Pyrometric cone
A pyrometric cone is a small, pyramid-shaped ceramic device designed to measure heatwork—the combined effect of temperature and time—during the firing of ceramic materials in a kiln.[1] These cones, composed of precisely formulated mixtures of ceramic materials and minerals, deform or bend at specific points to indicate when the desired heatwork has been achieved, ensuring consistent results in pottery, porcelain, and industrial ceramic production.[2] Unlike simple thermometers that only record temperature, pyrometric cones account for the rate of heating and soaking time, providing a more accurate gauge of the kiln's overall performance.[3] The mechanism of pyrometric cones relies on the controlled melting and softening of their ceramic composition under heat and gravity. As the kiln temperature rises, the cone's material reaches a low-viscosity state, causing it to bend forward until it tips over, typically at an angle of about 90 degrees from vertical when fully matured.[1] This deformation occurs over a narrow temperature range, often the last 100°C (180°F) of firing, and varies slightly with the heating rate—for instance, faster ramps may cause bending at slightly higher temperatures.[1] Cones are available in numbered series, from low-fire (e.g., cone 022 at around 600°C or 1112°F) to high-fire (e.g., cone 10 at over 1300°C or 2380°F), with equivalents depending on the firing schedule.[2] The development of pyrometric cones traces back to the late 19th century, pioneered by German chemist Hermann August Seger, who created the first prototypes in 1886 to control porcelain firings at the Royal Porcelain Factory in Berlin.[2] Seger studied the melt dynamics of oxide compounds to formulate cones that deformed predictably, establishing a standardized system for heat measurement in ceramics.[2] In the United States, Edward Orton Jr. advanced this technology by founding the Standard Pyrometric Cone Company in 1896, which evolved into the Edward Orton Jr. Ceramic Foundation, the primary manufacturer of these devices today.[1] Orton's work standardized cone production and distribution, making them essential tools worldwide for kiln monitoring since the early 20th century.[2] In practice, pyrometric cones are placed inside the kiln at various locations—such as the top, middle, and bottom shelves—to verify uniform heat distribution and calibrate electronic controllers.[1] They come in types like large cones for visual observation through kiln peepholes, self-supporting cones for easier placement, and small cones for automatic kiln shutoff devices.[2] Users interpret results by comparing the bend angle to a template, with a 25-75 degree deformation indicating optimal maturity, helping potters achieve reliable glaze and clay body outcomes while identifying hot or cold spots in the kiln.[1] Even with modern digital pyrometers, cones remain a vital, low-cost method for quality assurance in both hobbyist and industrial settings.[3]Fundamentals
Definition
Pyrometric cones are slender, pyramid-shaped ceramic indicators that deform under heat to gauge the combined effects of temperature and time, collectively known as heatwork, during kiln firing processes.[4] These devices provide a visual measure of the total thermal energy absorbed by materials in the kiln, responding in a manner similar to the clay bodies and glazes being fired.[3] Developed with precisely controlled ceramic compositions, they bend and soften progressively as heatwork accumulates, serving as reliable witnesses to firing conditions.[2] In ceramics, pyrometric cones fulfill a primary role by ensuring the consistent maturation of clay bodies and glazes, which is essential for achieving desired physical properties such as strength, vitrification, and surface finish.[5] By indicating when sufficient heatwork has been applied, they help potters and manufacturers avoid underfiring or overfiring, thereby promoting uniformity across batches without the need for direct temperature monitoring.[4] This approach prioritizes the functional outcome of the firing over isolated temperature readings, as maturation depends on the integrated exposure rather than peak heat alone.[3] Distinct from pyrometers, which record instantaneous temperature via thermocouples or other sensors, pyrometric cones measure cumulative heat exposure, accounting for both the rate of heating and soak time.[2] Physically, they feature a triangular base and stand approximately 2 to 3 inches tall, with the standard large cones measuring about 2½ inches in height to allow gravity to influence deformation effectively.[5] Cones are typically deployed in sets, often as a trio including a guide (lower temperature), target (desired heatwork), and guard (higher temperature) cone, enabling progressive monitoring of the firing schedule.[3]Composition and Materials
Pyrometric cones are formulated from approximately 100 unique mixtures of ceramic oxides designed to deform at specific temperatures, primarily consisting of silica (SiO₂) as the primary glass former, alumina (Al₂O₃) for structural stability, fluxes such as feldspar to promote melting, and minor additives including lime (from whiting) or magnesia for fine-tuning viscosity.[6][7] These compositions mimic those of ceramic glazes, ensuring predictable softening without excessive liquidity. The key to their functionality lies in the formation of a glass phase during heating, where fluxes lower the melting point of silica, enabling a controlled viscous flow at targeted temperatures rather than abrupt fusion.[7] This glassy matrix, often incorporating a pre-formed glass component in the mix, allows the cone material to bend under gravity when sufficient heatwork is achieved, providing a reliable indicator of firing maturity.[6] Manufacturing involves precise batching of these oxide mixtures, followed by extrusion into pyramidal shapes to ensure uniformity in density and dimensions, a process overseen by organizations like the Edward Orton Jr. Ceramic Foundation.[8] Batches are rigorously tested against standards through sampling and controlled firings to maintain consistency across production.[8] While self-supporting cones feature a wider, integrated base for standalone placement on kiln shelves, and tripod-dependent (large) cones require external holders for support, both types share the identical core composition, differing only in structural design to facilitate observation.[9]Principles of Operation
Mechanism of Deformation
The deformation of pyrometric cones involves a progressive physical process driven by viscous flow under gravity, where the cone transitions from a rigid structure to a softened form that bends in response to accumulated heatwork. The sequence begins with the cone standing upright at 0% deformation, as its ceramic composition remains solid below the softening point. As temperature rises, the glassy matrix within the cone starts to soften and slump slightly, followed by bending that initiates at the tip—where temperatures are highest due to thermal gradients—before propagating downward along the cone's length. This continues until the tip reaches a 90-degree angle relative to the base, marking full deformation at 100% bend when the designated heatwork threshold is achieved.[10][11] Central to this mechanism is the role of viscosity in the cone's glassy phase, which decreases as heatwork integrates time and temperature to enable flow. At the deformation threshold, the effective viscosity of the partially molten material reaches the Littleton softening point of approximately $10^{7.6} poise, allowing the solid particles to suspend in the liquid phase and deform under gravitational stress without fracturing. This viscosity, calculated via models like the Einstein-Roscoe equation for two-phase mixtures, reflects the dissolution of crystalline components into the melt, creating a flowable matrix that responds predictably to heat exposure.[10] The influence of time on deformation arises from the viscous nature of the flow, where slower heating rates provide extended periods for the material to reach the critical viscosity at lower peak temperatures, shifting the bend point downward compared to rapid firings. Conversely, faster heating compresses the time available for flow, requiring higher temperatures to achieve the same deformation due to thermal lag effects. Visual indicators track this progression: an upright cone signifies insufficient heatwork, partial slumping or "down" positions (e.g., 20–80% bent) indicate intermediate stages, and a fully "flat" cone at 90 degrees confirms completion.[10][11]Heatwork Measurement
Heatwork refers to the cumulative thermal energy imparted to ceramic materials during firing, representing the integrated effect of temperature and time rather than peak temperature alone. This concept captures how prolonged exposure at lower temperatures can achieve equivalent results to shorter durations at higher temperatures, as the total heat input determines material maturation. Pyrometric cones provide a practical measure of heatwork by deforming when this cumulative energy reaches a calibrated threshold specific to their composition.[1][10] Unlike pyrometers or thermocouples, which record only instantaneous or peak temperatures and overlook factors such as heating ramp rates, soak times, and even cooling phases, pyrometric cones integrate these variables into a single observable indicator. For instance, a slower ramp allows more time at intermediate temperatures, increasing overall heatwork and causing a cone to bend at a lower final temperature than under rapid heating. This makes cones particularly valuable in non-uniform kiln environments, where temperature gradients can lead to inconsistent results if relying solely on electronic sensors.[3][12] Pyrometric cones are empirically calibrated to represent real-world firing variability, typically under standard conditions such as a 60°C per hour heating rate over the final 100°C of the schedule. This calibration ensures that cone deformation correlates with the heatwork needed for specific clay and glaze maturations, with manufacturers providing temperature equivalence charts adjusted for common ramp rates (e.g., 15°C/hr for slow firings or 150°C/hr for fast ones). Soak periods at peak temperature further accumulate heatwork, often equivalent to advancing one or two cone numbers per hour of hold.[1][12] Despite their effectiveness, pyrometric cones are not direct thermometers; their bending signals the maturity point for particular material formulations rather than an absolute temperature reading, and results can vary slightly with kiln atmosphere or non-standard ramps. This empirical nature underscores their role as a complementary tool to digital controls, ensuring reliable outcomes across diverse firing scenarios.[3][10]Practical Usage
Placement and Observation
Pyrometric cones are positioned within the kiln to ensure accurate monitoring of heatwork, typically on kiln shelves near the ware being fired, where they can be viewed through peepholes to avoid interference from drafts or direct flame contact.[13] Sets of three cones—known as the guide (one temperature rating lower than the target), the target (or firing cone, at the desired heatwork), and the guard (one rating higher)—are arranged in a row, spaced approximately 2 to 3 inches apart to prevent interference during bending, with the target cone in the center.[5] For optimal visibility, cones should be placed at eye level on the shelf, and multiple sets may be used across different shelves to assess kiln uniformity.[14] Observation occurs primarily through visual checks via kiln peepholes during firing, using protective welder's glasses to safely monitor the bending process without opening the kiln door.[5] Self-supporting cones, which stand upright without additional holders, facilitate easier viewing as they maintain their position until deformation begins.[13] Post-firing inspection allows for confirmation of the cones' final positions, providing a record of the achieved heatwork.[11] In modern kilns equipped with digital controllers and pyrometers, pyrometric cones serve as a critical backup for verification, detecting discrepancies in temperature readings that may arise from thermocouple inaccuracies, such as errors exceeding 25°F at higher cone temperatures.[13] This integration ensures reliable heatwork assessment beyond mere temperature control.[11] For safety and stability, non-self-supporting cones are prepared by packing their bases into a small pat of clay or using dedicated stands to prevent tipping during firing, while all cones must be positioned away from direct flame paths to avoid premature or uneven deformation.[15] Proper preparation includes ensuring the kiln is loaded with adequate airflow around the cones and ware to promote even heating.[13]Interpreting Results
Interpreting the deformation of pyrometric cones provides a direct assessment of the heatwork achieved during a firing, which combines the effects of temperature and time. The extent of bending indicates whether the target heatwork for maturing specific clays or glazes has been reached. Cones are typically observed after cooling, using a measurement template to quantify the angular deformation from the original position. A deformation between 25° and 75° from the vertical—corresponding to the tip reaching roughly the 4 to 6 o'clock position—signals appropriate heatwork for the firing profile, while deviations require adjustments to future schedules.[1] The standard endpoint for cone bending is defined as a 90° angular deformation from the cone's initial slight lean (about 8° from vertical), where the tip points toward the 5 o'clock position without fully touching the base for self-supporting cones. Partial bends, such as 45° from vertical (around the 3 o'clock position), indicate underfiring, meaning insufficient heatwork has been applied, potentially leaving clay or glazes immature. In contrast, a full 90° bend confirms the target heatwork, ensuring optimal results for the intended materials.[2][16] Troubleshooting firing inconsistencies relies on observing multiple cones placed strategically within the kiln. An upright target cone suggests underfiring, while one that has melted into a puddle denotes overfiring, where excessive heatwork has been delivered. Using a set of three cones—a guide cone (lower number, bends first if underheated), the target firing cone, and a guard cone (higher number, bends if overheated)—helps identify imbalances. Variations across placements, such as greater bending at the kiln's top or back, reveal hot spots, allowing users to map temperature gradients and refine loading or controller settings.[1][11] Post-firing analysis involves comparing observed cone behaviors to expected outcomes for the specific clay body or glaze maturity. If the target cone shows partial bending, the firing schedule can be adjusted by extending the soak time or increasing the peak temperature slightly; conversely, overfiring prompts reductions in ramp rate or hold duration to prevent defects like glaze running. These evaluations ensure consistent material performance across repeated firings.[1] For repeatable results in studio or industrial settings, documentation of cone deformations is essential, including notes on heating rates, soak times, and positions relative to kiln zones. Recording these details facilitates predictive adjustments, such as shifting the target cone number by 1-2 for a one-hour soak, enhancing process control and reducing variability.[1][11]Factors Influencing Performance
Variability Control
Pyrometric cones can exhibit variability due to differences between manufacturing batches and inherent tolerances in production processes, such as variations in raw material composition or forming techniques.[1] These inconsistencies may lead to slight differences in deformation temperatures, potentially affecting heatwork measurements in ceramic firings. To mitigate such issues, manufacturers adhere to international standards like ISO 1146:1988, which specifies the characteristics of standard pyrometric reference cones, including their dimensions, composition, and performance criteria for laboratory use, ensuring reproducibility across production runs.[17] Users can further control variability by implementing consistent firing schedules that match the heating rates used in cone calibration, such as maintaining rates between 108°F/hr and 540°F/hr to align with standard equivalence data.[8] Proper storage in dry conditions prevents moisture absorption, which could alter cone viscosity and bending behavior, while periodic testing against known reference cones—such as placing guide (cooler) and guard (hotter) cones alongside the target—verifies performance and detects any drift in kiln conditions.[11] The Edward Orton Jr. Ceramic Foundation plays a key role in reducing errors by producing certified pyrometric cones that meet rigorous quality benchmarks and providing equivalence charts, which convert cone bending angles to temperature equivalents based on known heating rates, enabling accurate selection and interpretation.[1] These resources promote uniformity by allowing users to cross-reference results from different cone series or manufacturers. Quality assurance in cone production involves the use of witness cones during test firings to verify batch uniformity, ensuring that each set deforms predictably under controlled heatwork conditions and maintaining the high reproducibility for which Orton cones are known.[1] This practice, combined with dry-pressing methods that minimize forming variations, results in cones with enhanced green strength and consistent performance across applications.[8]Environmental Effects
The behavior of pyrometric cones is notably influenced by the kiln atmosphere, particularly in reducing conditions characterized by excess carbon monoxide (CO). In such environments, cones typically mature at lower temperatures than in oxidizing atmospheres because the organic binders and materials cannot fully oxidize, resulting in black coring and potential bloating that alters deformation.[18] This effect stems from the reduced oxygen availability, which impacts the cone's internal composition and softening process.[19] Sulfurous atmospheres or those containing alkali vapors can further modify cone performance, often in contrasting ways depending on the cone's composition. Sulfur exposure, common in certain gas firings, causes iron-containing cones (typically numbers 010 to 3) to form a rigid outer shell over a softened interior, delaying deformation and requiring higher temperatures for bending.[18] Conversely, alkali vapors, such as those from sodium in specialized firings, act as fluxes that accelerate melting and cause premature bending.[19] Heating rates also play a critical role through thermal lag, where rapid temperature increases—such as rates exceeding 300°C per hour—prevent the cone from heating uniformly, delaying its bending and necessitating higher peak temperatures to achieve the same heatwork.[5] Slower ramps allow more even heat absorption, leading to earlier deformation at lower temperatures.[20] Kiln type contributes to variability as well: electric kilns provide more uniform oxidizing conditions, while gas kilns often exhibit localized reducing zones and less consistency. Placement within the kiln exacerbates this, with cones in hotter zones bending 1-2 cones earlier than those in cooler areas due to temperature gradients.[13] To mitigate these environmental effects, users should select atmosphere-specific cone sets, such as iron-free variants for reducing or sulfurous conditions to avoid shelling and ensure accurate results.[18] Additionally, adjusting firing schedules—such as incorporating slower ramps or protective placements away from drafts and flames—helps compensate for thermal lag and zonal differences, maintaining reliable heatwork measurement.[19]Historical Development
Origins and Invention
The control of ceramic firing processes has ancient roots, with potters relying on empirical observations such as the color of the flame, the sound of the ware, and the appearance of test pieces to gauge heat levels and avoid failures like cracking or incomplete vitrification.[21] These methods, while effective for small-scale production, lacked precision and standardization, particularly as ceramic manufacturing scaled up during the Industrial Revolution. In the late 18th century, English potter and industrialist Josiah Wedgwood advanced this field by inventing a pyrometric device in the early 1780s to measure high temperatures beyond the range of mercury thermometers.[22] Wedgwood's gauge used the measurable shrinkage of specially prepared clay pieces—doped with iron oxide for consistent behavior—fired alongside production ware; the degree of contraction, read against a brass scale, provided a proxy for temperature, with his 1782 paper on the subject earning him election to the Royal Society.[23] This innovation, known as the Wedgwood scale, served as a key precursor to later pyrometric tools by introducing quantifiable indicators for kiln conditions in industrial settings.[24] The modern pyrometric cone emerged in the late 19th century amid the rapid growth of Europe's ceramic industry, where inconsistent firing led to variable product quality in expanding factories producing porcelain and other wares. German ceramic chemist Hermann August Seger (1839–1893), director of the chemical-technical laboratory at the Royal Porcelain Factory in Berlin, invented the first pyrometric cones in 1886 to address these challenges. Seger formulated a series of oxide-based mixtures with progressively higher melting points, shaped into small pyramids with triangular bases that would soften and bend under combined heat and time exposure, providing a visual indicator of "heatwork" tailored to porcelain firing control.[25] His work built on empirical traditions and Wedgwood's shrinkage principles but shifted focus to deformation as a more reliable metric for process standardization.[26] Seger's cones were initially developed to ensure uniform maturation of glazes and bodies in industrial kilns, enabling chemists and manufacturers to replicate successful firings without direct temperature measurement, which was then imprecise at high ranges.[25] By the late 1880s, they gained traction in European porcelain and brick factories, where their placement in kilns allowed for consistent quality amid increasing production demands; translations of Seger's writings by organizations like the American Ceramic Society further promoted their use across the continent.[26] This early adoption marked a pivotal step in transforming ceramics from artisanal craft to scientifically managed industry.[25]Standardization and Evolution
Edward Orton Jr. played a pivotal role in standardizing pyrometric cones in the United States by founding the Standard Pyrometric Cone Company in 1896 to manufacture these devices, ensuring consistent production and availability for ceramic firing control.[27][28] Following his death in 1932, the Edward Orton Jr. Ceramic Foundation was established as a not-for-profit entity dedicated to advancing ceramic research and development, with proceeds from cone sales funding ongoing innovations in high-temperature materials processing.[27][28] Key advancements in the 20th century included the development of self-supporting cones by Orton engineers to minimize inconsistencies from manual mounting, providing more reliable deformation observation during firings.[11] By the mid-20th century, the cone range had expanded significantly to cover low-fire applications starting at cone 022—composed of soda-lead borosilicate glass for visible incandescence—and high-fire up to cone 42, made from pure aluminum oxide, accommodating diverse ceramic processes from bisque to refractory testing.[8][29] For international consistency, Orton cones were designed to align closely with the earlier Seger cone system, with equivalent numbering and deformation behaviors facilitating global adoption in ceramic industries, particularly in Europe where Seger cones originated.[2][30] This alignment supported the adoption of ISO 528 standards for determining pyrometric cone equivalents in refractory materials, with Orton achieving certification for manufacturing precision and traceability to National Bureau of Standards benchmarks established in 1956, enhancing global reliability since the 1980s.[8][31] Recent developments through 2025 have integrated pyrometric cones with digital kiln controllers, where programs simulate cone-equivalent heatwork schedules to automate firings while using witness cones for verification, ensuring accuracy despite thermocouple drift.[32][1] Orton has also refined cone formulations and provided atmosphere-specific charts to account for variations in alternative fuels like gas and wood, which introduce reducing conditions that accelerate deformation compared to oxidizing electric kilns.[18][8]Applications
In Ceramic Arts
In studio pottery, artists rely on pyrometric cones to control firing outcomes, targeting specific cones such as cone 6 for mid-range temperatures to achieve optimal vitrification in clay bodies and desired effects in glazes, like glossy finishes or color development.[3] These cones serve as visual indicators placed within the kiln, allowing potters to monitor heatwork and adjust firing schedules manually, ensuring pieces mature without over- or under-firing that could lead to cracking or weak structures.[33] In educational settings, pyrometric cones play a key role in art schools and workshops, teaching students the concept of heatwork as the combined effect of time and temperature on ceramic materials, rather than relying solely on kiln thermostats.[34] Their affordability and simplicity make them ideal for beginners, providing a hands-on, visual method to observe firing progression and understand how subtle variations influence final results. In artistic techniques like wood firing, cones are packed in multiple locations to account for kiln zones, where intentional variability contributes to aesthetic qualities such as ash glazing and natural flashing on surfaces.[35] As of 2025, while hobbyist kiln controllers have become more integrated with digital programming for precise ramps, pyrometric cones remain essential for verifying maturity through direct observation, often called "eyeballing" the bend to fine-tune artistic firings beyond automated settings.[36] This hybrid approach allows small-scale artists to blend technology with traditional judgment, maintaining creative control in variable environments like raku or atmospheric kilns.[33]Industrial and Scientific Uses
Pyrometric cones play a critical role in industrial ceramics manufacturing, particularly for quality control in the production of tiles, bricks, and sanitaryware. These devices are placed within large-scale kilns to monitor heatwork—the integrated effect of temperature and time on ceramic materials—ensuring consistent firing conditions that prevent defects such as warping, cracking, or underfiring. By deforming at predetermined points, cones verify that the kiln delivers uniform thermal energy across batches, allowing operators to adjust processes in real-time or post-firing to maintain product standards. In high-volume operations, cones are strategically positioned at multiple locations within the kiln to detect hot or cold spots, supporting reproducible outcomes essential for commercial scalability.[1][37] In scientific and research contexts, pyrometric cones are utilized to evaluate new materials and refine firing protocols. Researchers determine the pyrometric cone equivalent (PCE) of experimental ceramics by observing cone deformation alongside sample behavior, which helps assess softening points and thermal stability under controlled conditions. Cones also calibrate pyrometers by providing a reference for heatwork in laboratory furnaces, ensuring accurate temperature measurements during tests that simulate industrial atmospheres, such as varying humidity or gas compositions. This application supports advancements in refractory and advanced ceramics development, where precise heat exposure is vital for material innovation.[38][39][40] As of 2025, alternatives like digital thermocouples and programmable controllers—such as Bartlett models—provide precise ramp-and-hold temperature management in industrial kilns, reducing manual oversight and enabling automated firing schedules. However, these systems measure instantaneous temperature rather than cumulative heatwork, making pyrometric cones indispensable for validation, especially in variable environments. Hybrid approaches integrate digital controllers with cone packs for comprehensive monitoring, where controllers handle primary operation and cones confirm endpoint accuracy, minimizing discrepancies from kiln drift.[32][41][11] The economic benefits of pyrometric cones in the ceramics sector are significant, as routine use detects inconsistencies early, reducing scrap rates and energy waste in production lines. Suppliers like the Edward Orton Jr. Ceramic Foundation provide these tools globally to manufacturers, with the low cost of cones yielding substantial returns through improved yield and quality assurance in tile, brick, and sanitaryware facilities.[1][11][37]Types and Temperature Equivalents
Cone Numbering System
The pyrometric cone numbering system provides a standardized method to indicate the heatwork required for ceramic firings, with cone numbers ranging from 022 to 42. Lower numbers, such as 022, correspond to lower firing temperatures suitable for low-fire applications, while higher numbers, like 42, denote progressively higher temperatures for high-fire processes. The system distinguishes low-fire cones with three-digit designations beginning with 0 (e.g., 022 to 01), which are used for temperatures below approximately 1100°C, from single- or two-digit high-fire cones (e.g., 1 to 42) that extend to over 2000°C. This convention originated from adaptations of earlier systems but has been refined for practical use in modern kilns.[1] Orton cones represent the standard in the United States, produced by the Edward Orton Jr. Ceramic Foundation, while Seger cones serve as the European equivalent, both sharing similar numbering but with historical differences in sequence—Seger originally numbered from high (10) to low (1), later aligned with Orton's reversed low-to-high progression for the 0XX series. Alternative compositions, such as those under the Peterson system, offer variations in formulation for specific testing needs, though Orton and Seger remain the most widely adopted. Junior cones, smaller in size, are designed for use in compact or hobbyist kilns where space is limited, maintaining the same numbering for consistency. Pyramids constitute the primary shape across these types, ensuring reliable bending behavior.[1][42] Selection of the appropriate cone number depends on matching the heatwork to the specific requirements of clays and glazes, ensuring optimal maturation without under- or over-firing. Cone sets typically include a witness cone to verify actual heatwork achieved, a firing cone as the target for the desired endpoint, and a dropout cone (one number higher) to signal potential overfiring if it begins to bend. Non-standard variants, such as pyrometric bars or plaques, provide alternatives for specialized tests like uniformity checks in large industrial kilns, but the traditional pyramid cones remain the primary tool due to their precision and ease of observation.[1][43]Comparative Temperature Ranges
Pyrometric cones provide a standardized measure of heatwork in ceramic firings, with temperature equivalents varying by cone number under controlled conditions of a 150°C per hour ramp rate in an oxidizing (air) atmosphere using Orton self-supporting cones. Representative examples include cone 022 bending at approximately 600°C (1112°F), cone 04 at 1063°C (1945°F), cone 6 at 1243°C (2269°F), and cone 10 at 1284°C (2345°F); these values indicate the point where the cone tip touches the base after deformation over 15-25 minutes. Higher cones, such as cone 42, reach up to 2015°C (3659°F) for refractory testing, while the relationship between cone numbers and temperatures is non-linear, with progressively larger intervals at higher temperatures to account for increasing heatwork demands.[44][8] Variations in firing parameters significantly affect these equivalents, as cones measure cumulative heatwork rather than peak temperature alone. At faster ramp rates, such as 270°C per hour, cones require higher temperatures to bend compared to slower rates of 60°C per hour; for example, cone 6 deforms at about 1243°C under fast conditions versus 1221°C under slow ones. In reducing atmospheres, iron-containing cones (common in numbers 010 to 3) may bend 20-50°C earlier due to compositional changes, necessitating the use of iron-free variants for accurate results in gas-fired kilns. Soaking times also influence outcomes, with 1-2 hours potentially advancing the next higher cone by one position.[45][8] The following table summarizes temperature ranges for selected common cones under varying ramp rates in an oxidizing atmosphere, using Orton self-supporting cones (approximate values; consult manufacturer charts for precise applications):| Cone Number | Slow Ramp (60°C/hr) °C (°F) | Standard Ramp (150°C/hr) °C (°F) | Fast Ramp (270°C/hr) °C (°F) |
|---|---|---|---|
| 022 | 585 (1085) | 600 (1112) | 630 (1166) |
| 04 | 1046 (1915) | 1063 (1945) | 1076 (1971) |
| 6 | 1221 (2232) | 1243 (2269) | 1264 (2307) |
| 10 | 1259 (2298) | 1284 (2345) | 1300 (2372) |
| 14 | 1410 (2570) | 1450 (2642) | 1490 (2714) |