid, , and vapor phases coexist in equilibrium, is defined as exactly 273.16 K, corresponding to 0.01 °C; thus, 0 °C is precisely 273.15 K. The reverse conversion adds 273.15: T(K) = T(°C) + 273.15 For Fahrenheit, which is based on a non-absolute scale with an arbitrary zero point (32 °F for the freezing point of water) and a degree size of 5/9 that of Celsius, the conversion from Kelvin first shifts to Celsius and then applies the Fahrenheit ratio: T(°F) = (T(K) - 273.15) \times \frac{9}{5} + 32 This simplifies to T(°F) = T(K) \times \frac{9}{5} - 459.67, where -459.67 °F marks absolute zero. The reverse formula is: T(K) = (T(°F) + 459.67) \times \frac{5}{9} Practical examples illustrate these conversions: the boiling point of water at standard atmospheric pressure is 373.15 K, equivalent to 100 °C or 212 °F, while absolute zero is 0 K, or -273.15 °C and -459.67 °F. A key feature of the Kelvin and Celsius scales is that their degree intervals are identical, so a temperature change of 1 K equals a change of 1 °C; however, a 1 K change corresponds to 1.8 °F due to Fahrenheit's different degree size.

Historical Development

Precursors and Early Concepts

The development of concepts leading to an absolute temperature scale began with early experiments on gas behavior. In 1703, French physicist constructed an air thermometer of constant volume, observing that the pressure of trapped air increased linearly with temperature rises above a reference point, such as the freezing point of water. By extrapolating this linear relationship downward, Amontons inferred a theoretical "extreme cold" at which pressure would reach zero, approximately 240 degrees below the freezing point on his scale, marking an initial conception of derived from pressure-volume observations in gases. Building on such empirical foundations, Jacques Alexandre César Charles conducted unpublished experiments around 1787, noting that the volume of a gas held at constant pressure expands proportionally with increasing temperature. This relationship, expressed as V \propto T where T is absolute temperature, implied that the ratio V/T remains constant for a given quantity of ideal gas, further supporting the idea of an absolute zero at which volume would theoretically vanish. Charles's observations suggested a temperature scale independent of arbitrary fixed points, though they remained private until later dissemination. In 1802, Joseph Louis Gay-Lussac publicly refined and quantified Charles's findings through meticulous measurements on various gases, confirming that their volumes increase by approximately 1/273 of the value at 0°C for each degree Celsius rise at constant pressure. Gay-Lussac's work extended the proportionality to multiple gases, excluding those soluble in water, and highlighted the universality of the effect, thereby strengthening the empirical basis for an absolute scale. Concurrently, John Dalton's emerging atomic theory, formalized in his 1808 publication A New System of Chemical Philosophy, posited gases as collections of discrete atoms whose repulsive forces and motions underpin volume and pressure changes with temperature, offering a rudimentary kinetic interpretation that aligned gas laws with particulate behavior. During the early 1800s, efforts to formalize absolute scales drew on these , as seen in Pierre-Simon Laplace's collaborations with on and specific heats, which explored as a influencing gas without yet defining a fixed, reproducible unit for absolute . These precursors established the linear gas thermometry but lacked a standardized reference, setting the stage for subsequent theoretical unification.

Lord Kelvin's Contributions

William Thomson, later known as , proposed the first absolute temperature scale in his paper "On an Absolute Thermometric Scale founded on Carnot's Theory of the Motive Power of Heat, and calculated from Regnault's Observations." In this work, Thomson utilized Sadi Carnot's theorem on the efficiency of heat engines, which posits that the maximum efficiency depends solely on the temperature difference between the source and sink, to define an absolute measure of temperature independent of any particular substance. He argued that the mechanical effect produced by between two bodies is proportional to the temperature interval on this scale, providing a universal standard for thermometry. Thomson's initial formulation relied on the air as a practical reference, extrapolating to using , which describes the linear expansion of gases with temperature. By extending the air 's readings downward, he determined to be approximately -273°C on the conventional scale, establishing 0 on the new scale at this point where molecular motion theoretically ceases. To calibrate the scale, Thomson incorporated Henri Victor Regnault's experimental data on the physical properties of air and vapors, calculating that the temperature of the ice point (freezing of at standard pressure) corresponded to about 273 units above , while the of was around 373 units. This setup ensured the absolute scale's degrees matched those of the air between 0°C and 100°C, offering a consistent framework for thermodynamic calculations. The development of this thermodynamic temperature concept was significantly influenced by James Prescott Joule's experimental demonstrations that heat is a form of convertible to mechanical work, challenging the underlying Carnot's original assumptions. Thomson, who had encountered Joule's findings around 1847, integrated this insight in subsequent writings, refining the absolute scale to align with the and establishing as a measure tied to the average of particles. This synthesis bridged empirical with emerging thermodynamic principles, laying the groundwork for modern .

Standardization and Triple Point

The practical realization of the Kelvin scale prior to 1954 relied on the normal thermometer, a constant-volume gas thermometer using gas to approximate the for measuring absolute temperatures, calibrated against the ice point of water at 0 °C and 1 atm pressure. This method provided a reproducible but indirect approach to the thermodynamic scale, with the kelvin defined as equivalent to the degree interval on the scale extrapolated from . In 1954, the 10th Conférence Générale des Poids et Mesures (CGPM) adopted Resolution 3, formally defining the as the unit of such that the temperature of the of water, denoted T_\text{t}, is exactly 273.16 K, establishing the as the fundamental fixed point for the scale. This single-point definition replaced earlier two-point calibrations (such as and points) to enhance precision and universality in thermometry. The of represents the unique condition of where its solid (), , and vapor phases coexist, occurring at a of 0.01 °C (exactly 273.16 K) and a of 611.657 . This state is realized in sealed cells containing high-purity , providing an exceptionally reproducible reference with uncertainties as low as 0.1 when properly prepared, far surpassing the variability of single-phase transitions like the ice point under . The selection of the triple point over single-phase points, such as the point, was driven by its superior precision for primary thermometry, as the coexistence of three phases yields a sharp, unambiguous boundary that minimizes measurement errors from impurities, pressure variations, or effects. In 1967–1968, the 13th CGPM further refined this through Resolution 3, officially naming the unit "kelvin" (symbol ) rather than "degree Kelvin" (°K) and explicitly defining it as \frac{1}{273.16} of the at the of water, solidifying its role in the . This adjustment also aligned practical temperature scales, like the International Practical Temperature Scale of 1968 (IPTS-68), with the as the anchor for calibrations above 0 , improving consistency across global .

2019 SI Redefinition

The 26th General Conference on Weights and Measures (CGPM), held in November 2018, adopted Resolution 1 approving the redefinition of the kelvin as part of the broader revision of the (SI), with the change taking effect on May 20, 2019. Under this redefinition, the kelvin is now defined by fixing the numerical value of the k to exactly $1.380\,649 \times 10^{-23} joules per kelvin (J/K), thereby linking the unit directly to a fundamental physical constant rather than a material artifact. This shift was motivated by the desire to base the on invariant constants of nature, such as the h, to ensure long-term stability and universality, while addressing limitations of the prior definition tied to the of , which suffered from challenges due to isotopic variations in water samples that could cause discrepancies of up to about 0.2 mK. As a result, the of , previously exactly 273.16 K by , is now an approximate value of 273.16 K, measured relative to the fixed , which enhances the scale's independence from material properties and improves consistency across global measurements. The redefinition has no immediate impact on existing temperature values or calibration practices, as the numerical value of k was chosen to preserve continuity with prior measurements. However, it promotes greater precision in fields like low-temperature physics by facilitating primary thermometry methods that directly link measurements to the , potentially ushering in advanced techniques for realizing the kelvin without reliance on secondary standards.

Practical Applications

Thermodynamic and Scientific Uses

In thermodynamics, the Kelvin scale serves as the absolute temperature measure essential for fundamental equations describing gas behavior and energy transfer. The , expressed as PV = nRT, relates P, V, n, and temperature T in kelvins, with R as the ; this formulation ensures thermodynamic consistency by avoiding negative temperatures inherent in other scales. Similarly, the Stefan-Boltzmann law states that the total power radiated per unit surface area of a is proportional to the fourth power of its absolute temperature, j = \sigma T^4, where \sigma is the Stefan-Boltzmann and T is in kelvins; this relation underpins calculations of in high-temperature environments. Wien's law further illustrates the Kelvin scale's role, asserting that the wavelength \lambda_{\max} at which peaks satisfies \lambda_{\max} T = b, with b \approx 2.897 \times 10^{-3} m·K as Wien's constant; this enables determination of source temperatures from spectral peaks. The Kelvin scale is indispensable in specialized scientific domains requiring precise low- or high-temperature assessments. In cryogenics, phenomena like emerge at temperatures near , such as the 4.2 K transition in mercury, where electrical vanishes below critical thresholds; the scale's origin at 0 K facilitates studies of quantum effects in materials cooled to millikelvins. employs kelvins to quantify lapse rates, the rate of temperature decrease with altitude, typically around 6.5 K/km in the under standard conditions, aiding models of and patterns. In stellar physics, surface temperatures of stars are routinely expressed in kelvins, ranging from about 2,500 K for cool red dwarfs to over 50,000 K for hot O-type stars, allowing astrophysicists to classify spectral types and infer evolutionary stages via black-body approximations. Accurate temperature measurement in scientific contexts relies on devices calibrated against the Kelvin scale for traceability to the International Temperature Scale of 1990 (ITS-90). Thermocouples, which generate voltage from the Seebeck effect across dissimilar metals, are calibrated over wide ranges (e.g., type K from 0 K to 1,700 K) to ensure precision in dynamic environments like engines or reactors. Resistance thermometers, particularly platinum models, exhibit resistance changes proportional to temperature and are standardized at fixed points like the triple point of water (273.16 K), achieving uncertainties below 0.001 K for cryogenic and high-accuracy applications. The Kelvin scale also anchors the third law of thermodynamics, which posits that the entropy S of a perfect crystalline substance approaches a minimum value—typically zero—as T nears 0 K, implying unattainability of through finite processes; this establishes an absolute reference for thermodynamic calculations.

Color Temperature in Lighting and Imaging

Color temperature describes the color appearance of a light source by referencing the absolute temperature, in kelvins, at which a theoretical blackbody radiator would emit light of comparable chromaticity on the CIE 1931 chromaticity diagram. For instance, warm incandescent bulbs typically have a color temperature around 2700 K, producing a yellowish-reddish hue, while midday daylight approximates 6500 K, yielding a neutral to bluish-white tone. This metric is perceptual rather than a direct measure of physical heat, focusing on visual similarity to blackbody radiation. The perceived warmth or coolness of light arises from the governed by , which dictates that lower temperatures shift the emission peak toward longer, redder wavelengths, while higher temperatures favor shorter, r wavelengths. As temperature increases, the blackbody spectrum broadens and intensifies in the visible range, enhancing blue content and reducing dominance, thus altering from warm (e.g., below 4000 ) to cool (above 5000 ). For sources deviating from ideal blackbody spectra, such as LEDs or fluorescent lamps, () is used instead, defined as the temperature of the nearest point on the to the source's coordinates. In , color guides selections for ambiance and functionality, with LEDs often specified by ranges like 3000 for residential warmth or 5000 for task-oriented coolness in offices. relies on matching or white balance to source to avoid color casts, as emulsions or digital profiles are calibrated for specific temperatures like 3200 tungsten or 5500 daylight. Similarly, technologies set white points using standards, such as 6500 for to simulate daylight viewing, ensuring consistent color reproduction across devices. The of for illuminants emerged in the 1930s, with early work correlating non-blackbody sources to blackbody equivalents for standardized description, distinct from thermodynamic measurements.

Noise Temperature in Electronics

In , particularly in (RF) and systems, quantifies the level of generated by a device or system, expressed in (K). It represents the temperature at which a hypothetical would produce the same as the actual noise source under consideration. This is fundamental to characterizing the performance of sensitive receivers where unwanted can degrade signal quality. The P_n delivered by such a into a matched load across a B is given by the Nyquist : P_n = k T B where T is the in kelvin and k is the , fixed at $1.380649 \times 10^{-23} J/K since the 2019 SI redefinition. This derives from the of thermal agitation of charge carriers in conductors, providing a direct link between and an equivalent . For a device with T_n, the effective matches that of a at T_n, enabling standardized comparisons across components. Unlike physical temperature, which measures the actual of particles, noise temperature is a metaphorical that solely describes the statistical equivalent of fluctuations in terms of power . It does not imply literal heating of the device; instead, it serves as a convenient for in non-equilibrium or active systems, such as amplifiers, where physical cooling may reduce but not eliminate other sources. This distinction allows engineers to model total system without directly measuring thermal states. In practical applications, noise temperature is essential for designing antennas, receivers, and low-noise amplifiers (LNAs) in high-sensitivity systems. For antennas, it accounts for contributions from sky noise, ground emissions, and atmospheric effects, helping to optimize signal-to-noise ratios in or deep-space communications. In receivers, the overall system noise temperature combines contributions from the antenna, feed lines, and front-end electronics, influencing the —a dimensionless measure of degradation defined relative to a 290 K reference. LNAs, often cryogenic to minimize their own noise, are critical in satellite communications, where low noise temperatures (e.g., below 10 K at frequencies) enable detection of weak signals from distant . For instance, NASA's Deep Space Network employs cooled LNAs with noise temperatures under 4 K at 8.4 GHz to support interplanetary missions. Representative examples highlight the scale of noise temperatures in advanced systems. The (CMB) radiation, a pervasive noise source in radio receivers, has an effective antenna temperature of 2.725 K, as precisely measured by the Cosmic Background Explorer (COBE) satellite's Far Infrared Absolute Spectrophotometer (FIRAS). This uniform background sets a fundamental limit for low-frequency observations. In , cryogenic amplifiers operating at millikelvin physical temperatures achieve noise temperatures as low as 2.3 K across 1–11 GHz, enabling readout of superconducting qubits with minimal added noise and preserving quantum coherence. These ultra-low values are vital for scaling quantum processors, where even slight noise can cause decoherence.

Units and Notation

Derived Units and SI Prefixes

The kelvin serves as the base unit for in the () and is integral to several derived units that quantify thermal phenomena. One key derived unit is , expressed as joule per kelvin (J/), which measures the energy required to increase the of a system or substance by one kelvin at constant volume or pressure. Another is thermal conductivity, given in watts per meter kelvin (W/(m·)), representing the rate of through a unit area of material per unit along the direction of heat flow. Additionally, temperature differences or intervals are expressed in kelvins, with the unit K used identically for both absolute temperatures and differences, ensuring numerical consistency with degree intervals. SI prefixes may be attached to the kelvin to form decimal multiples and submultiples, facilitating the expression of extreme temperatures across scientific domains, though such prefixed units are not coherent SI units. For cryogenic applications, the millikelvin () is commonly employed; for example, dilution refrigerators routinely achieve base temperatures around 10 , enabling experiments in and low-temperature physics. In cosmology, the microkelvin (μK) describes minute temperature fluctuations in the cosmic microwave background radiation, which are on the order of ±200 μK and provide insights into the early universe's structure. At the opposite extreme, prefixes like kilokelvin (kK) and megakelvin () are used for high-temperature regimes in astrophysics and plasma physics; Big Bang nucleosynthesis, for instance, occurred at approximately 109 K during the universe's first few minutes. While prefixes are permitted with the kelvin for both absolute temperatures and intervals according to the official guidelines, some contexts—particularly in or traditional thermometry—avoid prefixing temperature differences to prevent , though this is not a formal restriction.

and Usage

The kelvin, symbol K, is the of , with the symbol written as an uppercase K without any preceding degree sign (°). The unit name is spelled "kelvin" in lowercase letters when used in running text, following the general convention for SI unit names treated as common nouns. The plural form of the unit name is "kelvins," applied according to standard English grammar rules for countable quantities greater than one. Numerical values are expressed with a between the number and the symbol (e.g., 273 ), and the symbol remains unchanged in the plural (e.g., 25 ). In textual descriptions, temperatures can be written out fully as "25 kelvins" or using the symbol as "25 ," but the phrase "degrees Kelvin" or "degrees kelvin" is incorrect and prohibited. Examples include the of water at exactly 273.16 or approximated as 293 . Historically, the notation "°K" and the term "degree Kelvin" were used but were officially deprecated by the 13th General Conference on Weights and Measures (CGPM) in , which adopted the current symbol K and name "kelvin" to align with principles and avoid confusion with interval units like the degree Celsius. The unit name "kelvin" is the standard in English-language publications, but the symbol K is universally adopted across all languages in accordance with conventions, ensuring consistent international communication. In scientific equations, is conventionally denoted by the italicized variable T, expressed in kelvins, to distinguish it from other quantities that may share the letter T (such as time or tension) based on contextual usage. For instance, the is written as pV = nRT, where T represents temperature in K.

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