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Ligation

Ligation is the process of or tying structures, primarily employed in surgical procedures to apply a ligature—such as , wire, or a clip—to occlude blood vessels, ducts, or other anatomical tubes, thereby controlling hemorrhage or facilitating isolation during operations. In , it denotes the enzymatic joining of fragments, typically or RNA, into a continuous chain via phosphodiester bonds catalyzed by ligases like T4 , a cornerstone technique in technology and . Medically, ligation has been a fundamental hemostatic method since antiquity, evolving from rudimentary ties to precise applications in procedures like tubal ligation for permanent female sterilization—where fallopian tubes are severed and sealed to prevent egg transport—or vein ligation and stripping for varicose vein treatment, which removes diseased saphenous veins to alleviate symptoms such as pain and swelling. These interventions carry risks including infection or ectopic pregnancy in sterilization cases, though they offer high efficacy for their intended outcomes when performed correctly. In biotechnology, ligation enables vector-insert assembly for genetic engineering, with efficiency influenced by factors like fragment compatibility (sticky versus blunt ends) and reaction conditions, underpinning advancements in gene therapy and synthetic biology. Despite its ubiquity, ligation's precision demands careful execution to avoid incomplete sealing in surgery or low-yield joins in labs, highlighting its role as both a reliable tool and a technique sensitive to procedural variables.

Surgical Applications

Definition and Techniques

Surgical ligation is a fundamental procedure in operative medicine involving the application of a ligature—a , suture, wire, or mechanical clip—to encircle and occlude an anatomical structure, typically a , lymphatic channel, duct, or , thereby arresting hemorrhage, diverting blood flow, or preventing the passage of fluids or gametes. This technique relies on mechanical compression or induction to achieve or functional interruption, with ligatures selected based on material properties such as absorbability (e.g., or synthetic polymers) or permanence (e.g., or clips) to suit the tissue type and procedural goals. Techniques for ligation vary by surgical approach and target but generally emphasize precision to minimize and slippage risk. In open surgery, direct allows for suture ligation, where a needle-mounted suture is passed around the and tied with knots (e.g., surgeon's or knots) to secure , often employing a figure-of-eight pattern for enhanced on bleeding vessels. Clip ligation uses preformed devices like metallic hemoclips or silicone-lined clips (e.g., Filshie clips), applied via to compress the without sutures, providing rapid deployment in both open and minimally invasive settings. Laparoscopic or minimally invasive variants employ specialized instruments, such as laparoscopic graspers or coagulators, to isolate the target (e.g., fallopian tubes) through small incisions or trocars, followed by ligation via clips, loops, or energy devices like electrocautery, which desiccates by controlled sealing to induce protein denaturation and wall fusion. For vascular applications, adjunct methods include rubber band or silastic ring application to avulse and ligate segments, or combined ligation-stripping for , where the is tied proximally before mechanical extraction. Efficacy depends on factors like diameter (typically effective for <5 mm) and operator skill, with slippage rates under 1% for properly tensioned ligatures in controlled studies.

Historical Development

The practice of surgical ligation, involving the tying of blood vessels to control hemorrhage, originated in ancient medicine. Heliodorus, a Greco-Roman surgeon of the first century AD, described ligation and torsion of vessels as methods for achieving hemostasis during operations. Antyllus, a second-century AD practitioner often regarded as an early pioneer in vascular techniques, advocated ligating arteries both proximal and distal to an aneurysmal sac before evacuating its contents to prevent vessel slippage and rupture, marking one of the earliest systematic approaches to aneurysmal repair through ligation. These methods relied on silk or linen threads but were largely supplanted by cauterization in subsequent eras due to infection risks and inconsistent outcomes, with ligation described only intermittently in pre-modern texts. A pivotal advancement occurred in the 16th century with , a French barber-surgeon serving in military campaigns, who reintroduced and popularized arterial ligatures as an alternative to hot irons for hemostasis in amputations. During the 1537 siege of Turin, Paré exhausted his supply of boiling oil—a standard cauterizing agent—and improvised by dressing wounds with a mixture of egg yolk, rose oil, and turpentine, while using thread ligatures to tie vessels, resulting in lower mortality from secondary hemorrhage compared to cauterized cases. He first applied ligation to the common carotid artery in 1552 for trauma-related injury. Paré detailed these techniques in his 1564 Treatise on Surgery, emphasizing their gentleness and efficacy in reducing pain and tissue destruction, though he was not the inaugural user of ligatures but the most effective promoter, influencing widespread adoption over predecessors' sporadic applications.31061-9/fulltext) By the 19th century, ligation had become a standard for managing vascular injuries and aneurysms, as seen in early operations like innominate artery ligation for subclavian aneurysms, though outcomes remained variable due to risks of gangrene and ischemia. In military contexts, such as World War II, ligation was the predominant method for acute arterial injuries when repair was infeasible, underscoring its reliability despite limitations in preserving distal perfusion. The technique's evolution paralleled advances in antisepsis and instrumentation, transitioning from emergency hemostasis to a foundational element in elective procedures, though later supplanted in many cases by vascular anastomosis following Alexis Carrel's early 20th-century refinements in suturing.

Specific Procedures

Tubal ligation, a procedure for permanent female sterilization, involves occluding the fallopian tubes to prevent sperm from reaching the ovaries. Performed laparoscopically or via mini-laparotomy, the surgeon accesses the tubes through small abdominal incisions, then applies methods such as tying with sutures, clipping, cauterizing, or excising segments to block patency. The laparoscopic approach, common since the 1970s, uses a telescope inserted near the navel to visualize and ligate the tubes, often under general anesthesia, with the procedure lasting 30-60 minutes. Success rates exceed 99% for preventing pregnancy, though ectopic pregnancies remain possible if failure occurs. Vasectomy, a male sterilization technique, ligates or seals the vas deferens to interrupt sperm transport. In the conventional method, a small scrotal incision exposes the vas, which is then divided and secured via ligation with sutures, fascial interposition, or clips, sometimes combined with cautery for enhanced occlusion. The no-scalpel variant, introduced in the 1980s, punctures the skin without incision using specialized forceps, reducing hematoma risk by up to 66% compared to scalpel techniques. Post-procedure semen analysis confirms azoospermia after 8-16 weeks, with failure rates under 0.15% in properly confirmed cases. Vein ligation and stripping addresses severe varicose veins by isolating and tying off the great or small saphenous vein at its junction with deeper vessels, followed by removal via a thin wire threaded through the vein. Performed under general or regional anesthesia through incisions at the groin and ankle, the procedure diverts blood flow to healthier veins, alleviating symptoms like pain and ulceration in chronic venous insufficiency. Though less common today due to endovenous alternatives, it remains indicated for tortuous or recurrent varicosities, with recurrence rates of 10-20% over five years. Left atrial appendage ligation prevents thromboembolism in atrial fibrillation patients by surgically excluding the appendage, a site of thrombus formation, often via thoracoscopic or epicardial approaches during concomitant cardiac surgery. The LARIAT procedure, for instance, uses external snares to encircle and ligate the appendage percutaneously, achieving closure rates over 95% in eligible non-valvular AFib cases unsuitable for anticoagulation. This method reduces stroke risk comparably to occlusion devices in observational data, though long-term randomized evidence is limited. In general vascular surgery, ligation controls hemorrhage by encircling vessels with absorbable or non-absorbable sutures perpendicular to the vessel axis, often after clamping with . Techniques like the Roeder slipknot enable secure laparoscopic ligations of pedicles, minimizing slippage risks in minimally invasive settings. Such procedures are routine in , , and trauma surgeries, where vessel diameter and wall integrity dictate suture choice to avoid necrosis or recanalization.

Risks, Complications, and Efficacy

Surgical ligation, as a technique to occlude blood vessels, ducts, or other tubular structures, shares general perioperative risks with other invasive procedures, including hemorrhage, infection, anesthesia-related adverse events, and inadvertent injury to adjacent tissues or organs. These risks are influenced by patient factors such as obesity, diabetes, or prior abdominal surgery, which can elevate complication rates. For instance, in for sterilization, reported intraoperative complications occur in approximately 0.5-2% of cases, encompassing bowel or bladder perforation, while postoperative issues like wound infection affect 1-3% of patients. Procedure-specific complications further vary by anatomical site. In vascular ligation for varicose veins, potential issues include deep vein thrombosis (0.5-1% incidence), nerve injury leading to numbness or pain, scarring, and recurrence of varicosities due to neovascularization, though overall major complication rates remain low at under 5%. Hemorrhoidal rubber band ligation carries risks of post-procedure bleeding (up to 1-2%), thrombosis, or infection, with severe events like bacteremia rare but documented in case series. Patent ductus arteriosus ligation in neonates associates with higher morbidity, including vocal cord paralysis (2-10%) and chylothorax, reflecting the procedure's complexity in vulnerable populations. Ectopic pregnancy risk is notably elevated following tubal ligation failures, comprising 30-50% of post-procedure pregnancies compared to 2% in the general population. Efficacy of surgical ligation is generally high for achieving immediate occlusion, but long-term outcomes depend on the indication and method. Tubal ligation demonstrates a 10-year cumulative pregnancy failure rate of 1.85 per 100 procedures based on the U.S. Collaborative Review of Sterilization (CREST) study, though real-world effectiveness may be lower at 2.9-5.2% due to technique variations like partial salpingectomy versus clips, with failures often from tubal recanalization or undetected patency. Bipolar coagulation exhibits higher failure (7.5 per 1000 at 10 years) compared to partial salpingectomy (2.0 per 1000). For vascular applications, ligation effectively controls hemorrhage intraoperatively with near-100% initial success, but in varicose vein treatment, symptom relief occurs in 80-90% of cases, tempered by 10-20% recurrence over 5 years. Endovascular alternatives often match or exceed ligation efficacy with fewer complications in comparative trials for conditions like type II endoleaks.

Controversies and Ethical Debates

In the early 20th century, eugenics programs in the United States resulted in the forced sterilization of approximately 70,000 individuals, many through tubal ligation procedures, targeting those deemed "unfit" such as the poor, disabled, and racial minorities. The U.S. Supreme Court upheld such practices in Buck v. Bell (1927), affirming the sterilization of Carrie Buck, a woman institutionalized for intellectual disability, as a means to prevent hereditary "defects." These programs, active through the mid-20th century, disproportionately affected women of color and Indigenous populations, with ongoing allegations of coercion persisting into later decades, including reports of non-consensual procedures on Indigenous women as late as the 1970s. Such historical abuses have informed contemporary ethical frameworks emphasizing reproductive autonomy and opposition to coercive practices. Modern ethical debates center on informed consent for tubal ligation, particularly under federal Medicaid regulations requiring a signed consent form at least 30 days prior to the procedure, which has led to over 25% of desired sterilizations being denied due to procedural errors or timing issues. This requirement, intended to prevent coercion, has been criticized for inadvertently restricting access for low-income women, especially postpartum, where delays can necessitate repeat surgeries or unintended pregnancies. Regret rates, reported at 12.7% cumulatively in long-term studies like the U.S. Collaborative Review of Sterilization, rise to 20% for women sterilized at age 30 or younger, prompting concerns about inadequate counseling on permanence and reversibility challenges. Factors correlating with higher regret include youth at procedure time, fewer children, and cohabitation rather than marriage, underscoring the need for thorough risk-benefit discussions. The American College of Obstetricians and Gynecologists (ACOG) advocates a reproductive justice approach, urging providers to address social determinants like poverty that may influence decisions without assuming coercion. Provider refusals based on institutional policies, such as in Catholic hospitals adhering to conscience clauses, have sparked debates over patient access, with some ethicists arguing that denying postpartum exposes women to higher risks from subsequent procedures or unintended births. Post-Dobbs (2022), requests for surged, amplifying discussions on balancing autonomy with regret prevention, as evidenced by increased sterilizations amid restricted abortion access. Allegations of coercion persist in vulnerable populations, including reports from U.S. immigration detention facilities in 2020 involving hysterectomies and sterilizations on migrant women, echoing historical patterns despite federal safeguards. These cases highlight tensions between protecting against abuse and ensuring equitable access, with ethicists recommending enhanced decision aids and mental health evaluations for high-risk candidates.

Molecular Biology Applications

Definition and Mechanism

In molecular biology, ligation refers to the enzymatic process of covalently joining two DNA molecules or fragments by forming a phosphodiester bond between the 3'-hydroxyl group of one strand and the 5'-phosphate group of the adjacent strand. This reaction seals nicks in DNA backbones or connects disparate segments, such as plasmid vectors and inserts during recombinant DNA construction. DNA ligases, the enzymes catalyzing this process, are ubiquitous in cells for completing DNA replication, repair, and recombination, where they ensure genomic integrity by linking Okazaki fragments on the lagging strand or mending double-strand breaks. The mechanism proceeds via a three-step nucleotidyl transfer reaction dependent on a high-energy cofactor—typically ATP in eukaryotic and T4 bacteriophage ligases, or NAD+ in bacterial ligases like that from Escherichia coli. First, the ligase's active site lysine residue performs a nucleophilic attack on the α-phosphate of the cofactor, releasing pyrophosphate (from ATP) or NMN (from NAD+) and forming a covalent ligase-adenylate intermediate. Second, this activated adenylate transfers to the 5'-phosphate terminus of the DNA substrate, generating a pyrophosphate-linked DNA-adenylate (AppDNA) complex while freeing the enzyme. In the final step, the proximate 3'-hydroxyl group attacks the adenylated 5'-phosphate, displacing AMP and forging the stable phosphodiester bond; magnesium ions (Mg²⁺) are essential as cofactors for stabilizing the transition state and facilitating phosphate transfer. Ligation efficiency varies with end compatibility: cohesive (sticky) ends, featuring complementary single-stranded overhangs, anneal via base pairing to position substrates optimally, yielding higher rates than blunt-end ligation, which relies solely on transient collisions without such guidance and often requires higher enzyme concentrations or polyethylene glycol to enhance encounters. The reaction demands double-stranded DNA contexts for stability, as single-stranded substrates bind poorly, and fidelity mechanisms, including proofreading by associated factors like aprataxin, suppress errors such as single-base insertions during sealing. In vitro applications, such as cloning, predominantly employ due to its robustness across temperatures (optimal at 16–25°C) and tolerance for diverse substrates.

Enzymes and Reaction Factors

DNA ligases are the principal enzymes used in molecular biology for catalyzing the formation of phosphodiester bonds between the 3'-hydroxyl and 5'-phosphate termini of double-stranded DNA fragments, sealing nicks or joining compatible ends during cloning and recombinant DNA construction. These enzymes operate via a three-step mechanism: adenylylation of the ligase with or to form a ligase-AMP intermediate, transfer of AMP to the 5'-phosphate of DNA, and subsequent nucleophilic attack by the 3'-hydroxyl to form the bond, releasing AMP. -dependent ligases, prevalent in eukaryotes and viruses like bacteriophage , predominate in laboratory applications due to their versatility, while -dependent ligases, found in bacteria such as , exhibit greater specificity for cohesive ends. T4 DNA ligase, isolated from bacteriophage T4-infected E. coli, is the most widely employed for its efficiency in ligating both cohesive (sticky) and blunt-ended DNA fragments, enabling applications in plasmid construction and next-generation sequencing library preparation. In contrast, E. coli DNA ligase preferentially seals nicks in double-stranded DNA with cohesive ends but fails to efficiently join blunt ends under standard conditions, limiting its use to scenarios requiring high specificity for annealed sticky ends.
FeatureT4 DNA LigaseE. coli DNA Ligase
CofactorATP NAD+
Blunt-end ligationEfficient Inefficient
Cohesive-end specificityModerate High
SourceBacteriophage T4 E. coli bacterium
Ligation efficiency depends on several reaction factors, including cofactor availability, divalent cations, pH, temperature, incubation duration, and DNA parameters. T4 DNA ligase requires 1 mM ATP in the reaction mix, with magnesium ions (typically 10 mM MgCl₂) serving as a cofactor for phosphodiester bond formation; ATP depletion, often from repeated freeze-thaw cycles, reduces yields, necessitating fresh aliquots stored at -20°C. Buffers are optimized at pH 7.5–8.0 with reducing agents like 1–10 mM DTT to maintain enzyme activity, and reactions should exclude residual restriction endonucleases, which can be inactivated by heat (65–80°C for 10–20 min) or purification to prevent re-cleavage. Temperature balances enzyme activity and end annealing: for cohesive ends with T4 ligase, 20–25°C for 10–30 minutes suffices, while blunt ends benefit from 16°C overnight or thermal cycling (e.g., 25°C annealing followed by 16°C ligation) to enhance stability without favoring exonuclease side activities. DNA concentration should total 1–10 ng/µL to minimize concatemer formation, with vector:insert molar ratios of 1:1 to 1:3 for single inserts or up to 1:10 for challenging ligations, calculated via tools accounting for fragment sizes. High salt or ethanol carryover from purification inhibits reactions, underscoring the need for clean, equimolar preparations.

Techniques and Variations

Classical DNA ligation techniques primarily involve the use of ATP- or NAD+-dependent to seal nicks or join DNA fragments with compatible ends. Cohesive-end (sticky-end) ligation, which relies on complementary overhangs generated by , is the most efficient method due to the increased effective molarity of the reacting groups, often achieving transformation efficiencies exceeding 10^6 colonies per microgram of vector in optimal conditions. Blunt-end ligation, lacking such overhangs, proceeds more slowly and requires higher DNA concentrations (typically 10-50 ng/μL), longer incubation times (e.g., overnight at 4-16°C), or crowding agents like to enhance efficiency, as the entropy loss in aligning termini reduces reaction rates by orders of magnitude compared to sticky ends. T4 DNA ligase, derived from bacteriophage T4, is the predominant enzyme for both, operating via a three-step mechanism: adenylation of the enzyme, transfer to the 5'-phosphate, and phosphodiester bond formation, with optimal activity at 16°C for cohesive ends and room temperature for blunts. Variations in ligation protocols adapt to specific substrates and goals, including the use of alternative ligases like E. coli DNA ligase (NAD+-dependent, less effective on blunt ends) or thermostable Taq ligase for high-temperature applications such as ligase chain reaction (LCR). Splint-assisted or template-directed ligation employs an auxiliary oligonucleotide to align non-complementary ends, improving specificity and yield in synthetic biology or nick-sealing assays, as demonstrated in methods for de novo oligonucleotide synthesis where shortmers are iteratively joined with >90% efficiency per step. Ligation-independent cloning (LIC) methods bypass ligases entirely by generating 10-15 nucleotide single-stranded overhangs via T4 exonuclease treatment of PCR products, allowing homologous recombination in vivo or in vitro annealing, which rivals or surpasses traditional ligation efficiencies (up to 90% positive clones) while eliminating restriction scars and enabling seamless multi-fragment assembly. Sequence and ligation-independent cloning (SLIC), a LIC variant, further optimizes this by combining exonuclease recursion with controlled denaturation-annealing cycles, suitable for complex assemblies without specialized vectors. Advanced variations address and substrate specificity, such as high-fidelity ligases engineered to discriminate against or bulged nicks, reducing rates in Okazaki fragment maturation models to below 10^-5 per ligation event. Proximity ligation assays () adapt ligase specificity for detecting protein-DNA or interactions by templating ligation only upon molecular proximity, amplifying signals for visualization with single-molecule resolution. Recent innovations include deoxyribozyme-mediated "" ligation, which achieves rapid, scarless joining under mild conditions via in vitro-selected ribozymes, offering alternatives to protein enzymes for orthogonal chemistries in . These techniques collectively expand ligation's utility, with selection guided by factors like end compatibility, reaction kinetics (e.g., k_cat/K_M values differing by 10-100 fold between sticky and blunt), and downstream compatibility.

Applications in Biotechnology

DNA ligation is a cornerstone technique in , enabling the precise joining of DNA fragments to create recombinant molecules for and . Primarily facilitated by enzymes like T4 DNA ligase, it covalently seals phosphodiester bonds between compatible DNA ends, typically those generated by restriction enzymes or amplification, allowing the integration of foreign DNA into vectors for propagation and expression in host cells such as . This process underpins , where a of interest is inserted into a , forming a construct that can be transformed into bacteria for amplification and downstream applications like . In recombinant DNA technology, ligation facilitates the construction of expression used to produce therapeutic proteins, including insulin and monoclonal antibodies, by linking coding sequences to promoter regions and selectable markers. For instance, T4 DNA ligase's ability to join both cohesive (sticky) and blunt-ended fragments supports efficient workflows, with reaction efficiencies often exceeding 80% under optimized conditions involving ATP and appropriate molar ratios of insert to vector. Beyond basic , ligation enables the assembly of multi-fragment constructs in , such as synthetic genes or metabolic pathways, by sequentially or simultaneously joining or products into larger plasmids. Ligation also plays a key role in library preparation for next-generation sequencing (NGS), where adapters are ligated to sheared DNA fragments to enable high-throughput analysis of genomes, transcriptomes, or epigenomes in biotechnological research and diagnostics. In vector engineering for gene therapy, it allows the incorporation of therapeutic genes into viral backbones, such as adeno-associated virus plasmids, enhancing delivery efficiency in applications like CRISPR-Cas9-based editing constructs. These methods have been refined since the 1970s, with commercial kits now standardizing protocols to minimize background ligation and improve transformation yields up to 10^6 colonies per microgram of DNA.

Recent Advances and Innovations

In recent years, advancements in DNA ligation have emphasized enzyme-free chemical strategies and enhanced enzymatic efficiencies to address limitations in specificity, yield, and compatibility with modified nucleotides. For instance, template-dependent DNA ligation using T3 DNA ligase has enabled the de novo synthesis of modified oligonucleotides by joining shortmer fragments with high fidelity, offering an alternative to traditional phosphoramidite chemistry for incorporating non-natural bases. Similarly, enzyme-free chemical ligation methods, such as amine-crosslinker-mediated approaches, have been developed for miRNA detection, achieving robust splint-assisted joining without relying on ligases, which reduces costs and improves stability in diagnostic applications. Innovations in ligation-assisted assembly include ligation-induced self-assembly protocols that leverage DNA ligase activity to drive dynamic nanostructure formation, rather than mere post-assembly stabilization, enabling programmable architectures with potential in nanotechnology. In cloning technologies, refined Golden Gate systems have incorporated optimized Type IIS restriction-ligation cycles for seamless multi-fragment assembly, simplifying vector construction and expanding compatibility with diverse inserts as of 2024. Chemical ligation techniques have also progressed to connect DNA with analogs like l-α-threofuranosyl nucleic acid (l-aTNA) via template-directed hydroxyl-monophosphate coupling, broadening applications in synthetic biology. Enzymatic improvements include high-fidelity variants of , commercially introduced around 2022, which enhance accuracy in next-generation sequencing library preparation by minimizing errors during blunt-end joining. Splint ligation methods for single-stranded DNA library preparation have shown superior efficiency over traditional CircLigase approaches, particularly for full-length analysis, as demonstrated in protocols refined by 2023. These developments collectively improve scalability and precision in genome engineering, though challenges persist in handling large constructs without off-target effects.

Other Contexts

Chemical and Peptide Ligation

Chemical ligation encompasses chemoselective methods for covalently linking unprotected or protein fragments in , typically forming bonds without enzymatic . These techniques enable the assembly of larger polypeptides from smaller segments, facilitating total or of proteins that are challenging to produce recombinantly. Unlike enzymatic ligations, chemical approaches rely on orthogonal reactivity, often at specific residues like or thioesters, to achieve high selectivity under mild conditions. Native chemical ligation (NCL), the cornerstone of modern ligation, was introduced by and colleagues in 1994 as a strategy to synthesize native backbone proteins of moderate size (up to approximately 150 initially). The reaction proceeds between a peptide bearing a C-terminal and another with an N-terminal residue. The involves initial transthioesterification, where the cysteine thiol attacks the thioester carbonyl, forming a , followed by an intramolecular S-to-N acyl shift to yield a native amide bond. This process occurs efficiently in aqueous buffers at neutral pH and , with yields often exceeding 80% for optimized fragments. To overcome limitations of dependence (occurring in only about 1-2% of protein residues), extended NCL variants incorporate removable auxiliaries or desulfurization protocols. For instance, cysteine-to-alanine conversion via deselenization or radical reduction allows ligation at non-cysteine sites, enabling access to proteins up to 300 residues. , a hybrid method developed in the late , integrates recombinant with NCL by using engineered inteins to generate C-terminal thioesters from expressed fragments, which then ligate to synthetic peptides. This semisynthetic approach has been applied to ubiquitinated proteins and modifications, yielding homogeneous samples for structural studies. Thiol-independent peptide ligations, reviewed in mechanisms from 2006 onward, employ alternative chemistries such as hydrazide-thioester reactions or alpha-ketoacid-hydroxylamine couplings to form bonds at diverse sites. These methods expand applicability to cyclic and post-translationally modified proteins, with recent advances like trifluoroacetic acid-mediated enhancements achieving ligation efficiencies over 90% for difficult sequences. Overall, chemical and ligation techniques have revolutionized , enabling precise incorporation of unnatural , labels, or mirrors for therapeutic and biophysical applications, as demonstrated in syntheses of enzymes like (76 residues) in fully active forms.

Applications in Dentistry and Miscellaneous Fields

In , ligation secures the archwire to brackets on teeth to apply corrective forces. Traditional ligation employs ties or elastomeric modules, which encircle the wire and bracket slot to maintain alignment, though they can increase and require frequent adjustments. Self-ligating brackets, introduced in the late and refined through systems like Damon, use an integrated clip or door mechanism to hold the wire without external ties, potentially reducing treatment duration by 4-6 months and chair time by minimizing ligation visits. In oral surgery, ligation achieves by tying off vessels with absorbable or nonabsorbable sutures during procedures like extractions or flap surgeries, preventing excessive from sites such as the . For impacted teeth, surgical exposure involves incising the gingiva, bonding an attachment to the crown, and ligating an elastic chain or wire to guide eruption via orthodontic traction, a standard since the 1970s with success rates exceeding 90% for canines. Rubber dam ligation uses ties—often overhand knots with one or two loops—to isolate teeth, enhancing and control in restorative work. Beyond dentistry, surgical ligation occludes anatomical structures for or functional interruption. In gynecology, —performed laparoscopically or via minilaparotomy since the 1970s—severs and ties fallopian tubes to achieve permanent sterilization, with failure rates under 1% for methods like Pomeroy. General applications include vessel ligation in or surgeries to control hemorrhage, and duct ligation for conditions like sialorrhea, where submandibular and parotid ducts are tied to reduce flow, offering efficacy in pediatric cases refractory to conservative measures.

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