Fact-checked by Grok 2 weeks ago

Population inversion

Population inversion is a non-equilibrium condition in a quantum mechanical system, such as a collection of atoms or molecules, where the of particles occupying a higher-energy exceeds that of a lower-energy , defying the natural tendency described by the in . This phenomenon is fundamentally non-thermal and requires external energy input, known as pumping, to elevate more particles to the upper than the lower one. Achieving population inversion is essential for the of in devices like lasers and masers, as it enables the process of to dominate over , leading to coherent output. In a typical two-level system, population inversion is unstable and difficult to maintain because the rates of and are equal (via the Einstein B s), while rapidly depopulates the upper state (via the Einstein A ); thus, practical implementations often rely on three- or four-level schemes to sustain the inversion efficiently. Common pumping methods include , where intense excites atoms from the to higher levels, or electrical discharge in gas lasers. The concept underpins modern and , enabling applications from medical lasers for to via fiber-optic amplifiers. While lasing without inversion has been theoretically explored to bypass some limitations, traditional population inversion remains the cornerstone for most coherent light sources.

Fundamentals

Definition and Condition

Population inversion refers to a non-equilibrium state in an or molecular where the number of particles occupying a higher exceeds the number in a lower , contrary to the natural tendency described by the in . In such a state, denoted mathematically for a simple two-level as N_2 > N_1, where N_2 is the population of the upper and N_1 is the population of the lower level, the deviates from the equilibrium condition where N_1 > N_2. This concept was first theoretically proposed by in 1917 as part of his analysis of and the interaction between matter and radiation, highlighting its potential for light amplification. Practical realization of population inversion occurred in the 1950s, with early demonstrations including the work of Edward Purcell and Robert Pound in 1950 using lithium fluoride crystals under a . The significance of population inversion lies in its enablement of net over , allowing for the coherent of and serving as the foundational for the of lasers and masers.

Thermal Equilibrium Contrast

In , the populations of atomic or molecular levels follow the , given by the ratio N_2 / N_1 = (g_2 / g_1) \exp(-\Delta E / kT), where N_1 and N_2 are the populations of the lower and upper levels, respectively, g_1 and g_2 are the respective degeneracies, \Delta E is the between the levels, k is the , and T is the . This inherently favors lower states, ensuring that N_2 < N_1 for \Delta E > 0, as the exponential term diminishes with increasing but never inverts the population ratio under positive temperatures. Consequently, systems in exhibit net rather than for transitions between such levels. Population inversion, characterized by N_2 > N_1, starkly contrasts with this state and cannot persist without external intervention, as it corresponds to a negative in the Boltzmann framework, rendering it thermodynamically unstable. The primary mechanisms driving the system back to are , where excited atoms decay radiatively to lower states, and collisional processes that redistribute through interactions, both of which deplete the upper level faster than it can be sustained. These relaxation pathways ensure that any transient inversion decays exponentially, with lifetimes typically on the order of nanoseconds to microseconds depending on the transition. Maintaining population inversion requires continuous energy input, such as through optical or electrical pumping, to counteract the entropic drive toward lower energy configurations and replenish the upper level against ongoing losses. This non-equilibrium condition increases the system's , necessitating a steady to achieve and sustain the inverted , as the second of prohibits stable negative temperatures in isolated systems. Experimentally, population inversion is often verified by observing the inversion of the lineshape in measurements: in , a probe beam experiences net , manifesting as a dip in spectra, whereas under inversion, the medium exhibits optical , appearing as a peak or emission-like feature in the . This transition from to signatures confirms the achievement of N_2 > N_1 and is a hallmark diagnostic in development.

Light-Matter Interactions

Absorption

Absorption is a fundamental light-matter interaction in which an or in a lower state, typically the denoted as level 1 with E_1, absorbs a of precise h\nu = E_2 - E_1 to transition to a higher , level 2 with E_2. This process requires the photon's \nu to match the energy difference between the levels, ensuring for efficient energy transfer. The rate of absorption for a single atom is governed by the Einstein coefficient B_{12}, which quantifies the transition probability per unit spectral energy density of the radiation field; the overall absorption rate in a medium is thus proportional to both the incident light intensity (via the radiation density \rho(\nu)) and the population N_1 of atoms in the ground state. In practice, does not occur at a single frequency but over a broadened spectral lineshape, primarily due to Doppler broadening from the thermal motion of atoms, which shifts frequencies according to their velocities, and pressure broadening from collisional interruptions that perturb the energy levels during the . In media without population inversion, where the population N_1 exceeds that of the N_2, dominates other processes, resulting in net of the propagating as photons are continuously absorbed by the atoms. This reversal of dominance occurs under population inversion, enabling optical gain instead of loss.

Spontaneous Emission

Spontaneous emission occurs when an atom or molecule in an excited upper state E_2 decays to a lower state E_1, releasing a with h\nu = E_2 - E_1, where the emitted 's direction, phase, and are random and isotropic. This process is characterized by the excited 's lifetime \tau = 1/A_{21}, with A_{21} representing the Einstein that quantifies the average rate per atom in photons per second. Unlike stimulated processes, the rate of spontaneous emission remains constant and independent of any external radiation field, arising instead from interactions with the zero-point quantum vacuum fluctuations of the electromagnetic field. These fluctuations effectively "stimulate" the decay, ensuring that spontaneous emission proceeds even in the absence of photons at the transition frequency. In the context of population inversion, spontaneous emission serves as a primary loss mechanism by continuously depleting the upper-level population N_2 through random downward transitions, which disrupts the condition N_2 > N_1. To sustain inversion, excitation or pumping must therefore occur at a rate exceeding the spontaneous decay rate A_{21} N_2, preventing rapid thermalization back to equilibrium. Representative examples of spontaneous emission include the fluorescence observed in organic dye molecules, such as , where excited states decay to produce visible emission, and in atomic gases like sodium vapor, exhibiting characteristic spectral lines from upper-to-lower state transitions.

Stimulated Emission

Stimulated emission occurs when an incoming of frequency \nu and h\nu interacts with an atom or molecule in an , prompting the system to transition to a lower state while emitting a second that is identical to the incident one in frequency, , polarization, and propagation direction. This process produces coherent , distinguishing it from , and was theoretically predicted by in his 1917 paper on the quantum theory of radiation. The rate of stimulated emission, expressed as the number of transitions per unit volume per unit time, is given by R_{21} = B_{21} N_2 \rho(\nu), where B_{21} is the Einstein for stimulated emission, N_2 is the of atoms in the upper , and \rho(\nu) is the spectral energy density of the radiation field at frequency \nu. Similarly, the rate of is R_{12} = B_{12} N_1 \rho(\nu), with B_{12} the Einstein for and N_1 the of the lower level. These coefficients are linked by the Einstein B_{21} = \frac{g_1}{g_2} B_{12}, where g_1 and g_2 are the degeneracies of the lower and upper levels, respectively; this ensures consistency with and the Planck distribution for . In a medium exhibiting population inversion, where N_2 > N_1 \frac{g_2}{g_1}, the rate surpasses the rate, resulting in net of the . For a propagating , the I grows along the medium length L according to the factor G = \exp\left[ (B_{21} N_2 - B_{12} N_1) \frac{L}{c} \right], where c is the ; this exponential form derives from the for propagation, \frac{dI}{dz} = (B_{21} N_2 - B_{12} N_1) \frac{I}{c}. Population inversion is essential for positive , as without it, dominates and the medium attenuates the . This amplification mechanism underpins the operation of devices relying on coherent light generation, with the threshold for net gain directly tied to achieving and maintaining the inverted population.

Selection Rules and Transitions

Atomic Selection Rules

Atomic selection rules govern the allowed transitions between quantum states in atoms, determining the probability of light-matter interactions such as , , and . These rules arise from the symmetries of the quantum mechanical operators involved in the transitions, particularly the electric operator, which dominates radiative processes due to its strength. For electric (E1) transitions, which are the strongest and most relevant for efficient population inversion, specific changes in quantum numbers are permitted. In single-electron atoms, such as hydrogen-like ions, the electric dipole selection rules require a change in the orbital angular momentum quantum number by \Delta l = \pm 1 and in the magnetic quantum number by \Delta m = 0, \pm 1, with no change in the spin magnetic quantum number (\Delta m_s = 0). These rules stem from the angular momentum carried by the photon and the parity of the dipole operator, which necessitates a parity change (from even to odd or vice versa) for the transition to occur. In multi-electron atoms under LS (Russell-Saunders) coupling, the rules extend to the total angular momentum: \Delta L = 0, \pm 1 (but not 0 ↔ 0), \Delta S = 0 (conserving total spin), and \Delta J = 0, \pm 1 (but not 0 ↔ 0), again with a required parity change. The spin rule ensures that transitions between states of different multiplicity (e.g., singlet to triplet) are forbidden in the electric dipole approximation, though weak violations can occur in certain cases. Transitions violating these electric dipole rules are termed forbidden and proceed through weaker mechanisms, such as (M1) or electric (E2) interactions. For M1 transitions, remains unchanged, \Delta l = 0, and \Delta S = 0, while E2 allows \Delta l = 0, \pm 2 with no change. These forbidden processes have Einstein A coefficients that are typically orders of magnitude smaller than those for allowed E1 transitions—often by factors of $10^3 to $10^8—resulting in much longer radiative and lower efficiencies. Consequently, atomic selection rules dictate which upper and lower pairs are viable for achieving and sustaining population inversion, as only allowed transitions provide the necessary rates for practical and lasing.

Implications for Inversion

In media, non-radiative decay processes mediated by phonons enable fast relaxation from higher pumped levels to metastable upper laser levels, effectively bypassing selection rules that would otherwise prohibit certain radiative pathways and thereby aiding the establishment of population inversion. For instance, in neodymium-doped aluminum garnet (Nd:YAG), multiphonon relaxation rapidly populates the long-lived ^4F_{3/2} upper level from broader pumped manifolds, with rates exceeding 10^12 s^{-1} for intermediate steps, ensuring efficient inversion despite the intra-configurational nature of the lasing transition. This phonon-assisted mechanism is crucial for practical operation, as it decouples pumping efficiency from the strict dipole selection rules applicable to direct radiative transitions. Achieving and maintaining population inversion requires the upper laser level to have a substantially longer lifetime than the lower level, a condition influenced directly by selection rules that determine probabilities. Weakly allowed or forbidden , governed by rules such as ΔJ ≤ 6 for electric intra-4f processes in rare-earth ions, yield extended upper-level lifetimes typically ranging from 0.1 to 1 ms, far exceeding those of lower levels that often decay via faster allowed channels. These 4f-4f in ions like Nd^{3+} or Er^{3+} are particularly favored in solid-state lasers, as the partial shielding of 4f electrons by outer shells minimizes crystal field perturbations, preserving long lifetimes essential for sustained inversion and low operation. In systems where lifetimes are mismatched, such as in two-level schemes with comparable decay rates, inversion becomes transient and inefficient. Selection rules also dictate the polarization of stimulated emission, impacting the design and performance of laser devices by constraining the orientation of the electric field vector relative to the atomic or molecular axis. For atomic transitions, the Δm = 0 rule corresponds to π-polarized emission (parallel to the quantization axis), while Δm = ±1 allows σ-polarized light (perpendicular), requiring careful alignment of magnetic fields or cavity modes to optimize output polarization. In practical devices, such as vector lasers or those integrated with polarizing optics, these rules necessitate tailored resonator configurations to suppress unwanted polarizations, enhancing efficiency in applications like precision spectroscopy where linear or circular polarization is mandatory. In gaseous laser media, the lack of phonon-mediated relaxation enforces stricter adherence to electric dipole selection rules, limiting population inversion to discrete transitions with specific wavelengths determined by allowed Δl = ±1 and ΔJ = 0, ±1 criteria. This confinement restricts operational wavelengths to narrow lines, such as the 632.8 neon transition in He-Ne lasers, where inversion is viable only for permitted pathways without solid-state broadening or non-radiative shortcuts. Consequently, gas lasers exhibit challenges in wavelength versatility, often requiring precise conditions to selectively populate allowed upper states while avoiding forbidden routes that hinder inversion.

Methods of Creation

Optical Pumping

is a fundamental technique for achieving population inversion in a gain medium, where high-intensity light from an external source, such as a flashlamp or another , is absorbed by atoms or ions to excite them from lower to higher energy levels. This process selectively populates the upper laser levels, creating a non-equilibrium distribution where the population of the exceeds that of the lower state, enabling to dominate over . The absorption typically occurs via direct or indirect transitions, often involving intermediate states to facilitate efficient without requiring exact at the lasing wavelength. The dynamics of population inversion under can be described using rate equations for a simplified two-level system. The rate of change of the in the upper level N_2 is given by \frac{dN_2}{dt} = B_{12} \rho N_1 - A_{21} N_2, where B_{12} is the Einstein for stimulated , \rho is the density of the pump light, N_1 is the of the lower level, and A_{21} is the Einstein for from the upper to the lower level. In , setting dN_2/dt = 0 yields N_2 = (B_{12} \rho N_1)/A_{21}, implying that inversion (N_2 > N_1) requires the pumping rate B_{12} \rho to exceed the decay rate A_{21}, assuming total conservation and neglecting at the pump frequency. This condition highlights the need for sufficiently intense pump light to overcome . The efficiency of optical pumping is quantified by the quantum yield \phi, defined as the ratio of the number of atoms or ions excited to the upper per absorbed, \phi = (N_2 \text{ created})/(\text{[photons](/page/Photon) absorbed}). Losses arise from unwanted transitions, such as non-radiative relaxation or absorption to non-lasing levels, which reduce \phi below unity and limit overall energy conversion. High efficiency demands strong overlap between the pump spectrum and absorption bands, often achieved through broadband sources like flashlamps for solid-state media. Historically, the first demonstration of population inversion was achieved in the maser developed by and colleagues in 1954, using a molecular beam apparatus with inhomogeneous electric fields to selectively focus excited-state molecules into the resonant cavity while deflecting ground-state molecules, thereby creating the inversion for amplification. Optical pumping with visible or ultraviolet light became the dominant method for achieving inversion in visible and near-infrared lasers, as exemplified by the demonstrated by in 1960 using flashlamp excitation of chromium ions.

Three-Level Systems

In three-level systems, population inversion is realized through a scheme involving three levels: the (denoted as level 1), a metastable upper (level 2), and a higher-energy pump level (level 3). Atoms or ions are excited from level 1 to level 3 via , after which they undergo rapid non-radiative decay to level 2 due to its intermediate and favorable interactions in the host material. The extended lifetime of level 2 compared to level 3 enables the accumulation of a significant in level 2, facilitating transitions back to the (level 1). To achieve and maintain population inversion (N_2 > N_1), the total pump rate R (atoms excited per unit time) must satisfy R > \frac{N_{\text{total}}}{2 \tau_2}, where N_{\text{total}} is the total number of active atoms and \tau_2 is the lifetime of the upper level. This condition arises from steady-state rate equations, where the pumping must overcome the decay from level 2 while populating more than half the atoms in level 2, as N_3 \approx 0 due to fast relaxation and N_{\text{total}} \approx N_1 + N_2. The pump rate is inherently higher than in systems without ground-state depletion, as extracting over 50% of the population from level 1 requires intense pumping to compensate for the large initial ground-state occupancy. A canonical example is the , employing trivalent chromium ions (Cr³⁺) doped into an aluminum oxide (Al₂O₃) crystal host at low concentrations (approximately 0.05% by weight). This system was the first to demonstrate laser action, achieved by Theodore H. Maiman in 1960 using flashlamp to produce at 694.3 nm. Despite their historical significance, three-level systems exhibit drawbacks including elevated pump thresholds, which demand high-intensity sources for efficient operation, and substantial thermal heating arising from ground-state involvement in pumping and non-radiative relaxation processes that dissipate energy as phonons.

Four-Level Systems

In four-level laser systems, the energy level structure consists of a (level 1), a lower (level 3), an upper (level 2), and a pump level (level 4). Rapid non-radiative decays from level 4 to level 2 and from level 3 to level 1 ensure that the population of the lower remains negligible (N_3 \approx 0), while nearly all atoms reside in the (N_1 \approx N_\text{total}). This configuration facilitates population inversion between levels 2 and 3, as even a small population in the upper (N_2 > N_3) suffices to achieve net . The condition for population inversion in these systems requires the pumping rate R to exceed the spontaneous emission rate from the upper level, approximately R > A_{21} N_2, where A_{21} is the Einstein for the from level 2 to 3. This leads to a significantly lower compared to systems where the lower laser level is the , since N_3 \ll N_1 minimizes competition from and allows inversion with minimal depletion of the population. A key advantage of four-level systems is the ability to sustain (CW) operation, as the fast relaxation of level 3 prevents thermal buildup and enables steady-state inversion without excessive pumping. The neodymium-doped aluminum garnet (Nd:YAG) laser exemplifies this, first demonstrated in 1964 by J. E. Geusic, H. M. Marcos, and L. G. Van Uitert at Bell Laboratories, and now widely used in industrial applications such as cutting, welding, and medical procedures due to its reliability and versatility. These systems can achieve slope efficiencies up to 50% with respect to absorbed pump power, attributed to the efficient recycling of the population and reduced reabsorption losses.

Applications in Devices

Lasers

A laser operates by placing a population-inverted gain medium within an optical resonator, typically formed by two highly reflective mirrors, where stimulated emission amplifies light through multiple passes, producing a coherent output beam that exits via a partially reflective mirror. The process relies on the non-equilibrium condition of population inversion to achieve net optical gain, enabling the light to build up intensity as photons bounce back and forth, selectively amplifying those matching the medium's transition frequency, phase, and polarization. Laser oscillation begins only above a power, where the coefficient equals the total losses in the , given by the condition g_{\text{th}} = \alpha + \frac{1}{2L} \ln \frac{1}{R_1 R_2}, with g_{\text{th}} the small-signal , \alpha the internal loss coefficient, L the cavity length, and R_1, R_2 the mirror reflectivities. Below , dominates and no coherent output occurs; above it, sustains , with output power scaling linearly with excess power. The spectral and spatial properties of laser output are determined by cavity modes, which arise from the boundary conditions of standing waves. Longitudinal modes, spaced by \Delta \nu = \frac{c}{2 n L} (where n is the and c the ), result from the cavity length and select frequencies within the gain bandwidth, often leading to multi-mode operation unless the inversion is spectrally narrow. Transverse modes, characterized by indices m and n (e.g., the fundamental TEM_{00} Gaussian mode), depend on the 's transverse dimensions and the uniformity of the population inversion, influencing beam quality and divergence. Various laser types exploit population inversion for coherent optical emission, including solid-state lasers (e.g., Nd:YAG, using crystal hosts doped with rare-earth ions), gas lasers (e.g., He-Ne, employing electrical discharge in low-pressure mixtures), and semiconductor lasers (e.g., diode lasers, based on p-n junctions in materials like GaAs). All configurations maintain inversion to overcome losses and achieve phase-locked output, differing primarily in their gain media and excitation methods but unified by the need for dominance.

Masers and Amplifiers

Population inversion is fundamental to the operation of , which function as the analog of lasers by achieving amplification through in the frequency range. The first , constructed in by James P. Gordon, Herbert J. Zeiger, and , utilized a beam of molecules to create population inversion between the upper and lower states of the molecule's inversion transition in its rotational , enabling coherent emission at approximately 24 GHz. This device demonstrated sustained oscillation by directing excited molecules through a resonant cavity, where the inversion amplified signals without external feedback. The , developed by F. Ramsey and his collaborators in 1960, achieves continuous population inversion through an atomic beam technique that selects atoms in the higher-energy hyperfine state of the ground level. In this setup, hydrogen atoms are dissociated from molecular hydrogen, formed into a beam, and passed through a state selector—typically a sextupole magnet—that filters atoms into the excited F=1 state, creating an effective inversion relative to the F=0 state upon storage in a Teflon-coated bulb. This continuous inversion sustains oscillation at the 1.42 GHz hyperfine transition , providing exceptional stability and serving as a cornerstone for clocks in precision timekeeping applications, such as those used in global navigation systems. Beyond oscillating s, population inversion enables non-lasing amplifiers that boost weak signals without generating , as seen in traveling-wave designs. These amplifiers propagate the signal through an inverted medium, such as (chromium-doped ), where the three-level system allows pumping to an intermediate state followed by inversion between the upper lasing level and , yielding net gain while avoiding cavity feedback. For instance, early traveling-wave s achieved gains of over 20 dB at frequencies with bandwidths around 25 MHz, and the inversion minimizes added noise by reducing contributions to the output. Population inversion also underpins optical amplifiers, such as erbium-doped fiber amplifiers (EDFAs), which use to invert erbium ions in silica fibers, providing gain at 1550 nm for amplifying signals in systems without converting to electrical form. In modern , population inversion underpins low-noise amplifiers that approach the of added , essential for detecting weak quantum signals. Diamond-based quantum amplifiers, for example, exploit electron spins in nitrogen-vacancy or P1 centers, where pumping creates inversion between spin sublevels, enabling phase-preserving amplification with internal as low as the even at temperatures above (77 K). These devices, demonstrated with gains as high as 30 and noise temperatures near the standard of h\nu / 2 k_B (where h is Planck's constant, \nu the frequency, and k_B Boltzmann's constant), find applications in readouts and sensitive detection. Such amplifiers highlight how inversion maintains in quantum-limited regimes, contrasting with classical amplifiers that introduce excess thermal .

References

  1. [1]
    Quantum properties of light - HyperPhysics Concepts
    A population inversion cannot be achieved with just two levels because the probabability for absorption and for spontaneous emission is exactly the same, as ...
  2. [2]
    [PDF] Optical Sources
    emission only if a population inversion is present. And a population inversion can be achieved only through external excitation of the atomic population.
  3. [3]
    Lasers
    At any given time more of the atoms are at level "2" than at level "1", there is a "population inversion". The rate of stimulated emission will exceed the ...
  4. [4]
    [PDF] Chapter 7 Lasers
    Inversion by optical pumping can only be achieved ... We want to derive the equations of motion for th population inversion, or population in the upper laser ...
  5. [5]
    Laser Gain - Stanford
    Dec 15, 2014 · The state in which there are more higher energy particles than lower energy ones is referred to as 'population inversion', and any medium that ...
  6. [6]
    [PDF] Theory of lasing without population inversion
    The quantum theory of the laser without inversion attempts to uncover information on the statistical properties of the laser field. The photon statistics of ...
  7. [7]
    Population Inversion - an overview | ScienceDirect Topics
    The possibility of amplifying light by stimulated emission became evident after Einstein's theoretical study (in 1917) of the basic processes of absorption and ...
  8. [8]
    Topic guide: Masers and Lasers, 1951-1960
    ### Summary of Population Inversion in the 1950s with Masers
  9. [9]
    [PDF] Astronomy 501: Radiative Processes
    Sep 12, 2018 · in thermodynamic equilibrium, atom state populations follow Boltzmann distribution n1 n2. = g1e. −E1/kT g2e. −E2/kT. = g1 g1 e. (E2−E1)/kT.
  10. [10]
    [PDF] Chemical Bonding Michael Morse, University of Utah morse@chem ...
    A population inversion cannot be achieved if a sample is in thermal equilibrium, because Boltzmann tells us that the ratio of the population ... spontaneous ...
  11. [11]
    [PDF] arXiv:1403.4299v3 [cond-mat.stat-mech] 17 Jul 2014
    Jul 17, 2014 · In the conventional picture of course, a population inverted state has a negative Boltzmann tem- perature and is always “hotter” than a normal ...
  12. [12]
    Section 2.3: Principles of Lasers — Spontaneous Emission ...
    If N2>N1, we say population inversion exists. Spontaneous radiation is only one of the two forms of atomic relaxation or decay, the other is non-radiation ...
  13. [13]
    [PDF] Laser Physics - bingweb
    Oct 5, 2013 · The population inversion (N3>N2) can occur readily in comparison with the case of three-level laser, since the population of N3 and N4 are much ...
  14. [14]
    [PDF] Population Inversion, Negative Temperature, and Quantum ... - arXiv
    Apr 9, 2009 · We revisit the basic principle for lasing : Population inversion which is nevertheless closely linked to the negative temperature state in non- ...
  15. [15]
    [PDF] Fluorescence
    Depends on the absorption spectrum, extinction coefficient, and emission ... The gain coefficient is positive only if there is a population inversion.
  16. [16]
    [PDF] Population Inversion & Giant Bandgap Renormalization in WS2
    Jun 15, 2015 · Instead of a peak in the absorption, we observe the emergence of a broad dip in the spectrum, several hundreds of meV below the initial ...<|control11|><|separator|>
  17. [17]
    [PDF] ON THE QUANTUM THEORY OF RADIATION
    This paper was published as Phys. Zs. 18 (1917) 121. It was first printed in Mitteilungen der Physikalischen Gesellschaft Zurich, No. 18, 1916.
  18. [18]
    Atomic Spectroscopy - Spectral Line Shapes, etc. | NIST
    Oct 3, 2016 · Spectral line broadening in atomic spectroscopy is caused by Doppler (thermal motion) and pressure (collisions) broadening.
  19. [19]
    7 Spectral Lines‣ Essential Radio Astronomy
    7.3.1 Einstein Coefficients ... The spontaneous emission coefficient AUL is the average photon emission rate (s-1) for an “undisturbed” atom or molecule ...
  20. [20]
    Amplified spontaneous emission and gain in highly concentrated ...
    2 Eyl 2021 · Here γ sp is the spontaneous emission rate (of a single dye molecule), N inv is the density of excited fluorophores (small signal population ...
  21. [21]
  22. [22]
    [PDF] Rate Equations and Detailed Balance Initial question: Last time we ...
    Then we have a transition rate of B12 ¯. J for absorption and B21 ¯. J for stimulated emission, where B12 and B21 are the Einstein B coefficients. How are the ...
  23. [23]
    Atomic Spectros. - Spectral Lines - NIST
    Selection rules for discrete transitions. Electric dipole (E1) ("allowed"), Magnetic dipole (M1) ("forbidden"), Electric quadrupole (E2) ("forbidden") ...
  24. [24]
    Electric Dipole Transitions - Richard Fitzpatrick
    The electric dipole selection rules permit a transition from a $ 2p$ state to a $ 1s$ state of a hydrogen-like atom, but disallow a transition from a $ 2s$ to ...
  25. [25]
    [PDF] APAS 5110. Internal Processes in Gases. Fall 1999. - JILA
    Electric dipole selection rules include: for single electron, ∆L = ±1, ∆M = 0,±1; for many electron atoms, parity changes, ∆J = 0,±1, ∆MJ = 0,±1, and ∆L = 0,±1.
  26. [26]
    Forbidden Transitions – weakly allowed transitions, selection rules
    Forbidden transitions are transitions between different energy levels of some atoms or ions for which dipole transitions are suppressed via symmetries.Missing: spin | Show results with:spin<|control11|><|separator|>
  27. [27]
    Non-radiative Transitions - RP Photonics
    On the other hand, nonradiative transitions are essential for the function of many solid-state laser gain media: They often facilitate the population in the ...
  28. [28]
  29. [29]
    Rare-earth-doped Laser Gain Media - RP Photonics
    A characteristic property of the trivalent rare earth ions is that their electronic transitions usually occur within the 4f shell, which is somewhat shielded ...
  30. [30]
    Optical transitions of rare earth ions for amplifiers - ScienceDirect.com
    Several properties of 4f optical transitions of rare earth ions in glasses utilized as optical amplifiers for telecommunications are discussed.
  31. [31]
    Polarization selection rules in exciton-based terahertz lasers
    Aug 28, 2013 · We calculate the polarization dependence of the THz emission and identify photon polarization configurations for achieving maximum THz photon ...
  32. [32]
    Population Inversion and Energy Transfer in CO Lasers
    As with V–V processes P w , w −1 ∝ w and Δv = 1 selection rules are expected. Spontaneous Emission. Molecules in molecular excited states may lose excitation by ...Missing: implications | Show results with:implications
  33. [33]
    Optical Pumping - RP Photonics
    A requirement for achieving a high power conversion efficiency in an optically pumped laser is that the pump light is efficiently absorbed in the gain medium.Missing: historical development
  34. [34]
    [PDF] CHM 502 – Module 8 – Spontaneous Emission & Einstein Coefficients
    This rate is the same for either absorption or stimulated emission of radiation, which one can check simply by flipping the i and f labels.
  35. [35]
  36. [36]
    The first laser - The University of Chicago Press
    Aug 6, 2025 · Theodore Maiman made the first laser operate on 16 May 1960 at the Hughes Research Laboratory in California, by shining a high-power flash lamp on a ruby rod ...
  37. [37]
    Four-level and Three-level Laser Gain Media - RP Photonics
    Because the population inversion requires that more than half of the atoms are in the upper laser level, pumping with fairly high optical intensity is required.
  38. [38]
    Section 2.4: Rate Equations and Population Inversion
    Population inversion is not possible in two-level systems. It is possible in three-level systems with specific conditions, and readily achieved in four-level ...
  39. [39]
    Stimulated Optical Radiation in Ruby - Nature
    Stimulated Optical Radiation in Ruby. T. H. MAIMAN. Nature volume 187, pages 493–494 (1960)Cite this article.Missing: original | Show results with:original
  40. [40]
    Ruby Laser - an overview | ScienceDirect Topics
    ... laser operation. Ruby is a three-level system, so that more than 50 percent of the electrons must be excited to cause a population inversion. Thus, the ...
  41. [41]
    Ruby Laser Construction and Working with Energy Digram - Studyop
    Jul 9, 2025 · Ruby laser is a Solid state laser, in which a three-stage scheme is used for population inversion, which makes laser action possible.<|control11|><|separator|>
  42. [42]
    advantage of the four level laser
    To create population inversion, there is no need to pump more than 50% of the atoms to the upper laser level.
  43. [43]
    Slope Efficiency – laser, differential efficiency
    Some optimized solid-state lasers reach slope efficiencies well above 50% with respect to incident pump power, while in other cases it may be difficult to reach ...Missing: Nd: | Show results with:Nd:
  44. [44]
    Lasers - RP Photonics
    In the stimulated emission process, the laser-active ions are made to emit light in the direction of already existing light, and also with the same optical ...
  45. [45]
    Laser Threshold - RP Photonics
    The threshold of a laser is the state where the small-signal gain just equals the resonator losses, so that laser emission can just begin.
  46. [46]
    Resonator Modes - RP Photonics
    Resonator modes are modes of an optical or microwave resonator. Their properties are important for laser performance, e.g. for beam quality and alignment ...What are Resonator Modes? · TEMnm Modes, Axial and... · Mode Frequencies
  47. [47]
    [PDF] Charles H. Townes - Nobel Lecture
    The first paramagnetic masers suggested involved impurity atoms of this type in crystals of silicon or germanium. Relaxation between the two states was slow ...
  48. [48]
    Molecular Microwave Oscillator and New Hyperfine Structure in the ...
    Molecular Microwave Oscillator and New Hyperfine Structure in the Microwave Spectrum of N H 3. J. P. Gordon, H. J. Zeiger*, and C. H. Townes. Department of ...Missing: ammonia original
  49. [49]
    Invention of the Maser and Laser - Physics Magazine
    Jan 27, 2005 · Charles Townes and his colleagues were the first to build a “maser,” which operated in the microwave frequency range. It was the precursor of the laser.Missing: inversion realized
  50. [50]
    Atomic Hydrogen Maser | Phys. Rev. Lett.
    Atomic Hydrogen Maser. H. M. Goldenberg*, D. Kleppner, and N. F. Ramsey. Harvard University, Cambridge, Massachusetts. *National Science Foundation Predoctoral ...Missing: original | Show results with:original
  51. [51]
    Review of the development of the hydrogen maser technique and a ...
    Sep 13, 2022 · The atomic hydrogen beam then passes through a fractional population inversion component called the magnetic state selector, which utilizes a ...
  52. [52]
    The Atomic Hydrogen Maser - IOPscience
    The Atomic Hydrogen Maser. Norman F Ramsey. Published under licence by IOP Publishing Ltd Metrologia, Volume 1, Number 1Citation Norman F Ramsey 1965 ...Missing: original paper
  53. [53]
    Diamond-based microwave quantum amplifier | Science Advances
    Dec 7, 2022 · One can use MW pumping to reach a state of population inversion in which there are more electrons in a higher energy level than in a lower one.
  54. [54]
    Room-Temperature Solid-State Maser Amplifier | Phys. Rev. X
    We construct our amplifier using diamond, which hosts a quantum system called the nitrogen-vacancy center. We show that the noise added by the nitrogen-vacancy ...