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White oil

White oil is a horticultural insecticide spray used to control a wide range of soft-bodied garden pests, such as aphids, mites, scale, and mealybugs, by smothering them through blockage of their breathing pores (spiracles).^[1] It is derived from highly refined mineral oils, specifically paraffinic petroleum distillates that are colorless, odorless, and low in toxicity to plants and beneficial insects when properly formulated and applied.^[2] These oils are produced by distilling crude petroleum to obtain base stocks, followed by refining processes like hydrotreating and filtration to remove impurities such as aromatics and sulfur, ensuring suitability for plant application without phytotoxicity.^[3] Horticultural grades are typically emulsified with surfactants for dilution in water (e.g., 1-2% solutions) and applied during cool periods to avoid leaf burn.^[4] While highly refined white mineral oils have broader applications in industry, pharmaceuticals, and cosmetics, in gardening contexts, white oil specifically refers to these pesticide formulations.

Definition and History

Definition

In a horticultural context, white oil refers to an insecticide emulsion used primarily in gardening to control soft-bodied insect pests such as aphids, mites, and scales by smothering them through blockage of their breathing pores.^[5]^[6] It consists of an oil base—either highly refined mineral oil or vegetable oil—emulsified with a surfactant, typically dish soap, and diluted in water for application as a spray. Commercial formulations often use USP-grade mineral white oil for its purity and stability, while do-it-yourself versions commonly employ vegetable oils such as canola or sunflower oil.^[3]^[7] This formulation exhibits general properties that make it suitable for home and organic use: it is non-toxic to humans and pets when applied as directed, biodegradable (especially vegetable-based versions due to their natural components), and approved for organic farming practices as it avoids synthetic chemicals.^[8]^[6]^[9] The term "white oil" can vary by region and source; it often refers to traditional vegetable oil-based emulsions for DIY pest control, while in some contexts, it specifically denotes refined mineral oil products. It is distinguished within the broader category of horticultural oils, which include both mineral and plant-based options designed for similar pest control with varying viscosities and application timings.^[10]^[11]

History

The use of oils and soaps for pest control dates back to ancient civilizations. In China around 1100 A.D., soaps were employed to manage insect pests on crops.^[2] Similarly, in Rome circa 200 B.C., the statesman Cato the Elder recommended oil sprays, including mixtures of oil and ash, to protect fruit trees from insects.^[11] Advancements in the 19th century marked the transition to more systematic applications in the United States. By the 1880s, kerosene-soap emulsions were introduced as effective treatments for aphids and other soft-bodied pests on fruit trees, representing one of the earliest uses of petroleum-derived products in horticulture.^[12] These emulsions gained recognition for their efficacy against scale insects and other pests by 1890, as documented in early entomological reports.^[13] The early 20th century saw refinements in oil formulations, particularly the development of dormant oils applied during winter to target overwintering pests like eggs and nymphs on deciduous trees, minimizing harm to actively growing foliage.^[14] However, heavier oils often caused phytotoxicity, leading to a mid-20th-century shift toward lighter, more refined summer oils through improved distillation techniques that reduced impurities and plant damage.^[15] In the late 20th century, the rise of organic gardening practices promoted vegetable-based white oil recipes as accessible, non-petroleum alternatives for home gardeners, emphasizing their role in sustainable pest management without synthetic chemicals.^[11]

Composition and Types

Composition

White oil, also known as horticultural oil, primarily consists of a base oil that forms the active component of the emulsion, typically diluted to a 1-2% concentration for application. The base is either highly refined mineral oil derived from petroleum distillates or plant-derived vegetable oils such as canola, sunflower, cottonseed, or soybean oil.^[16]^[17] Mineral oils are the most common, comprising paraffinic hydrocarbons with carbon chain lengths of 16 to 32 atoms, ensuring low volatility and stability.^[18] To enable mixing with water and form a stable sprayable emulsion, white oil includes an emulsifier, which breaks the oil into fine droplets that remain suspended. Common emulsifiers in homemade formulations are natural soaps like potash-based or pure liquid castile soap, while commercial products use surfactants such as potassium salts of fatty acids or other approved mixing agents.^[2]^[19] Water serves as the primary diluent and carrier, comprising the bulk of the final emulsion to facilitate even application on plants.^[11] Purity variations in white oil are critical to minimize phytotoxicity, measured by the unsulfonated residue (UR) level, which indicates the percentage of saturated hydrocarbons remaining after refining. Summer-use oils typically have a UR greater than 90% (often 92-99%), reducing the risk of plant damage compared to dormant oils with lower UR (50-90%).^[20]^[15] Formulations contain no synthetic active chemicals, making them compatible with organic standards when using approved ingredients like mineral or vegetable oils with natural emulsifiers.^[21]

Types of Horticultural Oils

Horticultural oils, commonly referred to as white oils in some contexts, are classified into several types based on their degree of refinement, viscosity, and suitability for specific plant growth stages. This classification primarily revolves around mineral oil-based variants derived from petroleum, which are distinguished by their unsulfonated residue (USR) content—a measure of purity that indicates the proportion of oil not reacting with sulfuric acid, directly influencing phytotoxicity and efficacy. Less refined oils with lower USR percentages are suited for dormant applications, while highly refined ones enable safer use on actively growing foliage. Non-mineral alternatives and specialized versions further expand options for targeted pest management.^[15]^[22] Dormant oils represent the heavier, less refined category of horticultural oils, typically featuring 50-90% unsulfonated residues, which allows them to adhere longer to plant surfaces despite their coarser composition. These oils are designed for application during the plant's dormant period, such as late winter or early spring before bud break, when trees and shrubs lack leaves, reducing the risk of phytotoxicity. Applied at higher concentrations of 2-3%, dormant oils effectively smother overwintering eggs, scales, and mites by coating bark and twigs, penetrating crevices where pests hide. Their thicker viscosity enhances coverage on woody structures, making them ideal for broad-spectrum control of hibernating insects without harming leafless plants.^[22]^[2]^[23] In contrast, summer oils are lighter and more highly refined mineral oils, boasting over 92% unsulfonated residues—often exceeding 99% in superior formulations—to minimize plant damage while maintaining pesticidal properties. These oils are safe for use on actively growing plants with foliage, as their finer distillation removes impurities that could burn leaves or disrupt photosynthesis. Diluted to lower concentrations of 0.5-2%, summer oils provide contact control against soft-bodied pests like aphids and whiteflies without excessive residue, allowing repeated applications during the growing season. The high refinement level ensures better emulsification and even distribution when mixed with water, prioritizing plant safety alongside efficacy.^[22]^[24]^[25] Vegetable-based oils offer eco-friendly, non-petroleum alternatives to traditional mineral horticultural oils, commonly formulated as emulsions from sources like canola, soybean, or cottonseed oils, and frequently labeled as "white oil" in do-it-yourself gardening contexts. These plant-derived products break down more rapidly in the environment compared to mineral oils, enhancing biodegradability and reducing long-term soil accumulation. Approved for organic use by certifications such as OMRI, they provide similar smothering action against pests while aligning with sustainable practices, though they may require adjuvants for stability in sprays. Examples include neem or sesame oil blends, which maintain efficacy without the refining processes of mineral variants.^[2]^[26]^[27] Specialized formulations, such as ultra-fine or stylet oils, elevate refinement to over 99% unsulfonated residues, enabling versatile applications beyond standard insect control to include suppression of fungal pathogens like powdery mildew. These highly purified oils disrupt spore germination and mycelial growth by coating surfaces and altering moisture levels, while also targeting a wider array of mites and insects at low concentrations. Their narrow distillation range ensures minimal volatility and phytotoxicity, making them suitable for year-round use on sensitive crops, including vegetables and ornamentals, often in integrated pest management programs.^[22]^[2]^[16]

Preparation Methods

Homemade Recipes

White oil can be easily prepared at home using simple household ingredients, making it a practical option for gardeners seeking an organic pest control solution. The basic recipe begins with creating a concentrate by combining 1 cup of vegetable oil, such as canola or sunflower oil, with 1/4 cup of mild dish soap that contains no bleach, such as a pure liquid castile soap.^[6]^[28] Stir or shake the mixture vigorously in a jar until it turns milky white, indicating proper emulsification. To use, dilute 2-3 tablespoons of this concentrate in 1 gallon of water, then shake well before transferring to a spray container.^[6]^[29] Variations in the recipe allow for customization based on the season and plant condition to optimize effectiveness while minimizing damage. For dormant use on bare plants during late winter or early spring, increase the oil concentration to approximately 3-4% by using more concentrate per volume of water, which helps target overwintering eggs and pests more aggressively.^[30] In contrast, for summer applications on actively growing plants, reduce to a 1-2% concentration with less concentrate to avoid phytotoxicity and leaf burn, especially on sensitive foliage.^[30] The concentrate should be stored in a cool, dark place in a sealed container, where it remains usable for 1-2 months; always shake vigorously before diluting to re-emulsify the ingredients.^[6]^[29] Essential tools for preparation and use include a sealable jar for mixing the concentrate and a spray bottle or pump sprayer for even application.^[29] Before full application, test the diluted spray on a small, inconspicuous area of the plant and wait 24-48 hours to check for adverse reactions like discoloration or wilting.^[6] This DIY approach is highly cost-effective, requiring only inexpensive pantry staples to produce multiple batches, thereby enhancing accessibility to organic pest management for home gardeners.^[28]^[6]

Commercial Formulations

Commercial white oil products, also known as horticultural oils, are widely available as ready-to-use sprays or concentrates designed for pest control in gardens and orchards.^[31]^[32] Popular examples include Monterey Horticultural Oil, a mineral oil-based concentrate effective against soft-bodied insects on ornamentals, vegetables, and fruit trees, and Safer Brand Horticultural & Dormant Spray Oil, which targets over 94 insect species and 20 plant diseases across 131 crops.^[31]^[33] Other notable brands are Bonide All Seasons Horticultural Spray Oil, suitable for year-round use on deciduous and evergreen plants, and Southern Ag Parafine Horticultural Oil, formulated for scale, whiteflies, and mealybugs.^[34]^[35] These products are typically offered in emulsion or concentrate forms, with concentrates requiring dilution in water for application.^[2] Formulations of commercial white oils are pre-emulsified with stabilizers and emulsifiers to ensure even mixing with water and consistent coverage on plant surfaces.^[2] They generally contain 92% to 99% highly refined mineral oil, such as paraffinic oil at 98% concentration, along with minor additives for stability.^[2]^[35] Labels specify oil content and dilution rates, often ranging from 80% to 99% active ingredient to balance efficacy and plant safety.^[20] These commercial products offer advantages over homemade versions through standardized manufacturing, which ensures uniform quality and purity, reducing variability in effectiveness.^[2] They also provide extended shelf life due to refined processing and stabilization, often lasting several years when stored properly.^[31] Many are certified OMRI-listed for organic gardening, allowing use in certified organic production without synthetic additives.^[31]^[36] Commercial white oils are readily available at garden centers, hardware stores like Home Depot, and online retailers such as Amazon.^[37]^[33] Pricing typically ranges from $10 to $20 per quart for concentrates, depending on brand and volume, making them accessible for both home gardeners and commercial growers.^[35]^[38]

Mechanism of Action

How White Oil Works

White oil functions primarily as a physical insecticide through a smothering mechanism, where it coats the external surfaces of insects and eggs upon contact, blocking their spiracles—the small breathing pores—and causing asphyxiation, especially in soft-bodied pests.^[2] This mechanical action clogs respiratory systems and may involve secondary effects such as cell membrane disruption, though it primarily avoids chemical toxicity, reducing the risk of pest resistance development.^[39]^[2] The refined composition of white oil enables it to emulsify effectively, ensuring even coverage on plant surfaces for optimal pest contact.^[40] Beyond immediate suffocation, white oil disrupts insect life cycles by coating eggs to prevent hatching and targeting immature stages through coating and suffocation, while also coating protective coverings on certain pests like scales and mites, which leads to dehydration and death.^[23] These effects stem from the oil's ability to penetrate and alter surface barriers, halting normal physiological processes such as growth and reproduction.^[41] Operating strictly as a contact pesticide, white oil lacks systemic activity, meaning it does not translocate within the plant or require ingestion by pests to be effective; instead, its success hinges on comprehensive spray coverage to ensure direct exposure.^[41] Once the oil dries, it provides no residual protection, emphasizing the need for targeted application timing.^[2] Despite its efficacy, white oil has limitations, proving ineffective against hard-bodied insects with robust exoskeletons, as the oil cannot sufficiently block their respiration, though highly refined formulations can enhance penetration into waxy exteriors for broader utility.^[39]

Applications and Uses

Target Pests

White oil, a type of horticultural oil, primarily targets soft-bodied insects that lack protective hard exoskeletons, making them highly susceptible to smothering by the oil's film-forming action.^[26] Common examples include aphids, which feed on plant sap and cause distorted growth; whiteflies, small winged pests that transmit viruses; thrips, slender insects that rasp plant tissues; and mealybugs, waxy-covered sap-suckers that excrete honeydew.^[39] These pests are effectively controlled as the oil coats their bodies, blocking spiracles and preventing respiration.^[4] For pests with tougher coverings, white oil penetrates or dissolves protective layers to reach vulnerable stages. Armored scales, such as San Jose scale on fruit trees, and soft scales like oystershell scale are disrupted when the oil targets crawlers or immature forms.^[42] Spider mites, including spruce and southern red mites, and citrus leaf miners, which tunnel into foliage, are similarly managed as the oil dissolves waxy barriers or smothers active individuals.^[43] Beyond these, white oil addresses a range of other insects, particularly their eggs and overwintering stages, enhancing its utility in integrated pest management. Caterpillars, such as fall webworms that defoliate trees, leafhoppers that vector plant diseases, and adelgids infesting conifers like hemlocks are controlled through direct contact on exposed life stages.^[17] It proves especially valuable against overwintering eggs of aphids, mites, and scales, reducing populations before spring emergence.^[39] While selective in its action, white oil generally spares beneficial insects like bees and predatory mites when applied during low-activity periods such as evenings, as it only affects direct contacts.^[4] However, it is ineffective against soil-dwelling pests like root-feeding grubs or nematodes, which remain protected below ground.^[26]

Application Guidelines

White oil applications should be timed carefully to maximize efficacy and minimize plant stress. Dormant applications are best performed in late winter, prior to bud break, when temperatures remain above 40°F (4°C) for at least 24 hours to ensure proper coverage without freezing.^[44] For growing season use, apply during cooler periods such as early morning or late evening to prevent leaf scorch from high temperatures and sunlight.^[30] Dosage rates vary by season and plant condition, with concentrations typically expressed as a percentage of oil in water. A 1-2% solution is recommended for general summer applications on actively growing plants, while dormant sprays may use 2-3% for broader pest suppression.^[30]^[25] Applications can be repeated every 7-14 days as needed, depending on pest pressure and environmental conditions.^[45] Effective application requires thorough coverage of plant surfaces using appropriate equipment. Fine-mist pump or hose-end sprayers are ideal for achieving even distribution without excessive runoff, ensuring pests on stems, trunks, and foliage are contacted.^[26]^[45] Focus on spraying the undersides of leaves where pests often reside, and always conduct a small-scale test on a few plants first to confirm compatibility with the species.^[39] White oil is generally compatible with other organic pesticides, such as neem oil, for tank-mixing to enhance control of soft-bodied pests like aphids and mites. However, it should not be combined with sulfur-based fungicides, as this can lead to phytotoxic reactions; maintain a separation of at least two weeks between applications.^[40]^[46]

Safety, Environmental Impact, and Regulations

Safety Considerations

White oil, a refined mineral oil used in horticulture, presents low acute toxicity risks to humans and pets when used as directed. It may cause mild skin or eye irritation upon direct contact and inhalation of spray mist should be avoided by wearing protective gloves, eyewear, and masks during application.^[2] Once the oil has dried on plant surfaces, it is generally safe for children and pets to be around treated areas, as residues evaporate quickly with minimal absorption.^[39] For pets such as dogs and cats, horticultural oils like white oil are considered safe for mammals due to their low toxicity profile, though direct contact with wet spray should be prevented to avoid potential irritation.^[11] Phytotoxicity, or plant injury from white oil, primarily manifests as leaf burn, chlorosis, or drop, particularly when applied during high temperatures above 90°F (32°C) or in conditions of high humidity exceeding 90%.^[26] Sensitive plants such as maples, junipers, ferns, and evergreens with blue-gray foliage are more prone to damage, and testing on a small area is recommended before full application.^[40] Dormant-season oils, applied to woody plants during winter when foliage is absent, pose a lower risk of phytotoxicity compared to summer oils on actively growing tissues.^[11] Proper handling minimizes safety risks: store white oil in its original container in a cool, dry, well-ventilated area away from food, feed, and oxidizing agents to prevent contamination or degradation.^[47] Empty containers should be disposed of according to local waste guidelines, typically by triple-rinsing and recycling if possible. On edible crops, white oil leaves no harmful residues if fruits and vegetables are rinsed thoroughly before consumption, due to its rapid breakdown and non-systemic nature.^[39] In case of exposure, first aid measures include washing affected skin with soap and water, flushing eyes with running water for at least 15 minutes, and moving to fresh air if inhalation occurs; seek medical attention if irritation persists or if large amounts are ingested, as this may cause nausea or gastrointestinal discomfort.^[48] To further mitigate risks, apply white oil during cooler parts of the day, such as early morning or evening, aligning with optimal timing for efficacy.^[2]

Environmental Effects

White oil, also known as horticultural oil, exhibits favorable biodegradability characteristics, breaking down rapidly in soil and water through microbial degradation and evaporation, with soil half-lives averaging around 10 days and up to 75% degradation in 21 days in aqueous environments.^[18] This quick dissipation results in moderate to high bioaccumulation potential, as indicated by a log Kow of 5.18, though limited by rapid environmental dissipation in soil and water.^[18] The use of white oil offers environmental benefits by reducing dependence on broad-spectrum chemical pesticides, thereby helping to preserve pollinator populations such as bees, to which it shows low toxicity (NOEL >25 μg/bee).^[18] It supports integrated pest management (IPM) strategies by targeting pests through physical smothering without leaving toxic residues, allowing beneficial insects to recolonize treated areas once the oil dries.^[2]^[18] However, white oil can pose drawbacks to non-target organisms, including temporary disruptions to beneficial arthropods like ladybugs and predatory mites if oversprayed during active periods, potentially reducing their populations short-term.^[18] Runoff from applications may harm aquatic life, as it is highly toxic to organisms such as Daphnia magna (EC50 0.10 ppm) and can inhibit oxygen transfer in water bodies, leading to risks for fish and invertebrates.^[18]^[15] In terms of sustainability, petroleum-derived white oils are less eco-friendly due to their fossil fuel origins and slower biodegradation relative to alternatives, whereas vegetable-based formulations degrade more readily—often over 70% within 28 days—making them preferable for minimizing environmental persistence.^[18]^[49]

Regulatory Status

In the United States, white oil, also known as horticultural oil, is regulated by the Environmental Protection Agency (EPA) as a pesticide under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA). Many formulations qualify as minimum-risk pesticides under Section 25(b), which exempts them from full federal registration requirements provided they contain only EPA-listed low-risk active and inert ingredients, such as certain mineral or vegetable oils, and pose minimal risk to human health and the environment.^[50]^[51] For organic production, vegetable-based white oil formulations are approved by the USDA through the Organic Materials Review Institute (OMRI), allowing their use in certified organic operations. Dormant oil variants, often derived from narrow-range petroleum or plant sources, are commonly listed on the OMRI Generic Materials List for compliance with USDA National Organic Program standards.^[36]^[52] Internationally, in the European Union, horticultural oils such as paraffin oil are approved as active substances under Regulation (EC) No 1107/2009, enabling their use in plant protection products meeting low toxicity and efficacy criteria, and they are included in lists of active substances permitted in organic agriculture. In Australia and New Zealand, white oils are registered by the Australian Pesticides and Veterinary Medicines Authority (APVMA) and approved under the New Zealand Environmental Protection Authority (EPA) as low-toxicity products for garden and horticultural use, subject to import, manufacture, and application approvals under respective hazardous substances regulations.^[53]^[54]^[55]^[56] Labeling requirements for white oil pesticides mandate clear directions for use, including dilution rates and application timing, along with precautionary statements on hazards, first aid, and storage. Restrictions often prohibit application in ways that could contaminate water bodies, such as avoiding runoff into storm drains, ditches, or surface waters to protect aquatic environments.^[57]^[58]

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Feb 25, 2016 · This product is non-hazardous but a combustible liquid. Avoid skin/eye contact and inhalation. Store in a cool, dry, well-ventilated place. ...Missing: horticultural humans pets
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[PDF] Biodegradation of vegetable oils: A review - Academic Journals
Jun 9, 2009 · The superior biodegradation of vegetable oils in comparison with mineral based oils has been demonstrated severally, leaving scientists with ...Missing: horticultural | Show results with:horticultural
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Minimum Risk Pesticides Exempted from FIFRA Registration | US EPA
Oct 6, 2025 · Minimum risk pesticides are exempted from FIFRA registration because EPA determines they pose little to no risk to human health or the ...Pesticide · Conditions for Minimum Risk... · Inert Ingredient and Active...Missing: horticultural | Show results with:horticultural
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[PDF] Active Ingredients Eligible for Minimum Risk Pesticide Products
This list contains active ingredients exempt from FIFRA, like Castor oil, Cedarwood oil, and Cinnamon. Compare by label, chemical name, and CAS number.Missing: registration | Show results with:registration
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[PDF] OMRI Generic Materials List
The OMRI Generic Materials List includes crop production, livestock production, and processing and handling materials.
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EU Pesticides Database - Active substances - Active substance details
Active substance: Paraffin oil/(CAS 97862-82-3) Where no units are shown, the ADI and AOEL are expressed in mg/kg bw per day. The ARfD is expressed in mg/kg bw.Missing: list | Show results with:list
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[PDF] List of active substances approved for use in EU organic agriculture ...
List of active substances approved for use in EU organic agriculture under EU Regulation (EC) No 889/2008: ... Only those basic substances within the meaning of ...
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Registrations and permits | Australian Pesticides and Veterinary ...
Before an agricultural or veterinary chemical product can be legally supplied, sold, or used in Australia it must be registered by the APVMA. Applying for ...Chemical product registration · Search products and permits · Permits
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Apply for approval to import or manufacture a new substance for ...
If you are importing or manufacturing a pesticide, veterinary medicine, or other hazardous substance for use in New Zealand, you must ensure it's approved.
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Pesticide Labeling Questions & Answers | US EPA
The precautionary statements required on a label are specified in Subparts D and E of 40 CFR Part 156. Further, EPA may require product specific precautionary ...
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[PDF] US EPA - Label Review Manual - Chapter 8: Environmental Hazards
Do not contaminate bodies of water when disposing of equipment rinsate or washwaters”. 4. Users should consult with the State or Tribal agency for pesticide ...Missing: horticultural | Show results with:horticultural