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Wegener–Bergeron–Findeisen process

The Wegener–Bergeron–Findeisen process, often abbreviated as the WBF process or simply the Bergeron process, is a key microphysical mechanism in that describes the preferential growth of ice crystals within mixed-phase —those containing both supercooled liquid water droplets and ice particles—at temperatures between 0°C and -40°C, where ice crystals rapidly accrete through deposition while nearby supercooled droplets evaporate, ultimately leading to cloud glaciation and formation. This process arises from a fundamental thermodynamic difference: at subfreezing temperatures, the saturation over is lower than over supercooled , meaning that in an environment where the ambient relative humidity is supersaturated with respect to but subsaturated with respect to , diffuses toward crystals faster than it does toward droplets, causing the latter to shrink and the former to enlarge. For the process to initiate and sustain, mixed-phase must exist with sufficient and at least a few nuclei to formation, often triggered by heterogeneous on aerosols; once underway, growing crystals can fall through the , collecting droplets via riming or further deposition, and produce snowflakes or other frozen that may melt into rain upon reaching warmer air layers—a pathway known as the "cold-rain process." The concept was first theorized by German meteorologist in 1911, who recognized the instability of coexisting and supercooled water phases in his work on atmospheric . Swedish meteorologist Tor Bergeron advanced the idea in 1935 during proceedings of the International Union of Geodesy and Geophysics, linking it to observations of formation and precipitation in layered clouds, emphasizing the role of supersaturation. German physicist Walter Findeisen provided the definitive theoretical framework and experimental validation in 1938 using simulations, demonstrating enhanced growth rates in mixed conditions and integrating it into broader colloidal . Beyond its historical significance, the WBF process plays a pivotal role in global weather and climate dynamics, as it governs the phase partitioning of water—shifting liquid-dominated s toward , which alters radiative properties by increasing reflectivity and longevity while enabling in mid-latitude and polar regions. In and climate models, such as general circulation models (GCMs), accurate parameterization of the WBF process is essential for simulating feedbacks, interactions, and events, though challenges persist in resolving sub-grid-scale mixing and nucleation variability that can limit or enhance its efficiency. Studies have shown its relevance in Arctic mixed-phase s, where it influences melt rates and , underscoring ongoing research into its interactions with .

Historical Development

Discovery and Key Contributors

The Wegener–Bergeron–Findeisen process originated with the foundational thermodynamic insights of , a and polar explorer. During his early expeditions to in 1906–1908, where he served as the expedition's and , Wegener conducted observations of atmospheric phenomena, including hoarfrost formation. These experiences informed his 1911 publication, Thermodynamik der Atmosphäre, in which he argued that the coexistence of supercooled liquid water droplets and crystals in clouds is thermodynamically unstable. Wegener posited that crystals would preferentially grow through vapor deposition at the expense of surrounding droplets due to the lower saturation vapor pressure over relative to supercooled water, providing the initial conceptual basis for the process. Tor Bergeron, a meteorologist associated with the Bergen School of Meteorology in , advanced Wegener's ideas through observational and theoretical work in the 1920s and early 1930s. In the winter of 1922, while recovering from at a health resort in Voksenkollen near , Bergeron observed the rapid clearance of supercooled and the deposition of on trees at temperatures between -5°C and -10°C, attributing this to the growth of s via diffusion from liquid droplets. He incorporated these findings into his 1928 doctoral dissertation, Über die dreidimensionale verknüpfende Wetteranalyse, where he linked ice crystal growth to broader mechanisms in mixed-phase clouds. Bergeron further refined and publicized the concept during lectures at the Bergen School and in his 1933 presentation at the International Union of Geodesy and Geophysics assembly in , emphasizing how ice crystals serve as the primary initiators of , , and formation by aggregating vapor from coexisting water droplets. Walter Findeisen, a , provided critical experimental validations and theoretical refinements in the late , solidifying the process's understanding. Building on Wegener and Bergeron's work, Findeisen's 1932 doctoral thesis examined droplet size distributions in clouds, but his seminal 1938 paper, Kolloid-meteorologische Vorgänge bei der Niederschlagbildung, offered a comprehensive synthesis, including detailed calculations of vapor rates and the role of nuclei. Using a novel 2 m³ equipped with adiabatic expansion capabilities, Findeisen experimentally demonstrated the preferential growth of crystals over liquid droplets in mixed-phase conditions, confirming the process's efficiency for precipitation development. His contributions led to the process being eponymously named the Wegener–Bergeron–Findeisen process, honoring the trio's collaborative advancements despite the challenges of the .

Evolution of Understanding

Following the foundational theoretical proposal by in 1911, further developed by Tor Bergeron in the 1930s, and experimentally validated by Walter Findeisen in 1938, the understanding of the Wegener–Bergeron–Findeisen process advanced significantly through post-World War II observations. In the 1950s, airborne measurements provided initial empirical confirmation of growth in mixed-phase clouds, revealing formation mechanisms consistent with differential vapor deposition even in clouds extending below the freezing level. These aircraft-based studies, conducted at altitudes around 14,000 feet, captured echoes from ice particles and small snowflakes, demonstrating the process's role in rapid particle enlargement. By the and , more sophisticated aircraft instrumentation, including early probes, enabled direct in-situ measurements of nuclei and concentrations in supercooled s, quantifying the depletion of droplets and supporting the process's efficiency in development. Radar networks during this period tracked echo evolution in orographic and stratiform s, corroborating observational evidence of supersaturation and fallout. Concurrently, Neville H. Fletcher's seminal 1962 analysis integrated the process into classification schemes, linking thresholds (around -10°C to -20°C for typical atmospheric nuclei) to the onset of differential growth and emphasizing its dependence on heterogeneous sites. Laboratory experiments in the further refined comprehension by simulating mixed-phase conditions to measure differential growth rates, showing ice crystals enlarging at rates up to 10-100 times faster than coexisting droplets under ice-supersaturated environments. These controlled setups, using cloud chambers to replicate vapor gradients, highlighted ventilation effects and particle spacing as modulators of growth efficiency. The 1980s marked a transition from qualitative observations to quantitative frameworks, with early numerical cloud models incorporating parameterized vapor deposition equations to simulate the process's dynamics. Pioneering simulations, such as those resolving ice microphysics in convective systems, demonstrated how the process drives net water transfer toward ice phases, establishing benchmarks for efficiency in layered clouds. These models, often one-dimensional or bulk schemes, laid groundwork for integrating the into mesoscale forecasts without resolving individual particle interactions.

Physical Mechanism

Required Environmental Conditions

The Wegener–Bergeron–Findeisen (WBF) process operates within mixed-phase clouds, where supercooled water droplets coexist with a smaller number of crystals, typically at ranging from 0°C to -40°C. This temperature interval allows for the persistence of supercooled water while enabling formation and growth, with the process being most efficient between -10°C and -20°C due to the pronounced difference in saturation vapor pressures over and . The initial scarcity of crystals relative to droplets is crucial, as it permits the buildup of with respect to before widespread glaciation occurs. A key prerequisite is an ambient relative humidity positioned between saturation over (e_{si}) and saturation over (e_{sw}), where e_{si} < e_{sw} for temperatures below 0°C, creating a subsaturated environment for liquid droplets but supersaturated conditions for . This vapor pressure disequilibrium drives the preferential deposition onto without immediate droplet growth, though in practice, mixed-phase clouds often hover near water saturation due to dynamic influences. Cloud dynamics play an essential role in initiating and sustaining the WBF process, particularly through vertical air motions that maintain the necessary supersaturation with respect to ice. The process is efficient when the vertical velocity w lies between a downdraft threshold u_z^0 (where liquid droplets evaporate while ice grows) and an updraft threshold u_z^* (where both phases can grow without excessive liquid supersaturation dominating). These thresholds depend on particle concentrations, sizes, and thermodynamic parameters, typically on the order of 0.1 to several m/s for common cloud conditions. Vertical velocities in observed mixed-phase clouds often have standard deviations of 0.06–0.52 m/s, ensuring the persistence of the mixed-phase regime against rapid glaciation or liquidation.

Vapor Deposition Dynamics

The Bergeron–Findeisen effect, central to the vapor deposition dynamics in mixed-phase clouds, arises because the vapor pressure over is lower than over supercooled at temperatures below 0°C, creating a net flux of from the ambient air toward crystals while supercooled droplets evaporate to sustain this gradient. This differential drives the preferential growth of crystals at the expense of liquid droplets, with the ambient vapor density typically lying between the saturation values over (ρ_{v,i}) and (ρ_{v,w}). The mass growth rate of an individual by is governed by the equation \frac{dm_i}{dt} = 4\pi C_i D_v (\rho_{v,\text{amb}} - \rho_{v,i}), where m_i is the mass, C_i is the (dependent on shape and size, approximately equal to the for spherical equivalents), D_v is the coefficient of in air, \rho_{v,\text{amb}} is the ambient vapor density, and \rho_{v,i} is the vapor density at the surface (equal to over under ). This formulation assumes quasi-stationary in the continuum regime and neglects thermal effects for simplicity; the growth is supersaturation-driven relative to , accelerating as the difference increases. Simultaneously, surrounding supercooled droplets experience net , depleting their mass as vapor diffuses away to the ice crystals. The radius change rate for a water droplet is approximated by \frac{dr_w}{dt} = -\frac{D_v (\rho_{v,\text{amb}} - \rho_{v,w})}{r_w \rho_w}, where r_w is the droplet , \rho_w is the liquid density, and \rho_{v,w} is the over water; the negative sign reflects evaporation when \rho_{v,\text{amb}} < \rho_{v,w}. This inverse dependence on radius implies smaller droplets evaporate faster, potentially leading to their complete disappearance before larger ones. In dynamic environments, ventilation effects enhance deposition rates by increasing the effective diffusion flux around falling crystals. The ventilation coefficient f_v modifies the growth equation as \frac{dm_i}{dt} = 4\pi C_i D_v f_v (\rho_{v,\text{amb}} - \rho_{v,i}), where f_v \approx 1 + 0.27 \text{Re}^{1/2} \text{Sc}^{1/3} for moderate Reynolds () and Schmidt () numbers, with values exceeding 1 for crystals with significant fall speeds. At low temperatures (below −40°C), kinetic effects further amplify growth for particles in general, as molecular collisions at the surface limit accommodation; the deposition coefficient \alpha_D (typically 0.5–1 at warmer temperatures) decreases, but enhanced kinetic jump distances in the free-molecular regime can increase effective growth rates by up to 20–50% compared to predictions.

Ice Crystal Formation and Growth

Nucleation Processes

The formation of initial in mixed-phase clouds, essential for initiating the Wegener–Bergeron–Findeisen process, primarily occurs through heterogeneous on ice nuclei (IN), which are insoluble particles that lower the energy barrier for embryo formation. Heterogeneous dominates in clouds at temperatures between 0°C and -40°C, where supercooled droplets coexist, allowing IN such as mineral , biological particles, and artificially introduced agents like to serve as templates for crystallization. For example, mineral particles from regions act as effective IN by providing lattice structures similar to , facilitating at relatively warm temperatures down to -20°C. Specific biological IN, such as the bacterium Pseudomonas syringae, exhibit high nucleation activity through ice-nucleating proteins on their surface, enabling ice formation at temperatures as warm as -2°C, which is critical for initiating glaciation in shallow convective clouds. Silver iodide, commonly used in cloud seeding, promotes heterogeneous nucleation at temperatures around -10°C due to its crystallographic similarity to ice, making it a benchmark for artificial IN efficiency. These IN activate via different modes: immersion freezing, where the nucleus is engulfed within a supercooled droplet and triggers freezing upon reaching a critical temperature or supersaturation; contact freezing, involving collision between the IN and a droplet; and deposition nucleation, where water vapor directly deposits onto the IN surface at ice supersaturations exceeding 10-20%. Critical supersaturation thresholds for IN activation vary by particle type, typically requiring ice supersaturations of 5-15% for mineral dust and biological IN to overcome the nucleation barrier. In the absence of sufficient heterogeneous IN, homogeneous nucleation becomes relevant at colder temperatures, where supercooled water droplets spontaneously freeze without foreign particles, forming at approximately -35°C to -40°C due to the high required for formation in pure . This process is rare in most mixed-phase clouds because heterogeneous typically occurs first, but it sets a lower for formation in pristine environments. Typical atmospheric IN concentrations range from 0.01 to 100 L⁻¹, depending on loading and temperature, with lower values (0.01–1 L⁻¹) in remote regions and higher (10–100 L⁻¹) in polluted or dusty air masses; these concentrations determine the initial number and thus seed the mixed-phase conditions necessary for the process. Once nucleated, these crystals can grow by vapor deposition, as detailed in subsequent sections.

Ice Multiplication Mechanisms

Ice multiplication mechanisms refer to secondary processes that generate additional ice crystals from pre-existing ones, amplifying ice concentrations beyond primary rates in mixed-phase clouds. These mechanical fragmentation pathways enhance the efficiency of the Wegener–Bergeron–Findeisen process by rapidly increasing the number of ice particles available for vapor deposition. While initial provides the seed crystals, multiplication occurs through physical breakup under specific dynamic and thermal conditions. One key mechanism is riming-splintering, where ice crystals or particles accrete supercooled liquid droplets, leading to splintering upon impact or during the freezing of accreted mass. Laboratory studies have demonstrated that this process produces up to several hundred fragments per milligram of rime accreted, particularly effective at temperatures between -5°C and -10°C, where the formation of a brittle ice shell around freezing droplets facilitates fragmentation. This splintering is driven by the mechanical stress from rapid freezing and collision, releasing small ice shards that serve as new nuclei. Dendritic breakup involves the mechanical fracture of branching crystals under aerodynamic , , or their own , commonly observed in plate-like or dendritic habits formed at temperatures around -10°C to -15°C. These complex structures, with extended arms, are prone to shattering during collisions with other particles or turbulent airflow, generating multiple smaller fragments per event. Observations and modeling indicate that such breakups contribute significantly to production in regions with high particle concentrations and moderate . The Hallett-Mossop process, a variant of rime splintering, occurs in temperature gradients between -3°C and -8°C, where shearing forces on growing ice surfaces or frozen droplets cause prolific splintering. This mechanism is activated when ice particles traverse zones of varying temperature, promoting the ejection of small ice splinters from the edges of riming particles or growing crystals. It is particularly relevant in convective clouds with vertical motion, leading to enhanced secondary ice formation through repeated fragmentation cycles. In situ observations of mixed-phase clouds have documented ice crystal concentrations up to ~10³ L⁻¹, representing multiplication factors of up to ~10⁴ from initial levels near 0.01 L⁻¹ to over 100 L⁻¹ within minutes, underscoring the profound impact of these mechanisms on cloud microphysics. However, a 2024 laboratory study found limited evidence for efficient rime-splintering under controlled conditions, suggesting potential refinements needed in parameterizations of these processes.

Particle Interaction Processes

Aggregation

Aggregation in the Wegener–Bergeron–Findeisen process refers to the collision and subsequent sticking of ice crystals, serving as a key non-vapor growth mechanism that enlarges particles beyond diffusional growth limits. This process is primarily driven by collision-coalescence, where ice particles of varying sizes and shapes encounter each other due to differential settling velocities induced by in the turbulent environment of mixed-phase clouds. Additionally, electrostatic charges on ice crystals can enhance collision probabilities by altering trajectories through forces, particularly in regions with charge separation from vapor growth or fragmentation. The sticking efficiency, which determines the fraction of collisions resulting in permanent aggregation, exhibits a strong dependence, peaking around -15°C. At this , dendritic habits dominate, promoting upon contact, while thin quasi-liquid films on surfaces further enhance through or van der Waals forces, especially for branched habits like dendrites and side planes. These conditions favor the formation of loose aggregates, contrasting with lower efficiencies at colder temperatures where surfaces remain drier and less adhesive. Observations and parameterizations confirm sticking efficiencies ranging from 0.1 to 1.0, with higher values near the peak enhancing aggregate development. multiplication processes can increase the abundance of small available for such collisions, amplifying aggregation rates in supersaturated environments. The rate of aggregation is quantified by the aggregation kernel, given by K_{\text{agg}} = E_{\text{agg}} \frac{\pi}{4} (r_1 + r_2)^2 |v_1 - v_2|, where E_{\text{agg}} is the sticking efficiency (0.1–1.0), r_1 and r_2 are the radii of the colliding ice particles, and |v_1 - v_2| is the magnitude of their relative velocity, often dominated by differential settling. This formulation captures the geometric cross-section for collision modulated by efficiency factors and is widely used in microphysics models to simulate ice growth. Resulting aggregates, commonly observed as snowflakes, exhibit low bulk densities of 0.05–0.2 g cm⁻³ due to their porous, branched structures, which further influence fall speeds and radiative properties in clouds.

Accretion

Accretion, also known as riming, involves the collision and freezing of supercooled liquid water droplets onto falling ice crystals within mixed-phase clouds, contributing to the overall growth of ice particles under the conditions favored by the Wegener–Bergeron–Findeisen process. This mechanism is distinct from vapor deposition, as it directly incorporates liquid mass into the ice structure, altering particle density, shape, and . The collision efficiency (E_\text{col}) governing ice-droplet impacts varies with habit and droplet size. Plate-like and broad-branched crystals generally achieve higher E_\text{col} (up to ~1.0) than columnar crystals due to their larger projected areas and flow fields that better capture droplets. For small droplets, E_\text{col} is negligible (<0.1), but it rises sharply and exceeds 0.5 for droplet radii greater than 10 μm, enabling efficient collection of typical cloud droplets in this size range. Upon collision, the supercooled droplets rapidly freeze on the colder surface, accreted as a layer of rime that adds mass and increases the particle's fall speed, promoting further interactions. The mass growth rate for an individual ice particle is approximated by \frac{dm_i}{dt} = E_\text{col} \pi r_i^2 |v_i - v_w| \rho_w N_w, where m_i is the ice mass, r_i the effective ice radius, v_i and v_w the terminal velocities of the ice particle and droplet, \rho_w the water density, and N_w the droplet number concentration; this rate scales with relative velocity and droplet abundance. Continued riming transforms pristine crystals into denser, irregular structures, with the added frozen droplets enhancing the particle's and collection cross-section. Prolonged or intense riming leads to the formation of , characterized by conical or lump-like aggregates of rime layers over the original crystal skeleton, typically 2–5 mm in diameter. In environments with high liquid water content and vigorous updrafts, such as convective storms, particles can grow rapidly and act as embryos for larger , transitioning from soft rime to denser, layered hail through sustained accretion. Riming efficiency shows a marked dependence, with optimal collection below -10°C where the process is more effective than at warmer subfreezing levels. This enhancement arises from faster freezing of impacted droplets at greater degrees, shortening the solidification time and improving sticking to the ice surface.

Role in Precipitation Formation

Development of Precipitating Particles

In the Wegener–Bergeron–Findeisen (WBF) process, initial growth of ice crystals occurs primarily through vapor deposition, where with respect to ice drives the uptake of from the surrounding environment, often at the expense of evaporating supercooled droplets. This phase allows nascent ice particles, starting from nuclei on the order of micrometers, to expand rapidly to sizes where becomes significant, typically reaching a critical of approximately 100 μm for pristine crystals. At this threshold, the particles acquire sufficient mass relative to drag to begin of the cloud layer under typical conditions. The terminal fall speeds of these growing ice particles vary markedly with size, shape, and environmental factors. For pristine crystals, fall speeds range from 10 to 100 cm/s, influenced by —such as plates or columns—and the , which accounts for aerodynamic and particle during descent. As particles or accrete, forming snowflakes or rimed structures like , their fall speeds increase to 50–200 cm/s for snowflakes and 200–800 cm/s for , enabling faster removal from the . These dynamics are governed by power-law relationships between particle dimension, mass, and , as established in and measurements. The combined effects of vapor deposition followed by aggregation and accretion propel ice particles toward precipitation sizes of 1–10 mm in , where fallout heightens due to enhanced velocities and reduced to turbulent suspension. This sequential growth integrates the differential vapor uptake of the WBF process with collision-based mechanisms, transforming small crystals into viable precipitating entities. Ultimately, the WBF process facilitates glaciation by progressively depleting through droplet , shifting the cloud composition toward an -dominated state that alters radiative properties and potential.

Pathways to Surface Precipitation

As ice particles generated through the Wegener–Bergeron–Findeisen process descend from cold cloud regions, they encounter varying sub-cloud environmental conditions that determine the final precipitation type reaching the surface. In scenarios where a deep warm layer exists above the 0°C melting level, typically at altitudes of 1-3 km, these particles fully melt into liquid raindrops upon falling through temperatures exceeding 0°C, provided the layer's depth—often 650-1300 m or more—allows complete phase transition based on particle mass and lapse rates ranging from -5°C/km to -15°C/km. This pathway is common in mid-latitude winter storms transitioning from snow to rain as surface temperatures rise above freezing. Partial melting occurs in shallower warm layers, where ice particles partially liquefy before entering a colder sub-cloud layer below 0°C, leading to refreezing and the formation of —small, translucent typically 2-5 mm in diameter. This refreezing process is facilitated by the presence of residual ice nuclei within the partially melted particles, requiring a cold layer depth of 200-550 m at temperatures of -5°C to -10°C for complete solidification into . In drier sub-cloud environments with low relative humidity, falling particles may instead undergo or before reaching the ground, producing —visible shafts of precipitating that dissipate into fall streaks without accumulating at the surface. Under convective conditions with intense updrafts, such as in thunderstorms, ice particles experience rapid accretion of supercooled , growing into larger than 5 mm through repeated cycles of ascent and descent in updrafts exceeding 20 m/s (approximately 45-72 km/h). These strong vertical motions, often sustained in cumulonimbus clouds, allow hail embryos—initially frozen droplets or small —to collide with supercooled , forming layered structures via wet or dry growth regimes, with larger hail (e.g., golf ball-sized at 4.4 cm) requiring updrafts up to 29 m/s. typically develops at higher altitudes in regions of extreme , like the . Freezing rain arises when ice particles fully melt in an elevated warm layer (1-3 km altitude) into supercooled raindrops that remain liquid through a shallow cold layer near the surface, only to refreeze upon impact with sub-freezing ground or objects below 0°C, forming glaze ice accumulations. This contrasts with ice pellets, as the cold layer is insufficiently deep (less than 200 m) or warm enough to prevent in-air refreezing, allowing droplets with minimal ice fractions (e.g., 0.01) to supercool until surface contact. Particle fall speeds, influenced by size and shape from prior growth stages, modulate the time available for these phase changes during descent.

Significance and Modern Applications

Impacts on Weather and Climate

The Wegener–Bergeron–Findeisen (WBF) process plays a critical role in enhancing efficiency within extratropical cyclones, particularly in frontal systems where mixed-phase clouds dominate. By facilitating the rapid growth of crystals at the expense of supercooled liquid droplets, the process promotes the formation of larger precipitating particles that can fall through warmer cloud layers, often into rain. In mid-latitude winter storms, this ice-phase mechanism contributes significantly to overall through the glaciation and subsequent of crystals. On climatic scales, the WBF process influences radiative feedbacks in mixed-phase clouds, which are prevalent between 0°C and -40°C. Glaciation driven by the process reduces the liquid water path while increasing the ice water path, leading to decreased and enhanced , particularly in the midlatitudes where net warming effects range from 0.18 to 0.76 W/m². In the , this contributes to amplification of warming by altering the lifecycle of persistent mixed-phase clouds, sustaining low-level stratus that trap heat and exacerbate sea ice loss through modified patterns. The process also underpins several weather hazards by enabling the development of heavy in mixed-phase environments. In wintertime synoptic systems, WBF-initiated ice crystal growth followed by aggregation results in intense snowfall rates, often exceeding 5 cm/h in mid-latitude storms. In convective scenarios, such as thunderstorms, the process supports formation in the mixed-phase region through accretion of supercooled droplets onto ice particles, producing hailstones up to several centimeters in diameter. Additionally, by influencing droplet evaporation and cloud persistence, it can exacerbate supercooled formation, reducing to below 1 km in affected areas. Observational evidence from satellite missions underscores the global prevalence of the WBF process in mixed-phase clouds. Data from the CALIPSO lidar reveal that such clouds, where the process dominates ice growth, comprise 30–50% of cloud layers in mid- to high-latitude regions, with supercooled liquid coexisting with ice in nearly 50% of low-level Antarctic clouds during austral summer. These observations highlight the process's role in ~13% of Arctic liquid-containing clouds producing snowfall, confirming its efficiency in natural settings despite model biases that overestimate glaciation rates.

Modeling Parameterizations and Limitations

In bulk microphysics schemes used in and climate models, the Wegener–Bergeron–Findeisen (WBF) process is typically parameterized within two-moment frameworks that prognose both the mixing and number concentration of particles to capture the evolution of particle size distributions. For instance, the Morrison double-moment scheme implemented in the Weather Research and Forecasting (WRF) model represents via vapor deposition as the primary mechanism driving the WBF process, where supercooled droplets evaporate to sustain with respect to . Similarly, the ICON model's two-moment scheme incorporates comparable formulations, emphasizing the transfer of vapor from liquid to phases in mixed-phase clouds. The mixing in these schemes is often expressed as \frac{dq_i}{dt} = \frac{4\pi C_i D_v (\rho_{v,amb} - \rho_{v,i}) N_i}{\rho_{air}}, where q_i is the ice mixing ratio, C_i is the capacitance of ice particles (dependent on shape assumptions like spherical or hexagonal), D_v is the water vapor diffusivity, \rho_{v,amb} and \rho_{v,i} are the ambient and ice-saturated vapor densities, N_i is the ice number concentration, and \rho_{air} is air density; this form derives from diffusion-limited growth theory adapted for bulk distributions. Despite these advancements, parameterizations exhibit limitations, particularly in underestimating the WBF process under entrainment-mixing conditions, where inhomogeneous mixing can enhance local supersaturations and accelerate beyond model predictions, as highlighted in large-eddy simulations from 2020–2021 studies. Additionally, many schemes neglect kinetic effects at cold temperatures below -40°C, where molecular accommodation coefficients reduce deposition rates, leading to overestimations of formation in polar environments. These shortcomings contribute to biases in simulated lifetimes and efficiency. Recent developments have addressed some dependencies, such as the 2024 evaluation of in large-eddy mode, which improved WBF representations by incorporating velocity effects on and , enhancing agreement with in-situ observations from the . A January 2025 evaluation of mid-to-high-latitude surface snowfall and cloud phase biases in CMIP6 models and ERA5 reanalysis, using CloudSat– observations, reveals persistent overestimations of supercooled liquid-containing frequencies and associated snowfall rates in polar regions, highlighting the need for refined microphysical parameterizations including WBF processes. Observational gaps further complicate validation, as sub-grid scale WBF dynamics—such as rapid local glaciation—are challenging to resolve with and , which struggle with distinguishing ice habits and small-scale mixing in mixed-phase layers, limiting direct comparisons to model outputs.

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