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Howlite

Howlite is a calcium borosilicate hydroxide mineral with the chemical formula Ca₂B₅SiO₉(OH)₅, belonging to the inoborate group, and typically appears as white or colorless porcelaneous nodules, masses, or veins marked by gray, black, or brown intersecting patterns resembling marble.^[1] Named after Canadian geologist and chemist Henry How (1828–1879), who first identified and described the mineral in 1868 from specimens collected in Windsor, Nova Scotia, howlite was initially termed silicoborocalcite before being renamed by James Dwight Dana in 1868.^[1] It crystallizes in the monoclinic system, though it rarely forms distinct crystals and instead occurs in compact, massive habits.^[1] Physically, howlite has a Mohs hardness of 3.5 in its massive form (up to 6.5 for rare crystals), a specific gravity of 2.58–2.62, and a sub-vitreous to dull luster, with perfect cleavage in one direction and a white streak.^[1] It is translucent to opaque, soluble in hydrochloric acid, and exhibits weak fluorescence under ultraviolet light, appearing orange or bluish-white.^[1] Howlite forms in evaporitic environments through the alteration of boron-rich volcanic ash or tuff in arid or semi-arid conditions, often associated with other borates like colemanite and gypsum, as well as anhydrite and calcite in sedimentary deposits.^[1] Notable occurrences include the Bay of Fundy region in Nova Scotia, Canada; the Kramer District in California's Mojave Desert; and deposits in Mexico, Turkey, and Serbia.^[1]^[2] Due to its attractive veining and relatively low cost, howlite is primarily valued as an ornamental stone for carvings, cabochons, beads, and decorative objects, and it is frequently dyed blue or green to imitate turquoise in jewelry.^[3] Its softness limits industrial applications, though it has minor historical use in small sculptures.^[3]

Properties

Chemical Composition

Howlite is a borate mineral classified within the inoborates group, specifically as an ino-triborate borosilicate, characterized by its chain-like borate structures.^[1] Its ideal chemical formula is \ce{Ca2B5SiO9(OH)5}, representing a calcium borosilicate hydroxide where calcium cations are balanced by a complex polyanion consisting of silicate and borate tetrahedra along with hydroxyl groups.^[4]^[1] This composition accounts for approximately 13.8% boron by weight, underscoring its significance as a boron-bearing mineral.^[4] The crystal structure of howlite is monoclinic, belonging to the space group P2_1/c with four formula units per unit cell (Z = 4).^[5] Unit cell parameters are typically a = 12.82 Å, b = 9.351 Å, c = 8.608 Å, and β ≈ 104.8°.^[1] In this arrangement, calcium atoms are coordinated by eight oxygen and hydroxyl atoms, forming distorted polyhedra that link the structure together.^[5] Boron plays a central role in howlite's structure by forming tetrahedral coordination polyhedra, such as isolated \ce{BO4} and \ce{BO3(OH)} units, which integrate with silicate tetrahedra to create colemanite-like chains and silicoborate spirals.^[5] These boron-centered chains run parallel and are interconnected via shared oxygen atoms and hydrogen bonding involving the hydroxyl groups, resulting in a layered-like framework that imparts stability to the mineral.^[5]^[6] While the ideal formula predominates, some specimens exhibit minor substitutions, including sodium and potassium as common impurities replacing calcium or altering site occupancies, though magnesium or iron substitutions are not typically reported in standard analyses.^[1]

Physical Characteristics

Howlite is typically white or colorless, often exhibiting gray, black, or brown veining that gives it a marbled appearance resembling turquoise or other stones.^[6]^[7] This veining occurs naturally in its nodular formations, contributing to its distinctive aesthetic.^[8] In terms of durability, howlite registers 3.5 on the Mohs hardness scale in massive form (up to 6.5 for rare crystals).^[1] Its specific gravity ranges from 2.58 to 2.62, making it lightweight compared to many other minerals.^[1] The mineral displays a luster that varies from dull to sub-vitreous or porcelaneous, with a conchoidal to uneven fracture and no distinct cleavage.^[9]^[4] It produces a white streak and is generally opaque to translucent, though rare crystalline forms may show greater transparency.^[1] Howlite commonly forms in compact nodular or massive habits, often with a chalky, earthy texture attributed to its borate composition, and it has a refractive index of approximately 1.59 to 1.60.^[9]^[6]^[1] It is soluble in hydrochloric acid, forming a gelatinous silica residue, and exhibits weak fluorescence under ultraviolet light, appearing orange or bluish-white.^[1] These traits make it easy to handle but prone to absorption, influencing its use in polished forms.^[6]

Formation and Occurrence

Geological Formation

Howlite is a secondary borate mineral that primarily forms in evaporite deposits through the reaction of boron-rich hydrothermal solutions with calcium-bearing host rocks such as limestone or dolomite. These solutions, often derived from volcanic or geothermal activity leaching boron from surrounding bedrock, infiltrate and interact with the carbonates under evaporative conditions in arid, closed-basin lacustrine or marine environments, leading to the precipitation of howlite as nodules, veins, or masses.^[10]^[11] The formation process is typically diagenetic, occurring contemporaneously with the precipitation of calcium sulfate minerals like gypsum and anhydrite, where howlite develops from silica- and boron-enriched gels or brines in unconsolidated sediments. Host rocks commonly include evaporitic sequences of clays, marls, and limestones, as well as altered volcanic tuffs or basalts in boron-enriched settings; in some cases, it appears in contact metamorphic zones or altered ultramafic rocks where boron mobilization enhances precipitation. Formation conditions involve low temperatures, generally under 100°C, in concentrated, alkaline brines driven by evaporation and fluid circulation along faults or fractures.^[12]^[13]^[10] Howlite shares paragenesis with other borates such as colemanite and ulexite, often forming in alternating layers or replacing primary borates during burial diagenesis in these environments, reflecting sequential precipitation based on evolving brine chemistry and silica availability. Its nodular or cauliflower-like morphology further indicates gel precipitation in low-energy, stable depositional settings.^[14]^[10]

Major Deposits

The type locality for howlite is near Windsor, Nova Scotia, Canada, where it was discovered in 1868 within gypsum and anhydrite deposits formed in evaporative environments.^[6]^[1] Significant deposits occur in the same region, including Iona on Cape Breton Island, where howlite forms nodules embedded in anhydrite matrices along ancient evaporite sequences from the Windsor Sea.^[15] In the United States, a key deposit is at Tick Canyon in Los Angeles County, California, part of a borate-rich evaporite sequence where howlite nodules are found alongside other borates in volcanic and sedimentary beds.^[1]^[16] Another notable site is the East Kramer borate area near Boron, California, in the Mojave Desert, yielding large nodules from open-pit operations historically focused on borax extraction.^[1] Mexico hosts deposits in Baja California, including areas near the border region, where howlite occurs in evaporite settings similar to those in California.^[6] Other occurrences include the Pobrdje mine in Serbia's Jarandol Basin, with minor howlite associated with colemanite in boron-bearing layers.^[17]^[1] Howlite is commonly associated with gypsum, anhydrite, and calcite in these evaporite deposit matrices, occasionally with serpentine in altered zones.^[1]^[16] Mining primarily involves open-pit methods to extract nodules from gypsum quarries or borate operations, with Canada serving as the historical main source of commercial production.^[6]^[15]

History

Discovery

Howlite was first noted in the early 19th century as unusual white nodules occurring within gypsum deposits in Nova Scotia, Canada, where they were regarded by miners as impurities disrupting the quality of the extracted material, though no formal scientific identification was made at the time.^[15] These nodules, often as large as a man's fist, were encountered during gypsum quarrying operations that began in the 1820s near Windsor.^[8] The mineral was formally discovered in 1868 by Canadian chemist, geologist, and mineralogist Henry How (1828–1879), a professor at King's College in Windsor, Nova Scotia, who was alerted to the specimens by local gypsum miners at a quarry on the Clifton Estate in Brookville.^[1] How initially mistook the compact, white, cauliflower-like nodules for a novel boron-containing compound and named it silicoborocalcite based on his preliminary observations.^[15] Through chemical tests, including qualitative analysis for boron via flame coloration and quantitative assays revealing significant boron content alongside calcium and silica, How confirmed its unique borosilicate composition, distinguishing it from known minerals.^[1] How's findings were published in the Philosophical Magazine in 1868, marking the first scientific description of the mineral.^[18] Shortly thereafter, American geologist James Dwight Dana renamed it howlite in honor of its discoverer, solidifying its recognition as a distinct mineral species within the borate group by the early 1870s.^[1] This transition elevated the local curiosity from a mining nuisance to a formally accepted borosilicate mineral in geological literature.^[15]

Etymology and Early Uses

The mineral howlite derives its name from Canadian chemist, geologist, and mineralogist Henry How (1828–1879), who first described it in 1868.^[1] It was initially classified as silicoborocalcite based on its borate composition, but American mineralogist James D. Dana soon renamed it howlite to honor How's analytical contributions to its identification.^[4] In the late 19th century, howlite attracted scientific interest in Nova Scotia due to its boron content, contributing to studies of regional evaporite deposits and boron geology.^[19]^[20] Although no large-scale extraction attempts materialized—given howlite's limited abundance compared to other borates like borax—its presence advanced understanding of local mineralogy.^[20] By the late 19th century, howlite had evolved from a curiosity for mineral collectors to an ornamental material, with specimens from Nova Scotia being carved into small decorative items, cabochons, and early jewelry elements for their porcelain-like appearance and ease of working.^[15] In the early 20th century, additional specimens from California deposits expanded its availability for such uses.^[21] This shift reflected growing appreciation for its aesthetic qualities beyond scientific analysis.

Uses

Jewelry Applications

Howlite is commonly fashioned into beads, cabochons, carvings, and tumbled stones for use in necklaces, earrings, bracelets, and other adornments, leveraging its uniform white color and veined patterns for aesthetic appeal.^[22]^[8]^[23] Its porous structure allows howlite to readily absorb dyes, enabling it to imitate more valuable gemstones such as turquoise with blue-green hues, lapis lazuli with deep blue tones, or malachite with green variations; this dyeing process involves soaking the stone in pigment solutions followed by heating to set the color.^[22]^[8]^[23] Due to its relative softness (Mohs hardness of 3–3.5), howlite requires careful handling in jewelry to prevent scratching or chipping, and it should avoid prolonged water exposure or acidic substances, as it is partially soluble in dilute acids; cleaning is best done with a soft cloth and mild soapy water, followed by immediate drying and occasional polishing to maintain luster.^[3]^[8]^[24] Undyed howlite typically retails for $0.30–$1 per carat, making it an inexpensive option that gains popularity in bohemian and Native American-inspired designs, where its affordability supports elaborate beadwork and carvings without compromising style.^[8]^[23] Originally employed in the 20th century primarily as an imitation for turquoise and other stones, howlite transitioned by the 2000s into a widely accepted affordable alternative in mainstream jewelry, valued for its versatility rather than solely as a simulant.^[22]^[23]^[8]

Other Applications

Howlite is frequently carved into small sculptures, bookends, and figurines that highlight its distinctive white color and gray veining, making it a popular choice for decorative home accents such as coasters, wind chimes, bowls, and vases. It is also used in architectural elements like countertops and tiles for its marble-like appearance.^[25]^[6] These objects leverage the mineral's porcelain-like texture and relative ease of carving, though its softness limits it to finer, non-structural pieces. Its porosity also allows for occasional dyeing to enhance aesthetic appeal in decorative items.^[6] In metaphysical and spiritual practices, howlite is valued for its purported calming properties, believed to absorb negative emotions like anger, reduce stress and anxiety, and alleviate insomnia by soothing the mind and nervous system.^[25]^[6] It is commonly incorporated into meditation aids, such as grids or tumbled stones placed under pillows for restful sleep, and is associated with enhancing focus, emotional healing, and spiritual awareness, particularly linked to the crown chakra.^[25]^[6] Though primarily ornamental, howlite has minor industrial applications due to its boron content and physical properties. It has served as a source for boron extraction to produce boric acid and other compounds through processes like solvent extraction from calcium borate minerals.^[26]^[27] Culturally, howlite features in modern Native American crafts, where it is shaped into small sculptures, sacred objects, and beads. In contemporary New Age products, it appears in crystal healing items like tumbled stones, worry stones, and essential oil diffusers, capitalizing on its soothing reputation.^[6] Mining of howlite, particularly from low-impact deposits in Nova Scotia, Canada—the primary commercial source—employs environmentally friendly practices that minimize habitat disruption and adhere to sustainable extraction standards.^[28]^[6] These operations focus on selective excavation of evaporite deposits, supporting ongoing availability without significant ecological harm.^[28]

Identification and Varieties

Distinguishing Features

Howlite is readily identifiable in its natural state by its characteristic spiderweb-like veining patterns consisting of gray to black inclusions, which form within compact nodules and distinguish it from other white minerals.^[1] These threadlike impurities, often resembling erratic webs, are a hallmark of howlite's massive habit and result from associated mineral inclusions during formation.^[22] Practical field tests confirm howlite's softness, with a Mohs hardness of 3.5, allowing it to be scratched by a copper penny (approximately Mohs 3) but not by a knife (Mohs 5.5).^[1] Due to its relatively high thermal conductivity compared to synthetics like plastic, natural howlite feels noticeably cool to the touch when held in the hand.^[7] A key diagnostic chemical test involves exposing howlite to dilute hydrochloric acid (HCl), where it may exhibit mild fizzing if calcium carbonate impurities are present, though pure specimens dissolve slowly without effervescence, forming a gelatinous silica residue.^[1] Under longwave ultraviolet (UV) light, howlite displays weak white to bluish-white fluorescence, providing another authentication trait, particularly in nodular samples.^[29] Advanced identification relies on spectroscopic methods, such as X-ray fluorescence (XRF) analysis, which reveals distinct boron peaks alongside calcium and silicon, confirming howlite's borosilicate composition (Ca₂B₅SiO₉(OH)₅).^[1] This elemental signature sets it apart from similar borates formed in evaporite environments.^[7]

Treatments and Imitations

Howlite, due to its natural porosity, readily absorbs dyes and resins, making it susceptible to various treatments that enhance its appearance and durability for commercial use.^[30] Common treatments include dyeing with synthetic colors to mimic more valuable gems, such as turquoise; this process often involves cobalt-based dyes to achieve a blue-green hue, allowing howlite to be marketed as an affordable alternative.^[31]^[32] Additionally, stabilization with colorless resins is applied to improve hardness and prevent crumbling, as untreated howlite has a Mohs hardness of only 3.5, rendering it prone to wear in jewelry.^[33]^[34] Imitation materials frequently substitute for howlite in the market, including magnesite, which shares similar white coloration and veining but possesses greater hardness (3.5-5) and a sticky texture when licked due to its magnesium carbonate composition.^[35] White marble serves as another low-cost fake, offering a comparable marbled look but with higher density and lack of porosity, while plastic replicas, often molded and dyed, exhibit uniformity and lightness that natural stones lack.^[36]^[37] Detection methods for treated or imitation howlite include testing for dye bleeding by immersing the stone in hot water, where synthetic colors may leach out, revealing the treatment; under ultraviolet (UV) light, uneven fluorescence or a lack of natural glow can indicate artificial coloration in dyed specimens.^[38] Density tests further distinguish fakes, as genuine howlite has a specific gravity of 2.5-2.6, while plastics register lower (around 1.3-1.5) and feel unnaturally light.^[39] Ethical concerns in the gem trade center on disclosure requirements, with organizations like the Gemological Institute of America emphasizing that non-disclosure of treatments or mislabeling as "turquoise howlite" deceives consumers and undermines market integrity; such practices are prevalent.^[40]^[31]^[41] The use of howlite imitations surged in the 1970s amid turquoise scarcity, as major deposits like those in the American Southwest depleted, prompting manufacturers—particularly in China—to dye and stabilize howlite and similar stones to meet demand for affordable jewelry components during that era.^[42]^[43]^[44]

References

[1]
Howlite: Mineral information, data and localities.
Howlite ; Hardness: 6½ ; Specific Gravity: 2.62 ; Crystal System: Monoclinic ; Name: First described as silicoborocalcite by Henry How (11 July 1828, London, ...
[2]
[PDF] Borate minerals from the Kramer district, Mohave Desert, California
The development of the borate deposits of the Kramer dis trict, in the Mohave Desert, Calif., received a strong impulse in 1926 by the discovery there of'a ...
[3]
Howlite Gem Guide and Properties Chart - Gemstones.com
Howlite is a basic calcium silico-borate that is used for ornamental and decorative objects. It is whitish or cream in color often with gray or brown veining.
[4]
http://webmineral.com/data/Howlite.shtml
[5]
Howlite Mineral Data - Mineralogy Database
Howlite's chemical formula is Ca2B5SiO9(OH)5. It is colorless or white, translucent, with a density of 2.58, and a hardness of 2.5-3.5. It is found in arid ...
[6]
[PDF] crystal structure of the calcium silicoborate, howlite
These two structural features link through o(4) oxygen atoms, which are common to the silicate tetrahedra and borate tetrahedra of two colemanite-like chains.
[7]
Howlite | Properties, Formation, Occurrence - Geology Science
May 13, 2023 · Magnesite is composed of magnesium carbonate (MgCO3), while howlite is a calcium borosilicate hydroxide. Magnesite is sourced from various ...
[8]
Howlite gemstone information - Gemdat.org
It often forms in nodules which resemble cauliflower heads. The nodules are opaque, white with gray or black veins, often showing web-like pattern.
[9]
Howlite Gemstone: Properties, Meanings, Value & More
### Summary of Howlite Jewelry Applications
[10]
Howlite – Mineral and Healing Properties - Kidz Rocks
May 1, 2025 · Because of its porous texture, howlite can be easily dyed to imitate other minerals, especially turquoise because of the superficial similarity ...
[11]
None
### Summary of Borate Formation from https://saltworkconsultants.com/downloads/57%20Borates.pdf
[12]
Contributions of arid climate and hydrothermal fluid flow on ...
May 23, 2025 · Howlite forms fine-grained milky to white aggregates, nodular masses or wormlike bodies within clay-rich groundmass. It forms along the ...2 Geological Setting · 4.1 Depositional... · 5.1 Depositional...<|control11|><|separator|>
[13]
[PDF] HOWLITE AND UTEXITE FROM THE CARBONIFEROUS GYPSUM ...
The howlite is believed to have been formed from a gel; the formation of the borates was contempo- ran€ous with the precipitation of calcium sulphate. Borate ...
[14]
[PDF] Geology of the Monte Blanco Borate Deposits, Furnace Creek Wash ...
The howlite commonly occurs as a white mineral that has a satiny micaceous sheen on fresh surfaces. It has roughly columnar structure developed ...
[15]
[PDF] Howlite Ca2B5SiO9(OH)5
Distribution: In Canada, near Windsor; at Wentworth; large crystals on the shore of Bras. D'Or Lake, 2.5 km south of Iona, Cape Breton Island, Nova Scotia.
[16]
The Mineralogy of Nova Scotia - Howlite
Howlite has since been found throughout the deposits that were formed by the Windsor Sea. It has been reported from Cape Breton (Dingwall and Iona), ...<|control11|><|separator|>
[17]
None
Nothing is retrieved...<|control11|><|separator|>
[18]
Canada's Boron One to refurbish Pobrdje colemanite mine in Serbia
May 7, 2025 · The boron bearing minerals found at Pobrdje include primarily colemanite with minor howlite. The Piskanja Project is a boron deposit with a ...Missing: Boronik | Show results with:Boronik
[19]
https://pubs.usgs.gov/pp/0440y/report.pdf
[20]
[PDF] Data of Geochemistry - USGS Publications Warehouse
This is the sixth edition of 'Data of Geochemistry', covering topics like chemical elements, Earth's composition, and marine evaporites.<|separator|>
[21]
https://www.mindat.org/loc-28183.html
[22]
Howlite Value, Price, and Jewelry Information
Jul 1, 2018 · Howlite is frequently dyed blue to resemble turquoise, and it makes a most convincing simulant. The white material is relatively unexciting in ...
[23]
Turquoise Howlite : Properties, Formation, Uses, Locations
Jul 1, 2024 · Ornamental Use: In addition to jewelry making, Turquoise Howlite is also popular for ornamental use in sculptures, carvings, and decorative ...
[24]
How to Care for Howlite? - Rock Identifier
Howlite should not be submerged in water or exposed to intense light and heat due to the risk of structural weakening, discoloration, and possible damage.Missing: instructions solubility
[25]
Howlite Gemstone Information: Your Essential Guide
### Summary of Howlite Uses Beyond Jewelry
[26]
Process for the preparation of boric acid from colemanite and/or ...
In that method treats minerals containing calcium borate, such as colemanite and howlite, are treated to recover useful boron compounds from said minerals.
[27]
https://www.wirejewelry.com/jewelry_making_articles/Gem-Profile--Howlite_234.html
[28]
Gemstone - Howlite, its Meaning, History and Uses - MYKU
Howlite is believed to open attunement and prepare the mind to receive wisdom. Howlite absords your anger and any that is directed toward you. Howlite ...
[29]
https://www.fluomin.org/uk/fiche.php?id=400
[30]
Howlite
Longwave UV (365nm) colors: Orange , Bluish White ,. Shortwave UV (254nm) colors: Orange , Bluish White ,. Do you have a photo of this mineral you would like ...
[31]
Dyed Howlite and Magnesite - The Turquoise Impostors
Most likely it is one of two other minerals, howlite or magnesite, that have been skillfully dyed to colors so similar to turquoise that it fools almost ...
[32]
https://jiehonggem.com/howlite-dyed-treatment-imitation-turquoise/
[33]
Howlite, Imitation Turquoise, dyed treatment. - Jie Hong Gem
Sep 23, 2022 · Howlite, white color with gray or black veining, is a natural gemstone that promotes peace and clarity. Ideal for stress relief, ...
[34]
Complete Buyer's Guide for Howlite Gemstone
Aug 5, 2020 · Howlite is a borate mineral found in the evaporite deposits. This versatile gemstone has the texture of unglazed porcelain and is usually found in irregularly ...
[35]
https://rockseeker.com/magnesite-vs-howlite/
[36]
Magnesite VS Howlite - How to Tell Them Apart - Rock Seeker
When tested, magnesite will show a RI of 1.509-1.700, and howlite will show 1.583-1.608. Hydrochloric Acid Test. For this test, you'll need a couple of spare ...
[37]
Fake Turquoise ID - is it Howlite, Magnesite, plastic, resin, or real?!
A few simple ways to identify fake Turquoise pieces, one of the most faked stones sold online today. Is it Turquoise, Magnesite, Howlite, resin, or plastic?Missing: marble | Show results with:marble
[38]
https://www.gemexi.com/blog/healing-crystals/how-to-differentiate-between-turquoise-and-dyed-howlite
[39]
https://www.thebeadtraders.com/blogs/news/identify-authentic-natural-stone-beads-testing-guide
[40]
https://www.gia.edu/gem-treatment
[41]
An Introduction to Gem Treatments - GIA
A guide describing frequently encountered gem treatment processes, their detection, and special care tips for treated gems.Surface Coating · Fracture Or Cavity Filling · Heat Treatment
[42]
Turquoise vs Howlite: Key Differences, Identification & Buying Tips
Apr 9, 2025 · ... Egypt, El Salvador, Equatorial Guinea, Estonia, Falkland Islands, Faroe ... Many jewelry pieces labeled as turquoise are actually dyed howlite.
[43]
Magnesite, Howlite & Turquoise
Aug 20, 2021 · Especially in the 60s to 90s of the last century large quantities of these fake turquoises were offered. After the deposits dried up, genuine ...
[44]
Turquoise History - Durango Silver Company
Chinese manufacturers found Magnisite, Howlite and a few other types of white chalk and began dying them and then stabilizing them with plastic resins to make ...
[45]
The Best Turquoise Is More Valuable Than Diamonds | HowStuffWorks
only about 100 pounds was mined before the deposit completely ran out in the 1970s.