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Calcium silicate hydrate

Calcium silicate hydrate (C-S-H), often abbreviated as such, is the primary binding phase in hydrated Portland cement, constituting 50–70% of the volume of hardened cement paste^[1] and serving as the main contributor to the mechanical strength and durability of concrete.^[2] It forms as a poorly crystalline, nanoscale gel through the hydration of calcium silicate phases like tricalcium silicate (C₃S, alite) and dicalcium silicate (C₂S, belite), which are the dominant components of cement clinker.^[2] The hydration process involves a multi-step nucleation pathway, beginning with the formation of pre-nucleation clusters of calcium and silicate ions, followed by aggregation into amorphous globules that evolve into the characteristic C-S-H structure resembling defective tobermorite minerals.^[3] The composition of C-S-H is variable, with a typical Ca/Si ratio ranging from 1.5 to 2.0, and a general empirical formula approximating (CaO)₁.₇(SiO₂)(H₂O)₁.₈, though it can incorporate additional ions such as aluminum, sodium, or potassium, leading to variants like C-A-S-H.^[2] Structurally, C-S-H consists of layered sheets featuring dreierketten silicate chains—short, finite chains of three silica tetrahedra—intercalated with calcium ions and water molecules in interlayer spaces, resulting in a disordered, foil-like morphology at the nanoscale with thicknesses of 1–10 nm.^[2] This amorphous nature, lacking long-range order detectable by X-ray diffraction, arises from defects in the tobermorite-like framework, which cause curvature and prevent dense packing, contributing to its gel-like consistency and high surface area.^[4] Key properties of C-S-H include a density of approximately 2.6 g/cm³, an elastic modulus ranging from 20–80 GPa, and the ability to bind aggregates through nanoscale interactions, which underpin concrete's compressive strength exceeding 100 MPa in mature pastes.^[2] Its formation kinetics and microstructure significantly influence cement hydration rates, rheology, and long-term performance, including resistance to chemical attack and dimensional stability, making C-S-H a focal point for advancing sustainable cementitious materials.^[3] Over a century of research, from early colloidal models in the 1920s to modern atomistic simulations, has elucidated these features, enabling nanoengineering approaches to enhance C-S-H's ordering and properties for ultra-high-performance concretes.^[5]

Fundamentals

Definition and Importance

Calcium silicate hydrate (C-S-H) is a poorly crystalline, nanoscale material that forms in the CaO-SiO₂-H₂O system and is denoted using cement chemistry notation, where C stands for CaO, S for SiO₂, and H for H₂O.^[6] This gel-like phase arises primarily from the hydration reactions of calcium silicates in Portland cement, exhibiting a tobermorite-like layered structure that binds the material together.^[7] As the principal binding phase in hydrated Portland cement, C-S-H constitutes 50-70% of the volume of the hydrated cement paste and accounts for nearly all of concrete's compressive strength.^[8] Its formation during cement hydration is essential for the development of concrete's mechanical properties, making it indispensable for modern construction.^[1] The significance of C-S-H was first recognized in 19th-century studies of cement hydration, notably by Henry Louis Le Chatelier, who proposed its role in concrete strength despite limitations in early microscopy.^[9] Key advancements came in the 1930s through the work of William Lerch and Robert H. Bogue, who investigated hydration heats and products, solidifying its central role in cement chemistry. C-S-H is not a single compound but a family of phases characterized by variable stoichiometry, with Ca/Si ratios typically ranging from 1.2 to 2.0 and commonly around 1.7, reflecting its compositional flexibility in different hydration environments.^[10] This variability contributes to its adaptability as the dominant phase in cementitious materials.^[11]

Chemical Composition

Calcium silicate hydrate (C-S-H) is characterized by the general chemical formula (\ce{CaO})_x \cdot \ce{SiO2} \cdot (\ce{H2O})_y, where the values of x and y vary depending on formation conditions, reflecting its non-stoichiometric nature. In cementitious materials, the Ca/Si (C/S) molar ratio typically ranges from 1.2 to 2.1, with an average of approximately 1.7 observed in plain Portland cement pastes. This ratio determines the relative proportions of calcium oxide and silica in the phase, influencing its overall stoichiometry without a fixed composition.^[10] The C/S ratio in C-S-H exhibits significant variability based on synthesis conditions and environmental factors. In high-silica environments, such as those involving supplementary cementitious materials like fly ash or silica fume, the C/S ratio is lower, often below 1.5, due to increased silicate polymerization and reduced calcium availability. Conversely, in calcium-rich settings typical of ordinary Portland cement hydration, the C/S ratio exceeds 1.7, leading to more calcium incorporation and shorter silicate chains. This compositional flexibility arises from the dynamic equilibrium during formation, where excess calcium or silica alters the phase's elemental balance.^[10]^[12] C-S-H also incorporates minor elements that modify its composition, primarily aluminum from aluminate phases, sulfate, and alkali ions. Aluminum substitutes into the silicate structure, with uptake levels up to an Al/Si ratio of 0.05 in phases with C/S around 1.0, forming calcium aluminate silicate hydrate (C-A-S-H). Sulfate ions adsorb onto or incorporate within C-S-H, particularly in sulfate-containing environments, affecting surface charge and stability. Alkali ions such as Na^+ and K^+ occupy interlayer sites, with incorporation increasing at lower C/S ratios and higher initial alkali concentrations in the solution. These trace elements, typically at low concentrations, arise from cement clinker impurities or additives and influence the phase's charge balance.^[13]^[14]^[15] The chemical composition of C-S-H is determined using analytical techniques tailored to its amorphous nature. X-ray fluorescence (XRF) spectroscopy provides bulk elemental analysis, quantifying major components like Ca, Si, and minor elements in solid samples without dissolution. For precise C/S ratios, inductively coupled plasma (ICP) optical emission spectrometry is employed after acid digestion, offering high sensitivity for dissolved cations and accurate molar ratio calculations. These methods ensure reliable characterization, often complemented by selective dissolution to isolate C-S-H from other hydration products.^[16]^[17]

Structure and Morphology

Atomic and Molecular Structure

Calcium silicate hydrate (C-S-H) possesses a layered atomic structure closely analogous to the crystalline minerals 11 Å tobermorite and jennite, serving as primary structural models for its organization. In this arrangement, the fundamental building units are calcium-silicate sheets that form the main layers, separated by interlayers containing loosely bound calcium ions and water molecules, which act as bridges between adjacent sheets.^[18] The mainsheet itself comprises edge-sharing calcium octahedra coordinated with silicate tetrahedra, creating a corrugated framework that accommodates structural flexibility. The silicate components within these sheets are organized into dreierketten chains, characterized by repeating motifs of three tetrahedra: paired dimers and pentamers linked by bridging units in a 3n-1 configuration, where n represents the repeat length.^[18] This chain structure arises from the polymerization of isolated silicate tetrahedra (Q^0) into linear and occasionally branched forms, with the degree of polymerization predominantly reflected in Q^1 (end-of-chain dimers) and Q^2 (middle-of-chain) silica environments, as determined by ^{29}Si nuclear magnetic resonance (NMR) spectroscopy.90046-2) These Q^1 and Q^2 units dominate the spectra of synthetic and cement-derived C-S-H, indicating finite chain lengths typically ranging from 3 to 11 silicate tetrahedra, depending on synthesis conditions.90046-2) Cross-linking between dreierketten chains occurs through bridging silica tetrahedra (Q^3 sites), enhancing connectivity within the layers, though such links are infrequent in low-Ca/Si C-S-H. However, inherent nanoscale disorder, including vacant bridging sites, stacking faults, and irregular chain terminations, results in poor long-range crystallinity, distinguishing C-S-H from its more ordered mineral analogs.^[18] This disorder manifests in broadened X-ray diffraction peaks and is a key feature of C-S-H's amorphous-like character at the atomic scale.

Nanoscale Features

Calcium silicate hydrate (C-S-H) exhibits distinctive nanoscale morphology characterized by foil-like or needle-shaped nanoparticles, typically consisting of thin sheets 5-10 nm thick that aggregate into fibrillar or honeycomb networks. These foil-like structures, often observed as crumpled or layered nanosheets with thicknesses around 3.5-7 nm, form the basic building blocks in both synthetic and cement-derived systems. Needle-like particles, with lengths exceeding widths by a factor of 10 and diameters of approximately 20 nm, display a layered internal arrangement and contribute to reticulated patterns at the nanoscale.^[19]^[20]^[19] The nanoscale features of C-S-H include high porosity and specific surface area, arising from gel pores in the 1-10 nm range that form an interconnected nanoporous network. This porosity accounts for approximately 28% of the volume in hydrated cement paste, primarily within the C-S-H gel phase, enabling significant water adsorption and ion transport. The specific surface area typically ranges from 200-300 m²/g, reflecting the extensive exposure of the thin sheet surfaces and contributing to the material's reactivity and durability in cementitious systems.^[20]^[21]^[20] Due to its colloidal nature, C-S-H demonstrates aggregation behavior that results in fractal-like clusters, with dimensions typically between 1.4 and 2.2, forming stable suspensions or dense packs depending on environmental conditions. These clusters, observable as low-density aggregates up to 700 nm in size, exhibit random nanoscale organization that evolves into continuous foil or needle structures. Techniques such as atomic force microscopy (AFM) reveal agglomerations of 60 × 30 × 5 nm³ particles on surfaces, while small-angle X-ray scattering (SAXS) confirms the planar, two-dimensional fractal features and high surface area in suspensions.^[22]^[19]^[22] The calcium-to-silicon (C/S) ratio significantly influences C-S-H morphology at the nanoscale, with lower ratios (e.g., below 1.58) promoting more elongated, fiber-like or foil-like forms that enhance structural anisotropy. In contrast, higher C/S ratios (e.g., above 1.58) lead to denser, globular or fibrillar aggregates with reduced porosity and increased packing density. These variations arise from differences in layer spacing and crystallite growth, affecting the overall texture and mechanical response of the hydrate phase.^[23]^[19]^[23]

Formation Processes

In Cement Hydration

Calcium silicate hydrate (C-S-H) forms primarily through the hydration reactions of the main clinker phases in Portland cement, tricalcium silicate (C₃S) and dicalcium silicate (C₂S). The hydration of C₃S proceeds according to the reaction $2\mathrm{C_3S} + 6\mathrm{H} \to \mathrm{C_3S_2H_3} + 3\mathrm{CH}, where C represents CaO, S represents SiO₂, H represents H₂O, C₃S₂H₃ denotes C-S-H, and CH denotes calcium hydroxide; this process is the major contributor to the cement's early strength and is highly exothermic.^[24] Similarly, C₂S hydrates via $2\mathrm{C_2S} + 4\mathrm{H} \to \mathrm{C_3S_2H_3} + \mathrm{CH}, contributing to longer-term strength development but producing less heat.^[24] These reactions result in C-S-H with a typical calcium-to-silicon ratio (C/S) of about 1.7.^[25] The kinetics of C-S-H formation are characterized by rapid initial precipitation from C₃S, which dominates the first 24 hours of hydration and involves nucleation on clinker particle surfaces, leading to an acceleration period of intense growth.^[26] This phase is followed by a deceleration as the protective C-S-H layer thickens, limiting further dissolution. In contrast, C₂S hydration is slower, extending over 28 days or more, with gradual C-S-H formation that fills remaining pores and enhances durability.^[25] The overall process is exothermic, with peak heat evolution during the early C₃S reaction, influencing the setting time and early microstructure development.^[24] Several factors influence the rate and extent of C-S-H formation during cement hydration. The water-to-cement ratio (w/c) is critical, with an optimal range around 0.40–0.42 allowing complete hydration without excess porosity; lower ratios limit reaction progress, while higher ones dilute ions and slow nucleation.^[26] Temperature affects kinetics significantly, with an ideal range of 20–30°C promoting balanced hydration rates—elevated temperatures accelerate early reactions but can lead to uneven microstructure, whereas lower temperatures prolong the dormant period.^[24] Admixtures, such as superplasticizers, modify the process by dispersing particles to enhance nucleation sites and growth, thereby improving workability and early strength without altering w/c.^[27] During hydration, volume changes occur as anhydrous clinker phases convert to hydration products, resulting in an overall expansion that densifies the paste microstructure by filling capillary pores with C-S-H gel.^[28] This densification reduces porosity and permeability, contributing to the hardened cement paste's mechanical integrity, though the process involves a net chemical shrinkage offset by product precipitation.^[25]

Laboratory Synthesis

One common laboratory method for synthesizing pure calcium silicate hydrate (C-S-H) involves precipitation from aqueous solutions of calcium nitrate and sodium silicate, typically conducted under alkaline conditions at pH 12-13 to promote rapid nucleation and gel formation.^[29] Concentrations are often set at 0.2 mol/L for calcium nitrate and 0.1 mol/L for sodium silicate, with the solutions mixed at controlled rates to achieve desired Ca/Si ratios ranging from 0.8 to 2.0.^[29] Following initial precipitation, the resulting gel is aged for several hours to days at room temperature or elevated temperatures (e.g., 40-60°C) to stabilize the structure and refine particle size, allowing precise control over the C/S ratio which influences the interlayer spacing and morphology. Hydrothermal synthesis provides an alternative route to produce more crystalline C-S-H phases, such as tobermorite analogs, by reacting calcium oxide (CaO) and silica (SiO₂) under elevated pressure and temperature conditions of 150-200°C.^[30] The reactants are typically mixed in a molar CaO/SiO₂ ratio of 0.8-1.0, sealed in an autoclave with water to achieve saturated steam pressure (around 8-16 bar), and heated for 8-24 hours to facilitate phase transformation from amorphous precursors to layered structures like 11 Å tobermorite.^[31] This method yields denser, more ordered materials compared to ambient precipitation, with crystallinity increasing with longer reaction times and higher temperatures within the specified range.^[32] Sol-gel routes enable nanoscale control over C-S-H formation by hydrolyzing tetraethyl orthosilicate (TEOS) in the presence of calcium salts, such as calcium nitrate tetrahydrate, under acidic or basic catalysis.^[33] The process begins with the acid-catalyzed hydrolysis of TEOS to form a silica sol, followed by addition of the calcium salt and adjustment to neutral or alkaline pH for co-gelation, often incorporating surfactants to tune particle morphology into spheres or fibers with diameters below 100 nm.^[34] Aging and drying steps at 60-80°C promote cross-linking and densification, resulting in hybrid gels that mimic the nanoscale features of cementitious C-S-H.^[34] Post-synthesis characterization of laboratory-produced C-S-H frequently employs thermogravimetric analysis (TGA) to quantify bound water content, which typically ranges from 20-30 wt% and corresponds to interlayer and hydroxyl-bound water lost between 50-300°C.^[35] This technique distinguishes evaporable water (below 105°C) from structurally bound components, providing insights into the hydration degree and stability, with higher bound water fractions observed in lower C/S ratio samples.^[36]

Properties

Physical and Thermal Properties

Calcium silicate hydrate (C-S-H) exhibits a range of physical properties that are critical to its role in cementitious materials, with density varying based on water content and structural packing. The apparent density of nanoscale C-S-H gel particles, including physically bound water, is measured at 2.604 g/cm³ using small-angle neutron and X-ray scattering techniques on hydrated cement samples. This value reflects the solid phase incorporating interlayer and gel-bound water, as determined from the mean chemical formula (CaO)_1.7(SiO₂)(H₂O)_1.80. The skeletal density of the anhydrous C-S-H structure is approximately 2.6 g/cm³, derived from neutron scattering data and consistent with molecular models of the silicate framework. Apparent density typically ranges from 2.0 to 2.5 g/cm³ in hydrated forms, decreasing with higher water content due to the incorporation of evaporable and bound water within the nanostructure.^[37]^[2] Porosity in C-S-H arises from its gel-like morphology, featuring an intrinsic bimodal distribution at the nanoscale that influences water retention and transport. Interlayer pores measure approximately 1.2 nm, accommodating bound water molecules between silicate sheets, while smaller intralayer pores around 0.5 nm contribute to the tight packing of the structure. This nanoscale porosity is complemented by larger gel pores (1-10 nm), resulting in a total porosity of up to 50% by volume in the C-S-H gel phase, as observed through small-angle scattering and packing density analyses. These pores, derived from the stacking of disordered silicate layers, enable high water sorption but also affect the overall compactness of cement paste.^[38] Thermal properties of C-S-H are characterized by distinct dehydration stages, revealing its sensitivity to temperature and implications for durability under heat exposure. Thermogravimetric analysis (TGA) shows initial loss of evaporable water below 105°C, corresponding to free and loosely bound moisture in gel pores. Subsequent dehydration of bound water and partial decomposition occurs between 105°C and 400°C, followed by silicate framework breakdown in the 400-600°C range, where weight loss reflects the release of hydroxyl groups and structural rearrangement. The hydration process contributes to the exothermic nature of cement setting and influences early-age thermal management.^[39]^[40]^[41] Electrical properties of C-S-H stem from its hydrated structure, exhibiting a high dielectric constant due to polarized water layers within pores. Values range from 20 to 80, depending on frequency and hydration state, as measured by impedance spectroscopy on hydrating pastes where water mobility enhances permittivity. This response is anisotropic, with in-plane constants increasing with pore thickness, reflecting the influence of interlayer water on charge storage and conduction in cementitious systems.^[42]^[43]

Chemical Properties

Calcium silicate hydrate (C-S-H) plays a key role in maintaining the high alkalinity of the pore solution in cementitious materials, typically sustaining a pH range of 12.5 to 13.5 primarily through the dissolution of portlandite (calcium hydroxide, CH).^[44] Once portlandite is depleted during leaching or long-term exposure, C-S-H contributes to pH buffering by releasing calcium ions through selective dissolution, thereby mitigating pH drops in the surrounding environment.^[45] C-S-H exhibits low solubility under neutral to alkaline conditions, characterized by a solubility product where the product of calcium and silicate ion activities is approximately 10^{-8} M², reflecting its stability in high-pH environments.^[46] However, at lower pH values below 9, C-S-H undergoes decalcification, preferentially leaching calcium ions and leaving behind a silica-rich gel that further alters the material's chemistry.^[44] The material demonstrates significant ion exchange capacity, particularly for heavy metal cations, which adsorb onto calcium sites within the C-S-H structure. For instance, lead (Pb²⁺) and cadmium (Cd²⁺) can be effectively bound, with adsorption capacities reaching up to 1-2 mmol/g depending on the C-S-H composition and environmental conditions.^[47] Exposure to carbon dioxide leads to carbonation of C-S-H, where calcium ions react to form calcium carbonate (CaCO₃) precipitates, progressively reducing the Ca/Si ratio—often down to around 0.67—and enhancing the overall stiffness of the structure through densification.^[48] This process not only sequesters CO₂ but also modifies the chemical reactivity of C-S-H by polymerizing silicate chains.^[49]

Mechanical Properties

Calcium silicate hydrate (C-S-H) exhibits mechanical properties that are critical to the performance of cement-based materials, primarily assessed at micro- and nano-scales using techniques such as nanoindentation. The elastic modulus of C-S-H gel, measured via nanoindentation, typically ranges from 20 to 30 GPa, with low-density variants showing values around 21.7 GPa and high-density variants around 29.4 GPa. These values are lower than those of portlandite (CH), which range from 35 to 45 GPa. The layered structure of C-S-H imparts anisotropy, with the modulus higher parallel to the sheets (up to 50 GPa) compared to the transverse direction (around 20-25 GPa). Porosity within the C-S-H gel reduces the effective modulus, linking nanoscale features to macroscopic stiffness. Hardness of C-S-H, also derived from nanoindentation, falls in the range of 0.5 to 1 GPa, with low-density phases at approximately 0.45 GPa and high-density at 0.66 GPa. This property is sensitive to indentation depth, decreasing at shallower depths due to surface effects, and to water content, where higher hydration levels soften the gel through interlayer swelling.^[50] C-S-H displays a viscoelastic response characterized by creep and shrinkage, arising from time-dependent deformation under sustained load. This behavior follows a logarithmic compliance model, with the gel exhibiting higher creep capacity upon rehydration after drying, governed by water diffusion within nanopores and sliding between silicate sheets. Toughness in C-S-H is limited, with a low fracture energy of about 1.7 N/m, resulting from brittle sliding of weakly bonded sheets during crack propagation.^[51] Crosslinking within the structure, such as through organosilane modifications, can enhance this energy by strengthening interlayer bonds. These intrinsic properties underpin the compressive strength of concrete, where C-S-H acts as the primary load-bearing phase.

Applications

In Construction Materials

Calcium silicate hydrate (C-S-H) serves as the primary binding phase in Portland cement concrete, forming an interlocking network of nanoscale fibers and particles that imparts the material's structural integrity and accounts for approximately 70-80% of the volume of hydrated products.^[52] This gel-like structure develops during the hydration process, where calcium silicates in the cement react with water to create a dense matrix that binds aggregates together, contributing the majority of the concrete's compressive strength, typically 20–40 MPa for standard mixes after 28 days of curing under standard conditions.^[53] The mechanical contributions of this network are essential for load-bearing applications in buildings, bridges, and infrastructure. The formation of C-S-H gel significantly influences the workability and handling properties of fresh concrete. As hydration progresses, the gel absorbs free water from the mix, leading to increased viscosity and a transition from fluid paste to a semi-solid state, which affects rheology by reducing flowability and promoting thixotropy.^[54] This water consumption also governs the setting time, with the initial set—defined as the point where the paste loses plasticity—typically occurring within 2-4 hours, depending on factors like temperature and admixtures.^[55] In blended cements, such as those incorporating supplementary materials like fly ash, the calcium-to-silica (C/S) ratio in C-S-H can be optimized to enhance overall performance. Fly ash reacts pozzolanically with calcium hydroxide from cement hydration to form additional C-S-H with a lower C/S ratio, resulting in a denser microstructure that improves long-term strength, reduces permeability, and enhances durability without compromising early-age properties.^[56] This approach allows for more sustainable formulations by partially replacing clinker while maintaining the binding efficacy of C-S-H. Global cement production, which relies on C-S-H as its core phase, reached approximately 3.9 billion metric tons in 2024, underscoring the scale of its application in construction worldwide.^[57]

Other Industrial Uses

Calcium silicate hydrate (C-S-H) serves as a key binder in synthetic calcium silicate boards used for high-temperature insulation in refractories, providing thermal stability and mechanical strength up to 1100°C.^[58] These boards, formed through hydrothermal synthesis of C-S-H phases like xonotlite, offer low thermal conductivity (typically 0.05-0.1 W/m·K at 500°C) and resistance to thermal shock, making them suitable for lining industrial furnaces, kilns, and boilers where they act as backup insulation to refractory linings.^[59] The C-S-H matrix in these materials ensures dimensional stability under cyclic heating, reducing cracking and extending service life in demanding environments.^[60] In biomedical applications, C-S-H-based materials exhibit bioactivity and controlled ion release, enabling their use in bone cements and scaffolds for tissue regeneration.^[61] These cements, often formulated as calcium silicate composites, promote apatite formation on their surface in simulated body fluids, enhancing osseointegration for orthopedic and dental implants.^[62] Additionally, mesoporous C-S-H structures facilitate drug delivery systems, achieving high loading capacities (up to 50 wt%) for antibiotics or growth factors, with sustained release over weeks due to their ion-exchange properties.^[63] For nuclear waste encapsulation, C-S-H in cementitious barriers adsorbs radionuclides through surface complexation and incorporation into its gel structure, leveraging its high calcium-to-silicon ratio for selective uptake.^[64] This sorption mechanism effectively immobilizes ions like cesium and radium, with distribution coefficients exceeding 10^4 mL/g under alkaline conditions typical of cement pore solutions, preventing leaching in long-term repositories.^[65] Molecular dynamics simulations confirm that radionuclides bind to silanol and calcium sites on C-S-H surfaces, enhancing the durability of waste forms.^[66] Emerging applications include the use of nano-C-S-H as additives in 3D-printed concrete to improve printability and early-age strength.^[67] These nanoparticles accelerate hydration, reducing thixotropy and enhancing shape retention during extrusion, allowing for complex geometries with minimal slump (less than 5 mm over 30 minutes).^[68] By seeding C-S-H nucleation, they increase compressive strength by 20-30% at 28 days without compromising flowability.^[69]

Advanced Topics

Durability and Degradation

Calcium silicate hydrate (C-S-H) plays a pivotal role in the long-term durability of cement-based materials, primarily through its ability to bind aggressive ions and maintain structural integrity under environmental stresses. However, exposure to external agents can lead to degradation mechanisms that compromise the C-S-H matrix, resulting in reduced performance over time. Key degradation pathways include sulfate attack, chloride penetration, alkali-silica reaction (ASR), and calcium leaching, each exploiting vulnerabilities in the C-S-H structure to induce expansion, cracking, or increased permeability.^[70] Sulfate attack involves the ingress of sulfate ions (SO₄²⁻) into concrete pores through diffusion and capillary action, driven by concentration gradients. These ions react with aluminates and C-S-H components to form expansive ettringite (3CaO·Al₂O₃·3CaSO₄·32H₂O), whose needle-like crystals generate internal stresses by increasing the solid phase volume up to eightfold. This expansion disrupts the C-S-H matrix, leading to micro-cracking and macro-scale surface cracks that accelerate further deterioration. In aggressive environments, such as sulfate-rich soils or seawater, the process reduces compressive strength and increases porosity, with diffusion depths reaching 3-5 mm after extended exposure periods.^[70]^[71] Chloride penetration poses a significant threat to reinforced concrete by facilitating corrosion of embedded steel. C-S-H binds chloride ions (Cl⁻) primarily through physical adsorption and chemical incorporation into its structure, with absorption following a Freundlich isotherm in concentrations of 0.1-1.0 M Cl⁻, typically achieving capacities of 0.5-1 mol/kg depending on pH and composition. This binding helps maintain the passive oxide layer on steel reinforcement, but once free chloride levels exceed a corrosion threshold of approximately 0.4% by weight of cement, depassivation occurs, initiating pitting corrosion. The process is exacerbated in de-iced roads or marine environments, where chloride ingress increases over time, weakening the C-S-H gel and promoting crack propagation.^[72]^[73] The alkali-silica reaction (ASR) arises when alkalis in the pore solution react with reactive silica in aggregates, forming expansive ASR gels that infiltrate C-S-H pores. These gels, characterized by low Ca/Si ratios (initially as low as 0.05, rising to 0.25), generate solidification pressures of 6-13 MPa in confined spaces less than 30 nm, driven by electrostatic repulsion and precipitation rather than mere water uptake. The resulting expansion within the C-S-H matrix induces tensile stresses, leading to cracking that propagates from aggregates into the surrounding paste. ASR manifests over years in high-alkali concretes exposed to moisture, causing map-like cracking patterns and substantial volume changes.^[74]^[75] Calcium leaching occurs when C-S-H is exposed to aggressive waters, such as acidic or soft groundwater, causing progressive dissolution of calcium ions from portlandite and the C-S-H gel itself. This decalcification increases porosity by degrading the solid phases, with capillary and gel pores expanding significantly; in natural conditions, leaching depths can reach 5-10 mm over 100 years, though accelerated in laboratory tests. The heightened permeability facilitates further ion ingress, mechanically weakening the matrix and reducing compressive strength by up to 50% in severe cases. Over decades, this process undermines the overall durability of structures like dams or tunnels in leaching-prone environments.^[76]^[77]

Modeling and Simulations

Molecular dynamics (MD) simulations have been instrumental in elucidating the nanoscale behavior of calcium silicate hydrate (C-S-H), particularly through models based on tobermorite-like structures that serve as proxies for the disordered C-S-H phase. These simulations predict key dynamical properties, such as water dynamics and ion diffusion, by resolving atomic interactions within nanopores. For instance, unbound water molecules in C-S-H pores exhibit self-diffusion coefficients on the order of 10^{-9} m²/s, while confined water diffuses more slowly due to interactions with the silicate framework. Such models draw from the atomic structure of tobermorite to validate predictions against nanoscale features observed experimentally. Calcium-silicate chain models provide insights into the polymerization processes governing C-S-H formation, incorporating Q^n speciation to describe the connectivity of silicate tetrahedra. This approach highlights the role of Q^1 and Q^2 species in the disordered chains typical of C-S-H, offering a theoretical framework for hydration kinetics.^[78]^[79] At the mesoscale, discrete element modeling (DEM) simulates the aggregate behavior in cement paste by representing C-S-H as bonded particle clusters, capturing mechanical interactions and deformation under load. These models treat C-S-H globules as discrete elements to predict creep and stress relaxation, revealing how microstructural evolution affects overall paste rheology. DEM approaches bridge atomic-scale insights with macroscale properties, such as load distribution around aggregates.^[80]^[81] Recent advances since 2020 have integrated machine learning potentials into large-scale simulations of C-S-H, enhancing accuracy for disordered structures beyond traditional force fields. Deep learning-based potentials, trained on ab initio data, enable efficient MD runs on systems with varying Ca/Si ratios, improving predictions of mechanical properties and ion transport in realistic, nanoscale amorphous configurations. These methods reduce computational costs while maintaining quantum-level fidelity, facilitating studies of hydration and degradation at extended timescales. High-throughput atomistic modeling frameworks and neuroevolution potentials have further advanced predictions of structural and mechanical properties across composition ranges as of 2025.^[82]^[83]^[84]^[85]^[86]

Environmental Impact

The production of calcium silicate hydrate (C-S-H) through cement hydration is closely tied to the environmental footprint of Portland cement manufacturing, which accounts for approximately 8% of global anthropogenic CO₂ emissions, or about 2.5 Gt per year as of recent estimates. These emissions primarily arise from the calcination of limestone in clinker production, releasing CO₂ during the decomposition of calcium carbonate to form calcium oxide, the key precursor for C-S-H formation upon hydration.^[87]^[88]^[89] Cement production also imposes significant resource demands, including high water consumption during mixing, typically at a water-to-cement ratio of around 0.4 for optimal workability and strength, which contributes to local water stress in water-scarce regions. Additionally, silica sourcing for clinker—often from clay, sand, or quartz quarries—leads to habitat disruption, soil erosion, and dust pollution, exacerbating land degradation and biodiversity loss in mining areas.^[90]^[91]^[92] Mitigation strategies focus on low-carbon alternatives to traditional cement, such as geopolymers derived from industrial byproducts like fly ash, which can reduce CO₂ emissions by up to 80% compared to Portland cement by avoiding clinker production altogether. CO₂-cured C-S-H systems, involving accelerated carbonation of calcium silicates, enable sequestration of up to 0.2 tons of CO₂ per ton of cement through mineral carbonation during curing, effectively offsetting a portion of production emissions.^[93]^[94] Lifecycle assessments of C-S-H-based materials highlight how enhanced durability—through optimized composition and reduced permeability—extends service life, thereby decreasing the frequency of replacements and lowering cumulative environmental impacts by 20-50% over the structure's lifespan compared to less durable variants. These assessments emphasize that while upfront emissions remain high, long-term eco-efficiency improves with materials that resist degradation, supporting broader sustainability in construction.^[95]^[96]

References

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A comprehensive review of C-S-H empirical and computational ...
After a brief description of related crystalline calcium silicate hydrates, empirical C-S-H models based on interpretation of experimental data are presented.
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Multi-step nucleation pathway of C-S-H during cement hydration ...
Dec 2, 2023 · The Calcium Silicate Hydrate (CSH) nucleation is a crucial step during cement hydration and determines to a great extent the rheology, microstructure, and ...
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Aug 11, 2021 · When Portland cement is mixed with water, nanometre-thin crumpled sheets/ribbons of C–S–H quickly grow from the cement particles and assemble in ...
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A century of research on calcium silicate hydrate (C–S–H): Leaping ...
Jan 4, 2022 · Abstract. Calcium silicate hydrate (C–S–H) gel is the glue of Portland cement that governs most of the physicochemical properties of concrete.
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Calcium Silicate Hydrate - an overview | ScienceDirect Topics
Calcium silicate hydrate is produced by reaction of C 3 S or C 2 S with water. It is frequently described as a gel rather than a crystalline material.
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The calcium silicate hydrates - ScienceDirect.com
This article is concerned with the calcium silicate hydrates, including crystalline minerals and the extremely variable and poorly ordered phase (CSH)
[7]
Structure, Fractality, Mechanics and Durability of Calcium Silicate ...
The main product of hydrated products of cement-based materials is calcium silicate hydrate (C-S-H) gels that are considered as the binding phase of cement ...
[8]
[PDF] Silicate-Hydrate (C-S-H) Binder - OSTI.GOV
In a micro-scale, concrete possesses a complex structure of multiple calcium silicate phases, which are produced during the cement hydration process [1].
[9]
[PDF] A century of research on calcium silicate hydrate (C–S–H) - Monash
One of the most notable discoveries was made by the cement chemist H. F. W. Taylor,. 117 in his series of XRD and phase equilibria experiments with C–S–H phases ...
[10]
Solubility and structure of calcium silicate hydrate - ScienceDirect
The poorly crystalline calcium silicate hydrate (C-S-H) phases that form near room temperature, which include the technically important C-S-H gel phase formed ...
[11]
Atomic-Level and Surface Structure of Calcium Silicate Hydrate ...
Sep 8, 2023 · C-S-H forms around 50 to 60% by volume of hardened cement paste and is the primary binder that binds together other crystalline hydration ...Introduction · Methods · Results · Discussion<|control11|><|separator|>
[12]
A method for the reliable and reproducible precipitation of phase ...
This paper focuses on a reliable method to produce single-phase C single bond S single bond H with Ca:Si molar ratios between 1 and 2.
[13]
Incorporation of aluminium in calcium-silicate-hydrates - ScienceDirect
The incorporation of aluminium leads to modification of the CSH structure at Ca/Si = 1.0. Up to Al/Si = 0.05, all aluminium is taken up in CSH.
[14]
Effect of sulfate on C-S-H at early age - ScienceDirect.com
Zeta potential measurements have shown that sulfate is easily adsorbed on/in calcium silicate hydrates (C-S-H) [8]. The amount of sulfate absorbed by the C-S-H ...
[15]
Effect of alkali hydroxide on calcium silicate hydrate (C-S-H)
O sheets and silicate chains, an interlayer region is present, which contains water molecules, Ca2+, and possible alkali ions (Na+ and/or K+). Fig. 1. Download: ...
[16]
Impact of Ca/Si and Al/Si ratios on the composition and structure of ...
The bulk chemical composition from X-ray fluorescence (XRF) analysis of the synthesized C-S-H is given in Table 2, whereas its phase composition determined by ...
[17]
(PDF) Influence of the Ca/Si Ratio on the Compressive Strength of ...
Jul 13, 2017 · The Ca/Si atomic molar ratio in the range of 0.8-1.2 restricts the connection of the pore network and limits water ingress by providing optimal ...
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https://doi.org/10.1107/S2052520614021982
[19]
Does nano basic building-block of C-S-H exist? – A review of direct ...
The morphological characteristics of four types of C-S-H, namely globule-like particle, foil-like structure, needle-like structure, micro-assembled structure ...
[20]
Atomic-Level and Surface Structure of Calcium Silicate Hydrate ...
Due to the calcium in the bridging site (CaB), the surface Ca/Si of the Ca-Surface equals 1.5, while for the Si-Surface 1 equals 1.0. The MCL decreases with an ...
[21]
[PDF] Modelling drying shrinkage of cement paste and mortar
The total internal porosity of the C-S-H gel was set at 28%, a generally accepted value for this parameter. The macro-level model was assigned a porosity of ...
[22]
Oriented aggregation of calcium silicate hydrate platelets by the use ...
The fractal nature of the aggregates has been characterized by TEM and SAXS . Based upon (U)SAXS data of different C–S–H suspensions, it is demonstrated that ...Missing: clusters AFM colloidal
[23]
Morphogenesis of Cement Hydrate: From Natural C-S-H to Synthetic ...
As the Ca/Si ratio was increased from the value below 1.58 to the value above 1.58, the morphology transformed from a foil-like morphology to fiber-like status.Missing: nanoscale | Show results with:nanoscale
[24]
CIVL 1101 - Part 4 - Hydration of Portland Cement
### Summary of Hydration of Portland Cement (https://www.ce.memphis.edu/1101/notes/concrete/everything_about_concrete/04_hydration.html)
[25]
Multiscale understanding of tricalcium silicate hydration reactions
Jun 4, 2018 · Tricalcium silicate, the main constituent of Portland cement, hydrates to produce crystalline calcium hydroxide and calcium-silicate-hydrates (CSH) ...
[26]
Cement Hydration Kinetics - National Precast Concrete Association
Mar 14, 2016 · The main products of cement hydration reactions are calcium silicate hydrate (CSH), calcium hydroxide (CH), and the AFt and AFm phases. The AFt ...Hydration · Cement Types And Their... · Resources
[27]
[PDF] Stages of Hydration
As the volume of hydration products grows, concrete porosity and permeability decreases, and the concrete gains strength. Eventually, the products—particularly ...
[28]
[PDF] Synthesis of nano-structured Calcium silicate hydrate
The aim of this project is to synthesis C-S-H via precipitation route at Ca/Si ratio varying from 0.7 to 2. All the physical parameters such as pH, Ca2+ ion ...
[29]
Mechanism of precipitation and phase composition of CaO–SiO2 ...
Aug 6, 2025 · Briefly, the sodium silicate solution was prepared by dissolution of ... Optimisation of the Aqueous Precipitation Synthesis of Silicate- ...
[30]
Hydrothermal formation of the calcium silicate hydrates, tobermorite ...
In situ energy-dispersive X-ray diffraction (XRD) techniques have been employed to study the hydrothermal formation of crystalline tobermorite and xonotlite.
[31]
Influence of Hydrothermal Synthesis Conditions on the Formation of ...
Hydrothermal treatment has been widely applied in the synthesis of well crystalline calcium silicate hydrate (CSH), such as tobermorite and xonotlite.
[32]
Influence of Hydrothermal Synthesis Conditions on the Formation of ...
Oct 3, 2018 · Hydrothermal treatment has been widely applied in the synthesis of well crystalline calcium silicate hydrate (CSH), such as tobermorite and ...
[33]
Sol-Gel Synthesis of Calcium Silicate Powder - AIP Publishing
One typical synthesis process for calcium silicate gels is the cogelation of tetraoxysilane (TEOS) and hydrated calcium nitrate. Because the rate of hydrolysis ...
[34]
Synthesis and structure of calcium silicate hydrate (C-S-H) modified ...
Jan 18, 2021 · Calcium silicate hydrate (CSH) gel particles modified by hydroxyl-terminated polydimethylsiloxane (PDMS) were synthesized by the sol–gel method.
[35]
[PDF] How much water is there within calcium silicate hydrates? Probing
CSH has thin water films on surfaces and inside nanopores, with varying water content and distribution, and the water is kept in structured surface layers.
[36]
Kinetics of Al uptake in synthetic calcium silicate hydrate (C-S-H)
The TGA data show a main water loss between 30 and 300 °C from interlayer and structurally bound water in C-A-S-H. The water loss of C-A-S-H increases from ...
[37]
A realistic molecular model of cement hydrates - PMC
Given the shortfalls of the natural analogs, tobermorite and jennite, to meet this compositional constraint, Richardson proposed a two-fold classification to ...
[38]
Evolving the C–S–H packing density at the micrometer-scale
The C-S-H gel with low density (LD) and C-S-H gel with high density (HD) had ... The packing density of the OPC was 2.34 g cm⁻³, increased to 2.39 g cm ...
[39]
Characterization of Calcium Silicate Hydrate Gels with Different ...
The first thermal step was observed in the range between ambient temperature and 240 °C which is related to the evaporation of the adsorbed and interlayer water ...
[40]
The degree of hydration assessment of blended cement pastes by ...
Aug 9, 2025 · -Removal of the evaporable water (25 to 105°C) -dehydration reaction of CSH and CASH noted as "Ldh" (105 to 400 °C) between 400 and 600 ...Missing: 105C 600C
[41]
[PDF] Influence of organosilicon admixtures on the hydration of Portland ...
Aug 24, 2020 · The heat of hydration of belite and calcium aluminoferrite is about 250 J g−1 and 400 J g−1, respectively [6]. Reactions of calcium silicates ...
[42]
Effect of hydration on the dielectric properties of C-S-H gel
Jan 20, 2011 · We show that a strong change in the dielectric relaxation of C-S-H gel occurs with increasing hydration, especially at a hydration level in ...
[43]
Dielectric permittivity of C-S-H - ScienceDirect.com
This study adopts a multiscale approach to estimate the complex dielectric response of C–S–H over the 0 to 1000 GHz frequency range.
[44]
Decalcification kinetics of calcium silicate hydrates: role of Al content ...
Oct 7, 2025 · As a result of the hydration process, Portland cement produces amorphous C-S-H, which makes up about 60% of the paste by volume. The increased ...<|separator|>
[45]
Calcium silicate hydrate (CSH) gel dissolution and pH buffering in a ...
Mar 3, 2017 · Calcium silicate hydrate phases are expected to play a crucial role in buffering the pH of the near-field porewater, once any Ca(OH)2(s) in the ...
[46]
Calcium silicate hydrate (C-S-H) gel solubility data and a discrete ...
Experimental C-S-H gel solubility data have been compiled from the literature, critically evaluated and supplemented with new data from the current study for ...
[47]
[PDF] Removal of Heavy Metal Cations (Copper, Lead, Zinc) from Water ...
May 14, 2021 · The sorption behavior of calcium silicate hydrate (CSH) with respect to lead, copper and zinc was studied to consider its application to remove ...
[48]
Effect of carbonation on calcium silicate hydrate - IOP Science
Prior studies have shown that carbonation can result in the Ca/Si ratio of CSH to decrease to near 0.67 through decalcification. The end product of carbonation ...
[49]
An intricately designed modeling of concrete carbonation utilizing ...
Aug 29, 2025 · It is confirmed that carbonation enhances mechanical performance, with fully carbonated concrete exhibiting increased stiffness and up to 10 ...
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https://doi.org/10.1016/j.conbuildmat.2018.08.215
[51]
https://doi.org/10.1016/j.jnoncrysol.2015.03.031
[52]
Nanoscale determination of calcium silicate hydrate (C-S-H ...
Calcium silicate hydrate (C-S-H) is the key component of hardened Portland cement paste, accounting for about 70%–80% of total hydration products. Therefore, ...
[53]
Time-dependent rheological behavior of cementitious paste under ...
Nov 30, 2019 · Bellotto [20] stated that the hydration products (i.g. C-S-H gel and Portlandite) caused a negligible effect and an upward inflection on the ...
[54]
How Long Does Concrete Take to Set
Standard Portland cement concrete typically has an initial set time of 2 to 4 hours. The final set occurs around 4 to 8 hours after mixing, though full ...
[55]
Optimizing calcium efficiency for sustainable cement with GGBFS-fly ...
Aug 26, 2025 · Both C3S and C2S are primary compounds responsible for generating calcium silicate hydrate (CSH), a robust molecular structure that ...
[56]
Global cement production has plateaued over the last decade
Jan 16, 2025 · There has been some variation from year to year, but overall, global production has stayed around 4 billion tonnes. This data comes from the ...
[57]
Optimizing SiO₂-based thermal insulation materials via CSH/SiO₂ ...
Oct 15, 2025 · Calcium silicate hydrate (CSH) refers to a group of compounds formed in the CaO-SiO2-H2O (C-S-H) system, known for its low thermal conductivity ...
[58]
US9670098B2 - High temperature calcium silicate insulation
A calcium silicate insulation product includes a calcium silicate hydrate matrix that is predominantly but not substantially all xonotlite, ...<|separator|>
[59]
ZIRCAL Board - ZIRCAR Refractory Composites, Inc.
ZIRCAL-18 Refractory Board is a high temperature calcium silicate block insulation with excellent mechanical properties and stability up to 1100°C(2000°F).
[60]
Advances in the use of calcium silicate-based materials in bone ...
Jun 1, 2023 · Synthesis of europium-doped calcium silicate hydrate via hydrothermal and coprecipitation method. Ceram. Int., 47 (2021), pp. 4803-4812. View ...
[61]
A Review on Calcium Silicate Ceramics: Properties, Limitations, and ...
Nov 10, 2022 · ... biomedical applications such as orthopedic, dental, wound healing and drug delivery. ... calcium-silicate-hydrate/polymer nanocomposites ...
[62]
Calcium silicate-based drug delivery systems - Taylor & Francis Online
Inorganic cements for biomedical application ... Tracking the transformations of mesoporous microspheres of calcium silicate hydrate at the nanoscale upon ...
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[PDF] Adsorption mechanisms of cesium at calcium-silicate-hydrate ...
Adsorption mechanisms of cesium at calcium-silicate-hydrate surfaces using molecular dynamics simulations. J. Bu, R. Gonzalez Teresa, K. G. Brown, F. Sanchez ...
[64]
The uptake of radium by calcium silicate hydrates and hardened ...
Aug 6, 2025 · ... sorption properties can be exploited for containment of radionuclide contaminants. In hardened cement paste, calcium silicate hydrate (C-S-H) ...
[65]
Atomistic insights into structure evolution and mechanical property of ...
Jun 5, 2021 · Bu et al. Adsorption mechanisms of cesium at calcium-silicate-hydrate surfaces using molecular dynamics simulations. J. Nucl. Mater. (2019).
[66]
3D Concrete Printing: A Systematic Review of Rheology, Mix ... - NIH
... 3D-printable concrete with the addition of bentonite. Szostak and Golewski [169] added nano-calcium silicate hydrate (CSH) seeds in concrete and observed a ...
[67]
Full article: 3D-printing of architected calcium silicate binders with ...
May 15, 2024 · Source: Cement and Concrete Composites. Effect of silica particle size on the formation of calcium silicate hydrate [C-S-H] using thermal ...
[68]
Enhancing the printability of 3D printing limestone calcined clay ...
May 9, 2025 · Metakaolin (MK) contains reactive aluminates and silicates, which can react with calcium hydroxide to form calcium silicate hydrate [7].
[69]
Mechanism and Performance Control Methods of Sulfate Attack on ...
This paper analyzes the existing literature on the chemical reactions and physical crystallization effects of sulfate attack on cement-based materials
[70]
A critical review on the interaction between calcium silicate hydrate ...
Jan 26, 2024 · This review provides a comprehensive overview of the latest studies regarding the interplay between CSH and different ions.
[71]
Chloride absorption capacity of calcium silicate hydrate (C-S-H) and ...
Aug 11, 2023 · C-S-H absorbs chloride, following a Freundlich isotherm, and promotes the chloride threshold value of steel corrosion, delaying corrosion ...
[72]
Beyond the chloride threshold concept for predicting corrosion of ...
Mar 29, 2022 · The CT conceptually indicates the level of chloride in the concrete adjacent to the steel that initiates active corrosion, i.e., the start of ...<|separator|>
[73]
Alkali silica reaction in concrete - Revealing the expansion ...
Alkali-silica reaction (ASR) is a major cause for concrete deterioration worldwide. However, the mechanism leading to cracking has not been identified yet.
[74]
Alkali-Silica Reaction (ASR) Expansion: The Role of C-S-H ...
Nov 21, 2024 · Sodium (Na) and potassium (K), both facilitate alkali-silica reaction in concrete causing expansions. However, the swelling mechanism remains unclear.
[75]
Effects of Leaching Behavior of Calcium Ions on Compression ... - NIH
Leaching of calcium ions increases the porosity of cement-based material, thus resulting in degradation including damage to the pore structure. Increasing ...
[76]
Calcium leaching behavior of cementitious materials in hydrochloric ...
Jun 11, 2018 · Furthermore, the calcium leaching decreases with increasing silica ... hydration products, resulting in an increase in porosity. On the ...
[77]
Understanding silicate hydration from quantitative analyses of ...
Mar 24, 2016 · Silicate hydration is prevalent in natural and technological processes, such as, mineral weathering, glass alteration, zeolite syntheses and ...
[78]
Tracing Polymerization in Calcium Silicate Hydrates Using Si ...
The calculations reveal that the highly polymerized structures have longer Si-O bonds and that the Ca2+ cations play a dual role in the stretching and bending ...
[79]
Mesoscale simulation of C–S–H creep and stress relaxation by ...
Jun 1, 2025 · This study employs a novel discrete element method to model creep and stress relaxation in C–S–H, enabling microstructure evolution exploration.
[80]
On the Shape Simulation of Aggregate and Cement Particles in a ...
Oct 11, 2015 · Discrete element modeling (DEM) is commonly employed for simulation of concrete structure. ... aggregate structure and fresh cement paste ...
[81]
Elucidating the constitutive relationship of calcium–silicate–hydrate ...
Dec 7, 2020 · Overall, by seamlessly integrating MD simulations with ML, this paper can be used as a starting point toward accelerated optimization of C–S–H ...
[82]
A deep learning-based potential developed for calcium silicate ...
Jun 5, 2023 · Additionally, the deep potential successfully reproduces precise predictions in C-S-H models with different calcium-to-silicon ratios ...
[83]
A deep learning potential applied in tobermorite phases and ...
Based on the datasets of first-principle simulations, machine learning potentials (MLPs) can achieve both accurate predictions of complex material systems ...
[84]
Projecting future carbon emissions from cement production ... - Nature
Dec 11, 2023 · The sector is currently responsible for 5% to 8% of global anthropogenic CO2 emissions every year3,4.<|separator|>
[85]
Getting to Net Zero - Global Cement and Concrete Association
Total global CO2 emissions from the sector today are in excess of 2.5Gt. They are primarily direct CO2 emissions which in turn are primarily from the heated ...01 / Emissions From Pure... · Savings In Clinker... · Savings In Cement And...
[86]
Global CO 2 emissions from cement production - ESSD Copernicus
We show that global process emissions in 2016 were 1.45±0.20 Gt CO 2 , equivalent to about 4 % of emissions from fossil fuels.Missing: percentage | Show results with:percentage
[87]
(PDF) Environmental Impact of Concrete - ResearchGate
Aug 5, 2025 · Cement production requires a source of calcium (usually limestone). and a source of silicon (such as clay or sand). Small amounts of bauxite ...
[88]
Water Cement Ratio: A Key Factor in Cement Strength and Durability
Oct 1, 2025 · Answer: The ideal ratio for strong concrete typically falls between 0.4 to 0.5, depending on the application and environmental conditions.
[89]
[PDF] Environmental Impacts of Industrial Silica Sand (Frac Sand) Mining
May 4, 2015 · WDNR, quarries and sand mines typically have few point source emissions and modeling has shown there is little chance industrial sand mining ...
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Sustainable low-carbon cement technologies for reducing U.S. ...
Aug 9, 2025 · The geopolymer has demonstrated to be ideal candidate to mitigate the typical carbon footprint emissions of cements, such as Portland. The ...
[91]
[PDF] Environmental Impact of Carbonated Calcium Silicate Cement ...
Apr 21, 2017 · Sequestration of up to 300 kg of CO2 per tonne of CSC in the concrete has been predicted while values in excess of 230 kg of CO2 per tonne of ...
[92]
Durability of concrete coupled with life cycle assessment: Review ...
This review covers the recent advances in durability-based LCA. Three aspects were highlighted: 1) how durability influences the eco-efficiency of cementitious ...
[93]
(PDF) Durability of concrete coupled with life cycle assessment
Mar 24, 2023 · This review covers the recent advances in durability-based LCA. Three aspects were highlighted: 1) how durability influences the eco-efficiency of cementitious ...<|control11|><|separator|>