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Dan Shechtman

Dan Shechtman is an materials scientist recognized for discovering quasicrystals, a class of solids exhibiting aperiodic atomic arrangements with forbidden rotational such as tenfold order, fundamentally challenging the that had long held that crystals must possess translational periodicity. While studying rapidly solidified aluminum-manganese alloys using at the U.S. National Bureau of Standards (now NIST) in 1982, Shechtman observed patterns indicative of icosahedral , a structure incompatible with periodic lattices, prompting him to annotate his notebook with three question marks in astonishment. This finding, published in 1984 after overcoming significant resistance—including dismissal by established figures like as "quasiscience"—eventually spurred theoretical validations and experimental confirmations, reshaping and . Shechtman received the in 2011 for this breakthrough, which demonstrated that matter can form ordered structures defying classical definitions of crystals, and has held professorships at the and , where he continues research on quasicrystalline materials.

Early Life and Education

Childhood and Family in

Dan Shechtman was born on January 24, 1941, in , within the British Mandate for Palestine, a territory that established the State of Israel in 1948 following the end of the Mandate and the ensuing War of Independence. His early years coincided with regional instability, including wartime rationing and scarcity that tested personal resilience in the nascent Jewish community. Shechtman grew up primarily in the neighboring towns of and , raised in a working-class Jewish family descended from Eastern European immigrants. His parents, Natania and Shechtman, navigated economic challenges, with employed as a printer, a echoing his father-in-law's amid the immigrant ethos of . This , rooted in Jewish heritage, emphasized practical skills and adaptability during periods of material hardship, providing a supportive environment that valued inquiry over formal privilege. An early fascination with science emerged through familial influences, particularly his grandfather, who introduced fundamental concepts by explaining mechanical principles and how everyday objects functioned, encouraging hands-on understanding independent of institutional resources. Shechtman also developed a passion for exploratory reading, devouring Jules Verne's adventure novels—such as The Mysterious Island multiple times—which fueled imaginative tinkering and a mindset oriented toward empirical observation amid the era's constraints. These formative experiences, bolstered by family encouragement during historical upheaval, cultivated a resilient approach to problem-solving grounded in direct evidence and persistence.

Academic Training at Technion

Shechtman earned his Bachelor of Science degree in Mechanical Engineering from the Technion–Israel Institute of Technology in 1966. He continued his studies at the same institution, obtaining a Master of Science in Materials Engineering in 1968. During this period, the Technion acquired its first transmission electron microscope, providing Shechtman with hands-on experience operating the instrument alongside technicians, which laid groundwork for his later expertise in microstructural analysis. In 1972, Shechtman completed his in at the Technion, focusing on topics in materials that honed his skills in experimental techniques central to solid-state research. This progression through Technion's engineering programs equipped him with a rigorous foundation in applied materials science, emphasizing empirical methods over abstract theorizing, consistent with the institution's orientation toward technological problem-solving in Israel's developing scientific .

Professional Career

Early Research Positions

Following his PhD in materials engineering from the Technion in 1972, Shechtman served as a National Research Council postdoctoral fellow at the Aerospace Research Laboratories of Wright-Patterson Air Force Base in Dayton, Ohio, from 1972 to 1975. In this role, he conducted research on the microstructure and physical metallurgy of alloys, applying materials engineering principles to aerospace and defense-related challenges, including the analysis of material properties under extreme conditions. In 1975, Shechtman returned to Israel and accepted a faculty position as a lecturer in the Department of Materials Engineering at the in . His early research there emphasized the mechanical properties of metallic alloys, particularly fracture behavior and microstructural influences on material strength, utilizing techniques such as scanning electron microscopy for detailed observations. Throughout the late 1970s, Shechtman advanced his expertise in rapid solidification processes through ongoing work at the Technion, where he explored non-equilibrium alloy structures and their potential for enhanced performance in engineering applications. These efforts, conducted via in-house experiments and collaborations within Israel's academic and industrial materials community, positioned him as a specialist in innovative alloy processing methods prior to international exchanges in the early .

Period at NIST and Key Experiments

In 1981, Dan Shechtman commenced a sabbatical from the at the National Bureau of Standards (NBS, predecessor to NIST) in , where he served as a visiting scientist through 1982. His research focused on rapidly solidified aluminum alloys doped with transition metals, such as , to probe metastable phases inaccessible under conventional slow cooling. This work built on NBS's expertise in non-equilibrium processing, aiming to map solidification pathways and phase diagrams under extreme conditions. Key experiments employed the melt-spinning technique, involving ejection of molten onto a chilled rotating wheel to achieve cooling rates exceeding 1 million kelvins per second, yielding thin ribbons typically 20–50 micrometers thick. Alloys with compositions near Al₆Mn (approximately 86 atomic percent aluminum and 14 atomic percent ) were prepared by technician Frank Biancaniello in the laboratory group of metallurgist William Boettinger. These ribbons were mechanically polished and electrochemically thinned to produce electron-transparent foils, then inserted into a transmission electron microscope (TEM) operating at accelerating voltages around 100–200 kilovolts for microstructural characterization. Shechtman collaborated closely with NBS senior scientist John Cahn, whose theoretical insights on and transformations informed sample selection and interpretation frameworks rooted in thermodynamic models assuming periodic atomic lattices. The lab dynamics reflected a hierarchical structure typical of federal research institutions, with experimentalists like Shechtman relying on shared facilities and interdisciplinary input from physicists and materials engineers, amid an overarching paradigm enforcing translational periodicity as a defining criterion for crystalline order.

Return to Israel and Professorship


Following the conclusion of his sabbatical at the National Bureau of Standards (now NIST) in 1983, Shechtman resumed his faculty position at the Technion – Israel Institute of Technology in Haifa, where he had been appointed as a lecturer in the Department of Materials Engineering in 1975.
He advanced through the academic ranks at the Technion, serving as from 1977 to 1984, from 1984 to 1986, and full professor from 1986 to 1998. In 1989, Shechtman was appointed to the Philip Chair in , and in 1998, he became Distinguished Professor in the department, a title he holds as . In 2004, Shechtman took on a partial appointment as Professor of and at , complemented by an associate role at the Ames Laboratory, enabling sustained academic exchanges and collaborative between Israeli and American institutions. Throughout his tenure, he established a laboratory at the Technion's Wolfson Centre, directing efforts toward development and supervising graduate students in materials engineering.

Discovery of Quasicrystals

The 1982 Electron Diffraction Observation

On April 8, 1982, Dan Shechtman, a visiting scientist at the National Bureau of Standards (now NIST) in , conducted an experiment on a rapidly solidified composed of 86 atomic percent aluminum and 14 atomic percent (approximating the Al<sub>6</sub>Mn). Using , he illuminated a thin sample of the with a high-energy beam and recorded the resulting pattern on photographic film. The pattern displayed discrete, sharp spots organized in rings that repeated every 36 degrees, indicating tenfold —a configuration incompatible with the translational periodicity required of conventional crystals. Shechtman immediately noted the unusual in his laboratory notebook, annotating the image with "10fold?" to record the apparent rotational order. The sharpness of the spots suggested long-range structural order, yet the pattern lacked the expected reflections consistent with three-dimensional periodicity. This emerged during routine studies of metastable phases in melt-spun ribbons, where rapid cooling (at rates exceeding 10<sup>6</sup> K/s) produced non-equilibrium microstructures. In the weeks following, Shechtman replicated the experiment on additional Al-Mn alloy samples prepared under similar conditions, consistently observing diffraction patterns with the same tenfold symmetry across multiple zones and orientations. These confirmations ruled out artifacts such as sample contamination or instrumental error, establishing the phenomenon as a reproducible feature of the alloy's atomic arrangement.

Initial Analysis and Forbidden Symmetries

Shechtman's examination of the pattern from the aluminum-manganese revealed spots arranged in a decagonal arrangement, signifying tenfold and thus fivefold axes, which violated the prohibiting such rotations in periodic crystals. Classical theory, predicated on translational periodicity, permitted only twofold, threefold, fourfold, or sixfold rotational symmetries, rendering fivefold order incompatible with lattice-based structures. Rotating the sample during analysis uncovered supplementary twofold, threefold, and fivefold axes, aligning with the full icosahedral (), characterized by 120 operations including these rotations. This configuration implied a causal of long-range orientational maintained by icosahedral clustering, yet devoid of repeating translational units, as evidenced by the sharp, non-lattice-indexable diffraction peaks. The persistence of discrete peaks at irrational angles relative to conventional lattices underscored an underlying quasiperiodic arrangement, where in multiple incommensurate directions generate the observed without periodicity. Mathematical modeling of this order invoked quasiperiodic functions and tilings, paralleling Roger Penrose's 1974 aperiodic tilings that enforce fivefold symmetry through hierarchical, non-repeating patterns of rhombi or kites, projecting effectively from higher-dimensional periodic lattices. Such frameworks explained the as projections of six-dimensional hypercubic lattices sliced at irrational angles, yielding icosahedral quasicrystals with forbidden symmetries via cut-and-project methods. Shechtman, in collaboration with Ilan Blech, Denis Gratias, and John W. Cahn, formalized these insights in a November 12, 1984, paper, designating the phase in Al-14 at.% Mn as possessing icosahedral symmetry inconsistent with translational order, thereby proposing a metallic .

Controversy and Scientific Debate

Ridicule from the Crystallographic Community

Shechtman's observation of ten-fold in the pattern of an aluminum-manganese alloy on April 8, 1982, at the National Bureau of Standards (NBS, now NIST) elicited immediate dismissal from colleagues, who attributed the pattern to experimental artifacts such as multiple twinning or faulty instrumentation rather than a novel crystalline structure. Senior researchers lectured him on foundational , emphasizing that true crystals require strict three-dimensional translational periodicity to form a space-filling , a principle codified by the International Union of Crystallography's definition at the time. They demanded he discard the data, viewing persistence as a misunderstanding of established theory over empirical anomaly. This institutional resistance culminated in 1984, after two years of Shechtman's insistence on the pattern's authenticity, when his research group leader confronted him, stating, "You are a disgrace to our group, and I cannot bear this disgrace," and required him to depart the group to preserve its reputation. Shechtman relocated to another NBS group, but the episode underscored the prioritization of conformity to paradigm-defining rules—like the prohibiting rotational symmetries beyond six-fold in periodic lattices—over replicable observations defying them. The wider crystallographic community echoed this rejection, subjecting Shechtman to ridicule and framing quasicrystals as quasi-science, with reviewers and peers ignoring the evidence in favor of authority-backed interpretations that preserved the impossibility of aperiodic long-range order in solids. This relied on mathematical proofs for periodic crystals, dismissing non-periodic alternatives as incompatible with the field's core tenets, even as Shechtman's repeated experiments confirmed the symmetry's .

Clashes with Linus Pauling and Expulsion from Lab

In 1982, shortly after Dan Shechtman's observation of tenfold symmetry in patterns from an aluminum-manganese alloy, , the double Nobel laureate in chemistry and peace, publicly rejected the existence of quasicrystals. Pauling, a staunch advocate of classical requiring translational periodicity, declared in lectures attended by Shechtman, "There is no such thing as quasicrystals, only quasi-scientists." This dismissal, rooted in theoretical priors over , exemplified resistance from established authority figures despite Shechtman's repeated verification of the patterns through multiple annealing cycles and sample preparations. Shechtman countered Pauling's critique by prioritizing experimental , noting that the defied conventional interpretation yet persisted across dozens of trials, challenging the that aperiodic order violated crystallographic rules. In one confrontation at an meeting at Stanford, Pauling reiterated the rejection before thousands, prompting Shechtman to defend the findings as grounded in observable rather than preconceived models. Shechtman's insistence on empirical validation over Pauling's appeals to authority highlighted a tension between credentialed consensus and direct , with Shechtman arguing that anomalies in warranted paradigm reevaluation rather than dismissal. The controversy extended to institutional repercussions; in defending his work at the U.S. National Bureau of Standards (NIST), Shechtman was asked to leave his research group, as colleagues viewed the claim as a undermining the team's . This expulsion, occurring amid broader , reflected how adherence to "heretical" findings threatened group funding and reputation, forcing Shechtman to relocate within NIST before his return to the Technion in 1984. Such actions underscored the causal role of institutional pressures in suppressing nonconforming evidence, prioritizing theoretical orthodoxy over replicable results.

Path to Acceptance and Paradigm Shift

The seminal publication in Physical Review Letters on November 5, 1984, by Shechtman, Ilan Blech, Denis Gratias, and John W. Cahn documented patterns from rapidly solidified Al-14% Mn revealing sharp tenfold symmetry, incompatible with traditional periodic crystal lattices, thereby compelling the crystallographic community to confront and replicate the anomalous data. Independent experiments soon followed; by mid-1985, multiple laboratories, including Japanese teams working with Al-Mn-based , reported analogous icosahedral diffraction patterns in metastable phases, establishing and shifting focus from dismissal to mechanistic explanation. Further empirical accumulation in the late included the of stable quasicrystals, such as icosahedral Al-Li-Cu phases reported in 1987, which resisted phase transformation under annealing and exhibited no detectable periodicity via high-resolution imaging, eroding alternatives like multiple twinning. This data-driven progression prompted the International Union of to amend its foundational in 1992, expanding "" to include solids with "long-range ordered arrangement" irrespective of periodicity, as formalized in Acta Crystallographica Section A. The shift was retrospectively affirmed by the 2011 , awarded solely to Shechtman for revealing quasicrystals' existence, which "proved that atoms in a solid do not need to be arranged in a repeating pattern" and engendered a new materials integrating aperiodic tilings with observable .

Awards and Recognition

Nobel Prize in Chemistry 2011

On October 5, 2011, the Royal Swedish Academy of Sciences awarded the solely to Dan Shechtman for his discovery of quasicrystals, recognizing the paradigm-shifting impact of identifying atomic structures with aperiodic order exhibiting forbidden fivefold rotational symmetry. The committee highlighted how Shechtman's 1982 observation, initially met with skepticism and dismissal by established crystallographers, demonstrated the triumph of over prevailing theoretical consensus, as quasicrystals challenged the foundational crystallographic restriction that aperiodic order could not produce sharp diffraction patterns. This 27-year interval from discovery to validation underscored the occasional delays in scientific acceptance when new findings contradict entrenched dogmas. The prize citation emphasized quasicrystals' mathematical elegance, incorporating the in their atomic arrangements, which bridged concepts from , physics, and , ultimately enabling applications in durable coatings and non-stick surfaces. In the presentation speech on December 10, , the committee praised Shechtman's persistence amid ridicule, noting that his work exemplified science's self-correcting mechanism, where persistent experimentation and data eventually compel shifts rather than deference to . Shechtman's Nobel Lecture, delivered on December 8, , at , detailed the experimental patterns that revealed the icosahedral symmetry, reinforcing the evidential basis that overcame initial suppression. The award's rationale explicitly tied the delay in to the scientific community's initial , including prominent rejections, yet affirmed that quasicrystals' was irrefutably established through reproducible synthesis and by the early 2010s, validating Shechtman's solitary empirical stance. This singular accolade, without co-recipients, highlighted the individual nature of amid collective opposition.

Other Scientific Honors

Shechtman was awarded the Rothschild Prize in Engineering in 1990 for his pioneering work on quasicrystals and related materials structures. In 1996, he was elected as a member of the Israel Academy of Sciences and Humanities, recognizing his foundational contributions to and . The following year, in 1998, Shechtman received the in Physics, Israel's highest civilian honor in the sciences, for his discovery of quasicrystals and its implications for understanding atomic order. He was then granted the in 1999 by the Wolf Foundation for the experimental discovery of quasicrystals, non-periodic structures exhibiting long-range order with forbidden rotational symmetries, which challenged traditional crystallographic paradigms. That same year, he also received the Gregori Aminoff Prize from the Royal Swedish Academy of Sciences for advancements in methods revealing quasicrystalline phases. In 2000, Shechtman was elected to the of the , honoring his innovations in materials engineering that demonstrated aperiodic crystalline forms with practical applications. Two years later, in 2002, he earned the EMET Prize in Chemistry, awarded by the Israeli Prime Minister's Office, for his role in establishing quasicrystals as a new class of materials with icosahedral symmetry.

Recent Accolades Post-2020

In 2023, Shechtman was conferred the title of Professor Honoris Causa by the University “St. Kliment Ohridski” in , , acknowledging his pioneering work in . On November 6, 2024, the Slovak University of Technology in awarded him an honorary doctorate (doctor honoris causa), citing his discovery of quasicrystals and its impact on and . Shechtman's ongoing recognition is evident in high-profile invitations to deliver keynote lectures, including his address on March 24, 2025, at Normal University-Hong Kong Baptist University United International College (BNBUUIC), titled "From Childhood Curiosity to Nobel Glory: A Journey Through Science and Perseverance," which emphasized the role of persistence in scientific breakthroughs. In October 2025, he spoke at the Sustainable Intelligent Processing of Solids (SIPS) conference, further highlighting his enduring influence on materials innovation.

Political Involvement

2014 Presidential Candidacy

In January 2014, Dan Shechtman, the Nobel laureate in , announced his candidacy for the presidency of , positioning himself as a non-partisan figure capable of providing moral and unifying leadership in the largely ceremonial role. The announcement came amid efforts to secure nominations from at least 10 members of the , as required by law for candidates to appear on the ballot in the indirect election conducted by the 120-member legislature. Shechtman actively lobbied Knesset members across parties, including meetings with figures such as , Avigdor Liberman, and Speaker , to build support for his bid. By late May 2014, Shechtman had successfully obtained the necessary nominations, allowing him to formally enter the race alongside other contenders, including and Meir Sheetrit. His campaign emphasized elevating public discourse through promotion of , ethical behavior, and care across societal divides, aiming to foster a "finer, fairer" national culture without alignment to any . As an outsider to , Shechtman framed the as an opportunity to influence societal values, drawing on his scientific background to advocate for rational, evidence-based approaches to national challenges. The Knesset election proceeded on June 10, 2014, with voting in multiple rounds among the candidates. Shechtman did not advance beyond the initial round, where Rivlin and Sheetrit secured the top positions leading to the runoff. Rivlin ultimately prevailed in the second round with 63 votes to Sheetrit's 53, succeeding as Israel's tenth president. Shechtman's candidacy highlighted the potential for non-political figures in the presidential contest but underscored the dominance of established politicians in garnering legislative backing.

Critiques of Israeli Society and Advocacy for Rationalism

Shechtman has voiced apprehensions regarding the expanding influence of Israel's ultra-Orthodox (Haredi) community, asserting that it undermines rational discourse and economic productivity. In a December 2023 address at an Israel Democracy Institute conference, he described Haredi society as one that "does not contribute to the state," citing widespread exemptions from military service, limited workforce participation, and minimal tax contributions, while forecasting that demographic trends could elevate Haredim to 50% of the population within decades, steering Israel toward becoming a "Haredi state." He has further lambasted the Haredi education system for omitting essential secular subjects such as mathematics and science, deeming its quality "terribly low" and inferior to that in Iran, as it leaves adherents ill-equipped for integration into a modern economy or society. To counteract these trends, Shechtman has championed a "behavioral revolution" through comprehensive ethics education, commencing in kindergartens and extending through military service, to cultivate respect, curb youth violence and rudeness, and foster social solidarity. He emphasizes instilling morality and tolerance early to promote fairness and non-violent conflict resolution, arguing that such reforms would address societal divisions exacerbated by inadequate behavioral training. In parallel, he advocates elevating scientific literacy and curiosity by mandating matriculation in disciplines like physics, chemistry, mathematics, and English, while boosting funding for institutions such as the Technion to reverse brain drain and prioritize evidence-driven progress over deference to non-empirical norms. Shechtman urges a cultural reorientation toward unity across Jewish denominations—spanning secular, , and identities—by highlighting shared values and rejecting tribal exclusions, positioning and empirical as antidotes to intolerance and . He contends that enhanced scientific education would enable better oversight of policy through informed citizenship, countering the erosion of secular foundations by religious insularity. These prescriptions, articulated post-2011 Nobel recognition, reflect his vision for an society grounded in verifiable knowledge and equitable conduct rather than unchecked demographic or ideological shifts.

Legacy and Contributions

Key Publications on Quasicrystals

Shechtman's foundational empirical documentation of quasicrystals appeared in the November 12, 1984, issue of Physical Review Letters with the paper "Metallic Phase with Long-Range Orientational Order and No Translational Symmetry," co-authored with Ilan Blech, Denis Gratias, and John W. Cahn. The article detailed electron diffraction patterns from a rapidly solidified Al–14 at.% Mn alloy exhibiting sharp spots indicative of icosahedral symmetry, possessing long-range orientational order but lacking translational periodicity, challenging prevailing crystallographic paradigms. In the mid-to-late , Shechtman contributed further experimental papers on phases in aluminum-transition metal , including studies of their formation via rapid solidification and structural characterization through techniques, as evidenced in subsequent works building on the initial Al-Mn . These efforts verified the of icosahedral ordering in metastable and explored phason-related defects. By the , his publications extended to investigations of stability under thermal treatments and potential in applications, documenting transformations and enhanced mechanical properties in like Al-Cu-Fe precursors, though primarily metastable in his early . Shechtman co-edited or contributed to compilations of and structural data in the late , such as proceedings from international workshops on quasicrystals, which aggregated from multiple systems to support the quasiperiodic model's consistency with observed long-range order. These works emphasized verifiable electron microscopy and results over theoretical modeling.

Influence on Materials Science and Broader Science Philosophy

Shechtman's discovery of quasicrystals revolutionized materials science by validating aperiodic atomic arrangements as viable for engineering applications, exploiting properties like low thermal and electrical conductivity, high hardness, and minimal friction. Quasicrystalline alloys, such as Al-Cu-Fe variants, serve as non-stick coatings in frying pans and utensils, where their low surface energy prevents adhesion without traditional lubricants. These materials also enhance diesel engine components by improving wear resistance and thermal barriers, reducing energy loss in high-temperature environments. In LED technology, quasicrystals contribute to efficient heat dissipation, enabling more durable and performant devices through their insulation qualities. The unique atomic ordering in quasicrystals—defying classical crystallographic rules—has spurred innovations in composite reinforcements and catalysts, where their oxidation resistance and quasi-periodic symmetry yield superior mechanical stability over periodic crystals. This shift expanded the design space for alloys, proving aperiodic structures' practical utility beyond theoretical curiosity and influencing fields from to . Ongoing developments include quasicrystal-inspired metamaterials, which exhibit tunable , photonic bandgaps, and deployable for applications in and adaptive structures. Philosophically, Shechtman's trajectory exemplifies the primacy of direct empirical evidence over consensus authority in scientific advancement. Facing dismissal from luminaries like Linus Pauling, who labeled quasicrystals nonexistent and their proponents "quasi-scientists," Shechtman persisted with diffraction data, ultimately vindicating observation against entrenched dogma on crystal periodicity. This episode critiques overreliance on theoretical priors, illustrating how paradigm resistance can delay but not preclude breakthroughs grounded in reproducible experiments. At the Technion, Shechtman's professorship has cultivated this through , urging students to master niche expertise while challenging unverified assumptions, thereby promoting inquiry resilient to institutional biases toward . His advocacy for science's revisability—contrasting it with rigid doctrines—reinforces causal realism in contentious domains, where data trumps credentialed opinion.

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