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Epoxy putty

Epoxy putty is a two-part, moldable adhesive material consisting of an epoxy resin and a hardener that, when kneaded together, initiates an exothermic chemical reaction to harden at room temperature into a strong, waterproof solid with durability comparable to steel.^[1] This versatile compound is designed for filling gaps, repairing cracks, and creating structural bonds on various surfaces, including damp or irregular ones, without shrinking or rusting during curing.^[2] Invented in the early 1960s by South African engineer George Montague Pratley and chemist Frank Robinson, epoxy putty emerged as the world's first epoxy-based putty formulation, initially developed for anchoring electrical terminals in junction boxes.^[3] Notably, the original Pratley Putty was used in NASA's Apollo 11 mission in 1969.^[4] Its typical composition includes an epoxy resin such as a bisphenol A-epichlorohydrin polymer, an amine-based curing agent, and inert fillers for body and strength.^[5] Once mixed, it cures within minutes to hours, achieving high tensile strength and resistance to chemicals, heat (up to 280°C in some formulations), and moisture, making it machinable for drilling, sawing, or painting post-cure.^[2] Epoxy putty finds widespread application in construction, plumbing, automotive repair, and marine environments for tasks such as sealing pipe leaks, patching concrete or wood, restoring engine components, and anchoring bolts in masonry.^[1] Specialized variants include concrete putty for matching building materials, wood putty blended with fibers for carpentry, steel putty for metal repairs, and WRAS-approved types safe for potable water systems.^[2] Its ease of use—no special tools required—and ability to bond to diverse substrates like metals, plastics, ceramics, and composites have made it a staple in both professional and DIY projects since its inception.^[3]

History

Development of Epoxy Resins

The development of epoxy resins originated in the 1930s through independent efforts by chemists in Europe and the United States, focusing on the synthesis of curable polymeric materials from epoxide compounds. In 1934, Paul Schlack, working at IG Farbenindustrie AG in Germany, patented the condensation of epoxides with amines to form high-molecular-weight polyamine derivatives, initially intended for textile auxiliaries but establishing the basis for amine-cured epoxy systems.^[6]^[7] This breakthrough provided the first practical method for crosslinking epoxides, enabling the creation of thermosetting resins with enhanced durability.^[6] Building on this foundation, Pierre Castan of De Trey Frères Company in Switzerland achieved a pivotal synthesis in 1936, reacting bisphenol A with epichlorohydrin to produce an amber-colored, low-melting solid epoxy resin that could be thermoset using phthalic anhydride.^[8] Castan subsequently filed a series of patents from 1940 to 1948, detailing the production of epoxide resins ranging from low-molecular-weight liquids to higher-molecular-weight solids and their hardening processes.^[8] His innovations, licensed to Ciba Limited, resulted in the commercial launch of Araldite-brand epoxy adhesives in 1946, primarily for dental fixtures and castings due to the material's minimal shrinkage and lack of volatile byproducts.^[8] Independently, Sylvan O. Greenlee at DeVoe & Raynolds Company in the United States developed analogous bisphenol A-epichlorohydrin resins starting around 1943, securing a key patent in 1948 for high-molecular-weight compositions suitable for industrial use.^[9] Epoxy resin research intensified during World War II, driven by military demands for reliable adhesives in applications such as bonding aircraft parts and providing protective coatings for ships and equipment.^[10] These wartime advancements underscored the resins' exceptional bonding strength and resistance to environmental stresses, facilitating their transition from laboratory curiosities to essential materials. By the late 1940s, commercial production of epoxy resins had begun, with initial markets centered on protective coatings and structural adhesives that paved the way for more specialized forms in the following decades.^[9]

Emergence of Epoxy Putty Products

Epoxy putty products emerged as a practical extension of epoxy resins, which were first synthesized in the 1930s, building on early discoveries of bisphenol A-based polymers for adhesive applications.^[10] Commercialization of epoxy-based adhesives accelerated in the 1950s and 1960s, initially targeting industrial sectors such as aerospace and automotive manufacturing, where their superior strength, adhesion, and resistance to heat and chemicals proved invaluable for bonding and sealing operations.^[10] During this period, early epoxy putties were developed to address on-site repair needs, with South African engineer George Montague "Monty" Pratley inventing the world's first epoxy putty in the early 1960s at his laboratory; originally formulated as an insulator and adhesive for fixing terminals in electrical junction boxes, it marked a shift toward moldable, hand-applicable formats.^[11] Pioneering brands soon followed, including Milliput, established in 1968 by Jack and Lena Rickman in the UK as a two-part epoxy putty for industrial and DIY markets, emphasizing its hand-kneadable consistency for precise modeling and repairs.^[12] Similarly, J-B Weld originated in 1969 when Sam Bonham developed a "cold weld" epoxy in his Texas machine shop to service trucks without traditional welding equipment, introducing a durable, two-part putty-like product for automotive fixes.^[13] In the 1970s and 1980s, epoxy putty products experienced significant growth through diversification into consumer markets, driven by the appeal of pre-measured, stable sticks that simplified mixing and extended usability for household and hobbyist repairs.^[14] This expansion was driven by advancements in the formulation of stable, hand-kneadable epoxy compositions in stick form, enabling broader adoption in plumbing, crafting, and general maintenance.

Composition

Resin Component

The primary ingredient in the resin component of epoxy putty is bisphenol A diglycidyl ether (BADGE), a glycidyl ether epoxy resin with a typical average molecular weight of ≤700 g/mol, which ensures low viscosity suitable for achieving a moldable consistency.^[15] This liquid resin, often characterized by a viscosity of ≤15,000 cps at 25°C, forms the base of the putty formulation and is produced by reacting bisphenol A with epichlorohydrin.^[16] Similar glycidyl ether epoxies, such as those derived from bisphenol F or bisphenol AD, may also serve as alternatives to BADGE for comparable viscosity and reactivity profiles.^[16] BADGE and related resins provide the adhesive and structural backbone essential to epoxy putty, enabling strong bonding to substrates like metal, wood, and concrete while forming a cohesive matrix upon curing.^[16] In this role, the resin's epoxide groups facilitate cross-linking, which contributes to the putty's durability and shapeability before full hardening.^[17] For specialized formulations, variations such as novolac epoxy resins—derived from phenolic novolacs and epichlorohydrin—are incorporated to meet requirements for higher functionality or tailored handling characteristics.^[18] Aliphatic epoxies, including glycidyl ether types from aliphatic alcohols, are sometimes blended in to further reduce viscosity or enhance specific processing needs without compromising the base structure.^[16] To attain the characteristic putty-like texture and improve post-application machinability, the resin is combined with inert fillers such as talc (often with particle sizes ≤50 μm), silica (including quartz powder or microballoons), or metal powders like aluminum or zinc oxide.^[16] These fillers, typically comprising 40-70 wt% of the composition, extend the resin volume, control rheology for easy hand-kneading, and promote a non-sagging consistency during use.^[17] The resin-filler blend remains stable until activation by a hardener, allowing the putty to be shaped as needed.^[16]

Hardener and Fillers

The hardener component of epoxy putty primarily consists of amine-based compounds, such as polyamides and aliphatic amines, which enable room-temperature curing through nucleophilic addition reactions with the epoxy groups in the complementary resin base. Polyamides, derived from the reaction of fatty acids with polyamines, offer flexibility and adhesion in the cured product, while aliphatic amines provide faster cure times and higher reactivity. Cycloaliphatic amines are also employed for their enhanced chemical resistance and reduced tendency to yellow upon exposure to light. These hardeners are typically formulated at concentrations of 8-15% in the overall putty composition to balance cure speed and pot life.^[19]^[20]^[21] Fillers are essential additives in epoxy putty formulations, serving to increase volume, improve mechanical properties, and achieve a non-sag, moldable texture suitable for application. Inert materials like calcium carbonate act as low-cost extenders, enhancing smoothness and reducing shrinkage while comprising up to 40-50% of the mixture by weight. Glass fibers or quartz powder are incorporated for reinforcement, boosting tensile strength and wear resistance without significantly altering the cure kinetics; for example, fine quartz (200-400 mesh) provides densification and hardness. These fillers are often distributed across both parts of the two-component system, with typical mix ratios of 1:1 by volume to facilitate user-friendly dispensing and uniform integration.^[21]^[22]^[23] Stabilizers, such as cellulose ethers (e.g., hydroxypropyl methylcellulose at 0.3-0.8%), are added to the hardener portion to control rheology, prevent settling of fillers, and extend shelf life by inhibiting premature cross-linking. Pigments are likewise included in the hardener to provide visual color contrast—often white or gray in the resin versus amber or red in the hardener—ensuring thorough mixing is evident during application. This combination maintains putty stability for up to 12-24 months under proper storage conditions.^[21]^[24]

Curing Process

Mixing Procedure

Epoxy putty is typically supplied in two-part stick form, consisting of separate resin and hardener components, often in contrasting colors such as gray and white or black and white. To prepare it for use, equal parts of each component are cut or broken off using a sharp knife or by hand for precise measurement in a 1:1 ratio by volume.^[25]^[26]^[27] The mixing process involves kneading the two parts together vigorously by hand, often on a clean, hard surface like a cutting board, until a uniform color is achieved without streaks, which generally takes 1 to 5 minutes depending on the formulation. Protective gloves, such as latex or nitrile, should be worn to prevent skin contact, as the uncured material can cause irritation. For easier handling, some products recommend dampening the gloves or surface with water to reduce sticking during kneading. Once mixed, the putty has a working time of 5 to 30 minutes before it begins to harden, during which it can be shaped or applied.^[25]^[26]^[27] Environmental factors, particularly temperature, influence the mixability and working time of epoxy putty. At temperatures above 77°F (25°C), the putty becomes more pliable and cures faster, potentially shortening the working window, while cooler conditions below 50°F (10°C) make kneading more difficult and extend the time needed for uniformity. Ideal mixing occurs at room temperature around 70–77°F (21–25°C) to ensure optimal homogeneity.^[28] A common error in mixing is incomplete kneading, which leaves unmixed resin or hardener pockets that result in weak spots, uneven curing, or soft areas in the final bond. To avoid this and minimize air bubbles, knead methodically from the center outward, pressing firmly to blend thoroughly without introducing excess air; if bubbles form, they can often be worked out by rolling the putty between gloved hands. Always mix only the amount needed for immediate use, as unused putty cannot be stored once activated.^[29]^[30]

Chemical Reaction Mechanism

The chemical reaction mechanism in epoxy putty curing is a ring-opening polymerization process where epoxy groups from the resin component react with amine hardeners to form a highly cross-linked, three-dimensional polymer network. This transformation occurs through a nucleophilic addition reaction, in which the lone pair of electrons on the amine nitrogen attacks the less substituted (terminal) carbon of the strained epoxide ring, leading to ring opening and the simultaneous formation of a β-hydroxy amine linkage. The reaction proceeds in a stepwise manner: primary amines initially react to produce secondary amines bearing hydroxyl groups, which then undergo further addition with additional epoxy groups to yield tertiary amines, thereby extending the polymer chains and establishing cross-links between multiple resin molecules. This mechanism can be simplified as:

\text{Epoxy (e.g., } \ce{R-CH-CH2-O} \text{ ring)} + \text{Amine (e.g., } \ce{R'-NH2} \text{)} \rightarrow \text{Hydroxyl-containing polymer (e.g., } \ce{R-CH(OH)-CH2-NH-R'}

The hydroxyl groups generated also act as catalysts by forming hydrogen-bonded complexes that accelerate subsequent epoxy openings.^[31]^[32] Curing progresses through defined stages influenced by reaction kinetics and formulation. The gelation stage marks the initial hardening, where the mixture reaches a point of infinite viscosity and transitions to a rubbery solid, typically occurring within 10-60 minutes at room temperature for standard epoxy putty systems. Full cure, where the cross-linked network achieves its maximum density and properties, generally requires 24-72 hours at ambient conditions (around 20-25°C). These durations are critically dependent on stoichiometry, with an ideal 1:1 equivalent ratio of epoxy to active amine hydrogens promoting complete reaction and uniform cross-linking; deviations can lead to unreacted groups or reduced network integrity.^[33]^[34] The polymerization is inherently exothermic, with the heat release (typically 300-500 J/g depending on the system) driving autocatalytic acceleration, especially in bulk applications where temperature rise sustains the reaction. To achieve faster cures in certain putty formulations, additional catalysts like tertiary amines may be incorporated, which facilitate etherification side reactions or enhance nucleophilic attack without becoming part of the final structure, reducing gel times by up to 50% in optimized blends.^[31]^[35]

Properties

Mechanical Characteristics

Epoxy putty, once fully cured, exhibits robust mechanical properties that make it suitable for structural repairs and load-bearing applications. Its tensile strength typically ranges from 2,000 to 5,000 psi (13.8 to 34.5 MPa), depending on the formulation and fillers used, allowing it to withstand pulling forces without fracturing under normal conditions.^[36]^[37] Compressive strength is notably higher, often reaching up to 10,000 to 12,000 psi (69 to 83 MPa), enabling the material to support heavy loads in applications like gap filling or reinforcement.^[36] The cured hardness of epoxy putty generally falls in the Shore D 80-90 range, providing a rigid yet machinable surface that can be drilled, sanded, or tapped without excessive wear on tools.^[36]^[38] This level of hardness contributes to its durability in abrasive environments, while the material's low shrinkage (typically less than 0.01%) during curing ensures dimensional stability.^[36] Adhesion is a key mechanical attribute, with epoxy putty forming strong bonds to a variety of substrates including metals, plastics, wood, and ceramics, often achieving lap shear strengths exceeding 1,000 psi (6.9 MPa).^[39]^[40] For instance, shear strengths on steel can reach 2,600 psi (18 MPa) in optimized formulations, while values on aluminum or wood may be slightly lower but still sufficient for secure attachment.^[39]^[38] Flexibility varies significantly with filler type; metal-filled variants tend to be more rigid with minimal elongation (1-5% at break), enhancing stiffness for rigid repairs, whereas less filled types may offer up to 10% elongation to accommodate minor movements without cracking.^[37]^[41] Cured epoxy putty performs best in non-dynamic applications. Certain epoxy adhesives retain over 90% of initial shear strength after millions of cycles in adhesive joints, suggesting potential reliability for long-term repairs prone to vibrational fatigue in similar formulations.^[42] These mechanical characteristics are further supported by the material's inherent resistance to environmental degradation, enhancing overall longevity in demanding uses.^[43]

Chemical and Thermal Resistance

Cured epoxy putty demonstrates strong chemical resistance, remaining impervious to water and suitable for marine applications where prolonged immersion is required. It also withstands exposure to oils and petroleum-based products without significant degradation, making it ideal for industrial environments involving lubricants or fuels.^[44] Additionally, the material resists dilute acids across a pH range of approximately 3 to 11, as well as alkaline solutions and common solvents, enabling its use in chemical processing plants for repairs on equipment handling such substances.^[44]^[45] In terms of thermal properties, standard epoxy putty formulations maintain structural integrity over a service temperature range of -40°C to 120°C, supporting applications in varying climatic conditions. High-temperature variants, often reinforced with specialized fillers, extend this capability up to 260°C, suitable for hot pipe repairs or engine components. The low coefficient of thermal expansion, typically around 50 × 10⁻⁶/°C, minimizes dimensional changes under thermal cycling, enhancing durability in fluctuating heat environments.^[46]^[47]^[48] Regarding UV and weathering resistance, epoxy putty performs well indoors, where limited light exposure preserves its appearance and properties over extended periods. Outdoors, however, it is prone to yellowing and surface degradation due to UV-induced radical oxidation without added stabilizers, though formulations with UV absorbers can mitigate these effects for prolonged exterior use.^[49]^[50]

Types

General-Purpose Formulations

General-purpose epoxy putty formulations consist of a two-part system comprising a bisphenol-A-based epoxy resin and a corresponding hardener, typically an amine or polymercaptan curing agent, blended with mineral fillers such as talc or silica to provide body, color, and reinforcement.^[51]^[52] These fillers, often comprising 30-50% by weight, result in a gray or white putty that is kneadable and moldable, with the resin-hardener ratio balanced for room-temperature curing without specialized accelerators.^[53] The working life of these formulations is generally 3-20 minutes after mixing, allowing sufficient time for application to various surfaces before the putty begins to set.^[54]^[55] Cure times range from 1-24 hours for full hardening, with initial handling strength achieved in 15-60 minutes, enabling sanding, drilling, or painting shortly after application.^[54]^[56] Commercial examples include Loctite Repair Putty All-Purpose and J-B Weld PlasticWeld, which are packaged as convenient sticks or tubes for household repairs on metals, plastics, wood, and ceramics.^[57]^[55] These putties offer versatile adhesion to non-porous and porous substrates, waterproof properties once cured, and machinability for finishing, making them suitable for broad, non-specialized fixes without requiring professional tools.^[54]^[55]

Specialized Variants

Specialized variants of epoxy putty are engineered with targeted modifications to hardeners, fillers, and resins to suit extreme conditions or specific substrates, building upon standard formulations for enhanced performance in niche scenarios.^[58] Underwater-curing epoxy putties employ amine-based hardeners that facilitate bonding and polymerization in submerged or wet environments, resisting water interference during the reaction.^[59] For instance, Sylmasta Superfast Aqua is a hand-moldable stick formulation designed for high adhesion on wet surfaces and underwater applications, with an open time of approximately 15 minutes to allow precise shaping before curing.^[60] These variants often incorporate polyaminoamide hardeners to promote rapid wet adhesion and corrosion resistance in marine settings.^[61] Metal-reinforced and high-temperature epoxy putties incorporate steel or ceramic fillers to boost structural integrity and thermal stability for demanding industrial uses. JB Weld SteelStik, a steel-filled epoxy putty, achieves a tensile strength of 4000 PSI and withstands continuous temperatures up to 350°F (177°C), making it suitable for metal repairs in heated environments.^[62] Conductive variants, such as silver-filled epoxies like MG Chemicals 8331D, provide low electrical resistivity (1.8 × 10^{-3} Ω·cm) for applications requiring electrical continuity while maintaining adhesive properties.^[63] Flexible options, including Smooth-On Free Form Habitat Flex FR, cure to a semi-rigid state with flame-retardant properties (E84 Class A), offering elongation to absorb vibrations without cracking.^[64] Other specialized formulations address substrate-specific needs, such as wood repair putties with low-shrinkage profiles to mimic natural wood expansion and prevent cracking. Abatron WoodEpox, a two-part epoxy system, exhibits minimal volumetric shrinkage (less than 1%) and sands to a wood-like finish, ideal for restoring rotted or damaged timber elements.^[65] Electrical-insulating variants, like Hercules Pro-Poxy, deliver high dielectric strength (over 400 volts/mil) for insulating electrical components without conductivity.^[66] Rapid-set types, such as Sylmasta AB Rapid, achieve handling strength in just 5 minutes through accelerated amine curing, enabling quick interventions in time-sensitive repairs.^[67]

Applications

Repair and Maintenance

Epoxy putty is widely used in plumbing applications to seal leaks in pipes and fittings, providing a durable, waterproof bond that adheres to materials such as PVC, metal, and ceramics even in wet conditions.^[68] Specialized formulations, like those rated NSF safe for potable water, enable quick emergency repairs without draining systems, curing in 60 minutes to form a hard, non-shrinking seal.^[69] In marine environments, epoxy putty excels at patching hulls and sealing cracks on boats, with underwater-curing variants allowing application directly to submerged surfaces without prior drying.^[70] These putties bond effectively to fiberglass, wood, and metals, resisting corrosion from saltwater and maintaining integrity under constant water exposure.^[71] For instance, products like JB Weld WaterWeld can plug holes in fuel tanks or repair pool drains, leveraging the material's adhesion to wet substrates for reliable, long-term fixes.^[72] Automotive repairs benefit from epoxy putty's ability to fill dents and bond components, such as rebuilding exhaust parts or securing trim, due to its steel-reinforced formulations that withstand vibration and high temperatures up to 350°F.^[62] In construction settings, it repairs cracks in concrete and masonry, forming a weather-resistant barrier that endures outdoor elements like rain while allowing sanding and painting for seamless integration.^[57] These applications draw on the putty's general mechanical strength and chemical resistance to ensure structural durability.^[73] For electrical maintenance, epoxy putty insulates damaged wires by encasing exposed conductors, preventing short circuits and providing a moisture-proof seal against environmental hazards.^[74]

Modeling and Crafts

Epoxy putty plays a central role in model building, particularly for hobbyists creating scale models like those in Warhammer games, where it is used to shape custom figures, terrain pieces, and bases. Its pliable consistency allows sculptors to add intricate details such as rocky outcrops or organic forms before it hardens, and its sandable properties facilitate refining surfaces for seamless integration with plastic or resin components. Popular formulations like Green Stuff are favored in wargaming communities for their flexibility during application and ability to hold fine edges without cracking.^[75] In arts and jewelry crafting, epoxy putty enables the molding of bespoke decorative items and the embedding of small objects like beads or natural elements within custom pieces. Artisans mix the two-part compound to form durable, lightweight structures that capture textures or patterns, often using tools for precise shaping. Specialized variants, such as colored epoxy putties matching crystal hues, are designed specifically for jewelry applications, allowing creators to fabricate pendants, rings, or inlays that mimic precious materials.^[75]^[76] For DIY projects, epoxy putty supports the fabrication of personalized elements like ergonomic custom grips on tools or handles, as well as enhancements in woodworking and cosplay accessories. Its adhesive qualities bond well to wood, foam, or fabric substrates, enabling builders to sculpt protective armor pieces or textured embellishments. Post-cure, the material's smooth, paintable surface accepts acrylics, enamels, or primers for finishing, while its machinability allows sanding or carving for custom fits.^[75]^[76]

Safety and Handling

Health Hazards

Epoxy putty, composed primarily of epoxy resins and amine hardeners, poses significant risks of irritation upon direct contact with skin and eyes during handling and mixing. The uncured resin can cause skin irritation, manifesting as redness, swelling, and itching, while the amine components may lead to allergic sensitization, resulting in more severe reactions such as dermatitis upon repeated exposure.^[5]^[77] Eye contact with the putty typically produces serious irritation, including pain, watering, and redness, necessitating immediate rinsing and medical attention if symptoms persist.^[5]^[78] Inhalation of vapors released during mixing or application can irritate the respiratory tract, causing symptoms such as coughing, shortness of breath, and throat discomfort, particularly in poorly ventilated areas.^[77]^[79] Ingestion of epoxy putty is harmful and may result in gastrointestinal distress, including nausea, vomiting, and diarrhea, due to the toxic nature of its chemical components; it should be avoided at all costs, with immediate medical consultation recommended if it occurs.^[80]^[81] Long-term exposure to epoxy putty increases the risk of chronic sensitization, where initial mild reactions escalate to persistent allergic dermatitis from epoxy resins or amines, potentially affecting workers with repeated contact.^[77]^[78] Certain components, such as epichlorohydrin residues in some epoxy formulations, are classified as probable carcinogens, with evidence from animal studies linking them to skin cancer and potential human risks upon prolonged exposure.^[77] These hazards can be mitigated through proper handling practices, including the use of protective gloves, eye protection, and adequate ventilation.^[5]

Storage and Disposal

Epoxy putty, being a two-part system, requires storage of its resin and hardener components separately in tightly sealed containers to prevent premature curing or contamination. These should be kept in a cool, dry, and well-ventilated area at temperatures below 25°C to preserve product stability and avoid degradation.^[5]^[52] The typical shelf life of unopened epoxy putty is 1-2 years when stored under these conditions, after which potency may diminish, though testing via a small mix can verify usability.^[82]^[83] Freezing should be avoided, as repeated freeze-thaw cycles can cause crystallization in the resin, potentially requiring warming and stirring to restore usability.^[83] Uncured epoxy putty is classified as hazardous waste primarily due to its aquatic toxicity, which can cause long-term adverse effects in water environments, and must be disposed of at licensed facilities in accordance with local regulations.^[84]^[85] In the European Union, such preparations are classified under the CLP Regulation (EC) No 1272/2008 as harmful to the aquatic environment.^[86] Once fully cured, however, epoxy putty solidifies into a non-hazardous inert material and can be discarded as regular solid waste, such as in municipal landfills.^[87] Empty packaging should be rinsed if possible and recycled through appropriate programs where facilities exist, following regional waste guidelines.^[5] For spill cleanup, immediately absorb the uncured material with an inert absorbent like sand, vermiculite, or sawdust, then transfer to a suitable container for hazardous waste disposal; ventilate the area to disperse vapors and prevent entry into sewers or waterways.^[5] This approach minimizes environmental release and helps prevent unintended health exposures from residual components.^[88]

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[PDF] DOW Epoxy Resins - New Mexico Tech
†Typical fillers only; not to be construed as a recommendation from Dow. Fillers†. The use of fillers in epoxy compositions can lower costs, reduce exotherm ...Missing: putty | Show results with:putty
[36]
Enhancing epoxy resin curing: Investigating the catalytic role of ...
Nov 15, 2024 · The epoxy–amine curing reaction occurs via a nucleophilic attack of the amine nitrogen on the terminal carbon of the epoxy functional group, ...
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Network Formation and Physical Properties of Epoxy Resins ... - NIH
Since the cross-linking reaction between epoxy and amine is exothermic, the temperature rises as the reaction progresses. Okabe et al. proposed an elegant ...Missing: putty | Show results with:putty
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### Mechanical Properties of Epoxy Resin Putty
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[PDF] WEICON Epoxy Resin Putty Plastic Metal
Mechanical properties after curing. Tensile strength. DIN EN ISO 527-2. 19 MPa ... Compressive strength. DIN EN ISO 604. 80 MPa. Bending strength. DIN EN ISO ...
[40]
[PDF] EPOXY PUTTY
Dielectric Strength. 300 volts/mils. Dielectric Constant. 28.1. Adhesive Tensile Shear Dry: 880 psi/Underwater 766 psi. Compressive Strength. 12,000 psi.
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[PDF] Dynaluminum Epoxy Putty - FreemanSupply.com
Hardness (Shore D) 24 Hrs. 80. Lap Shear Tensile Strength on Steel (PSI). 600. Lap Shear Tensile Strength on Aluminum (PSI). 500. Compression Strength (PSI).
[42]
[PDF] WEAR RESISTANT EPOXY PUTTY (WR-2) - Amazon AWS
CURED HARDNESS / SHORE D. 85 D. DIELECTRIC STRENGTH KV/MM. 15.7. ADHESIVE TENSILE SHEAR MPA. 18. COMPRESSIVE STRENGTH MPA. 68. COEFFICIENT OF THERMAL EXPANSION ...
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### Cured Mechanical Properties of Kneadatite A/B Epoxy Putty
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Overview of materials for Epoxy Adhesive - MatWeb
Tensile Strength, Ultimate, Average value: 42.9 MPa Grade Count:564; Tensile ... Compressive Yield Strength, Average value: 106 MPa Grade Count:212 ...
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Epoxy Strengths Compressive Tensile Flexural Bond
There are 4 primary strengths that are very important for most civil and mechanical engineering applications of epoxy: compressive strength, tensile strength, ...
[46]
Environmental Resistance and Fatigue Behaviors of Epoxy/Nano ...
Sep 24, 2021 · The double-lap shear strength still reached 35.55 MPa after 106 fatigue cycles, and the strength retention rate was 96.9%, indicating that the ...Missing: putty elongation
[47]
[PDF] WSRC-TR-2008-00090, Saltstone Vault-2 Interior Lining Review.
Epoxies are generally resistant to dilute acids, alkaline solutions, salt solutions, water, solvents, oils, petroleum-based products, heat, radiation, etc.
[48]
[PDF] Investigations of some applications of epoxy preparations on the farm
h) Resistance to moistirro and solvents - Once the epoxies harden they become insensitive to moisture, solvents and acids. They are also effective barriers ...
[49]
[PDF] EVO-STIK Hard & Fast Metal Epoxy Putty
Sep 15, 2015 · TYPICAL PERFORMANCE DATA (Approx.) Service. Temperature. -40°C to +120°C depending on conditions of use. Water Resistance.
[50]
[PDF] Technical Data Sheet Permatex High Heat Epoxy
Temperature range. -60°F to +500°F (-51°C to 260°C). GENERAL INFORMATION. This product is not recommended for use in pure oxygen and/or oxygen rich systems and ...Missing: putty | Show results with:putty
[51]
[PDF] Plastic Steel Putty (A) - Technical Data Sheet
Apr 17, 2012 · Coefficient of Thermal Expansion. 48 [(in)/(in) x °F)] x 10(-6). Color. Grey. Compresive Strength. 8260 psi. Coverage/lb. 48 sq. in @ 1/4 in.<|separator|>
[52]
Yellowing Mechanisms of Epoxy and Vinyl Ester Resins under ...
Sep 27, 2025 · This paper presents an experimental study on the yellowing mechanisms of epoxy and vinyl ester resins under thermal, UV and natural aging conditions.Missing: putty | Show results with:putty
[53]
Yellowing mechanisms of epoxy and vinyl ester resins under ...
This paper presents an experimental study on the yellowing mechanisms of epoxy and vinyl ester resins under thermal, UV and natural aging conditions.Missing: putty | Show results with:putty
[54]
[PDF] EPOXY PUTTY - Hp Adhesives
Hazardous ingredients according to Directive 1999/45/EC. Reaction Product: Bisphenol-A-(epichlorhydrin) epoxy resin (number average molecularweight <= 700).Missing: formulation | Show results with:formulation
[55]
[PDF] general purpose epoxy putty - safety data sheet
Apr 25, 2023 · Emits toxic fumes when heated. Section 3- Composition/ Information on Ingredients. CHEMICAL. CAS NUMBER. PERCENT. Talc ( non asbesotiform).Missing: formulation | Show results with:formulation
[56]
[PDF] Loctite Repair Putty – All Purpose - Henkel
It bonds metal, wood, ceramic, brick, most plastics* and concrete. It will ... Shear Strength – Underwater Bonding (24-hour cure):. Paintable: Yes. Steel ...
[57]
https://www.loctiteproducts.com/products/central-pdp.html/loctite-epoxy-putty/SAP_0201OGL029V2.html
[58]
https://www.unitedresin.com/introduction-conductive-epoxies/
[59]
Loctite Epoxy Putty
It can bond to damp surfaces, cure under water and can be sanded, drilled and painted after 60 minutes.Missing: composition life
[60]
An Introduction To Conductive Epoxies - United Resin, Inc.
Jun 22, 2023 · A conductive epoxy resin system consists of epoxy resin mixed with a conductive filler. The epoxy resin provides the adhesive and mechanical ...
[61]
Underwater curing of epoxy resin and amine-terminated liquid ...
Underwater cure time generally may range from about 1 hour to about 20 hours, more typically from about 3 hours to 12 hours. The compositions described ...
[62]
https://www.jbweld.com/product/steelstik-epoxy-putty-stick
[63]
Polyaminoamide : Tohmide｜Products - T&K TOKA
"Tohmide" is the hardener for epoxy resin. It is a polyaminoamide ... Wet surface adhesion, Underwater curing putty. TXA-529, -, 600～1,200, 350～390 ...
[64]
https://www.smooth-on.com/products/free-form-habitat-flex-fr-epoxy-putty/
[65]
8331D - Silver Conductive Epoxy Adhesive - MG Chemicals
8331D is a 2-part electrically conductive epoxy that is an improved version of our silver-filled epoxy, 8331. The glue is smooth, non-sag, thixotropic, and ...
[66]
Free Form™ Habitat™ Flex FR Product Information | Smooth-On, Inc.
Free Form™ Habitat™ Flex FR Epoxy Putty is a mix-and-apply-by-hand putty that is that is certified flame resistant (E84, Class A) and is used to create display ...
[67]
Abatron WoodEpox Kit - 12 oz - 2-Part Structural Epoxy Adhesive Filler
30-day returnsAbatron WoodEpox is a 2-part epoxy putty for filling and rebuilding wood, used for windows, doors, and other wood elements. It can be shaped and molded.
[68]
How to use Epoxy Putty - Oatey
Hercules® Pro-Poxy® is used in plumbing, heating, industrial, maintenance, and home repairs, including electrical insulating and underwater repairs. Hercules ...
[69]
https://www.paintsupply.com/product/2-oz-protective-coatings-250031-pc-plumbing-hand-moldable-epoxy-putty/
[70]
PC Products 4 oz. PC-Plumbing Putty Epoxy 045596
Rating 3.8 (51) · Free in-store returnsPC-Plumbing is a hand moldable putty epoxy designed for quick emergency-type repairs. PC-Plumbing is NSF rated safe for contact with potable water.
[71]
https://www.westmarine.com/west-marine-epoxy-putty-stick-3761483.html
[72]
PC Products PC-Marine Multiple Colors/Finishes Epoxy Adhesive
Rating 5.0 (1) · Free delivery over $45 · Free 90-day returnsPC-Marine is a hand moldable putty epoxy designed for quick emergency-type repairs. PC-Marine is formulated to adhere to wet, dry, and submerged, underwater ...
[73]
https://www.kbs-coatings.com/epoxy-putty
[74]
https://www.landmsupply.com/harvey-epoxy-putty-4-oz
[75]
https://sylcreate.com/epoxy-modelling-putty-your-guide-to-model-making-sculpting-putties/
[76]
https://avesstudio.com/shop/apoxie-sculpt/
[77]
RectorSeal EP-200 2 oz. Epoxy Putty Stick 97601 - The Home Depot
In stock Rating 4.1 (141) · Free deliveryEP-200 epoxy putty is a pre-measured kneadable reinforced epoxy putty stick that cures steel-hard within 15- 20 minutes of mixing at room temperature (77°F). ...
[78]
Epoxy modelling putty – Your guide to model making & sculpting putties
### Summary of Epoxy Putty Uses in Modeling, Crafts, Sandable, Paintable, Jewelry
[79]
Apoxie Sculpt - Aves Studio
In stock 30-day returnsApoxie Sculpt combines the features and benefits of sculpting clay with the adhesive power of epoxy! Its smooth, putty-like consistency is easy to mix & use.
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### Health Hazards of Epoxy Resins (Summary)
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### Summary of Health Hazards from Epoxy Putty MSDS (Sections 2, 11)
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Health Effects from Overexposure to Epoxy
Inhaling concentrated epoxy vapors, if done frequently or for long periods, can irritate your respiratory tract. Exposing sensitive skin areas, like the ...Missing: ingestion | Show results with:ingestion
[83]
[PDF] Epoxybond-Pool-Putty - SAFETY DATA SHEET
May 2, 2015 · resin (CAS 25068-38-6). Trimethylol propane triacrylate. N/Av. (CAS ... : Epoxy putty hardener. Use pattern: Consumer use. Recommended ...
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[PDF] ep 400 epoxy putty safety data sheet
Composition/Information on Ingredients. Mixture: Ingredient. CAS No. % by Weight. Page 2. - 2 of 5 -. EP 400 EPOXY PUTTY. SAFETY DATA SHEET. 2,4,6-tris ...<|control11|><|separator|>
[85]
https://epoxy-europe.eu/wp-content/uploads/2018/10/EPOXY_RESINS_AND_CURING_AGENTS-3.pdf
[86]
Epoxy Shelf Life & Proper Storage
WEST SYSTEM's epoxy can have a shelf life that lasts many years when resin and hardener are properly stored correctly.
[87]
Substance Information - ECHA - European Union
According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance is toxic to aquatic life with long lasting ...
[88]
[PDF] Toxicology, Health, Safety and Environmental Aspects - Epoxy Europe
Directive 67/548/EEC on the Classification and Labelling of Dangerous Chemical ... have the potential to bioaccumulate and are moderately toxic to aquatic.
[89]
[PDF] Safety data sheet of 'EPOXY RESIN' (Version 3) - Sea-Line
Aquatic Chronic 2: H411 - Toxic to aquatic life with long lasting effects. Eye Irrit. 2: H319 - Causes serious eye irritation. Skin Irrit. 2: H315 - Causes skin ...
[90]
Proper Disposal of Leftover Resin & Hardener - Epoxyworks
Leftover resin/hardener is hazardous waste when discarded. Cured epoxy is not. Empty containers can be disposed of if under 3% full. Check local regulations.Missing: putty | Show results with:putty
[91]
[PDF] Epoxy Resin - Safety Data Sheet - SP Bel-Art
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Information concerning particular hazards for human and ...