Coal refuse
Coal refuse is the solid waste material produced from coal mining, screening, processing, and preparation operations, comprising low-quality coal mixed with non-combustible rocks such as shale, slate, clay, and sandstone.[1][2] This refuse often contains pyrite and sulfur compounds that, upon exposure to air and water, oxidize to generate acidic drainage, leading to environmental contamination of soil and waterways through heavy metal leaching and erosion from unstable piles.[3][4] Historically accumulated in large, barren mounds from legacy mining, coal refuse poses risks of spontaneous combustion and structural failure, though modern management includes disposal in impoundments, reclamation with lime and soil covers to neutralize acidity, and utilization as fuel in fluidized bed combustion boilers that incorporate limestone for emission control.[5][6][7] These energy recovery efforts not only generate electricity but also facilitate site remediation by removing refuse piles, reducing long-term ecological hazards while providing an alternative to landfilling.[8]Definition and Properties
Composition
Coal refuse consists primarily of inorganic materials rejected during coal mining and preparation processes, including shale, sandstone, siltstone, slate, and clay minerals, along with small amounts of unrecovered coal particles.[9][3] These components originate from the sedimentary rock layers interbedded with coal seams, with the exact makeup varying by the geological source of the coal, mining method, and cleaning techniques employed.[9] Coarse refuse, comprising about 75% of the total volume, features particles ranging from 100 mm to 2 mm in size, dominated by rock fragments suitable for stockpiling or embankment use.[9] Fine refuse, making up the remaining 25%, consists of particles smaller than 2 mm, often sluiced as a slurry and containing higher proportions of clay and coal fines.[9] Mineralogically, coal refuse is dominated by quartz and clay minerals such as kaolinite and illite, which form the bulk of the matrix, with lesser amounts of chlorite, pyrite (FeS₂), and occasionally carbonates or feldspars.[10] Pyrite and marcasite contribute to potential acidity through oxidation, releasing sulfuric acid upon exposure to air and water.[9] Trace elements, including heavy metals like arsenic, mercury, and selenium, may be present in variable concentrations tied to the parent coal's geochemistry, though not uniformly across all refuse types.[11] Chemically, the composition reflects the siliceous and aluminous nature of associated rocks, with major oxides including silica (SiO₂), alumina (Al₂O₃), and iron oxide (Fe₂O₃).[9] Sulfur content, primarily pyritic, ranges from 0.5% to 7.1%, influencing environmental behavior such as acid mine drainage potential.[9] The material is generally acidic, with low nutrient levels and high corrosivity risks due to sulfate release (0.01-4.7%).[9]| Component | Typical Range (%) |
|---|---|
| SiO₂ | 37-62 |
| Al₂O₃ | 16.4-32.4 |
| Fe₂O₃ | 4.3-29.1 |
| S | 0.5-7.1 |