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Polyphenylsulfone

Polyphenylsulfone (PPSU), also known as PPSF, is a high-performance amorphous polymer from the family, renowned for its superior thermal stability, mechanical strength, and chemical resistance. Its consists of a repeating unit featuring aromatic phenylene rings connected by (-SO₂-) groups, linkages, and a moiety, typically synthesized via of 4,4'-dihydroxybiphenyl and 4,4'-dichlorodiphenyl , though variations may include . This rigid, conjugated backbone imparts a temperature of approximately 220°C and enables continuous use at temperatures up to approximately 200°C, with short-term exposure to 260°C, distinguishing it from related polymers like (PSU) and polyethersulfone (PES). Commercialized in 1976 by (now under Syensqo as Radel®), PPSU was developed to meet the needs of high-stress environments requiring durability and . Key properties include a tensile strength exceeding 70 , flexural around 105 , and exceptional impact resistance, with notched values of about 3.8 J/cm. It demonstrates outstanding hydrolytic stability, tolerating over 1,000 steam sterilization cycles at 134°C, and resists a broad range (1–13) as well as exposure to acids, bases, oils, and chlorinated solvents. Additionally, its inherent hydrophobicity supports applications in , though modifications can enhance wettability for specific uses. PPSU finds extensive use across industries due to these attributes. In medical and healthcare, it is for surgical instruments, trays, components, and baby bottles, being BPA-free and compliant with biocompatibility standards. In aerospace and automotive, it serves in interior panels, electrical connectors, and sensors for its lightweight strength and flame retardancy (UL94 V-0 rating). For filtration and water treatment, PPSU membranes excel in ultrafiltration, nanofiltration, and gas separation processes, offering high flux and fouling resistance in demanding conditions like and fuel cells. Other applications include fittings (e.g., PEX components) and housings, where its NSF ensures suitability for potable water contact. Overall, PPSU's balance of processability—via injection molding, , or —and performance makes it a preferred for solutions requiring reliability under extreme conditions.

Chemical Structure and Synthesis

Molecular Composition

Polyphenylsulfone (PPSU) is an aromatic thermoplastic polymer characterized by its backbone of phenyl rings interconnected via sulfone (-SO₂-) groups and ether (-O-) linkages, with biphenyl units incorporated to enhance chain rigidity and thermal performance. Commercial PPSU is a random copolymer derived from bisphenol S (4,4'-dihydroxydiphenyl sulfone) and 4,4'-dihydroxybiphenyl (biphenol) with 4,4'-dichlorodiphenyl sulfone. It contains two types of repeating units: one from bisphenol S and DCDPS, [-O-C₆H₄(1,4)-SO₂-C₆H₄(1,4)-O-C₆H₄(1,4)-SO₂-C₆H₄(1,4)-] (as in polyethersulfone), and one from biphenol and DCDPS, [-C₆H₄(1,4)-SO₂-C₆H₄(1,4)-O-C₆H₄(1,4)-C₆H₄(1,4)-O-] (biphenyl-containing unit), where all connections occur at the para positions of the benzene rings. This formulation incorporates the biphenyl moiety for added rigidity while including additional sulfone groups for stability; unlike polysulfone (PSU), it lacks isopropylidene (-C(CH₃)₂-) bridges, resulting in a more rigid and hydrolytically stable chain. PPSU's irregular molecular arrangement imparts an amorphous , which contributes to its optical transparency in unfilled forms and enables isotropic properties. Commercial grades of PPSU typically exhibit weight-average molecular weights in the range of 48,000–65,000 g/mol, balancing processability with mechanical integrity.

Polymerization Methods

Polyphenylsulfone (PPSU) is primarily synthesized through polycondensation, a reaction involving the dihalide 4,4'-dichlorodiphenyl (DCDPS) and a mixture of : (4,4'-dihydroxydiphenyl ) and 4,4'-dihydroxybiphenyl (biphenol). In this process, the phenoxide ions generated from the diols attack the electron-deficient carbon atoms attached to the substituents on DCDPS, facilitated by the electron-withdrawing group, leading to the displacement of chloride ions and formation of ether linkages. The reaction typically employs a base such as (K₂CO₃) to deprotonate the diols and generate the nucleophilic phenoxide species. The polymerization is conducted under anhydrous conditions in polar aprotic solvents, including N-methyl-2-pyrrolidone (NMP), N,N-dimethylacetamide (DMAc), dimethyl sulfoxide (DMSO), or N,N-dimethylformamide (DMF), which solvate the cations and enhance reactivity. A typical procedure involves initial mixing at around 80°C for 2 hours to form the phenoxide , followed by elevating the to 140–180°C for 6–10 hours to drive the polycondensation to high molecular weight. The molar ratio of DCDPS to total diols is equimolar (1:1) to achieve optimal chain extension, with the ratio of to biphenol varying (often around 1:1 in commercial grades) to tune properties, and excess base (typically 1.2 equivalents) to ensure complete . Post-reaction, the is precipitated in a non-solvent like , washed to remove s and residuals, and dried under . Among the solvents, DMAc often yields the highest molecular weight polymers due to its balance of solvating power and . The simplified reaction for the repeating unit formation can be represented as (for the biphenyl unit): \text{Cl-Ar-SO}_2\text{-Ar-Cl} + \text{HO-Ar'-OH} \xrightarrow{\text{K}_2\text{CO}_3, \text{solvent}, \Delta} \text{-[O-Ar'-O-Ar-SO}_2\text{-Ar]-}_n + 2\text{HCl} where Ar denotes the 1,4-phenylene group and Ar' the 4,4'-biphenylene group; a similar reaction occurs with (HO-Ar-SO₂-Ar-OH). Alternative synthesis routes for PPSU and related , though less common and not typically used industrially, include via Friedel-Crafts , which involves reacting aromatic compounds with sulfonyl s in the presence of Lewis acids like aluminum . Oxidative coupling methods, utilizing oxidants such as copper salts or electrochemical systems to form or linkages directly from or sulfides, have also been explored in laboratory settings but offer limited control over molecular weight and structure compared to the nucleophilic route.

Physical and Thermal Properties

Density and Morphology

Polyphenylsulfone (PPSU) possesses a typically ranging from 1.29 to 1.31 g/cm³, which exceeds that of many other thermoplastics due to its extensive aromatic backbone that contributes to a more compact molecular packing. This elevated underscores PPSU's suitability for applications requiring structural integrity under load, while maintaining a lightweight profile relative to metals. PPSU exhibits an amorphous morphology, characterized by a lack of long-range crystalline order, which imparts optical clarity and isotropic mechanical and thermal properties throughout the material. Its crystallinity is essentially zero under standard processing conditions, preventing the formation of a distinct and instead leading to thermal above approximately 500°C, where initial occurs around 545°C. This amorphous structure also results in smooth surface characteristics, enhancing processability and aesthetic appeal in molded components. A key feature of PPSU's is its low water absorption of 0.37% after 24 hours and approximately 1.1% at saturation, which minimizes dimensional changes and maintains performance in humid environments. This hydrophobicity arises from the non-polar aromatic and groups, contributing to the material's overall without compromising its inherent or uniformity.

Thermal Stability and Processing

Polyphenylsulfone (PPSU) exhibits a temperature () in the range of 220–230°C, which enables continuous service temperatures up to approximately 180°C without significant loss of mechanical integrity. As an amorphous polymer, PPSU lacks a distinct and instead undergoes starting at around 500°C in air, providing robust high-temperature performance for demanding applications. The material's high melt poses challenges during , necessitating elevated temperatures of 360–400°C for techniques such as injection molding and to achieve adequate flow. Prior to , PPSU must be thoroughly dried at 150–180°C for 4–6 hours to prevent and defects in the final product. This high requires precise control of parameters to ensure uniform filling and minimize shear-induced degradation. PPSU demonstrates excellent flammability resistance, achieving a UL94 V-0 rating, and generates low and upon , making it suitable for safety-critical environments.

Mechanical and Chemical Properties

Strength and Durability

Polyphenylsulfone (PPSU) exhibits robust performance that makes it suitable for demanding applications requiring high strength and rigidity. Its tensile strength typically ranges from 70 to 80 at , providing excellent resistance to pulling forces under standard conditions. This material retains more than 50% of its tensile strength at elevated temperatures up to 150°C, with values around 34-40 , ensuring reliable performance in thermally stressed environments. The of elasticity for PPSU is in the range of 2.5 to 2.7 GPa, offering a balance of stiffness and flexibility that prevents while maintaining structural integrity. PPSU demonstrates superior impact resistance, with a high notched impact strength of 70 to 90 J/m, attributed to the flexible linkages in its molecular that absorb and inhibit . This is particularly beneficial for components exposed to sudden loads. Additionally, PPSU offers excellent fatigue resistance, enabling it to withstand cyclic loading in dynamic applications without significant degradation over repeated stress cycles.

Resistance to Degradation

Polyphenylsulfone (PPSU) exhibits superior hydrolytic stability compared to (PSU), with the ability to withstand over 1,000 steam sterilization cycles at 132 °C without significant loss of mechanical properties, such as retaining 83 tensile strength and 50% after such exposure. In contrast, PSU typically endures only 80–100 cycles under similar conditions before . This exceptional stems from PPSU's robust molecular structure, which maintains over 85% of key properties, including tensile strength and impact , even after prolonged immersion in hot water at 90 °C for nearly two years. PPSU demonstrates excellent chemical resistance to a broad range of substances, including dilute acids (e.g., (10%), (20%), and (50%)), bases (e.g., sodium and solutions), showing no cracking after 24-hour exposure at . However, it is susceptible to attack by polar aprotic solvents such as (DMF), particularly at elevated temperatures above 100 °C, where swelling or partial dissolution can occur due to solvent-polymer interactions. This profile makes PPSU suitable for environments involving aqueous chemicals and disinfectants but requires caution with high-temperature polar solvent exposure. PPSU possesses good inherent UV and , with low yellowing under short-term exposure, as its aromatic absorbs UV wavelengths around 280 and dissipates as , minimizing scission. It excels in gamma sterilization, retaining better than (PEI) and other amorphous thermoplastics, with no significant property loss after typical medical doses. Prolonged outdoor UV exposure can lead to gradual color shifts and reduced , though tensile strength remains largely unaffected, often necessitating stabilizers for extended applications. The of PPSU is well-established, with FDA approval for repeated food contact under 21 CFR 177.1655 and for use in devices due to its biological inertness and minimal extractables. Its low leachables profile, free of (BPA) and other migratory compounds, supports applications in sterilizable healthcare products like surgical instruments and implant trays, ensuring compliance with Class VI and standards for tissue contact up to 24 hours. This inherent purity maintains mechanical integrity under chemical stress without introducing contaminants.

Production and Commercialization

Industrial Manufacturing

Polyphenylsulfone (PPSU) is manufactured on an industrial scale through nucleophilic aromatic polycondensation, typically involving the reaction of 4,4'-dihydroxybiphenyl with 4,4'-dichlorodiphenyl sulfone in the presence of a base such as , conducted in solvents like or N-methylpyrrolidone, or via melt processes. This occurs in agitated batch reactors or continuous systems such as twin-screw extruders and kneaders, operating at temperatures between 150°C and 350°C to achieve high molecular weights while managing the reaction's exothermic nature and buildup. Following , the resulting polymer melt is extruded into strands using a single-screw extruder at 180–300°C and then cooled and pelletized for and distribution. To enhance mechanical properties, reinforcement is commonly incorporated at levels up to 40 wt% during a subsequent step in twin-screw extruders, improving and dimensional for demanding applications; retardants may also be added, though PPSU exhibits inherent UL94 V-0 flammability. The process demands specialized equipment, including vacuum devolatilization and purging, due to the high temperatures exceeding 350°C, which can lead to thermal degradation if oxygen exposure or prolonged residence times are not controlled. Originally developed in the mid-1970s by under the Radel trademark, PPSU production has scaled significantly, with major producer Syensqo (formerly Solvay) operating facilities that contribute to global capacities exceeding 25,000 metric tons annually as of 2025. Yields typically surpass 96% in optimized continuous operations, enabling efficient commercialization while maintaining low levels of cyclic oligomers for consistent quality.

Market and Brands

Polyphenylsulfone (PPSU) was developed in the early to mid-1970s by Corporation, which introduced it commercially under the Radel brand in 1976 as part of the broader surge in high-performance thermoplastics from 1965 to 1985. This period marked significant innovation in engineering polymers to meet demands for materials with superior thermal and chemical resistance beyond existing options like . 's efforts laid the foundation for PPSU's , with the company later acquired by Solvay (now Syensqo), which continues to lead in its production. Major brands of PPSU include Radel from Syensqo (formerly Solvay), which offers grades such as R-5000 and R-5500 tailored for injection molding and extrusion. Other producers include BASF and SABIC, which manufacture polyarylsulfones encompassing PPSU variants for industrial applications. These companies dominate the supply chain, with demand primarily driven by sectors requiring high-reliability materials, such as medical devices and aerospace components. The global PPSU market was valued at approximately $398 million in 2023 and is projected to reach $812 million by 2032, growing at a (CAGR) of 8.25%. As of 2025 estimates, the market size is around $408 million. This expansion reflects increasing adoption in high-performance applications, supported by advancements in scalability from upstream manufacturing. Key economic factors include PPSU's of $20–30 per kg, attributed to its complex process, though this is offset by its exceptional durability and regulatory compliance in demanding fields.

Applications

Medical and Healthcare

Polyphenylsulfone (PPSU) is widely utilized in medical and healthcare applications due to its biocompatibility, high impact resistance, and ability to withstand repeated sterilization processes such as autoclaving, ethylene oxide, and gamma radiation without degradation. These properties make it suitable for devices requiring long-term durability and patient safety, as it meets USP Class VI standards for biocompatibility and is toxicologically inert. In healthcare settings, PPSU's transparency and chemical resistance further enhance its utility for reusable components that must maintain structural integrity under harsh conditions. In surgical applications, PPSU is employed for instruments, handles, and sterilization trays that endure over 1,000 autoclave cycles at 134°C without loss of mechanical properties or discoloration. For instance, large-format trays made from PPSU, such as those from Solvay's Radel brand, offer up to 50% weight reduction compared to aluminum alternatives while providing equivalent strength and resistance to high-pH cleaners. This durability supports efficient transport and storage of surgical tools, implants, and screws, reducing contamination risks during repeated use. For dental and orthopedic devices, PPSU's exceptional impact resistance enables its use in high-stress components like trial implant spacers for surgeries and prosthetic fittings. PPSU offers superior impact resistance to . Orthopedic applications benefit from its dimensional stability and resistance, ensuring reliable performance in load-bearing scenarios without cracking or deformation. In , PPSU forms instrument handles and clamps that resist chemical exposure from disinfectants while maintaining clarity for precise handling. PPSU serves as a shatter-resistant, transparent alternative to in baby bottles and feeding systems, approved by the FDA for contact and free from (BPA) and . Materials like BASF's Ultrason P 2010 exhibit high chemical resistance and heat tolerance up to 180°C, allowing safe and use while preventing breakage during drops. This makes PPSU ideal for products, where safety and ease of sterilization are paramount, as verified in assessments of non-intentionally added substances. In filtration applications, PPSU-based membranes are used for and due to their chemical inertness, low protein adsorption, and high permeability for . These membranes effectively separate proteins like while resisting from biological fluids, enhancing efficiency in blood purification processes. Modifications such as blending with carbon nanotubes further improve flux rates, making PPSU suitable for compact dialyzer filters that remove uremic toxins without compromising .

Engineering and Aerospace

Polyphenylsulfone (PPSU), commercially known as Radel® from Syensqo (formerly Solvay), is widely utilized in aerospace applications due to its exceptional combination of lightweight properties, high strength-to-weight ratio, and inherent flame retardancy. In aircraft construction, PPSU serves as a material for interior components such as thermoformable sheets for panels, ducts, and brackets, enabling significant weight reduction compared to traditional metals while maintaining structural integrity under operational stresses. These features are particularly valuable in meeting stringent Federal Aviation Administration (FAA) requirements under 14 CFR Part 25.853, where PPSU demonstrates low heat release (less than 65 kW·m⁻²), low smoke density, and minimal toxic gas emissions during combustion. Additionally, its high modulus at elevated temperatures facilitates efficient processing, further contributing to design flexibility and reduced material usage in cabin interiors. In the automotive sector, PPSU's superior thermal — with a heat deflection temperature (HDT) of 207°C under 0.45 MPa load—and resistance to automotive fluids make it ideal for under-hood components exposed to extreme heat and vibrations. Specific applications include brackets, system connectors, and housings, where the material withstands continuous exposure to oils, s, and coolants without degradation, outperforming alternatives like (PEI) in chemical resistance. Its impact strength, comparable to , ensures durability in high-stress environments, supporting lightweighting efforts to improve . For plumbing and fluid handling systems, PPSU is employed in pipes, valves, and fittings, such as Radel® piping systems, which serve as corrosion-resistant alternatives to in pressurized hot applications up to 95°C. The polymer's long-term hydrostatic strength, with a 50-year lower predicted limit (LPL) of 14.6 at 95°C per ISO 9080, ensures reliable performance in demanding distribution networks. However, while PPSU exhibits outstanding resistance to , improper installation—such as excessive torque during assembly or incompatibility with certain insulations like —can induce localized stresses leading to cracking over time. In , PPSU provides high-temperature insulation for housings, connectors, and wire coatings in environments requiring UL-94 V-0 flame retardancy and . Its ability to maintain electrical properties at temperatures up to approximately 200°C continuously makes it suitable for enclosures and high-voltage components in industrial settings, where exposure to heat and chemicals is prevalent. The material's hydrolytic stability further enhances its longevity in humid or fluid-exposed electrical systems. These applications leverage PPSU's thermal and mechanical properties, including a temperature around 220°C, to ensure reliability without the need for additional reinforcements.

References

  1. [1]
    Recent Advancements in Polyphenylsulfone Membrane Modification ...
    Feb 21, 2022 · Polyphenylsulfone (PPSU) membranes are of fundamental importance for many applications such as water treatment, gas separation, energy, ...
  2. [2]
    Order Polyphenylsulfone (PPSU/PPSF) Materials & Parts
    The polymer's backbone consists of aromatic rings linked by sulfone (–SO₂–) groups. This structure gives polyphenylsulfone exceptional thermal and chemical ...Molecular Structure And... · Available Forms And Grades · Applications
  3. [3]
    Polyphenylsulfone (PPSU) for baby bottles - PubMed
    PPSU is a polyether plastic formally composed of bisphenol S (BPS) and 4,4'-dihydroxybiphenyl (DHBP), which both have slight endocrine activities in in vitro ...
  4. [4]
    PSU vs PES vs PPSU - Tuntun Plastic
    Jun 8, 2022 · Compared with PSU, the molecular chain of PPSU does not contain isopropylidene but contains a large number of biphenyl groups, so its heat ...
  5. [5]
    Experimental Evaluation of Polyphenylsulfone (PPSF) Powders as ...
    Aug 13, 2021 · Polyphenylsulfone (PPSF/PPSU) is an amorphous polymer with a repeating unit of molecular form (-C6H4-4-SO2C6H4-4-OC6H4-4-C6H4-4-O-)n. The ...
  6. [6]
    Effect of Solvent and Monomer Ratio on the Properties of ... - NIH
    May 12, 2023 · Polyphenylene sulfone (PPSU) synthesis was carried out in a 500 mL three-neck flask equipped with a nitrogen inlet, a mechanical stirrer, a Dean ...
  7. [7]
    Synthesis and Properties of Copolyphenylene Sulphones with ... - NIH
    Copolymers based on 4,4′-dihydroxydiphenyl, phenolphthalein and 4,4′-dichlorodiphenyl sulfone were synthesized by the method of high temperature
  8. [8]
  9. [9]
    Overview of materials for Polyphenylsulfone (PPSU) - MatWeb
    Physical Properties, Metric, English, Comments. Density, 0.0500 - 2.00 g/cc, 0.00181 - 0.0723 lb/in³, Average value: 1.33 g/cc Grade Count:95.Missing: molecular | Show results with:molecular
  10. [10]
    PPSU Unfilled | Eagle Performance Plastics, Inc.
    (PPSU) Polyphenylsulfone. Trade Names (®, ™), Radel, Tecason P. Color, Black and White. Density (g/cm^3), 1.29, D 792. Mechanical. Property, Value, Typical ASTM ...Missing: water | Show results with:water
  11. [11]
    Mechanical and macromolecular changes during thermal ...
    Aug 5, 2025 · Additionally, the initial decomposition temperature (IDT) of 95% of the PSU (511.2°C) was lower than that of PPSU (545.7°C). The findings ...
  12. [12]
    Polyphenylene - an overview | ScienceDirect Topics
    Polyphenylene Sulfone (PPSU) is an amorphous material, with high glass transition temperature and low moisture absorption. It primarily consists of aromatic ...
  13. [13]
  14. [14]
    [PDF] TECHNICAL DATA SHEET - FormFutura
    Jun 14, 2024 · PPSU (Polyphenylsulfone) is an amorphous ultra-performance filament ... Water Absorption (24h). 0.37%. ASTM D570. Mechanical properties.
  15. [15]
    Understanding The “Polysulfone” Family (PPSU, PSU, PES)
    PPSU-(Polyphenylsulfone). Heat deflection temperature (after GF or CF filling): up to 207°C. Glass transition temperature: 220°C. Long-term use temperature: 180 ...
  16. [16]
    PPSU - Polyphenylene sulfone - Holm & Holm A/S
    PPSU is highly flammable and has a low smoke generation. Meets the requirements of UL 94 V-0. Electrical properties: Good electrical and dielectric ...Missing: polyphenylsulfone | Show results with:polyphenylsulfone
  17. [17]
    Polyphenylsulfone (PPSU) - MakeItFrom.com
    Glass Transition Temperature. 220 °C 430 °F. Heat Deflection Temperature At 1.82 MPa (264 psi). 210 °C 410 °F ; Heat Deflection Temperature At 455 kPa (66 psi).
  18. [18]
    Polyphenylsulfone (PPSU): High Performance for Tough Uses - Aprios
    Aug 4, 2025 · For lab applications, PPSU resists chemical exposure and repeated autoclaving, making it ideal for containers, sample holders, and structural ...
  19. [19]
    PPSU Injection Molding
    PPSU, or polyphenylsulfone, is a high-performance thermoplastic. It's known for being excellent rigidity, tough, and having a bunch of other great properties.
  20. [20]
    PPSU Injection Molding - Fictiv
    Oct 5, 2023 · Properties of Injection Molded PPSU ; Physical, Density, 1.29 g/cm ; Water Absorption at Equilibrium 23 °C/50% r.h, 0.3–0.6% ; Mechanical, Hardness ...
  21. [21]
    [PDF] Mitsubishi Chemical Advanced Materials PPSU LSG R5500 ...
    Tensile Strength. 75.8 MPa. 11000 psi. ASTM D638. Tensile Strength at 150°C (300°F). 34.5 MPa. 5000 psi. ASTM D638. Tensile Strength at 65°C (150°F). 55.2 MPa.
  22. [22]
    [PDF] Sultron LSG R5500 PPSU - Mitsubishi Chemical Group
    Sultron LSG R5500 PPSU. Polyphenylsulfone. Sultron LSG R5500 PPSU (Life Science Grade) stock shapes are made from unfilled Radel PPSU resin that is pre-assessed ...
  23. [23]
    [PDF] Design Guide - Nevicolor
    Udel polysulfone, isopropylidene moieties . These “bridging” moieties, shown in Figure 2, impart special performance characteristics to polysulfones:.
  24. [24]
    PPS vs. PPSU – Decoding the Differences - Rapid Axis
    Oct 26, 2023 · Its molecular structure comprises a sulfide group and aromatic rings, contributing to its robustness, stability, and suitability for injection ...
  25. [25]
    [PDF] Radel® PPSU - Effects of Steam Sterilization - Solvay
    Suitable for especially harsh environments, Radel®. PPSU (polyphenylsulfone) can be steam sterilized more than a thousand cycles without significant loss of ...
  26. [26]
    [PDF] Polysulfones and their applications Athipatla V
    Apr 11, 2023 · PPSU has steam autoclave resistance of over 1000 cycles when compared with 80-100 cycles for PSU and PES. PPSU also exhibits excellent ...
  27. [27]
    [PDF] Ultrason® - Resistance to chemicals | BASF
    The Ultrason® resins are amorphous thermoplastics based on polyethersulfone ( PESU), polysulfone. ( PSU) and polyphenylsulfone ( PPSU) and offer very.
  28. [28]
    Polysulfone (PSU) by Syensqo - UL Prospector
    Polysulfone is resistant to mineral acids, alkali, salt solutions, detergents and hydrocarbon oils. Contact with polar solvents such as ketones, chlorinated ...
  29. [29]
    The Importance Of The UV-Resistance Performance Of PPSU ... - IFAN
    Jun 12, 2025 · The benzene rings in PPSU absorb UV radiation (max absorption at 280 nm), converting it to harmless heat. This reduces the energy available to ...
  30. [30]
    Radel® PPSU - FAQ - Syensqo
    In its natural state, Radel® PPSU is inherently transparent and light amber in color. Syensqo also offers 12 standard opaque and transparent colors that are ...
  31. [31]
    [PDF] Declaration concerning food contact (FDA) Product: Sustason PPSU ...
    Jan 30, 2013 · Polyphenylsulfone (PPSU – ISO 1043) is compliant with applicable FDA regulations for food contact. These products are extruded by using raw ...Missing: medical biocompatibility leachables
  32. [32]
    Radel® PPSU Polyphenylsulfone - Syensqo
    It excels in high heat and humidity environments and provides operating temperatures around 200°C (392°F) and inherent flame retardant properties.Radel® PPSU HYRA · Radel® PPSU for Healthcare · FAQ · Properties
  33. [33]
    [PDF] Life Science Grades for Medical & Bioprocessing needs - MCAM
    Pre-assessed for biocompatibility for up to 24 hours contact with body and tissue according to USP VI and ISO 10993, as well as wetted contact in bioprocessing.
  34. [34]
    Process for preparing a poly(biphenyl ether sulfone) (ppsu) polymer
    The method is based on titration of the molecules present in the analysed sample, based on their end-groups, independently from the size of the molecules in the ...Missing: scale | Show results with:scale
  35. [35]
    Radel® RG-5010 - UL Prospector
    Radel® RG-5010 is a 10% glass-fiber reinforced polyphenylsulfone (PPSU). Compared to unreinforced polyphenylsulfone, this grade has increased strength, ...Missing: filled | Show results with:filled
  36. [36]
    PPSU Masterbatch Production Process - Kerke
    By high-speed stirring or screw conveying, PPSU resin and additives are thoroughly mixed evenly. The mixing time is generally 5-15 minutes, depending on the ...
  37. [37]
    Tracing the History of Polymeric Materials, Part 26: High ...
    Feb 28, 2023 · The majority of the polymers that we rely on today for outstanding performance were introduced in the period between 1965 and 1985.
  38. [38]
    Polyphenylsulfone Market Share - PPSU Industry Forecast Report ...
    The global polyphenylsulfone market valued at over USD 270 million in 2018 and the PPSU industry will exceed 25 kilo tons consumption to 2025; North America ...
  39. [39]
    Product Spotlight: Sultron™ PPU/PPSU and Duratron™ PEI
    Developed in the 1960s by Union Carbide (later Solvay, now Syensqo). Made to target hot water and high-temperature applications where PC could not perform ...
  40. [40]
    [PDF] 50 Years of U del PS U - Solvay
    • Union carbide introduced PSU. • Plant constructed in Marietta, OH. 1965. 20 Years. • Growing success in North America prompted PSU plant expansion.Missing: Polyphenylsulfone | Show results with:Polyphenylsulfone
  41. [41]
    Solvay Radel PPSU R-5000 NT Polyphenylsulfone Pellets
    Radel R-5000 is a transparent polyphenylsulfone (PPSU) which offers exceptional hydrolytic stability, and toughness superior to other commercially-available ...Missing: producers | Show results with:producers
  42. [42]
    [PDF] Polyarylsulfones (PSU, PESU, PPSU) | BASF
    Sabic has been producing its polyetherimides exclusively in the USA ... The 80-kg system, con- sisting of two extruded PPSU profiles (Radel, Solvay) be-.
  43. [43]
    Polyarylsulfone Companies - MarketsandMarkets
    Feb 24, 2014 · Major manufacturers of polyarylsulfone are identified as BASF SE (Germany), Solvay Chemicals Company (Belgium), SABIC (Saudi Arabia) and ...Missing: brands | Show results with:brands
  44. [44]
    US Polyphenylsulfone (ppsu) Market Size & Outlook
    The U.S. market is expected to grow at a CAGR of 4.6% from 2023 to 2030. In terms of segment, medical was the largest revenue generating end use in 2022 ...
  45. [45]
    Polyphenylsulfone Market Size, Share, Growth & Trends by 2032
    The Global Polyphenylsulfone Market Size Was Worth $397.81 Million in 2023 and Is Expected To Reach $811.95 Million by the end of 2032, CAGR of 8.25%.Missing: projection | Show results with:projection
  46. [46]
    Polyphenylsulfone Market - Industry Analysis, Market - Forecast(2025
    Among all the sulfone polymers, polyphenylsulfone is the most expensive. For instance, the price of polysulfone resins is US$16-20/kg, the price of ...Missing: factors | Show results with:factors
  47. [47]
    Investigation of the Properties of Polyphenylene Sulfone Blends - PMC
    Sep 14, 2022 · Polysulfones are a group of heat-resistant polyarylenes that remain functional at temperatures from −100 to +250 °C [1]. Due to good mechanical ...
  48. [48]
    Medical Plastics 101: PPSU
    PPSU can withstand continuous-use temperatures up to 260°C — and its resistance to chemicals ...<|control11|><|separator|>
  49. [49]
    Radel® PPSU for Healthcare | Syensqo
    Radel® PPSU is a strong, lightweight, super-tough, high-heat, transparent polymer used in healthcare for over 30 years, with ISO 10993 biocompatibility.Missing: datasheet thermal
  50. [50]
    Solvay's Radel® PPSU selected for large-format surgical instrument ...
    Feb 5, 2019 · The base tray is up to 50 percent lighter than competitive models fashioned with anodized aluminum, a traditional material of choice, and it ...
  51. [51]
    Solvay's Radel PPSU for large-format surgical instrument tray
    Feb 9, 2019 · Radel polyphenylsulfone (PPSU) resin's strength-to-weight ratio, ability to withstand high pH cleaners during repeated sterilization cycles and ...
  52. [52]
    Case Study Medical - Surgical Caddies / Trays - Ensinger
    Trays and caddies for transporting and storing surgical instruments as well as screws and additional implants are subject to stringent requirements ... PPSU – ...
  53. [53]
    Radel PPSU (Polyphenylsulfone) - 3D Systems
    Radel PPSU is an amorphous material that, is available as medical grade for instruments such as trial implant spacer for spinal fusion surgeries.
  54. [54]
    PPSU (Radel®) | Cope Plastics | For Medical & Dental Instruments
    It is USP class VI compliant, and can be used at temperatures approaching 400ºF. Applications. Clamps; Fittings; Fluid couplers; Instrument handles; Manifolds ...
  55. [55]
    Chinaplas 2024: The next generation: robust and colorful baby bottles
    Apr 1, 2024 · Ultrason® P 2010 is approved for food contact (FDA and NSF) and features high chemical resistance, excellent strength and resistance to ...<|separator|>
  56. [56]
    Polyphenylsulfone (PPSU) for baby bottles - ResearchGate
    Aug 8, 2025 · PPSU is a new material for the production of baby bottles. PPSU is a polyether plastic formally composed of bisphenol S (BPS) and 4,4ʹ-dihydroxybiphenyl (DHBP).
  57. [57]
    Fabrication of novel PPSU/ZSM-5 ultrafiltration hollow fiber ...
    Membranes filtration study was performed using different proteins namely bovine serum albumin (BSA), egg albumin (EA) and hazardous dyes like Reactive black 5 ( ...
  58. [58]
    Carbon nanotubes-blended poly(phenylene sulfone) membranes for ...
    Sep 25, 2012 · Hence, the present investigation is aimed to study the utility of PPSU in ultrafiltration applications. Carbon nanotube (MWCNT)-blended ...<|separator|>
  59. [59]
    [PDF] Thermoforming Sheet for Aircraft Interiors - Radel® PPSU - Solvay
    Thermoformed prototypes can be produced with many types of molds such as wood, metal-filled epoxy or cast aluminum. Hardwood molds will only last for about 10 ...
  60. [60]
    PPSF/PPSU Polyphenylsulfone - ADDMAN
    Polyphenylsulfone (PPSF/PPSU) is a high-performance thermoplastic known for its exceptional strength, thermal stability, and chemical resistance.Missing: formula | Show results with:formula
  61. [61]
    Radel® PPSU Stock Shapes - Alro
    Because of its corrosion resistance, Radel® is also used in plumbing applications as a replacement for brass in pressurized hot water fittings and valves.
  62. [62]
    [PDF] Evaluation of Long-Term Hydrostatic Strength of Sulfone Polymers
    A study of the long-term hydrostatic strength (LTHS) of several unfilled sulfone-based polymers has been conducted and is reported in this bulletin. The ...Missing: cracking | Show results with:cracking
  63. [63]
    PEX Plumbing Installation Tips - Plastics Pipe Institute
    Certain polymer fitting materials (e.g., polysulfone or PSU, polyphenlysulfone or PPSU) may be incompatible with spray foam insulation and might have chemical- ...
  64. [64]
    The Applications and Advantages of PPSU Profiles in Electrical ...
    Apr 25, 2025 · Key Properties of PPSU for Electrical Insulation · Thermal stability: Long-term heat resistance at 230°C and short-term resistance up to 260°C.
  65. [65]
    High-Temperature Resistance of PPSU for Industry
    Aug 20, 2025 · As an excellent insulator, PPSU is used in high-voltage and high-temperature electrical components: Switchgear housings. Connectors. Circuit ...