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Superconductivity

Superconductivity is a quantum mechanical phenomenon observed in certain materials that, when cooled below a characteristic critical temperature (T_c), exhibit zero electrical resistance to the flow of direct current (DC) electricity and the complete expulsion of magnetic fields from their interior, a property known as the Meissner effect.^[1] This behavior allows for the conduction of electrical current without energy loss, fundamentally distinguishing superconductors from ordinary conductors.^[1] The discovery of superconductivity occurred in 1911 when Dutch physicist Heike Kamerlingh Onnes observed the sudden drop in electrical resistance to zero in mercury cooled to approximately 4.2 K using liquid helium, a finding that earned him the 1913 Nobel Prize in Physics.^[1] Initially empirical, the phenomenon puzzled scientists until 1933, when Walther Meissner and Robert Ochsenfeld identified the magnetic field expulsion, solidifying its unique quantum nature.^[2] In 1957, John Bardeen, Leon Cooper, and John Robert Schrieffer developed the BCS theory, which explains superconductivity in conventional materials through the formation of Cooper pairs—bound electrons mediated by lattice vibrations (phonons)—leading to a coherent quantum state that enables resistance-free flow; this work was recognized with the 1972 Nobel Prize in Physics.^[1] Superconductors are classified into two main types: low-temperature (conventional) ones, which require cooling to near absolute zero (e.g., niobium-titanium alloys with T_c around 9-10 K), and high-temperature (unconventional) superconductors, first discovered in 1986 by J. Georg Bednorz and K. Alex Müller in a copper-oxide ceramic with T_c of 30 K, later advancing to over 90 K in yttrium barium copper oxide (YBCO) by 1987, with the current record for cuprates reaching about 134 K in mercury-based compounds, operable with liquid nitrogen cooling.^[2] The mechanism for high-T_c materials, often involving d-wave pairing and doping effects in cuprates and other unconventional families such as iron-based and nickelates, remains an active area of research beyond the phonon-based BCS framework.^[2]^[3] Superconductivity is also limited by critical parameters: a critical magnetic field (H_c) beyond which the Meissner effect fails, and a critical current density (J_c) above which resistance reappears.^[1] Practical applications of superconductivity leverage these properties for efficient energy use and advanced technologies, including superconducting magnets in magnetic resonance imaging (MRI) machines, particle accelerators like the Large Hadron Collider, and nuclear magnetic resonance (NMR) spectrometers, where zero resistance enables strong, stable fields without power loss.^[1] Emerging uses span power transmission lines to reduce energy dissipation in grids, magnetically levitated (maglev) trains for frictionless high-speed transport, and quantum computing components exploiting the quantum coherence of superconducting states.^[1] Five Nobel Prizes have been awarded for superconductivity-related discoveries (1913, 1972, 1973, 1987, 2003), underscoring its profound impact on physics and engineering.^[1]

Discovery and Basic Properties

Historical Discovery

In 1911, Dutch physicist Heike Kamerlingh Onnes and his team at the University of Leiden discovered superconductivity while investigating the electrical resistivity of pure mercury at cryogenic temperatures. On April 8, 1911, they observed an abrupt drop in resistance to apparently zero as the temperature reached approximately 4.2 K, achieved using liquid helium that Onnes had pioneered the liquefaction of in 1908.^[4]^[5] This unexpected result, detailed in Onnes's seminal paper "The Resistance of Pure Mercury at Helium Temperatures," marked the first identification of a material exhibiting zero electrical resistance below a critical temperature.^[6] The breakthrough relied heavily on prior advancements in low-temperature physics, particularly the development of the Dewar flask by Scottish physicist James Dewar in 1892. This vacuum-insulated vessel allowed for the efficient storage and transfer of liquefied gases like air and hydrogen, enabling Onnes to pre-cool helium gas effectively before its liquefaction and maintain the ultra-low temperatures required for his experiments.^[7] Without such innovations, reaching and sustaining temperatures near absolute zero would have been impractical, underscoring how incremental progress in cryogenics facilitated the discovery.^[4] Onnes initially viewed the phenomenon as a novel state of matter, coining the term "supraconductivity" in 1913 (later standardized as "superconductivity") to describe the complete disappearance of resistance. He speculated it might align with contemporary theories of electron behavior in metals, such as reduced scattering at low temperatures, but subsequent checks revealed no dissipation even after prolonged current flow, defying existing models and prompting recognition of it as a distinct physical effect.^[8]^[4] Building on the mercury findings, Onnes's group extended observations in 1912 to other pure metals, noting zero resistance in lead at about 7.2 K and in tin at roughly 3.7 K, establishing superconductivity as a property shared by multiple elements under similar cryogenic conditions.^[4] These early experiments highlighted the need for high-purity samples, as impurities had initially suggested gradual resistance decreases rather than the sharp transition observed in refined materials.^[5]

Zero Electrical Resistance

One of the defining characteristics of superconductivity is the complete disappearance of electrical resistance below a critical temperature, enabling infinite DC conductivity. This phenomenon was first observed in 1911 by Heike Kamerlingh Onnes, who measured the resistivity of mercury and found it to drop abruptly to zero at approximately 4.2 K when cooled using liquid helium.^[1] Subsequent experiments confirmed this zero-resistivity state in other materials, such as lead and tin, establishing it as a universal property of superconductors under appropriate conditions. The absence of resistance permits persistent currents to circulate indefinitely in closed superconducting loops without energy dissipation. These currents arise from induced electromagnetic forces and maintain themselves due to the lack of ohmic losses, allowing practical applications like superconducting magnets. Experimental verification includes observations of such currents in lead cylinders, where a persistent current persisted for over two years without measurable decay, limited only by an external interruption in cooling.^[9] Unlike an ideal classical conductor, which might sustain persistent currents through inertia but permit magnetic field penetration, a superconductor achieves zero resistance while expelling internal magnetic fields entirely—a complementary property known as the Meissner effect. In the phenomenological framework of the London theory, this zero-resistance behavior for DC fields is captured by the implication of the first London equation in steady state:

\mathbf{E} = 0

inside the superconductor, where \mathbf{E} is the electric field, ensuring no voltage drop and constant current flow.^[10]

Meissner Effect

The Meissner effect is the expulsion of a magnetic field from the interior of a superconductor upon cooling below its critical temperature T_c, resulting in perfect diamagnetism. This phenomenon was discovered in 1933 by German physicists Walther Meissner and Robert Ochsenfeld through experiments on lead and tin samples. Their work revealed that, unlike the normal state where magnetic fields penetrate materials, the superconducting state actively excludes internal fields, distinguishing it from mere zero electrical resistance observed earlier. In their experimental setup, Meissner and Ochsenfeld used cylindrical samples of polycrystalline lead and single-crystal tin, approximately 140 mm long and 3 mm in diameter, placed parallel and separated by 1.5 mm, within a uniform external magnetic field of about 5 gauss generated by an electromagnet. They measured magnetic flux changes using a small search coil, roughly 10 mm long, connected to a ballistic galvanometer, positioned either between the cylinders or inside a hollow lead tube (130 mm long, 3 mm outer diameter, 2 mm inner diameter) for internal field assessment. Upon cooling the samples below T_c (around 7.2 K for lead and 3.7 K for tin) via liquid helium, the galvanometer registered deflections indicating a sudden expulsion of flux from the interior, with the external field lines compressing around the sample surfaces as if the material had zero permeability. If the field was applied after achieving the superconducting state, no penetration occurred, confirming the effect's thermodynamic nature.^[11] This discovery had profound implications, establishing superconductivity as a true thermodynamic phase transition to an equilibrium state rather than a metastable condition tied solely to dissipationless current flow. Prior understanding of zero resistance, found in mercury by Heike Kamerlingh Onnes in 1911, suggested persistent currents but not field expulsion; the Meissner effect clarified that the superconducting state minimizes magnetic energy through flux exclusion, enabling thermodynamic treatments like specific heat measurements and phase diagrams. Theoretically, the effect is captured by the condition that the magnetic induction \mathbf{B} = 0 inside the superconductor in the absence of currents, arising from Maxwell's equations \nabla \cdot \mathbf{B} = 0 and \nabla \times \mathbf{H} = \mathbf{J} with \mathbf{J} = 0 in the bulk superconducting region, implying perfect screening. This idealization holds for fields below the critical value, underscoring the superconductor's role as a perfect diamagnet with susceptibility \chi = -1.

Phase Transition and London Moment

Superconductivity emerges as a second-order phase transition at the critical temperature T_c, below which the material abruptly loses electrical resistance and expels magnetic fields. In the Ehrenfest classification, second-order transitions are defined by continuous first derivatives of the free energy but discontinuities in higher-order derivatives, such as the specific heat at constant volume or pressure. For superconductors, this manifests as a sharp jump in the electronic specific heat capacity at T_c, reflecting the onset of coherent pairing among electrons that forms the superconducting state.^[12]^[13] The value of T_c serves as the defining transition point and varies significantly across materials, influenced by factors like atomic structure, electron-phonon coupling, and isotopic mass. Conventional low-temperature superconductors, such as elemental metals like niobium or lead, exhibit T_c values typically below 10 K, while high-temperature superconductors like cuprates can reach T_c exceeding 90 K under ambient pressure. This material dependence underscores the diversity in superconducting mechanisms, with T_c marking the boundary where thermal energy disrupts the quantum condensate of paired electrons.^[14]^[15] A notable consequence of superconductivity in rotating systems is the London moment, a phenomenon where a spinning superconductor generates an internal magnetic field aligned with its rotation axis. This arises from the conservation of angular momentum for the Cooper pairs, which carry zero orbital angular momentum in their ground state; rotation induces a uniform supercurrent that screens the mechanical angular momentum, producing a magnetic moment proportional to the angular velocity. Predicted by Fritz London in his molecular theory of superconductivity, the effect highlights the rigid, quantized nature of the superconducting wavefunction.^[16] Experimental verification of the London moment has been achieved using superconducting gyroscopes, where the induced magnetic field precisely tracks the spin axis, enabling ultra-stable orientation control. In the Gravity Probe B mission, niobium-coated quartz spheres served as gyroscopes, with their London moments monitored via superconducting quantum interference devices (SQUIDs) to detect minute drifts in angular momentum, confirming the effect's reliability for high-precision measurements. This application demonstrates the practical utility of the London moment in inertial navigation and tests of general relativity.^[17]^[18]

Theoretical Frameworks

Phenomenological Theories

Phenomenological theories of superconductivity provide macroscopic descriptions of the material's electromagnetic behavior near the critical temperature, without delving into microscopic mechanisms. These models treat superconductivity as a thermodynamic phase transition, using empirical relations to capture observable phenomena such as perfect diamagnetism and zero resistance.^[10] The foundational phenomenological approach was developed by Fritz and Heinz London in 1935, who proposed two constitutive equations relating the supercurrent density \mathbf{J} to the electromagnetic fields. The first London equation describes the acceleration of the supercurrent in response to an electric field: \frac{\partial \mathbf{J}}{\partial t} = \frac{n_s e^2}{m} \mathbf{E}, where n_s is the density of superconducting electrons, e and m are the electron charge and mass, and \mathbf{E} is the electric field.^[10] In the static limit, this implies \mathbf{E} = 0 for steady currents, explaining the persistence of supercurrents without dissipation. The second London equation relates the curl of the current to the magnetic field: \nabla \times \mathbf{J} = -\frac{n_s e^2}{m} \mathbf{B}, where \mathbf{B} is the magnetic induction.^[10] Combined with Maxwell's equations, this leads to the magnetic field penetrating the superconductor over a characteristic length, the London penetration depth \lambda_L = \sqrt{\frac{m}{\mu_0 n_s e^2}}, beyond which the field decays exponentially.^[10] A more comprehensive phenomenological framework was introduced by Vitaly Ginzburg and Lev Landau in 1950, extending the London theory to include spatial variations in the superconducting order parameter. In Ginzburg-Landau theory, the superconducting state is described by a complex order parameter \psi, where |\psi|^2 represents the density of Cooper pairs (or superconducting electrons). The theory is formulated through a free energy functional minimized to find equilibrium states:

F = \int \left[ \alpha |\psi|^2 + \frac{\beta}{2} |\psi|^4 + \frac{1}{2m^*} \left| \left( -i \hbar \nabla - 2e \mathbf{A} \right) \psi \right|^2 + \frac{|\mathbf{B}|^2}{2\mu_0} \right] dV,

where \alpha = \alpha' (T - T_c) (with \alpha' > 0) changes sign at the critical temperature T_c, \beta > 0, m^* is the effective mass of Cooper pairs, \mathbf{A} is the vector potential, and the last term is the magnetic field energy (in SI units).^[19] Minimizing this functional yields the Ginzburg-Landau equations, which generalize the London equations and introduce a coherence length \xi = \sqrt{\frac{\hbar^2}{2m^* |\alpha|}} over which \psi varies spatially.^[19] The Ginzburg-Landau framework has key applications in describing inhomogeneous superconducting states. For type-II superconductors, where the Ginzburg-Landau parameter \kappa = \lambda_L / \xi > 1/\sqrt{2}, the theory predicts a mixed state consisting of quantized magnetic flux lines or vortices, each carrying a flux quantum \Phi_0 = h / 2e. This vortex lattice structure was theoretically established by Alexei Abrikosov in 1957 using the Ginzburg-Landau equations.^[20] Additionally, the theory enables calculations of critical currents, such as the depairing current density J_c \propto (T_c - T)^{3/2}, above which the superconducting order parameter is suppressed, leading to a transition to the normal state.^[19] These applications highlight the theory's utility in modeling practical superconducting behaviors under magnetic fields and currents.

Microscopic BCS Theory

The Bardeen–Cooper–Schrieffer (BCS) theory, formulated in 1957, offers a microscopic quantum mechanical description of superconductivity in conventional materials, explaining the phenomenon as arising from the formation of electron pairs bound by lattice interactions.^[21] In this framework, conduction electrons near the Fermi surface experience an attractive potential mediated by phonons—quantized lattice vibrations—that overcomes their Coulomb repulsion at low temperatures.^[21] This attraction leads to the creation of Cooper pairs, composite bosons consisting of two electrons with opposite momenta and spins, which condense into a coherent ground state with long-range order.^[21] The pairing instability is treated using a mean-field approximation, where the many-body Hamiltonian is decoupled into a form resembling a non-interacting Bogoliubov quasiparticle spectrum, enabling analytical solutions for thermodynamic and transport properties.^[21] Central to BCS theory is the superconducting energy gap \Delta, which represents the binding energy of the Cooper pairs and suppresses single-particle excitations below the critical temperature T_c. In the weak-coupling limit, the zero-temperature gap is related to the critical temperature by \Delta(0) \approx 1.76 k_B T_c. The gap equation at zero temperature, derived from the self-consistent condition for pair formation, yields the approximate relation for T_c:

k_B T_c \approx 1.14 \hbar \omega_D \exp\left(-\frac{1}{N(0)V}\right),

where \hbar \omega_D is the Debye energy scale setting the cutoff for phonon-mediated interactions, N(0) is the single-spin density of states at the Fermi energy, and V is the effective pairing potential.^[21] This equation highlights how even a weak attraction (N(0)V \ll 1) can produce a finite gap due to the exponential sensitivity to the interaction strength. Near T_c, the gap vanishes, providing a direct link between observable T_c and microscopic parameters.^[21] A key experimental validation of the phonon-mediated pairing in BCS theory is the isotope effect, where T_c scales inversely with the square root of the ionic mass M as T_c \propto M^{-1/2}, stemming from the mass dependence of the Debye frequency \omega_D \propto M^{-1/2}.^[21] This relation was first observed in mercury isotopes in 1950, predating the full theory but confirming the role of electron-phonon coupling over purely electronic mechanisms. BCS theory also accounts for the thermodynamic signature of the superconducting transition, predicting a sharp discontinuity in the electronic specific heat at T_c. The jump is quantified as \Delta C = 1.43 \gamma T_c, where \gamma is the normal-state electronic specific heat coefficient, reflecting the abrupt opening of the energy gap and the associated entropy change in the paired state.^[21] On the electromagnetic front, the theory derives the superfluid density and acceleration equation for Cooper pairs, yielding a microscopic justification for the penetration depth and perfect conductivity, consistent with macroscopic phenomenological models.^[21]

Extensions and Unconventional Theories

While the BCS theory provides a foundational microscopic description for conventional superconductors mediated by phonon interactions in the weak-coupling limit, extensions are necessary to account for stronger electron-phonon couplings where retardation effects become significant. Eliashberg theory, developed as a strong-coupling generalization, incorporates the full frequency dependence of the phonon propagator and the resulting time retardation in the electron pairing interaction, leading to more accurate predictions of the superconducting transition temperature T_c and the gap function. This framework replaces the BCS energy-gap equation with a set of coupled integral equations for the renormalized Green's functions, capturing effects such as the isotope coefficient deviations observed in materials like lead and mercury.^[22] In unconventional superconductors, the pairing symmetry deviates from the isotropic s-wave state of BCS, often involving higher angular momentum states mediated by non-phononic mechanisms such as spin fluctuations. For instance, d-wave pairing, characterized by a gap function \Delta(\mathbf{k}) \propto \cos k_x - \cos k_y, has been identified in cuprate superconductors through phase-sensitive tunneling and neutron scattering experiments, where antiferromagnetic spin fluctuations provide the dominant attractive interaction in the pseudogap phase. Similarly, p-wave pairing with odd-parity symmetry appears in heavy-fermion systems, where spin-triplet states are stabilized by ferromagnetic or spin-fluctuation exchanges, as evidenced by the helical phase in materials exhibiting chiral superconductivity. These unconventional symmetries arise from the sign-changing order parameter, which suppresses impurity scattering and leads to distinctive thermodynamic properties like power-law behaviors in specific heat at low temperatures.^[23] Theoretical modeling of these systems often relies on the Hubbard model, a minimal framework for strongly correlated electrons on a lattice, where onsite Coulomb repulsion U competes with kinetic hopping t to drive Mott insulation and antiferromagnetic order. In the strong-coupling limit, the effective t-J model derived from the Hubbard Hamiltonian highlights the role of superexchange interactions in fostering d-wave pairing, with antiferromagnetism providing the spin-fluctuation glue that binds Cooper pairs near half-filling. Numerical methods like dynamical mean-field theory and variational Monte Carlo simulations confirm that doping away from the antiferromagnetic parent state can induce superconductivity, though the precise mechanism remains tied to the interplay of charge and spin degrees of freedom. Despite these advances, a unified microscopic theory encompassing all superconductors remains elusive, with ongoing debates centering on the universality of pairing mechanisms across diverse classes like cuprates, iron pnictides, and organic materials. Key challenges include reconciling the absence of a single dominant mediator—phonons for conventional cases versus spin or orbital fluctuations for unconventional ones—and addressing discrepancies between theory and experiments in pseudogap phases or under high pressure. While Eliashberg-like extensions handle strong phonon coupling effectively, adapting them to repulsive interactions or multi-orbital systems highlights the need for hybrid approaches that integrate beyond-mean-field correlations.^[24]

Classification of Superconductors

By Magnetic Response

Superconductors are classified into Type I and Type II based on their distinct responses to applied magnetic fields, particularly how they handle field penetration while maintaining the Meissner effect below critical thresholds.^[25] Type I superconductors exhibit complete expulsion of magnetic fields from their interior, achieving perfect diamagnetism up to a single critical field H_c, beyond which superconductivity abruptly ceases and the material transitions to the normal state.^[26] This behavior is characteristic of pure elemental metals such as aluminum and lead, where the Ginzburg-Landau parameter \kappa = \lambda / \xi < 1/\sqrt{2}, with \lambda as the penetration depth and \xi as the coherence length, favoring a positive interface energy that prevents partial field penetration.^[26] In Type I superconductors subjected to fields exceeding H_c in geometries like slabs or cylinders, an intermediate state can emerge to minimize free energy, consisting of macroscopic domains of alternating superconducting and normal regions threaded by magnetic flux.^[27] These domains form branched or lamellar structures, allowing partial accommodation of the external field without fully destroying superconductivity until the normal phase dominates.^[28] This state contrasts with the sharp transition in ideal conditions and highlights the role of demagnetization effects in real samples. Type II superconductors, defined by \kappa > 1/\sqrt{2}, display a more nuanced magnetic response with two critical fields: a lower critical field H_{c1} and an upper critical field H_{c2}. Below H_{c1}, they fully expel fields via the Meissner effect, similar to Type I materials. Between H_{c1} and H_{c2}, magnetic flux penetrates in a mixed state composed of quantized vortex lines, each carrying a flux quantum \Phi_0 = h/(2e), arranged in an ordered hexagonal Abrikosov lattice to stabilize the superconducting order parameter around the cores.^[29] This vortex structure, predicted theoretically and observed experimentally, enables Type II superconductors to sustain higher fields, making them essential for applications like superconducting magnets.^[30] The upper critical field H_{c2} marks the point where the vortex density becomes so high that the superconducting state collapses, given by the relation

H_{c2} = \frac{\Phi_0}{2\pi \xi^2},

derived from the Ginzburg-Landau theory in the limit of linearized equations near the normal transition.^[31] This formula underscores the inverse dependence on the coherence length, explaining why materials with shorter \xi support stronger fields before losing superconductivity.

By Critical Parameters

Superconductors are characterized by three primary critical parameters that delineate the boundaries of the superconducting state: the critical temperature T_c, the critical magnetic field H_c, and the critical current density j_c. These parameters define the thermodynamic and transport limits beyond which the material reverts to its normal resistive state. The critical temperature T_c is the maximum temperature at which superconductivity persists, corresponding to the onset of zero electrical resistance and perfect diamagnetism as the thermal energy becomes insufficient to disrupt the Cooper pairs binding electrons.^[32] Across known superconductors, T_c spans a wide range, from millikelvin scales in exotic systems such as heavy-fermion compounds to around 130 K in high-temperature variants, highlighting the diversity in pairing mechanisms and material properties.^[33]^[34] The critical magnetic field H_c(T) quantifies the strength of an external magnetic field at temperature T that destroys superconductivity by providing energy comparable to the superconducting condensation energy. For type I superconductors, this is the thermodynamic critical field, while in type II materials, it relates to the upper critical field H_{c2} where the mixed state transitions to normal. Its temperature dependence is approximately parabolic, described by the empirical relation

H_c(T) \approx H_c(0) \left[1 - \left( \frac{T}{T_c} \right)^2 \right],

where H_c(0) is the value at absolute zero; this form arises from the balance between magnetic and condensation energies near the phase transition.^[25]^[35] This dependence ensures that superconductivity is suppressed more readily at higher temperatures, as thermal fluctuations weaken the pairing. The critical current density j_c is the highest density of supercurrent that can flow without inducing dissipation, beyond which normal resistance emerges due to the motion of magnetic flux lines under Lorentz forces. In type II superconductors, j_c is particularly limited by flux flow, where unpinned vortices migrate under current drive, generating electric fields and resistivity analogous to viscous drag.^[36]^[37] Pinning centers, such as defects, enhance j_c by immobilizing vortices, enabling practical applications in high-current devices. Phase diagrams in the temperature-magnetic field (H-T) plane map the interplay of these parameters, with the H_c(T) curve forming a parabolic boundary enclosing the superconducting region below T_c.^[38] Incorporating current introduces additional complexity, as j_c varies with both T and H, often decreasing with increasing field due to enhanced vortex mobility; this three-dimensional parameter space guides the design of superconducting magnets and wires by revealing operational limits where flux flow or thermal activation destabilizes the state.^[39]

By Material Type

Superconductors are categorized by their material composition—ranging from elemental metals to complex compounds—and the symmetry and mechanism of electron pairing, which determine their critical temperatures (Tc) and other properties. This classification distinguishes conventional materials, which adhere to the Bardeen-Cooper-Schrieffer (BCS) theory of phonon-mediated s-wave pairing, from unconventional ones involving anisotropic pairing often driven by magnetic fluctuations or other non-phonon mechanisms.^[40] Conventional superconductors primarily include elemental metals, alloys, and compounds with Tc values generally below 40 K, where Cooper pairs form in an isotropic s-wave state via electron-phonon interactions. Notable elemental examples are niobium (Nb, Tc = 9.25 K) and vanadium (V, Tc = 5.4 K), which exhibit zero electrical resistance and the Meissner effect at these temperatures. A key compound example is magnesium diboride (MgB2, Tc = 39 K), discovered in 2001, representing the highest Tc for conventional superconductors at ambient pressure.^[41] Alloys such as niobium-titanium (NbTi, Tc ≈ 9.5 K) and niobium-tin (Nb3Sn, Tc = 18.3 K) are widely used in practical applications like superconducting magnets due to their high critical fields and mechanical properties, while maintaining the s-wave BCS pairing symmetry. A key hallmark of these materials is the presence of the isotope effect, where Tc scales inversely with the square root of the atomic mass (isotope coefficient α ≈ 0.5), confirming the role of lattice vibrations (phonons) in mediating pairing. Unconventional superconductors, often layered compounds, feature higher Tc and pairing symmetries that break rotational invariance, such as d-wave or p-wave, leading to nodes in the gap function and anisotropic properties. Cuprates like lanthanum-barium-copper oxide (La_{2-x}Ba_xCuO_4, Tc up to 35 K) exemplify this class, with their superconductivity arising from strongly correlated electrons rather than phonons. Iron pnictides, such as LaFeAsO_{1-x}F_x (Tc up to 26 K,^[42] with some variants reaching 55 K),^[43] also show anisotropic pairing, often s± symmetry, and are linked to spin-fluctuation mechanisms near antiferromagnetic instabilities. Unlike conventional superconductors, these materials generally exhibit a weak or absent isotope effect (α ≈ 0), underscoring non-phonon pairing origins. Organic superconductors, based on molecular charge-transfer salts, offer low Tc but unique tunable properties in low-dimensional structures. A representative example is κ-(BEDT-TTF)_2Cu(NCS)_2, where BEDT-TTF denotes bis(ethylenedithio)tetrathiafulvalene, achieving Tc = 10.4 K under ambient pressure and displaying exotic behaviors like potential Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) states in high magnetic fields.^[44] These materials often involve quasi-two-dimensional conduction planes and unconventional pairing symmetries.^[45] Heavy fermion superconductors, characterized by f-electron systems with large effective masses, exhibit low Tc alongside complex quantum critical phenomena. Cerium cobalt indium (CeCoIn_5, Tc = 2.3 K)^[46] is a prototypical case, featuring d_{x^2 - y^2}-wave pairing, nodal quasiparticles, and proximity to an antiferromagnetic quantum critical point, which enhances its unconventional nature. Like other unconventional types, it shows minimal isotope effect and anisotropic superfluid density. This material-based classification emphasizes mechanistic distinctions: conventional superconductors align with BCS predictions including the isotope effect, while unconventional, organic, and heavy fermion types deviate, often enabling higher Tc or exotic states, with high-temperature cuprates serving as prime examples of the latter (detailed further in the High-Temperature Superconductors section).^[40]

Historical Development

Early Experiments and Theories

The discovery of superconductivity occurred in 1911 when Heike Kamerlingh Onnes and his team at the University of Leiden observed that the electrical resistance of pure mercury suddenly vanished below 4.2 K upon cooling with liquid helium, a phenomenon they termed "superconductivity."^[6] This abrupt drop in resistance, plotted as a function of temperature, marked a sharp transition rather than a gradual decrease, prompting further investigations into the behavior of other metals under similar cryogenic conditions.^[6] From 1911 to 1933, Onnes' laboratory expanded these studies, mapping resistance-temperature curves for numerous pure elements and alloys. They identified superconductivity in materials like tin (at 3.7 K), lead (at 7.2 K), and thallium (at 2.4 K), revealing that the transition temperature varied by element but consistently involved a complete loss of resistivity below a critical point. In 1950, experiments on mercury isotopes revealed the isotope effect, where Tc varied inversely with the square root of the atomic mass, suggesting involvement of lattice vibrations (phonons) in the pairing mechanism.^[47] These experiments established superconductivity as a reproducible quantum effect limited to low temperatures, though the underlying mechanism remained elusive. A pivotal advancement came in 1933 when Walther Meissner and Robert Ochsenfeld at the Physikalisch-Technische Reichsanstalt in Berlin demonstrated that superconductors not only exhibit zero resistance but also expel applied magnetic fields from their interior upon entering the superconducting state—a property now known as the Meissner effect.^[11] Their measurements on lead and tin samples showed this flux expulsion occurs regardless of whether the field was present during cooling, distinguishing superconductivity from mere perfect conductivity and highlighting its diamagnetic nature.^[11] In response to the Meissner effect, Fritz and Heinz London, working in Oxford after fleeing Nazi Germany, developed the first phenomenological theory of superconductivity in 1935. Their London equations described superconductors as having a characteristic penetration depth, beyond which magnetic fields decay exponentially, providing a macroscopic framework to explain both zero resistance and perfect diamagnetism without invoking microscopic details.^[10] During the 1930s, experiments by J.G. Daunt and K. Mendelssohn at Oxford on the thermal properties of superconductors, including specific heat measurements near the transition temperature, provided early hints of lattice involvement. Their observations of anomalies in heat capacity suggested that electron-phonon interactions, tied to the ionic lattice vibrations, played a role in the superconducting state, challenging purely electronic models. Early theoretical efforts, such as applications of band theory from solid-state physics, largely failed to account for superconductivity's key features, including the sharp transition and magnetic expulsion, as they predicted gradual resistance changes or no such effect at low temperatures.^[48] By the 1940s, superconductivity had been confirmed in approximately 25 elements, primarily soft metals and some alloys, underscoring the phenomenon's specificity and the need for a more robust explanatory framework.

Mid-20th Century Advances

In the early 1950s, the phenomenological Ginzburg-Landau theory provided a framework for understanding superconductivity near the critical temperature, introducing a complex order parameter to describe the superconducting state and enabling predictions of vortex structures in magnetic fields. This theory, developed by Vitaly Ginzburg and Lev Landau in 1950, extended earlier London equations by incorporating spatial variations in the order parameter, which allowed for the classification of superconductors into Type I and Type II categories based on their response to magnetic fields. Specifically, it predicted the existence of Type II superconductors, where magnetic flux penetrates in quantized vortices rather than being completely expelled, a phenomenon later confirmed experimentally.^[49] The mid-1950s also saw significant advances in superconducting materials, particularly with the discovery of niobium-tin (Nb₃Sn) in 1954, which exhibited a critical temperature of approximately 18 K, higher than previously known elemental superconductors.^[50] This A15 intermetallic compound, identified by Bernd T. Matthias and colleagues at Bell Laboratories, demonstrated superior performance in high magnetic fields due to its elevated upper critical field (H_{c2}), with early measurements in the early 1960s showing values exceeding 10 T at 4.2 K.^[51] These properties made Nb₃Sn suitable for practical magnet applications, leading to the first superconducting electromagnets in the late 1950s and early commercial wire production by the 1960s.^[52] A major theoretical milestone came in 1957 with the publication of the Bardeen-Cooper-Schrieffer (BCS) theory, which provided the first microscopic explanation of superconductivity as arising from an attractive electron-phonon interaction forming Cooper pairs.^[21] John Bardeen, Leon Cooper, and Robert Schrieffer's model quantitatively predicted key observables, such as the energy gap and critical temperature dependence on isotope mass, aligning closely with experimental data and earning widespread acceptance within the scientific community by the early 1960s. This theory not only resolved long-standing puzzles from earlier phenomenological approaches but also laid the groundwork for understanding conventional superconductivity in metals and alloys. Building on BCS, Brian Josephson predicted in 1962 the tunneling of supercurrents across a thin insulating barrier between two superconductors, known as the Josephson effect, which demonstrated the macroscopic quantum coherence of the superconducting state. This DC Josephson effect, along with the AC variant under microwave irradiation, was experimentally verified shortly thereafter in 1962-1963 by teams using lead-based junctions, confirming the phase-dependent current flow without energy dissipation.^[53] These findings highlighted the quantum nature of superconductivity at larger scales and spurred further research into weakly coupled superconducting systems.

High-Tc Breakthroughs

In 1986, J. Georg Bednorz and K. Alex Müller at IBM's Zurich Research Laboratory reported the observation of superconductivity in a barium-doped lanthanum copper oxide (La-Ba-Cu-O) system with a critical temperature (Tc) of 35 K, marking the first breakthrough in high-temperature superconductivity beyond the limits of conventional materials.^[54] This discovery, published in a seminal paper, demonstrated a resistive transition indicating superconductivity at temperatures significantly higher than the previous record of 23 K for metallic superconductors, and it earned them the 1987 Nobel Prize in Physics for opening the field of ceramic high-Tc superconductors.^[55] The following year, in 1987, Ching-Wu Chu's group at the University of Houston advanced this work by synthesizing yttrium barium copper oxide (YBCO, YBa2Cu3O7-x), achieving a Tc of 92 K under ambient pressure, which surpassed the boiling point of liquid nitrogen (77 K) and enabled practical cooling without expensive liquid helium. This material's orthorhombic perovskite structure with CuO2 planes was confirmed to exhibit bulk superconductivity through zero resistance and the Meissner effect, revolutionizing potential applications by making high-Tc systems more accessible.^[56] Rapid material development followed, with bismuth-based cuprates (Bi-Sr-Ca-Cu-O, or BSCCO) reported in 1988 by Hiroaki Maeda's team, with the 2212 phase reaching Tc ≈ 85 K, and the Pb-doped 2223 phase achieving onset above 110 K and zero resistance near 105 K.^[57] Shortly thereafter, thallium-based cuprates (Tl-Ba-Ca-Cu-O, or TBCCO) were discovered by Z. Z. Sheng and Allen M. Hermann, achieving a record Tc of 125 K, further expanding the family of high-Tc oxides with multiple homologous phases containing varying numbers of CuO2 layers.^[58] These breakthroughs ignited a global research surge, with the 1987 American Physical Society March Meeting—dubbed the "Woodstock of Physics"—drawing over 1,800 presentations on high-Tc materials and spawning thousands of publications within months, as laboratories worldwide raced to replicate and extend the findings.^[56] However, initial efforts faced challenges in reproducibility due to multiphase samples, precise oxygen stoichiometry requirements, and sensitivity to synthesis conditions, leading to early skepticism and false alarms until confirmatory Meissner effect measurements solidified the results across institutions.^[56] This period highlighted the unconventional nature of cuprate pairing, though detailed mechanisms remained elusive at the time.^[59]

Unconventional Superconductivity

High-Temperature Superconductors

High-temperature superconductors are materials exhibiting superconductivity at temperatures above approximately 30 K, significantly higher than traditional low-temperature superconductors cooled by liquid helium. These materials, first discovered in the 1980s with the cuprates, have revolutionized the field by enabling potential applications at more accessible temperatures using liquid nitrogen.^[60] Despite their promise, the microscopic pairing mechanisms remain unconventional and not fully understood, distinguishing them from BCS theory.^[61] Cuprates, the archetypal high-temperature superconductors, feature a layered perovskite-like crystal structure composed of conducting CuO₂ planes separated by insulating charge reservoir layers.^[61] Superconductivity emerges upon doping these antiferromagnetic Mott insulators with holes, typically via chemical substitution, to achieve an optimal carrier concentration around 0.16 holes per Cu atom, where the critical temperature (T_c) reaches maxima, such as 92 K in YBa₂Cu₃O₇.^[62] This optimal doping suppresses the pseudogap phase and enhances pairing, though the exact mechanism involves strong electron correlations and possibly d-wave symmetry.^[63] Iron-based superconductors, discovered in 2008, include pnictides like LaFeAsO and chalcogenides such as FeSe, with T_c values up to 55 K under ambient conditions.^[64] These materials exhibit a multi-orbital, multi-band electronic structure, where superconductivity arises from interband pairing mediated by spin fluctuations, leading to s± symmetry with sign-changing order parameters between hole and electron pockets.^[65] Unlike single-band cuprates, the multi-band nature allows for complex vortex dynamics and higher robustness to disorder in some cases.^[66] Under extreme pressures, hydrogen-rich compounds like LaH₁₀ have achieved record T_c values, with superconductivity confirmed at approximately 250 K in 2019 at ~170 GPa.^[67] This discovery validated prior theoretical predictions based on electron-phonon coupling in metallic hydrides, where light hydrogen atoms enable strong phonon-mediated pairing within conventional BCS-Eliashberg theory, though at pressures far exceeding practical use.^[68] Despite their high T_c, high-temperature superconductors face significant challenges in practical implementation. Their layered structures impart strong anisotropy in superconducting properties, with critical currents and fields varying markedly along in-plane versus out-of-plane directions, complicating wire fabrication.^[69] Flux pinning, essential for maintaining high currents in magnetic fields, is often weak and requires engineered defects to enhance vortex immobilization.^[70] Additionally, grain boundaries in polycrystalline samples act as weak links, severely limiting intergranular critical currents due to suppressed pairing across misoriented interfaces, a persistent issue in both cuprates and iron-based materials.^[71]^[72]

Exotic Superconductors

Exotic superconductors encompass a diverse class of materials where the pairing mechanism deviates significantly from the conventional electron-phonon interactions described by BCS theory, often involving strong electron correlations, spin fluctuations, or topological order. These systems typically exhibit low critical temperatures but reveal profound insights into quantum many-body physics, including potential applications in topological quantum computing. Key examples include heavy-fermion compounds, organic materials, and non-centrosymmetric structures that support chiral or topological pairing symmetries.^[73] Heavy-fermion superconductors, such as URu₂Si₂, represent a paradigm of unconventional superconductivity mediated by spin fluctuations in strongly correlated f-electron systems. In URu₂Si₂, superconductivity emerges at a critical temperature T_c ≈ 1.5 K, below a mysterious "hidden order" phase transition at 17.5 K, where the order parameter remains unidentified despite extensive study. The superconducting state is unconventional, characterized by a nodal gap structure and evidence of spin-fluctuation-driven pairing, as indicated by colossal Nernst signals arising from superconducting fluctuations near the hidden-order phase.^[73] This material highlights how antiferromagnetic spin fluctuations can suppress conventional pairing and favor exotic order, with the heavy effective masses (up to 100 times the bare electron mass) arising from Kondo lattice interactions.^[74] Organic superconductors, exemplified by κ-(BEDT-TTF)₂Cu(NCS)₂, demonstrate superconductivity in molecular crystals tuned close to a Mott insulating state, where electron correlations dominate. This compound achieves a relatively high T_c of approximately 10 K under ambient pressure, making it one of the highest-T_c organic superconductors.^[75] The proximity to the Mott insulator, achieved by varying pressure or chemical substitution, leads to a pseudogap phase above T_c, attributed to precursor pairing fluctuations influenced by antiferromagnetic spin correlations. In this layered system, the BEDT-TTF molecules form dimers that support a quasi-two-dimensional band structure, where the metal-insulator transition at the Mott boundary enhances superconducting instability through enhanced density of states at the Fermi level. Topological superconductors introduce spatial structure to the order parameter, potentially hosting protected edge states and non-Abelian anyons. Strontium ruthenate, Sr₂RuO₄, is a prominent candidate for chiral p-wave pairing, with superconductivity at T_c ≈ 1.5 K in a layered perovskite structure.^[76] Experimental evidence for p-wave triplet pairing includes muon spin relaxation measurements indicating time-reversal symmetry breaking and Kerr effect observations consistent with chiral currents, though recent phase-sensitive tests have sparked debate on the exact symmetry.^[77] In hybrid systems combining conventional superconductors with topological insulators or semiconductors, proximity-induced superconductivity can realize one-dimensional topological phases hosting Majorana zero modes at the ends or vortices. These zero-energy modes, predicted in semiconductor-superconductor nanowires under magnetic fields, enable braiding operations for fault-tolerant quantum computation, with signatures observed in tunneling conductance plateaus.^[78]^[79] Non-centrosymmetric superconductors, lacking inversion symmetry, permit mixed-parity pairing due to antisymmetric spin-orbit coupling, leading to unique vortex structures like half-quantum vortices and chiral surface states. In such materials, the Rashba-type spin-orbit interaction splits the Fermi surface into spin-helical bands, allowing singlet and triplet components to mix and stabilize half-flux quanta (h/2e) in vortex cores, half the usual flux quantum.^[80] Examples include β-Bi₂Pd, where mesoscopic rings exhibit half-integer flux quantization at T_c ≈ 1.8 K, direct evidence of spin-triplet pairing.^[81] Similarly, α-BiPd shows half-quantum flux in Little-Parks oscillations, confirming a helical p-wave state with chiral Majorana modes bound to vortex edges.^[82] These chiral states propagate unidirectionally along surfaces, protected by topology, and can form closed loops with half-quantum vortices in multicomponent systems.^[83]

Recent Advances

2D and Nanostructured Materials

Superconductivity in two-dimensional (2D) and nanostructured materials arises from quantum confinement effects that alter electronic band structures, enhancing electron-electron interactions and pairing mechanisms compared to bulk counterparts. In these low-dimensional systems, reduced dimensionality flattens energy bands, increases density of states near the Fermi level, and promotes correlated states, leading to unconventional superconducting phases at low temperatures. These effects are particularly pronounced in van der Waals heterostructures, where stacking and gating enable precise tuning of carrier density and interlayer coupling.^[84] In magic-angle twisted trilayer graphene (MATTG), discovered around 2021-2022, superconductivity emerges in flat bands formed by moiré superlattices, with critical temperatures (Tc) reaching approximately 2-3 K under displacement fields that break layer symmetry. These flat bands, arising from interlayer hybridization at twist angles near 1.6°, enhance electron pairing by slowing charge carriers and amplifying Coulomb interactions, enabling tunable superconducting domes in the phase diagram. Experimental transport measurements reveal robust zero-resistance states, highlighting how confinement in the moiré potential mimics strong-coupling superconductivity. In November 2025, MIT researchers reported direct evidence of unconventional superconductivity in MATTG, observing a V-shaped density of states indicative of non-phononic pairing mechanisms.^[85]^[86]^[87] Recent observations in 2025 have identified signatures of chiral superconductivity in rhombohedral tetralayer and pentalayer graphene, without moiré patterns, exhibiting Tc up to 300 mK in gate-tuned flat conduction bands. This phase, embedded within a spin- and valley-polarized quarter-metal state, shows magnetic hysteresis in resistivity under out-of-plane fields up to 1.4 T, indicating time-reversal symmetry breaking and chiral pairing consistent with confinement-enhanced topological order. The robustness against in-plane fields underscores the role of dimensionality in stabilizing exotic pairing symmetries.^[84] In 2D transition metal dichalcogenides (TMDs), such as monolayer MoS₂, electrostatic gating induces superconductivity by doping carriers into the conduction band, achieving Tc around 2-4 K at densities of ~0.55 × 10¹⁴ cm⁻², with phonon softening of acoustic modes driving the pairing. Confinement in the monolayer limits interlayer screening, enhancing electron-phonon coupling and enabling a Berezinskii-Kosterlitz-Thouless transition indicative of 2D vortex physics. Similar gate-induced effects occur in other TMDs like NbSe₂, where proximity to substrates modulates charge density waves to favor superconducting order.^[88]^[89] Nanostructured systems, including 2D films and nanowires, exhibit enhanced Tc through proximity effects or strain engineering, where interfaces with conventional superconductors induce pairing in semiconductors or topological materials. For instance, in hybrid Ge-Si nanowires, proximity coupling yields hard superconducting gaps up to magnetic fields of 250 mT, while strain in thin films of materials like YBa₂Cu₃O₇-δ suppresses competing orders to boost Tc by several kelvin. These structures also host 2D Josephson junctions, such as van der Waals heterostructures with h-BN barriers, enabling supercurrent modulation via gating and revealing confinement-driven phase coherence over micrometer scales.^[90]^[91]^[92]

New Material Discoveries (2020-2025)

In 2024, researchers identified three novel superconducting materials, marking significant progress in the quest for higher critical temperatures under ambient conditions. Among these, atom-thin transition metal dichalcogenide (TMD) sheets, such as (InSe₂)ₓNbSe₂—a layered structure of indium selenide intercalated in niobium diselenide—exhibited unexpected superconducting properties at interfaces, challenging conventional models of pairing in two-dimensional systems.^[93]^[94] These discoveries highlight the potential of layered materials to enable superconductivity without extreme cooling, with implications for compact quantum devices. Additionally, Yale University experiments provided evidence for a novel type of superconductor, potentially involving chiral states or unconventional electron pairing mechanisms, observed through advanced imaging techniques on iron selenide materials doped with sulfur.^[95] Advancing into 2025, a team at SLAC National Accelerator Laboratory achieved a breakthrough by stabilizing a new class of high-temperature superconductors at room pressure, retaining properties previously requiring megabar pressures and pushing critical temperatures closer to practical thresholds.^[96] This stabilization involved nickelate-based structures, building on prior high-pressure findings in high-Tc nickelates. In October 2025, scientists demonstrated superconductivity in germanium for the first time using industry-compatible hyperdoping methods with gallium, achieving zero-resistance states at low temperatures and opening pathways for integrating superconductors into silicon-based electronics.^[97]^[98] The HTSC-2025 dataset, released in mid-2025, compiled ambient-pressure high-temperature superconductors, featuring promising hydride families like X₂YH₆ and perovskite-type MXH₃ structures, which exhibit enhanced electron-phonon coupling for elevated critical temperatures.^[99] Complementing this, MIT's SCIGEN tool, introduced in September 2025, leverages generative AI to predict superconducting materials by enforcing physical constraints, accelerating the discovery of candidates with exotic quantum properties.^[100] Amid these advances, the 2023 LK-99 claim of room-temperature superconductivity in a copper-substituted lead apatite was thoroughly debunked through replication efforts, revealing the observed effects as diamagnetism from impurities rather than true zero-resistance flow.^[101] Pursuit of room-temperature superconductivity continues via clathrate structures, with theoretical predictions suggesting hexagonal boron-rich variants could achieve high critical temperatures at ambient pressure through optimized phonon-mediated pairing.^[102]

Applications

Magnets and Levitation

Superconducting magnets leverage the persistent currents in superconductors to generate strong, stable magnetic fields without energy loss, enabling applications that require high-field homogeneity and reliability. These magnets typically employ Type II superconductors, which allow magnetic flux penetration in a controlled manner via flux pinning, supporting fields far exceeding those of conventional electromagnets.^[103] In medical imaging, niobium-titanium (NbTi) coils are widely used in magnetic resonance imaging (MRI) systems, producing fields from 1.5 tesla (T) in standard clinical scanners to 7 T in research-grade units, providing exceptional image resolution due to the uniform fields sustained by zero-resistance loops.^[103] For even higher fields, niobium-tin (Nb3Sn) windings are incorporated, as seen in advanced prototypes, though NbTi remains dominant for most operational MRI due to its ductility and cost-effectiveness.^[104] In particle physics, superconducting magnets form the backbone of large-scale accelerators like the Large Hadron Collider (LHC) at CERN, where NbTi dipole coils achieve an operational field of 8.3 T to guide proton beams in a 27-kilometer ring.^[105] These magnets operate in persistent mode, circulating currents indefinitely to maintain the field with minimal power input, a feat enabled by cryogenic cooling to 1.9 K. Upgrades for the High-Luminosity LHC incorporate Nb3Sn coils to reach 11 T in select dipoles, enhancing collision rates while preserving stability.^[106] Magnetic levitation exploits the Meissner effect and flux pinning in Type II superconductors for frictionless suspension. The Japanese Superconducting Maglev (SCMaglev) train exemplifies this, using onboard NbTi superconducting magnets cooled to 4 K to induce repulsive forces via electrodynamic suspension (EDS) against aluminum guideway coils, enabling levitation up to 10 cm and operational speeds of 500-600 km/h with minimal vibration.^[107] This repulsion arises from eddy currents generated in the guideway, interacting with the persistent fields to provide both lift and lateral stability, as demonstrated in test runs achieving 603 km/h.^[108] Superconducting magnetic energy storage (SMES) systems store energy in the magnetic fields of persistent-mode coils, releasing it rapidly for grid stabilization or power quality improvement. These devices use NbTi or high-temperature superconductors (HTS) like YBCO, cycled between charge and discharge states with efficiencies over 95%, and are projected to grow from a 2023 market value of USD 75 million to USD 168 million by 2030, driven by renewable integration needs.^[109] Flux pumping techniques enhance trapped fields in HTS bulks for compact, high-performance bearings by iteratively inducing currents to amplify flux density without direct electrical contacts. In YBCO-based trapped-field magnets, fields up to 1.35 T have been achieved at 77 K via multi-coil pumping arrangements, enabling repulsive forces for flywheel or rotor suspensions with load capacities exceeding 1 ton and rotational speeds over 10,000 rpm.^[110] These bearings benefit from the permanent trapping of flux lines in melt-textured HTS, providing passive stability and low losses for applications like energy storage rotors.^[111]

Electronics and Sensing

Superconducting electronics leverage quantum interference and tunneling phenomena to enable devices with exceptional performance in speed, sensitivity, and energy efficiency. Central to these applications are Josephson junctions, thin insulating barriers between two superconductors that allow Cooper pairs to tunnel coherently, leading to dissipationless supercurrents. Predicted in 1962, these junctions exhibit two key effects: the DC Josephson effect, where a supercurrent flows across the junction without applied voltage, and the AC Josephson effect, where an applied DC voltage induces an alternating supercurrent at a frequency proportional to the voltage. The AC effect underpins precise voltage-to-frequency conversion, governed by the relation $2eV = h f, where e is the elementary charge, V is the voltage across the junction, h is Planck's constant, and f is the oscillation frequency; this relation has been experimentally verified and forms the basis for superconducting voltage standards. A primary application of Josephson junctions is in superconducting quantum interference devices (SQUIDs), which exploit quantum interference in a loop containing one or two junctions to detect minute magnetic fields. DC SQUIDs, using two junctions, achieve ultrahigh sensitivity by measuring flux changes as small as a fraction of the magnetic flux quantum \Phi_0 = h / 2e. These devices reach magnetic field sensitivities down to $10^{-15} T \mathrm{Hz}^{-1/2}, enabling non-invasive brain imaging via magnetoencephalography (MEG), where they map neural activity with spatiotemporal resolution superior to electroencephalography.^[112] In geophysics, SQUIDs facilitate mineral exploration and crustal studies by detecting subtle geomagnetic anomalies in magnetotelluric surveys, outperforming conventional magnetometers in low-signal environments.^[113] For digital computing, rapid single flux quantum (RSFQ) logic uses Josephson junctions to process information via single magnetic flux quanta, enabling clock speeds exceeding 100 GHz with picowatt-level power dissipation per gate—orders of magnitude faster and more efficient than semiconductor counterparts.^[114] In RSFQ circuits, logic states are encoded as the presence or absence of a flux quantum within a short timing window, with junctions clocking operations through phase slips; prototypes have demonstrated shift registers operating at 20 GHz and arithmetic logic units at 50 GHz, positioning RSFQ for applications in high-performance signal processing and hybrid supercomputing.^[115] Superconducting qubits for quantum computing also rely on Josephson junctions to create anharmonic energy levels for quantum state manipulation. The transmon qubit, a charge-insensitive design, shunts a Josephson junction with a large capacitor to suppress charge noise, achieving coherence times up to milliseconds and gate fidelities over 99.9%; it operates in the regime where the Josephson energy greatly exceeds the charging energy, enabling robust two-level system behavior.^[116] Similarly, the fluxonium qubit incorporates a Josephson junction in series with a superinductance, providing exponential suppression of flux noise and coherence times exceeding 1 ms, with a multilevel energy spectrum tunable via external flux for improved scalability in quantum processors.^[117] These junction-based qubits form the core of leading superconducting quantum computers, demonstrating multi-qubit entanglement and error-corrected operations essential for fault-tolerant quantum information processing.^[118]

Energy Systems

Superconductivity plays a pivotal role in advancing energy systems by enabling lossless power transmission and enhancing the efficiency of generation and storage technologies. In electrical grids, superconducting materials eliminate ohmic losses, allowing for higher power densities and reduced infrastructure needs. This is particularly valuable for urban and renewable energy applications, where space and efficiency constraints are significant.^[119] Superconducting cables represent a breakthrough in power transmission, functioning as zero-resistance lines that minimize energy dissipation over long distances. The AmpaCity project in Essen, Germany, exemplifies this technology, featuring a 1 km-long, 10 kV cable with a 40 MW capacity that connects two city-center transformer stations. Installed in 2014, it replaces a conventional 110 kV line, transporting five times more power than traditional cables with negligible losses, thereby simplifying grid structures and reducing urban land use. The cable's high-temperature superconducting (HTS) design, cooled by liquid nitrogen, demonstrates economic viability for inner-city distribution, with potential to cut transmission costs and enhance reliability.^[119] Fault current limiters (FCLs) based on superconductivity provide critical protection in power grids by rapidly responding to short-circuit faults. These devices use HTS tapes that maintain zero resistance under normal operation at cryogenic temperatures, such as 70 K in liquid nitrogen. Upon detecting a fault, the surge in current heats the superconductor, inducing a rapid quench that transitions it to a high-resistance state, thereby limiting the fault current to safe levels—often reducing it by factors of 10 or more—without interrupting power flow. This allows existing switchgear to isolate the fault quickly while enabling faster recovery as the material recools and regains superconductivity. In applications like high-voltage AC and DC grids, resistive SFCLs (RSFCLs) relieve network congestion, support meshing for better reconfigurability, and avoid costly substation upgrades, as demonstrated in prototypes tested near Essen and in EU-funded initiatives like FASTGRID.^[120]^[121] In renewable energy generation, high-temperature superconductors enable lighter and more efficient wind turbine generators by replacing copper windings with HTS materials like ceramic-metallic tapes, which operate at temperatures around -196°C using cryogenic cooling. This reduces generator weight by up to 40% and electrical losses, allowing for compact designs that produce higher power outputs—such as over 3 MW per unit—while using far less rare-earth materials than permanent magnet alternatives. A landmark example is the ECOSWING project, which in 2018 installed the world's first full-scale HTS wind turbine off Denmark's coast in Thyborøn, powering approximately 1,000 homes with enhanced energy flow densities. These advancements promise 20-30% cost reductions for offshore installations greater than 10 MW, though challenges like wire affordability and cooling reliability persist.^[122] Superconductivity is essential for large-scale energy production in fusion reactors, where strong magnetic fields confine plasma for sustained reactions. The International Thermonuclear Experimental Reactor (ITER) incorporates Nb₃Sn superconductors in its central solenoid, a key component comprising six independent coil packs that induce and sustain a 15 MA plasma current for 300-500 seconds. Each module uses approximately 6,000 meters of cable-in-conduit Nb₃Sn conductor, heat-treated to form the superconducting alloy, enabling a maximum magnetic field of 13 tesla and storing 6.4 GJ of energy. This vertical stack, weighing 1,000 tonnes and standing 13 meters tall, is crucial for plasma shaping and control, marking a high-impact application of low-temperature superconductors in clean energy generation.^[123]

Recognition

Nobel Prizes

The discovery of superconductivity was recognized early in the Nobel Prizes in Physics. In 1913, Heike Kamerlingh Onnes was awarded the prize "for his investigation of the properties of matter at low temperatures, which led, inter alia, to the production of liquid helium."^[124] His work at the University of Leiden enabled the liquefaction of helium, allowing experiments at temperatures near absolute zero, where he observed zero electrical resistance in mercury in 1911, marking the first identification of superconductivity.^[125] Theoretical understanding advanced significantly with the 1972 Nobel Prize in Physics, shared by John Bardeen, Leon N. Cooper, and John Robert Schrieffer "for their jointly developed theory of superconductivity, usually called the BCS theory."^[126] Developed in the mid-1950s at the University of Illinois, the BCS theory explained superconductivity as arising from the formation of Cooper pairs of electrons mediated by lattice vibrations (phonons), providing a microscopic quantum mechanical framework that predicted key properties like the energy gap and critical temperature.^[127] Experimental insights into quantum tunneling in superconductors earned the 1973 Nobel Prize in Physics. Half was awarded jointly to Leo Esaki and Ivar Giaever "for their experimental discoveries regarding tunneling phenomena in semiconductors and superconductors, respectively," while the other half went to Brian D. Josephson "for his theoretical predictions of the properties of a supercurrent through a tunnel barrier (Josephson effects)."^[128] Esaki's work at Sony in the late 1950s demonstrated tunneling in semiconductor p-n junctions, leading to the tunnel diode, while Giaever at General Electric observed tunneling in superconductor-insulator-superconductor structures, revealing the superconducting energy gap. Josephson, then a Cambridge graduate student, predicted in 1962 that a supercurrent could flow without voltage across a thin insulating barrier between superconductors and that an AC current would arise at a finite voltage, enabling applications like SQUIDs for precise magnetic field measurements.^[129] A breakthrough in materials science came with the 1987 Nobel Prize in Physics, awarded to J. Georg Bednorz and K. Alexander Müller "for their important break-through in the discovery of superconductivity in ceramic materials."^[130] Working at IBM's Zurich Research Laboratory, they reported in 1986 the observation of superconductivity at 35 K in a barium-doped lanthanum copper oxide, the first above liquid nitrogen temperature (77 K) and in a non-metallic ceramic, challenging the prior focus on elemental metals and alloys and sparking global research into high-temperature cuprate superconductors.^[55] Further theoretical contributions were honored in 2003 with the Nobel Prize in Physics. Vitaly L. Ginzburg and Alexei A. Abrikosov shared half "for their pioneering contributions to the theory of superconductors and superfluids," while Anthony J. Leggett received the other half "for his pioneering contributions to the theory of superfluids." Ginzburg and Lev Landau's 1950 phenomenological theory described superconductivity using macroscopic wave functions, predicting behaviors near critical temperatures. Abrikosov extended this in the 1950s to type-II superconductors, introducing vortex lattices that allow magnetic flux penetration, essential for high-field applications like MRI magnets. Leggett's work on superfluidity, including macroscopic quantum coherence, paralleled and informed superconductivity theories.^[131]

Other Milestones

In 1961, researchers at Bell Laboratories, led by J. E. Kunzler, developed the first practical Nb₃Sn superconducting wire by filling niobium tubes with powders of niobium and tin, then drawing and heat-treating them into ribbons capable of sustaining high magnetic fields above 8 T, paving the way for advanced high-field magnet applications.^[132] This breakthrough marked a significant advancement over bulk Nb₃Sn samples, enabling the production of flexible wires with improved current-carrying capacity for electromagnets.^[133] The discovery of high-temperature superconductivity accelerated dramatically in the late 1980s, with the critical temperature (T_c) record reaching 92 K in yttrium barium copper oxide (YBCO) in 1987, achieved by replacing lanthanum with yttrium in cuprate structures, allowing operation above liquid nitrogen temperatures. This progression from the initial 35 K in lanthanum-based cuprates in 1986 represented a pivotal shift, making practical cooling feasible and spurring global research into ceramic superconductors.^[134] In 2015, hydrogen sulfide (H₃S) set a new benchmark for conventional superconductivity with a T_c of 203 K under high pressure of 155 GPa, confirmed through resistivity and magnetic susceptibility measurements, demonstrating phonon-mediated pairing in hydrides.^[135] This record, the highest for any superconductor at the time, highlighted the potential of compressed hydrogen-rich compounds to approach room-temperature superconductivity, though practical applications remain challenged by extreme pressures. Advancing toward ambient conditions, in February 2025, researchers at SLAC National Accelerator Laboratory and Stanford University achieved the first stabilization of a new class of high-T_c superconductors—nickelate-based materials—at room pressure, using thin-film epitaxial growth techniques that apply lateral compressive strain from substrates to induce the infinite-layer structure without high-pressure synthesis.^[96] This milestone enables further exploration of infinite-layer nickelates without diamond anvil cells, bridging the gap to pressure-free high-T_c systems.^[96] Complementing these efforts, in October 2025, scientists at New York University demonstrated the first superconducting germanium using industry-compatible fabrication methods, such as molecular beam epitaxy with gallium hyperdoping on semiconductor-grade wafers, achieving T_c of 3.5 K while enabling direct integration with existing silicon-germanium electronics for hybrid quantum devices.^[136] This integration breakthrough transforms germanium from a conventional semiconductor into a platform for scalable superconducting circuits, potentially revolutionizing quantum computing architectures.^[97]

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The spherical gyroscopes are made of fused quartz and are sputter coated with a Nb film. The superconducting Nb film generates the. London magnetic dipole ...
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Observation of the London moment and trapped flux in precision ...
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A Spin Fluctuation Model for D-wave Superconductivity - arXiv
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[PDF] SUPERCONDUCTIVITY - Portland State University
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None
### Summary of Type I vs Type II Superconductors, Magnetic Fields, Hc1, Hc2, Vortices, Intermediate State, Examples
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Equilibrium Topology of the Intermediate State in Type-I ...
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A body in the so-called 'intermediate' state consists of alternating layers of the supraconducting and normal phases.<|separator|>
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Abrikosov shows how the theory of type II superconductors, where the magnetic field penetrates, was developed. All unusual properties of the high-temperature ...<|separator|>
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Nobel Lecture: Type-II superconductors and the vortex lattice
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[PDF] Ginzburg-Landau Theory: Simple Applications
(3) in the same limit, the “upper critical field” at which superconductivity is com- pletely destroyed is ∼ φ0/ξ2, more precisely. Hc2 = φ0/2πξ2(T). (50) ...
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Superconducting Critical Temperature - ScienceDirect.com
Tc, superconducting critical temperature, can be defined as the temperature at which a material exhibits superconductivity, which is often calculated using ...
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Using ultra-low temperatures to understand high ... - TU Wien
Jul 21, 2021 · " In the case of high-temperature superconductors ... temperatures of only one millikelvin, the strange metal turns into a superconductor.
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The maximum T c of conventional superconductors at ambient ...
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Standards for Measurement of the Critical Fields of Superconductors
The critical field is temperature dependent, with an approximately parabolic dependence on T/Tc. Below the critical field the flux density is zero in the bulk ...
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[PDF] Critical current densities in superconducting materials
Critical current density (JC) is the current density at which a superconductor loses its zero resistance property, and the material develops a 'flux-flow ...
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[PDF] The critical current density in type-II superconducting bulk materials
Mar 1, 2012 · In this paper we investigate the critical current density c. J for type-II superconducting bulk materials based on the quantum theory of vortex ...
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Phase diagram of a type I superconductor in the H-T plane. The...
Phase diagram of a type I superconductor in the H-T plane. The transition is first order for finite field. The blue lines show the 4 steps in the Gorter cycle ...
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Current distribution across type II superconducting films - Nature
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[PDF] Thermodynamic Properties of κ-(BEDT-TTF)2X Salts
Jun 29, 2012 · The well known high-Tc superconductors among organic systems are κ-(BEDT-TTF)2Cu(NCS)2 (Tc = 10.4 K) and κ-(BEDT-TTF)2Cu[N(CN)2]Br (Tc = 11.6 K) ...<|separator|>
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[PDF] Heavy-fermion superconductivity in CeCoIn5 at 2.3 K - arXiv
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The isotope effect in superconductivity | Physics Today
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[PDF] Failed theories of superconductivity - arXiv
Of the “failures” to explain superconductivity during the early post quantum mechanics days, two theories are noteworthy for their elegance and the ...
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High-field superconductivity
Only after Eugene. Kunzler's 1958 discovery of high-field superconductivity at 8.8 T in Nb3Sn was the dream of constructing high- field magnets rekindled. Much ...
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[PDF] A History of Nb3Sn and Related A15 Wires - Florida State University
The first strand carried 50 times higher Jc than the bulk sample,1 and their best PIT strand (with 10% more Sn than was required to fully react the. Nb powder ...
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Last year, 1986, Bednorz and Müller reported finding superconductivity in an oxide material at a temperature 12°C higher than previously known. This was the ...
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April 1986: Bednorz and Müller Trigger Avalanche of High ...
Mar 16, 2023 · April 1986: Bednorz and Müller Trigger Avalanche of High-Temperature Superconductivity Research. The duo's work energized the 1987 APS meeting.
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Transport and optical studies of single crystals of the 80-K Bi–Sr–Ca ...
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[PDF] J. Georg Bednorz and K. Alex Müller - Nobel Lecture
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[PDF] High Temperature Superconductivity Abstract - arXiv
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Quasiparticle mass enhancement approaching optimal doping in a ...
... superconductivity near optimal doping in the cuprates has impeded access to the metallic ground state. The Fermi surface in underdoped cuprates is known to ...
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Interplay between hole superconductivity and quantum critical ...
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The Puzzle of High Temperature Superconductivity in Layered Iron ...
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Enhanced flux pinning isotropy by tuned nanosized defect network ...
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High tolerance of the superconducting current to large grain ... - Nature
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Dec 1, 2014 · Here we report on the observation of a colossal Nernst signal due to the superconducting fluctuations in the heavy-fermion superconductor URu 2 Si 2.
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Superconducting fluctuations in organic molecular metals enhanced ...
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Majorana modes with side features in magnet-superconductor ...
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Oct 11, 2019 · We report the observation of half-integer magnetic flux quantization in mesoscopic rings of superconducting β-Bi 2 Pd thin films.
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[PDF] Gate-induced Superconductivity in atomically thin MoS2 crystals.
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Hard Superconducting Gap and Diffusion-Induced Superconductors ...
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Interface-enhanced superconductivity in monolayer 1T′-MoTe 2 on ...
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Two-Dimensional van der Waals Superconductor Heterostructures
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MIT Discovers Three New 2D Superconductors That Challenge ...
Feb 14, 2025 · Two of MIT's three newly discovered superconductive materials are composed of graphene and transition metal dichalcogenides (TMDs) sheets; ...
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A basic science breakthrough: Evidence of a new type ... - YaleNews
Nov 13, 2024 · Yale physicist Eduardo H. da Silva Neto led an experiment that supports the existence of a new type of superconductor.<|control11|><|separator|>
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Scientists turn common semiconductor into a superconductor
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Superconductive magnet design - Questions and Answers in MRI
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Conductors for commercial MRI magnets beyond NbTi
Advantages of superconducting MRI systems include better performance, the highest temporal and spatial homogeneity of the magnetic field, high signal-to-noise ...
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[PDF] Superconducting Magnets and RF Cavities for the LHC
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[PDF] High-field Magnet Development toward the High Luminosity LHC
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[PDF] SUPERCONDUCTING MAGLEV (SCMAGLEV) - JR Central
This leading edge Japanese technology is the next generation of super fast train travel. Propulsion System. By passing current through the Propulsion Coils ...
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Superconducting Maglev - Technology
The current SCMAGLEV train, known as the L0 (L-zero) holds the Guinness record for the world's fastest maglev train – clocking in at 374.68 mph (603 km/h)!.
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Superconducting Magnetic Energy Storage (SMES) Market
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Review on high-temperature superconducting trapped field magnets
Nov 25, 2024 · Flux pumping involves sweeping a smaller magnetic field across the superconductors in a wave, inducing a consistent current direction ...
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Review of high temperature superconducting flux pumps
High temperature superconducting (HTS) magnets conduct DC currents ranging from hundreds to tens of thousands of amperes. To achieve such DC output ...
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[PDF] SQUID-based multichannel system for Magnetoencephalography
Oct 17, 2013 · Here we present a multichannel system based on superconducting quantum interference devices (SQUIDs) for magnetoencephalography (MEG).
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HTS rf-SQUID applications to geophysical exploration methods
SQUID systems offer an alternative to commonly used vector magnetometers (induction coils, fluxgate) in geophysical exploration methods like magnetotellurics ( ...
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Charge insensitive qubit design derived from the Cooper pair box
Feb 28, 2007 · Here, we introduce a new type of superconducting qubit called the "transmon." Unlike the charge qubit, the transmon is designed to operate in a ...
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[0906.0831] Fluxonium: single Cooper pair circuit free of charge offsets
Jun 4, 2009 · Access Paper: View a PDF of the paper titled Fluxonium: single Cooper pair circuit free of charge offsets, by Vladimir E. Manucharyan and 7 ...
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Operation of Longest Superconducting Cable Worldwide Started
In Essen, the 10,000 volt superconducting cable replaces a conventional 100,000 volt line. Prior to the AmpaCity project, technical feasibility and economic ...
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Superconducting fault current limiter protects national electricity grids
Apr 23, 2021 · Today, engineers achieve the same result of limiting (switching off) the fault current by various passive and non-ideal means. In 2014, the ...
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Resistive superconducting fault current limiter - SuperGrid Institute
Sep 9, 2025 · The RSFCL relieves congestion on your AC network by limiting short circuit currents in your substation without upgrading your existing switchyard.
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A superconductive breakthrough for wind energy
Aug 29, 2018 · The world's first superconducting wind turbine will be installed this year off the coast of Denmark - a landmark achievement by an EU-funded project.
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Magnets - ITER
For the most technically challenging raw material—the niobium-tin (Nb3Sn) superconducting strands used in ITER's toroidal field and central solenoid magnet ...
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The Nobel Prize in Physics 1913 was awarded to Heike Kamerlingh Onnes for his investigations on the properties of matter at low temperatures.
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The same year he received the Nobel Prize for the production of liquid helium, he also discovered the phenomenon of superconductivity—when current passes ...
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The Nobel Prize in Physics 1987 was awarded jointly to J. Georg Bednorz and K. Alexander Müller for their important break-through in the discovery of ...
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[PDF] Nb3Sn Wires and Cables for High-Field Accelerator Magnets
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Nb3Sn Wires and Cables for High-Field Accelerator Magnets
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First-Hand:Discovery of Superconductivity at 93 K in YBCO
In February of 1987, scientists at the University of Houston and The University of Alabama in Huntsville separately announced the discovery of superconductivity ...
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Scientists Create New Type of Semiconductor that Holds ... - NYU
“Germanium is already a workhorse material for advanced semiconductor technologies, so by showing it can also become superconducting under ...