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MAPP gas

MAPP gas, an acronym for methylacetylene-propadiene propane, is a stabilized liquefied petroleum gas mixture primarily composed of methylacetylene (propyne, 27-33%), propadiene (allene, 13-15%), propylene (40-50%), and smaller amounts of propane, n-butane, and isobutane, designed for use as a high-temperature fuel in oxy-fuel applications.^[1] It achieves a flame temperature of up to 2,925 °C (5,300 °F) when combined with oxygen, making it suitable for tasks requiring intense heat while being easier to handle and store than pure acetylene due to its lack of need for solvent stabilization like acetone.^[2] Originally trademarked by The Linde Group (formerly associated with Union Carbide and Dow Chemical), MAPP gas was introduced in the mid-20th century as a versatile industrial fuel for maintenance, repair, and fabrication work, particularly in environments where portability and safety were priorities.^[3] Its production in North America ceased in April 2008 following the closure of the sole manufacturing facility at the Petromont Varennes plant in Quebec, driven by economic pressures including a strong Canadian dollar, feedstock shortages, and reduced market demand, leading to the substitution of the original formula with alternatives like propylene-based "MAP-Pro" gases.^[4]^[5] In applications, MAPP gas excels in brazing, soldering, heating, cutting, and preheating metals such as copper, steel, and aluminum, offering over twice the usable volume of an equivalent acetylene cylinder (e.g., 70 pounds of MAPP yields about 1,500 cubic feet) and operational pressures up to 95 psig without explosion risk from shock.^[2] However, it is not ideal for high-strength steel welding due to hydrogen in the flame causing brittleness, and modern variants prioritize similar performance with enhanced stability. Safety considerations include its extreme flammability (lower explosive limit of 3.4%, upper 10.8%), potential for asphyxiation in confined spaces, and frostbite from rapid expansion, necessitating well-ventilated use, protective gear, and storage away from ignition sources.^[3]

History and Production

Development and Introduction

MAPP gas was invented in the mid-20th century by the Dow Chemical Company as a stabilized liquefied gas mixture designed to serve as a safer alternative to acetylene for welding and cutting applications.^[6] Developed during the 1960s, it addressed the instability and explosion risks associated with pure methylacetylene by incorporating propane as a stabilizing agent, allowing for safer handling and storage in portable cylinders.^[7] The trademark "MAPP" derives from MethylAcetylene-Propadiene Propane, which directly reflects the original composition of the gas mixture primarily consisting of methylacetylene (propyne), propadiene, and propane.^[8] This formulation was a byproduct of Dow's petrochemical processes, particularly the C3 splitter bottoms rich in methylacetylene-propadiene (MAPD), which were refined and marketed as a high-performance fuel.^[7] MAPP gas was commercially launched in the early 1960s, initially targeting industrial users for oxy-fuel torches where its enhanced stability provided significant safety advantages over pure methylacetylene, which could polymerize explosively under certain conditions.^[9] Shortly thereafter, distribution rights were adopted by Union Carbide, through its Linde division (later part of the Linde Group), enabling broader commercialization and availability for professional applications.^[10] Early marketing emphasized MAPP gas as a portable, high-heat fuel that delivered intense flame temperatures suitable for brazing and soldering while eliminating the need for specialized storage to mitigate acetylene's dissociation and explosion hazards.^[6] This positioning quickly gained traction in industrial settings, positioning MAPP as a practical substitute that balanced performance with reduced risk.

Manufacturing and Discontinuation

MAPP gas was produced by stabilizing liquefied petroleum gas (LPG) fractions rich in methylacetylene and propadiene through proprietary processes that incorporated alkane and alkylene hydrocarbons as inhibitors to prevent unwanted polymerization of these reactive components.^[8] This stabilization was essential to ensure the gas mixture remained safe and stable for storage and transport under pressure.^[7] The original formulation and production method were developed by Dow Chemical Company, which held the initial trademark and marketed the gas starting in the 1960s.^[11] Following Dow's involvement, production shifted to specialized facilities under license, with the trademark eventually transferred to The Linde Group, a division of Union Carbide.^[11] By the early 2000s, the sole North American manufacturing site was the Petromont facility in Varennes, Quebec, operated as a joint venture in the petrochemical sector. This plant handled the final stages of blending and stabilization for commercial distribution. Production of genuine MAPP gas ceased globally in 2008 when the Petromont Varennes plant shut down on April 30, marking the end of all manufacturing operations worldwide.^[4] The closure was driven by economic pressures, including persistently high costs for petroleum-based feedstocks, a strengthening Canadian dollar that eroded competitiveness, and the increasing value of propadiene as a petrochemical feedstock for higher-demand applications, making its diversion from fuel gas production more profitable.^[4] Additionally, regulatory challenges associated with handling the unstable methylacetylene and propadiene components contributed to elevated production and safety compliance costs.^[12] The discontinuation accelerated a market shift toward cheaper, more stable alternatives like propylene-based gases, which offered similar performance at lower expense. Existing stockpiles were rapidly depleted through 2009, resulting in widespread scarcity across major markets in the United States and Europe, where MAPP had been a staple for industrial and professional applications.^[4]

Composition

Original Formulation

The original formulation of MAPP gas, developed by Union Carbide in the 1960s, was designed to deliver acetylene-like performance for welding and cutting applications while minimizing associated hazards such as instability under pressure.^[13] This mixture primarily comprised approximately 48% methylacetylene (propyne,

\ce{CH3C#CH}

), 23% propadiene (allene, \ce{H2C=C=CH2}), and 27% propane (\ce{C3H8}), along with trace amounts of other hydrocarbons to enhance stability.^[14] In this composition, propane functioned as a diluent, inhibiting the polymerization and potential explosive decomposition of the more reactive methylacetylene and propadiene components by other alkane and alkene hydrocarbons.^[15] To preserve the mixture's integrity, the gas was liquefied under its own vapor pressure, which prevented unwanted reactions like polymerization during storage and transport.^[8]

Subsequent Variations

Following the discontinuation of the original MAPP gas formulation in the late 20th century, producers introduced modified compositions in the early 2000s to address production challenges and market demands. These subsequent variations shifted the mixture to incorporate a higher proportion of propylene (C₃H₆) at approximately 43%, while reducing propyne to 30% and propadiene to 14%; the blend also included 7% propane and 6% butanes (C₄H₁₀).^[16] This adjustment built on the foundational methylacetylene-propadiene-propane mix by integrating more readily available hydrocarbons.^[16] The primary motivations for these reformulations were cost efficiency, achieved through the use of abundant propylene as a refinery by-product, and enhanced stability during storage and transportation, as propylene is less prone to polymerization than higher concentrations of propadiene. Union Carbide, the original developer, and later Linde—implemented these tweaks to align with evolving safety regulations, such as updated OSHA standards on flammable gas handling and storage in the 1980s and 1990s, which emphasized reduced volatility in commercial mixtures. These changes resulted in a slight decrease in maximum flame temperature compared to the original formulation, from around 2,930°C to approximately 2,900°C, but preserved sufficient performance for welding, soldering, and heating tasks in industrial settings.^[16] Overall, the variations maintained broad usability while improving economic viability and compliance. Production of these formulations ceased in North America in April 2008.^[4]

Properties

Physical Properties

MAPP gas appears as a colorless substance in both its liquid and gaseous forms. It exhibits a characteristic pungent or fishy odor, detectable at concentrations above 100 ppm, attributable to trace impurities in the mixture.^[17]^[18] For storage and transport, MAPP gas is liquefied under pressure in cylinders rated at 250 psi, with its vapor density measuring approximately 1.5 times that of air at standard conditions. The gas density is about 0.11 lb/ft³.^[19]^[20]^[21] The boiling point of MAPP gas is approximately -48°C, while its melting point is around -185°C, ensuring stability without freezing under typical usage temperatures. It demonstrates slight solubility in water and high miscibility with other hydrocarbons.^[20]^[21]^[22] As a simple asphyxiant, MAPP gas can cause irritation to the respiratory tract at concentrations exceeding 500 ppm (ACGIH TWA), though its primary hazard stems from oxygen displacement rather than direct toxicity.^[20]^[17]

Thermal Properties

MAPP gas exhibits notable thermal characteristics that make it suitable for high-temperature applications, particularly in oxy-fuel processes. When combusted with oxygen, it achieves an adiabatic flame temperature of approximately 2,925 °C (5,300 °F), enabling efficient heating for tasks like brazing and cutting. In air, the flame temperature is lower, reaching about 2,020 °C (3,670 °F), which still surpasses that of propane under similar conditions. These temperatures reflect the gas's ability to deliver concentrated heat, with superior heat transfer efficiency for localized applications compared to propane due to its elevated adiabatic flame temperature.^[23] The energy content of MAPP gas is approximately 21,700 BTU per pound (50.5 MJ/kg), providing a high calorific value that supports sustained combustion. This is slightly higher than propane's 21,500 BTU/lb and comparable to acetylene's 21,600 BTU/lb, contributing to its effectiveness in professional torches despite the mixture's complexity. The combustion primarily involves the methylacetylene and propadiene components, following the general reaction for methylacetylene: \ce{[C3H4](/page/C3H4) + 4O2 -> 3CO2 + 2H2O + heat}, which yields a clean burn with minimal soot formation owing to the stabilized hydrocarbon blend.^[24]^[25]^[26] Ignition properties further define its thermal behavior, with an autoignition temperature of around 455 °C (851 °F) and a flammable range of 3% to 11% in air, allowing reliable initiation while minimizing unintended ignition risks in controlled environments. These attributes underscore MAPP gas's role in delivering precise, high-energy flames prior to its discontinuation.^[20]^[27]

Applications

Industrial and Professional Uses

MAPP gas found extensive application in oxy-fuel welding processes, particularly for joining small steel components up to approximately 1/4 inch thick, where its stable flame provided sufficient heat without the instability risks associated with acetylene.^[2] These capabilities made MAPP gas a preferred choice in metal fabrication shops for precise, localized heating tasks during the late 20th century. In brazing and soldering operations, MAPP gas excelled due to its sustained high-temperature flame, reaching up to 2,925°C when combined with oxygen, which allowed for efficient formation of strong joints in demanding professional settings.^[28] It was commonly used in plumbing for silver brazing copper pipes, in HVAC systems for refrigerant line connections, and in jewelry manufacturing for intricate metalwork requiring controlled heat to avoid warping delicate pieces.^[29] The gas's ability to maintain consistent heat over extended periods reduced cycle times in these applications, enhancing productivity in industrial workflows. Underwater, MAPP gas powered exothermic cutting torches in naval salvage operations, enabling divers to sever steel structures in shipwrecks and damaged vessels where electrical power for arc tools was unavailable.^[13] Developed as a safer alternative to acetylene, it was evaluated by the U.S. Navy in the 1970s for such uses, offering portability to depths up to 150 feet with standard equipment.^[30] However, it was later supplanted by advanced specialized tools like thermal lances for more efficient deep-water cutting. Compared to acetylene, MAPP gas offered key advantages in industrial settings, including the absence of cylinder porosity requirements—no need for acetone-soaked fillers to prevent decomposition—allowing higher storage pressures up to 95-100 psi and greater portability for field work.^[31] This stability eliminated acetylene's 15 psi limit, making MAPP cylinders lighter and more compact without compromising safety.^[2] Its adoption peaked from the 1970s to the 1990s in automotive repair shops for body panel fabrication and exhaust system brazing, as well as in broader metalworking industries for on-site maintenance.^[32]

Consumer and Specialized Uses

MAPP gas found widespread adoption in culinary settings due to its high flame temperature, enabling precise high-heat applications such as searing meats in sous-vide cooking and torching the sugar topping for crème brûlée.^[33] In professional kitchens, it was valued for tasks requiring intense, controlled heat, with cylinders designed to be safe for direct food contact during preparation.^[34] Chefs appreciated its efficiency over butane or propane for achieving a rapid Maillard reaction without imparting off-flavors when properly adjusted.^[33] Among hobbyists and DIY enthusiasts, MAPP gas powered handheld torches for soldering, where its hotter flame allowed for quicker joints.^[35] For small-scale metalworking, artisans employed it in tasks like bending or shaping thin metals for custom projects. In specialized fields, MAPP gas torches supported jewelry making through precise soldering and annealing of silver and gold pieces, offering a hotter alternative to propane for detailed work.^[36] Consumer formats typically consisted of portable 14.1-ounce cylinders compatible with handheld torches, making them accessible for non-professional use in garages or kitchens.^[37] These gained popularity in culinary trends from the 1980s onward, aligning with the rise of torch-based techniques in gourmet cooking until the gas's discontinuation.^[33]

Safety and Handling

Health and Exposure Risks

MAPP gas primarily presents health risks through inhalation, acting as a simple asphyxiant that displaces oxygen and reduces its availability in breathing air, particularly in confined or poorly ventilated spaces.^[38] This displacement can lead to rapid suffocation without warning, as the gas itself has low inherent toxicity but interferes with normal respiration.^[39] The Immediately Dangerous to Life or Health (IDLH) concentration for methyl acetylene-propadiene mixture is established at 3,400 ppm, equivalent to 10% of the lower explosive limit, beyond which exposure poses severe risks of both asphyxiation and potential ignition hazards.^[40] Occupational exposure limits are set to mitigate these risks: the Occupational Safety and Health Administration (OSHA) permissible exposure limit (PEL) is 1,000 ppm as an 8-hour time-weighted average (TWA), while the National Institute for Occupational Safety and Health (NIOSH) recommended exposure limit (REL) is also 1,000 ppm (8-hour TWA) with a short-term exposure limit (STEL) of 1,250 ppm for 15 minutes.^[38]^[3] Exceeding these thresholds increases the likelihood of adverse effects, with concentrations approaching the IDLH level considered immediately threatening. Acute effects from inhalation typically include respiratory tract irritation, excitement, confusion, and central nervous system depression leading to anesthesia.^[38] At elevated levels around 5,000 ppm, symptoms such as nausea and anesthetic-like effects may manifest, potentially progressing to dizziness and loss of consciousness at concentrations exceeding 10,000 ppm, based on observations from similar hydrocarbon gases.^[15] Liquid contact, though less common in gaseous exposure scenarios, can cause frostbite-like burns due to rapid evaporative cooling.^[41] Toxicity varies by component: propadiene primarily irritates the eyes and respiratory tract upon exposure, contributing to immediate discomfort in mucous membranes. Propyne, or methylacetylene, functions mainly as a simple asphyxiant with narcotic properties, inducing headaches, dizziness, nausea, and respiratory irritation during prolonged or high-level inhalation.^[42] Propane, the stabilizing component, exerts effects almost exclusively through oxygen displacement rather than direct chemical toxicity.^[43] Chronic exposure to MAPP gas or its hydrocarbon components has been linked to potential liver and kidney damage in occupational settings, as evidenced by cases of abnormal liver function and hepatitis from repeated inhalation of similar gases like propane.^[44] Animal studies on the mixture indicate possible long-term lung irritation, underscoring the need for controlled exposure.^[27] To prevent exposure in confined spaces, continuous monitoring with calibrated gas detectors is recommended to alert workers to accumulating MAPP concentrations and declining oxygen levels below 19.5%.^[45] MAPP gas possesses a faint sweet odor that may provide an initial sensory cue for leaks, though odor thresholds vary and should not replace instrumental detection.^[38]

Fire and Storage Hazards

MAPP gas is classified as an extremely flammable gas under hazardous materials regulations, specifically in the Flammable Gases Category 1, with a flash point below -100°C.^[46] It poses significant fire risks due to its ability to ignite easily and burn with a nearly invisible flame in well-lit conditions.^[46] The gas forms explosive mixtures with air between the lower explosive limit (LEL) of 3.4% and upper explosive limit (UEL) of approximately 11% by volume.^[47]^[46] Cylinders containing MAPP gas, which are under high pressure, can rupture violently if exposed to temperatures exceeding 50°C, potentially leading to a boiling liquid expanding vapor explosion (BLEVE).^[21] Such overpressurization risks are heightened in confined or hot environments, where heat buildup can compromise cylinder integrity.^[48] Proper storage is essential to mitigate these hazards; MAPP gas cylinders must be kept in cool, well-ventilated areas away from ignition sources, direct sunlight, and temperatures above 50°C, using U.S. Department of Transportation (DOT)-approved containers secured upright to prevent tipping.^[46]^[21] Grounding cylinders during handling helps avoid static electricity sparks.^[49] In emergencies, fires involving MAPP gas should be fought with dry chemical, foam, or water fog extinguishers, while avoiding direct streams that could scatter burning liquid; firefighters must use self-contained breathing apparatus and full protective gear.^[46] For gas leaks, immediately evacuate the area, eliminate ignition sources, and ventilate to disperse vapors before re-entry, as concentrations above 10% of the LEL require professional intervention.^[46]^[21] Incidents involving MAPP gas cylinders are rare but have included explosions due to overpressurization in hot environments, such as a 2010 case in Queensland, Australia, where a cylinder detonated inside a parked vehicle, highlighting the dangers of improper storage in enclosed or sun-exposed spaces.^[48] Other notable failures have stemmed from manufacturing defects, like faulty seals leading to leaks and potential ruptures.^[50]

Alternatives and Legacy

Reasons for Discontinuation

The production of MAPP gas ceased in early 2008 following the indefinite suspension of operations at the Petromont facility in Varennes, Quebec, the sole North American plant manufacturing the gas. This closure stemmed primarily from economic pressures, including difficulties in securing competitively priced petroleum-based feedstocks, a strong Canadian dollar that eroded export competitiveness, and elevated energy costs that rendered operations unprofitable.^[4]^[51] These challenges were exacerbated by rising costs for key raw materials such as propyne and propadiene, which increased the overall expense of production relative to market prices for the fuel.^[4] Concurrently, market dynamics shifted toward more cost-effective and stable alternatives like propylene, which offered comparable performance for many applications at lower prices, further diminishing demand for MAPP gas.^[51] Global supply chain disruptions in the petrochemical sector after 2000 compounded these issues, limiting access to specialized feedstocks and accelerating the transition away from MAPP gas. The period from 2008 to 2010 marked a challenging legacy phase, characterized by stockpiling, escalating prices for remaining authentic supplies, and the proliferation of counterfeit or relabeled products that misled consumers seeking the original formulation.^[4]

Modern Substitutes

Following the discontinuation of original MAPP gas, primary substitutes have centered on propylene-based fuels, with MAP-Pro emerging as the most widely adopted alternative for high-heat applications such as brazing and soldering. MAP-Pro, produced by Bernzomatic, consists primarily of propylene (99.5–100%) with trace amounts of propane (0–0.5%).^[52] This composition delivers a flame temperature of 3,730°F (2,054°C) in air, closely approximating the original MAPP's performance while offering improved stability due to the absence of more volatile components like propadiene.^[37] When combined with oxygen, MAP-Pro achieves temperatures around 5,200°F (2,870°C), enabling efficient heat transfer for tasks previously reliant on MAPP.^[23] Other propylene-based options include MAP-X and similar blends, which typically incorporate 90–99% propylene mixed with small percentages of propane or dimethyl ether for enhanced ignition and reduced cylinder pressure.^[53] These formulations maintain compatibility with MAPP-era torches and provide flame temperatures in the 3,600–3,800°F range in air, suitable for professional welding and cutting. For lower-heat requirements, such as general soldering or thawing, pure propane serves as a cost-effective substitute, burning at approximately 3,600°F in air but with about 10–20% less overall energy output compared to propylene mixes.^[54] In terms of performance, modern substitutes like MAP-Pro deliver 80–90% of the original MAPP's heat content (measured in BTU per cubic foot), with primary flame heating values around 500–570 BTU/cu ft versus MAPP's 570 BTU/cu ft benchmark, while exhibiting greater stability and lower risk of flashback.^[55] They are also more economical, with 14.1 oz cylinders typically priced at $10–15, compared to the $20+ for equivalent pre-discontinuation MAPP units.^[56] These gases are branded as "MAPP-compatible" and fit standard CGA 600 connections, ensuring seamless integration with legacy equipment for applications like HVAC repairs and metalworking.^[57] By 2012, the market had fully transitioned to these substitutes following the 2008 cessation of MAPP production in North America, driven by supply chain efficiencies and preferences for simpler hydrocarbon blends. As of 2025, propylene-based products continue to dominate global availability for industrial and consumer use, with no resumption of original MAPP production.^[53] In some regions, legacy references to "MAPP" persist for compatibility labeling, but propylene-based products dominate global availability for industrial and consumer use.^[58]

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### Summary of MAPP Gas (Liquefied Petroleum Gas with Methyl Acetylene-Propadiene)
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Feb 25, 2008 · Various factors are responsible for closure including problems in procuring competitively-priced petroleum-based feedstock, the unfavourable ...
[53]
DIFFERENCE BETWEEN MAPP GAS AND MAPP PRO - SHINGCHEM
Feb 17, 2025 · MAPP gas (Methylacetylene-Propadiene Propane) is a mixed gas composed of methylacetylene, propadiene and propane. Due to its high combustion ...
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[PDF] MAP-PRO Cylinder - MsdsDigital.com
May 22, 2017 · SAFETY DATA SHEET. Section 1. Identification of the material and the supplier. Product: BernzOmatic MAP-PRO® Cylinder. Product Code: 1811120 ...
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https://www.gossonline.com/oxy-fuel-equipment/kits/mapp-gas-cylinder6287a440
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[PDF] map-pro™ vs. propane - Tractor Supply
MAP-Pro fuel has more heat transfer in the primary flame than Propane. P ... Flame Temperature in Air. 3,600° F / 1982.2° C, ideal for general soldering ...Missing: energy properties
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Mapp Gas Cylinder | Goss
Combustion intensity is 91% higher than standard propane. Ideal for ... Flame Temperature(In Air)-°F, 4690, 3750, 3730, 3600, 3580, 3550. Primary Flame ...
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Bernzomatic - 14.1 Ounce MAP-Pro Cylinder | MSC Direct
$$12.39 /ea. Web Price. Bernzomatic · Propane & Butane Fuel Canisters & Cylinders. MSC # 70132618.
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Bernzomatic Pre-Filled MAP-Pro Gas Torch Style Cylinder 14.1 oz ...
30-day returnsHigh flame temperature: MAP-Pro fuel provides an impressive in-air flame temperature of 3,730 degrees Fahrenheit, allowing for powerful and precise heat ...
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BLUEFIRE (2) 14.1 oz Modern MAPP Gas Cylinder 99.9% High ...
30-day returnsCamping gas (approximately 70% Butane and 30% Propane): Special formula aim for outdoor uses, especially for camping and climbing sports in high altitude ...Missing: 48% methylacetylene 23% propadiene 27%