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Invar

Invar is a binary nickel-iron alloy composed of approximately 36% nickel and the balance iron, distinguished by its anomalously low coefficient of thermal expansion (CTE) of about 1.2 × 10⁻⁶ K⁻¹ over a wide temperature range near ambient conditions.^[1]^[2] This unique property, known as the Invar effect, arises from magnetoelastic coupling in the ferromagnetic phase below its Curie temperature of around 230–280°C, resulting in dimensional stability that minimizes changes in length or volume with temperature variations.^[1]^[3] Discovered in 1896 by Swiss physicist Charles Édouard Guillaume while investigating nickel-steel alloys for precision metrology at the International Bureau of Weights and Measures, Invar was named for its "invariable" expansion behavior.^[4]^[1] Guillaume's work earned him the Nobel Prize in Physics in 1920, recognizing the alloy's contributions to accurate physical measurements through its exceptional thermal stability.^[4] The optimal composition at 36% nickel was identified through systematic studies, revealing a sharp minimum in CTE at this ratio, with deviations increasing expansion rates.^[1]^[3] Invar's defining characteristics include not only low thermal expansion but also moderate strength, with a yield strength of around 240–550 MPa and good corrosion resistance in atmospheric environments, though it is ferromagnetic and susceptible to magnetic interference.^[1] Variants such as Super Invar (32% Ni, 5% Co, balance Fe) further reduce CTE to below 0.6 × 10⁻⁶ K⁻¹ for specialized cryogenic applications.^[1] Historically, Invar revolutionized timekeeping and surveying by enabling stable pendulums in clocks and accurate measuring tapes that resisted temperature-induced errors.^[1] Contemporary applications leverage Invar's stability in high-precision fields, including aerospace components like satellite structures and engine parts, semiconductor manufacturing tools, and optical systems such as telescope mirrors and laser frames.^[1] It is also used in bimetallic thermostats, shadow masks for cathode-ray tubes, and cryogenic containers due to its performance from -196°C to over 200°C.^[1]^[5] Despite challenges like higher cost and machinability issues compared to standard steels, Invar remains indispensable where dimensional precision is paramount.^[1]

History and Discovery

Discovery by Charles Édouard Guillaume

Charles Édouard Guillaume, a Swiss physicist serving as an assistant at the International Bureau of Weights and Measures (BIPM) in Sèvres, France, made the initial observation leading to the discovery of Invar in 1896 during systematic studies of nickel-iron alloys.^[6] His research was driven by the need for materials that could maintain dimensional stability across temperature fluctuations, particularly for precision instruments like the pendulums in astronomical clocks, where even minor expansions could introduce significant timing errors.^[7] In targeted experiments, Guillaume examined the thermal expansion behavior of various ferronickel compositions prepared in collaboration with the Société de Commentry-Fourchambault et Decazeville. He identified that an alloy with approximately 36% nickel and the balance iron demonstrated a coefficient of thermal expansion close to zero—ranging from about -0.5 × 10⁻⁶ to +1.2 × 10⁻⁶ per degree Celsius in the typical operating range—far lower than conventional steels.^[6] This unexpected property, which Guillaume named "Invar" (short for invariable), arose from anomalies in the alloy's magnetoelastic behavior but proved invaluable for metrological standards. Guillaume first documented these findings in a seminal 1897 paper presented to the Académie des Sciences, titled "Recherches sur les aciers au nickel: Dilatations aux températures élevées; résistance électrique," where he reported detailed measurements of expansion and electrical properties across alloy variants.^[8] For his pioneering work on such nickel-steel alloys, including Invar, which revolutionized precision physics by enabling temperature-independent length references, he received the Nobel Prize in Physics in 1920.

Early Development and Recognition

Following the initial observation of Invar's low thermal expansion properties in 1896, Charles Édouard Guillaume at the Bureau International des Poids et Mesures (BIPM) advanced the alloy through systematic experimentation, optimizing its nickel-iron composition for precision applications. Commercial production commenced in France around 1900 through a partnership with the Imphy steelworks, where the alloy was scaled for industrial use in metrology and scientific instruments.^[9] The trade name "Invar," derived from its invariant expansion behavior and suggested by Swiss engineer Marc Thury, was officially trademarked on April 1, 1904, by a French company associated with Imphy, marking the alloy's entry into broader markets.^[10] Early commercialization faced significant challenges in achieving reproducible low expansion rates, necessitating precise control of the nickel content at approximately 36% to minimize variability and the application of specific heat treatments, such as annealing, to stabilize the material's microstructure and reduce temporal dimensional changes.^[6] These processes were refined through iterative testing at BIPM, ensuring the alloy's suitability for high-precision tools like survey tapes and balance springs. Guillaume's 1897 publication detailing these findings accelerated adoption, with Invar wires produced for expeditions such as the 1899-1900 Spitsbergen survey.^[11] The alloy's impact was formally recognized in 1920 when Guillaume received the Nobel Prize in Physics "in recognition of the service he has rendered to precision measurements in Physics by his discovery of anomalies in nickel steel alloys," explicitly honoring Invar's role in enhancing measurement accuracy.^[4] Under Guillaume's direction at BIPM, Invar became integral to international standards for length measurement, with the organization establishing prototypes and calibration protocols using the alloy by the early 1910s to support global metrology efforts. By the 1910s, Invar had achieved widespread use in geodesy, timekeeping, and scientific instrumentation, solidifying its status as a foundational material for precision engineering.^[12]

Composition and Structure

Chemical Composition

Invar, a nickel-iron alloy renowned for its low thermal expansion, has a standard chemical composition consisting of approximately 64% iron and 36% nickel by weight, often denoted as FeNi36.^[13] This binary base is supplemented by controlled trace elements to enhance stability and processability, including carbon at less than 0.05%, manganese at less than 0.50%, and silicon at less than 0.3%.^[14] Other impurities such as phosphorus and sulfur are limited to a maximum of 0.02% each, while chromium, molybdenum, and copper are capped at 0.5% to prevent adverse effects on the alloy's properties.^[13] The nickel content plays a critical role in determining the alloy's thermal behavior, with an optimal range of 35-37% nickel yielding the minimal coefficient of thermal expansion (CTE) near room temperature.^[15] Deviations from this range, such as lower nickel levels, result in higher CTE values due to reduced suppression of the lattice expansion, while higher nickel increases both the CTE and the Curie temperature.^[16] Impurities are strictly controlled to maintain the alloy's integrity; for instance, low carbon levels below 0.05% are essential to avoid brittleness and preserve dimensional stability, as higher carbon can promote carbide formation that exacerbates thermal instability.^[17] Manganese, maintained below 0.50%, aids in deoxidation during melting and improves machinability without significantly altering the low-expansion characteristics.^[14] Similarly, silicon at levels under 0.3% supports deoxidation and enhances castability, but excess can elevate the CTE by influencing the magnetic properties.^[18] In naming conventions, Invar is designated as FeNi36 in European standards, reflecting the 36% nickel content, while in the United States it is commonly referred to as 64FeNi to emphasize the iron dominance.^[19] These designations align with international specifications such as ASTM F1684, ensuring consistency in composition across applications.^[20]

Crystal Structure and Phase Behavior

Invar possesses a face-centered cubic (FCC) austenitic crystal structure at room temperature, characterized by the gamma phase, which is stabilized by the high nickel content that suppresses the formation of body-centered cubic ferrite.^[21] This arrangement consists of a close-packed lattice of iron and nickel atoms, providing the foundational stability for the alloy's unique thermal behavior. The lattice parameter measures approximately 3.59 Å at 20°C, exhibiting only minimal expansion across a broad temperature range from -100°C to 100°C due to the inherent lattice softening associated with the Invar effect.^[22] A significant phase transition in Invar occurs at the Curie temperature, approximately 230–280 °C, marking the shift from a ferromagnetic to a paramagnetic state; this magnetic reorientation influences the lattice dynamics and contributes to the alloy's anomalous thermal expansion profile below this threshold.^[21] Above the Curie point, the structure remains FCC but loses its ferromagnetic ordering, leading to more conventional expansion characteristics. The phase stability is further maintained through controlled heat treatments, such as annealing at 800–900°C, which relieve residual stresses from processing while preserving the austenitic phase without inducing phase decomposition.^[23]

Physical Properties

Thermal Expansion Characteristics

Invar is renowned for its uniquely low coefficient of thermal expansion (CTE), denoted as \alpha, which quantifies the fractional change in length per unit temperature change according to the relation \Delta L / L = \alpha \Delta T. Over the temperature range of 0 to 100°C, the CTE of Invar is approximately $1.2 \times 10^{-6} K^{-1}, enabling dimensional stability in applications where thermal variations could otherwise cause significant deformation.^[24] In comparison, carbon steel exhibits a CTE of about $12 \times 10^{-6} K^{-1} in the same range, making Invar's expansion roughly one-tenth that of ordinary steels and earning it the descriptor "invariant" for room-temperature precision engineering.^[25] This low CTE arises from its specific iron-nickel composition but is particularly valuable for maintaining structural integrity in devices like clocks, measuring tapes, and optical instruments.^[15] The temperature dependence of Invar's CTE shows near-zero expansion persisting up to approximately 200°C, beyond which the value increases more rapidly, approaching that of other metals near the Curie temperature of around 230–280°C.^[21] Below 0°C, the CTE remains exceptionally low, typically between -100°C and $100°C, with values often cited as less than 2 \times 10^{-6} K^{-1}, though it can exhibit negative expansion in certain low-temperature regimes or under specific processing conditions.[21] This behavior ensures minimal dimensional changes across a broad ambient range, contrasting sharply with metals like aluminum (CTE \approx 23 \times 10^{-6} K^{-1}) or copper (CTE \approx 17 \times 10^{-6} K^{-1}$), which expand far more readily and are unsuitable for high-precision, temperature-variable environments.^[26] Standard measurement of Invar's CTE employs techniques such as dilatometry, which tracks length changes using a push-rod or optical lever system during controlled heating, and interferometry, which detects sub-micrometer expansions via laser fringe shifts for ultra-high precision.^[27] These methods, often calibrated against reference standards like quartz, confirm Invar's low expansion with accuracies down to $10^{-8} K^{-1}, supporting its use in metrology and aerospace where even ppm-level stability is critical.^[28]

Other Thermal and Magnetic Properties

Invar exhibits a thermal conductivity of approximately 10-12 W/m·K at room temperature, which is notably lower than that of pure iron (around 80 W/m·K).^[29] This relatively poor heat transfer characteristic arises from the alloy's composition and is consistent across standard processing conditions.^[30] The specific heat capacity of Invar is about 500-515 J/kg·K at room temperature, comparable to pure iron (approximately 450 J/kg·K) but influenced by the nickel content, which contributes to a slightly higher value in the Fe-Ni system.^[29]^[30] Invar is ferromagnetic below its Curie temperature of 230–280°C, above which it transitions to paramagnetic behavior.^[21] It exhibits moderate soft magnetic performance suitable for certain shielding applications.^[31] The electrical resistivity of Invar is approximately 80 μΩ·cm at room temperature and remains relatively stable over a range of temperatures up to the Curie point, with a low temperature coefficient of resistance.^[29]^[30]

Mechanical Properties

Strength and Ductility

Invar alloy exhibits moderate tensile strength in its annealed state, typically ranging from 450 to 600 MPa, which provides sufficient load-bearing capacity for precision applications without excessive brittleness.^[20] The yield strength is approximately 250 MPa, indicating the onset of plastic deformation under uniaxial loading, allowing the material to withstand stresses common in structural components while maintaining dimensional integrity.^[13] Ductility is a key attribute, with elongation at break measured at 30-40% in annealed condition, enabling significant deformation and forming operations without the risk of cracking or fracture.^[32] This high ductility arises from the alloy's face-centered cubic crystal structure, which facilitates dislocation movement under tensile loads. The Brinell hardness is around 130-140 HB in the annealed state, reflecting a balance between strength and formability; cold working processes, such as rolling or drawing, can increase hardness to 200 HB or more by introducing work hardening, thereby enhancing resistance to indentation and wear.^[33] Invar demonstrates good fatigue resistance, particularly under cyclic loading conditions encountered in precision parts like clock mechanisms or scientific instruments, where it endures repeated stresses without premature failure.^[34] This property, combined with its thermal stability, supports reliable long-term mechanical performance in environments with fluctuating temperatures.^[35]

Machinability and Workability

Invar 36 exhibits machinability similar to that of austenitic stainless steels, necessitating the use of sharp, high-speed steel or carbide tools to mitigate its high work-hardening tendency during cutting operations.^[36] Due to this work-hardening, cutting speeds are typically 20-30% lower than those for carbon steels, with recommended turning speeds of 50-100 surface feet per minute (sfm) using high-speed steel tools and up to 150-250 sfm with carbide, alongside adequate feeds and lubricants like sulfochloride oils to manage stringy chips.^[37] Interrupted cuts and tool dwelling should be avoided to prevent surface hardening and tool wear. Welding of Invar 36 is feasible using gas tungsten arc welding (GTAW) or gas metal arc welding (GMAW) with matching fillers such as VDM® FM 36, employing low heat input and stringer bead techniques to minimize distortion and hot cracking risks associated with its austenitic structure.^[36] Preheating is not strictly required, but maintaining interpass temperatures below 120°C and post-weld annealing at 820-900°C followed by rapid cooling help relieve stresses and prevent cracking; resistance welding is also possible for thinner sections with controlled parameters.^[38] Cleanliness is critical to avoid contamination from carbon steels or sulfur/phosphorus sources. The alloy demonstrates good cold workability in its annealed state, allowing reductions up to 50% through processes like stamping, deep drawing, or cold heading, owing to its inherent ductility, though intermediate annealing may be needed for heavier reductions.^[36] Hot forming is performed at 800-1050°C with rapid cooling to preserve properties, similar to austenitic stainless steels. Invar 36 offers moderate corrosion resistance in dry atmospheric conditions at room temperature but performs poorly in humid environments, acids, or chloride-containing media, where rust or pitting can occur; protective coatings are commonly applied for exposure to harsh conditions.^[36]

Explanation of Anomalous Behavior

The Invar Effect

The Invar effect describes the anomalously low thermal expansion exhibited by certain face-centered cubic iron-nickel alloys, such as Fe_{65}Ni_{35}, where spontaneous volume magnetostriction induces a lattice contraction that precisely counteracts the conventional phonon expansion, yielding a near-zero coefficient of thermal expansion (CTE) near room temperature.^[39]^[40] This compensation arises from strong magneto-volume instabilities in the itinerant electron magnetism of these alloys, allowing thermal excitations to favor lower-volume magnetic configurations over higher-volume non-magnetic ones.^[39]^[41] Observationally, the thermal expansion curve displays a minimum around 30°C, directly tied to the ferromagnetic ordering below the Curie temperature, where the spontaneous magnetostriction peaks and dominates the lattice response.^[39] This temperature dependence highlights how the effect manifests most prominently in the ferromagnetic phase, with the net expansion remaining nearly invariant over a practical range near ambient conditions.^[40] The phenomenon was first documented by Charles Édouard Guillaume in 1896 through measurements on Fe-Ni alloys, earning him the Nobel Prize in Physics in 1920 for his metallurgical contributions, though the specific terminology "Invar effect" arose in 1930s studies that probed its magnetic underpinnings via inhomogeneity models and early magnetoelastic experiments.^[42]^[41] These post-Guillaume investigations, including dilatometric and magnetic susceptibility analyses, established the effect as a hallmark of weak itinerant ferromagnetism rather than mere compositional tuning.^[39] Key experimental validation comes from X-ray diffraction experiments on Invar alloys, which reveal a distinct lattice contraction—up to several percent in volume—correlated with the development of spontaneous magnetization upon cooling into the ferromagnetic state.^[43] Such measurements, often combined with neutron scattering, confirm that the magnetostrictive strain alters interatomic distances, directly linking magnetic ordering to the observed dimensional stability.^[44]

Magnetoelastic Coupling Mechanism

The magnetoelastic coupling mechanism in Invar arises from the strong interaction between the material's magnetic moments and its lattice vibrations, where changes in magnetization induce strains in the crystal lattice, and conversely, lattice distortions influence the magnetic ordering. This coupling is particularly pronounced in the Fe-Ni Invar alloys due to the itinerant nature of the electrons, leading to a significant magneto-volume effect that counteracts normal thermal expansion.^[45] The strain induced by this mechanism can be described by the relation for the magnetostrictive strain \epsilon = \frac{3}{2} \lambda \left( \frac{M}{M_s} \right)^2, where \lambda is the magnetostriction coefficient (approximately $10^{-6} for Invar), M is the magnetization, and M_s is the saturation magnetization. This quadratic dependence reflects how the lattice distortion scales with the square of the reduced magnetization, manifesting as spontaneous volume magnetostriction that dominates the anomalous behavior at low temperatures.^[46] At the electronic level, Invar's high density of states at the Fermi level enhances spin fluctuations, which amplify the magnetoelastic interactions through band theory frameworks. Extensions of the Weiss two-state model incorporate these fluctuations, positing a near-degeneracy between low-spin (small-volume) and high-spin (large-volume) states, where thermal excitation promotes transitions that contract the lattice via electron repopulation from antibonding to bonding orbitals.^[47]^[45] The temperature dependence of this coupling is tied to the magnetic ordering; below the Curie temperature of around 230–280°C (503–553 K) for Fe-36Ni Invar, ferromagnetic alignment sustains the strong magnetoelastic effect, but it diminishes above the Curie point as thermal disorder weakens the magnetism, transitioning to a paramagnetic state with normal thermal expansion.^[45]^[31] Modern ab initio calculations, using density functional theory, confirm the instability of the two-γ state in the Ni-Fe system, revealing how the ferromagnetic-to-paramagnetic transition involves electron transfers that stabilize the low-volume phase through enhanced bonding in minority spin channels.^[45]

Variations

Invar 36

Invar 36 is the standard and original formulation of the low-expansion nickel-iron alloy, composed nominally of 36% nickel with the balance iron, along with trace amounts of elements such as carbon (maximum 0.1%), manganese (maximum 0.6%), silicon (maximum 0.35%), and others limited to 0.5% or less.^[13] This composition exhibits an exceptionally low coefficient of thermal expansion (CTE) of 1.0–1.5 × 10⁻⁶ /K across the temperature range of -100°C to 100°C, a property arising from the base Invar effect involving magnetoelastic interactions in the alloy lattice.^[13] Invar 36 is a registered trademark originally developed by the International Nickel Company and now held by entities including Carpenter Technology Corporation.^[25] The alloy adheres to the ASTM F1684-06 (reapproved 2021) standard, which specifies requirements for composition, mechanical properties, and dimensional stability under UNS designation K93603.^[20] It is commercially available in various forms, including sheets, plates, bars, rods, and wires, suitable for fabrication processes like hot and cold forming, machining, and welding.^[13] Common adjustments to the baseline Invar 36 include free-machining variants, such as Free-Cut Invar 36, which incorporate small additions of selenium (typically 0.15–0.30%) to enhance machinability while preserving the low CTE. Invar 36 is particularly suited for service in the temperature range of -50°C to 150°C, where its dimensional stability remains reliable without requiring specialized stabilization heat treatments beyond standard annealing.^[48] Within this range, the alloy's CTE stays below 2 × 10⁻⁶ /K, making it effective for components demanding precise tolerances under moderate thermal cycling.^[34]

Super Invar and Low Expansion Variants

Super Invar is an advanced nickel-iron-cobalt alloy with a nominal composition of 32% nickel and 4-5% cobalt (balance iron), designed to achieve an even lower coefficient of thermal expansion (CTE) than standard Invar alloys.^[49] Its CTE is typically less than $0.5 \times 10^{-6} \, \text{K}^{-1} over the range of 20–100°C, making it suitable for applications demanding dimensional stability at ambient temperatures.^[50] However, Super Invar exhibits dimensional instability over time due to aging effects, where the CTE gradually increases as a result of microstructural changes, such as phase transformations or stress relaxation, even at constant temperature.^[51] This aging can be partially mitigated through controlled heat treatments, but it remains a key limitation compared to the foundational Invar alloy. Other low-expansion variants derived from the Invar family include Kovar, an iron-nickel-cobalt alloy with approximately 29% nickel and 17% cobalt, which has a CTE of about $5 \times 10^{-6} \, \text{K}^{-1} that closely matches borosilicate glasses for reliable hermetic sealing in vacuum tubes and electronic components.^[52] Alloy 42, composed of 42% nickel (balance iron), offers a moderate CTE of around $4.5 \times 10^{-6} \, \text{K}^{-1} up to 300°C, finding use in glass-to-metal seals, lead frames, and thermostat elements where precise but not ultra-low expansion is required.^[53] These alloys represent tailored modifications to address specific matching needs, with cobalt additions in Kovar and Super Invar enhancing expansion control but introducing trade-offs, such as reduced ductility due to increased hardness and potential brittleness.^[54] The development of Super Invar and similar variants occurred primarily in the post-1950s era, driven by aerospace demands for materials in precision instruments, aircraft controls, and satellite components where thermal stability is critical under varying environmental conditions.^[1] By the 1960s, these alloys were commercialized to support space exploration and high-reliability electronics, building on the Invar base but optimizing for lower expansion at the expense of workability. As of 2025, recent advancements include stabilized Super Invar formulations achieved through precipitation hardening of intermetallic compounds, which enhance mechanical strength and reduce long-term relaxation while preserving the ultra-low CTE.^[55] These improvements, often combined with additive manufacturing techniques like laser powder bed fusion, enable better phase stability and mitigate aging effects for modern applications in optics and cryogenics.^[56]

Applications

Precision Measurement and Instruments

Invar's low coefficient of thermal expansion, approximately one-tenth that of typical steels, enables exceptional dimensional stability in precision instruments, minimizing errors from temperature fluctuations.^[7] Charles Édouard Guillaume's discovery of Invar in 1896 led to its pioneering use in clock pendulums, where the alloy's properties reduced thermal expansion effects on pendulum length, enhancing timekeeping accuracy in astronomical clocks.^[7] This application was particularly valuable in precision timepieces, including those developed for naval observatories in the 1910s, where stable pendulums ensured reliable measurements for navigation and scientific observations despite environmental variations. In geodesy, Invar tapes and rods revolutionized surveying by providing consistent length references over long distances. Included as standard equipment by the United States Geological Survey in 1913, these tools supported international baseline measurements with errors under 1 part in 500,000, far surpassing traditional steel tapes, and were integral to establishing accurate geodetic networks during that decade.^[10] Similarly, Invar yardsticks and bars served as working standards in metrology laboratories for defining and verifying length units, offering greater stability than platinum-iridium prototypes for routine calibrations until the 1960 redefinition of the meter in terms of krypton-86 wavelengths.^[57] For optical instruments, Invar's stability was employed in bimetallic strips and structural frames of telescopes, preserving alignment of lenses and mirrors across temperature ranges. Early 20th-century designs, such as those for large astronomical telescopes, incorporated Invar tubes and supports to counteract thermal distortions, ensuring precise focusing and imaging in observational applications.^[58]

Modern Industrial and Scientific Uses

Invar's low coefficient of thermal expansion makes it invaluable in modern electronics manufacturing, particularly for substrates and tools requiring precise thermal matching to prevent distortion during production processes. In the fabrication of OLED displays, Invar alloys serve as critical components in fine metal masks and deposition tools, enabling high-resolution patterning without thermal-induced misalignment, as demonstrated in advancements in electrodeposited Invar films that achieve near-zero expansion for enhanced yield in large-scale panel production.^[59] Similarly, Invar is employed in LCD assembly for shadow masks and structural elements that maintain dimensional stability under varying thermal conditions during semiconductor integration.^[60]^[61] In aerospace applications, Invar supports the construction of ultra-stable satellite components, including mirror mounts and structural frames that withstand extreme temperature fluctuations in orbit. Its use extends to advanced variants like Super Invar in high-precision satellite optics for zero-expansion requirements. In laser gyroscopes for navigation systems, Invar provides vibration-resistant housings and resonator supports, enhancing accuracy in inertial measurement units aboard aircraft and spacecraft.^[62]^[1] Within optics and photonics, Invar is integral to the design of high-stability mirrors and etalons used in interferometers, where thermal invariance preserves optical path lengths over wide temperature ranges. Protective structures in Fabry-Pérot etalons, for example, incorporate Invar tubes to shield against environmental variations, ensuring reliable interference patterns in laser spectroscopy and precision sensing.^[63] In space-based interferometric systems, specialized Invar alloys like High Purity Invar 36 minimize time-dependent dimensional changes, supporting applications in astronomical imaging and gravitational wave detection.^[64] In medical devices, Invar's properties enable the fabrication of stable frames for MRI machines, where components maintain magnetic field alignment despite operational heat generation.^[65] Precision surgical tools also leverage Invar for handles and fixtures that resist thermal distortion during sterilization and use, ensuring consistent performance in minimally invasive procedures.^[65] Invar is also used in cryogenic applications, such as containers for liquefied natural gas (LNG) and supports for superconducting magnets, due to its low thermal expansion over a wide temperature range including sub-zero conditions.^[1]

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Enhanced strength and fatigue life of ultra-fine grain Fe–36Ni Invar ...
Aug 9, 2025 · A significant enhancement of mechanical properties has been achieved via equal-channel angular pressing (ECAP); the yield stress and the fatigue ...
[35]
[PDF] VDM® Alloy 36 Pernifer 36
Mar 3, 2022 · In a dry atmosphere, VDM® Alloy 36 is corrosion-resistant at room temperature. In unfavorable conditions, for example a humid atmosphere, ...Missing: machinability | Show results with:machinability
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Invar Alloy Machining – A Guide | City Special Metals
Jul 8, 2019 · When working with the Invar “36” alloys, it is advisable to use a sharp three-cornered punch rather than prick punch to avoid work hardening the ...Missing: welding | Show results with:welding
[37]
Developing Invar Welding Procedures - Arc Machines
Sep 23, 2021 · To utilize the full potential of Invar, it is essential that the potential cracking and impurity be minimized during welding with control ...
[38]
Understanding the Invar Effect - Europhysics News
The spontaneous volume magnetostriction extrapolated to zero temperature, ωso' plotted in Fig. 3b peaks in the FM invar range around e/a ~ 8.7 and in the AF.
[39]
Origin of the Invar effect in iron–nickel alloys - Nature
Jul 1, 1999 · This effect, known as the Invar effect, has since been found in various ordered and random alloys and even in amorphous materials.
[40]
Magnetic state, magnetovolume effects, and atomic order in Invar alloy
Jul 13, 2007 · The anomalously low thermal expansion (Invar effect), discovered in fcc Fe-Ni alloys in 1897 by Guillaume, 1 is one of the oldest solid state ...
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[PDF] A simple theory of the Invar effect in iron-nickel alloys - arXiv
Guillaume, C. E. Recherches sur les aciers au nickel. Dilatations aux températures élevées; résistance électrique. C. R. Acad. Sci. 125, 235–238 (1897). 2 ...
[42]
Lattice Distortion and Magnetic Inhomogeneity in Fe-Ni Invar Alloy
X-ray diffraction and magnetization measurements were carried out on Invar alloy with magnetic inhomogeneity over the temperature range from room ...Missing: contraction | Show results with:contraction
[43]
Predictive Theory of Anomalous Volume Magnetostriction in Fe–Ni ...
Dec 28, 2023 · (Invar effect), this behavior is due to changes in the electronic structure induced by the effects of magnetic disorder leading to reduced local ...
[44]
[PDF] PROBLEMS CHAPTER 7 7.1 Show that the magnetostriction ...
magnetization roughly as e = (3/2)λs(cos2θ - 1/3) where λs is the saturation magnetostriction constant. Conversely, stresses σ imposed on the material which ...
[45]
[PDF] Two-state Weiss model for the anomalous thermal expansion ... - arXiv
The model was first proposed by Weiss [12] to explain the anomalous thermal expansion of γFe and the Fe-Ni Invar alloys [13]. It assumes the existence of two ...Missing: extensions | Show results with:extensions
[46]
[PDF] ATI 36™
ATI 36 alloy is a nickel-iron alloy combining low thermal expansion properties up to about 200°C (~400°F) along with moderately high strength and good toughness ...
[47]
Super Invar 32-5 Tech Data - High Temp Metals
Super Invar 32-5, a magnetic, austenitic, solid solution alloy containing iron, nickel, and cobalt, is designed to provide minimum thermal expansion at room ...Missing: composition effect sources
[48]
Super Invar Physical & Mechanical Properties - EFINEA Metals
Super Invar 32-5 Average Coefficient of Thermal Expansion - Annealed. Temperature Range, °C Heat Treatment 30°C to, UNS NO. K93500 871°C, 1 h, Furnace Cool μm/m ...
[49]
Effect of aging temperature on dimensional instability of invar alloys
Aug 9, 2025 · However, the CTE of the Invar alloy increased significantly with the increase of the aging temperature when the aging temperature was above 400° ...
[50]
Kovar Tech Data - High Temp Metals
Kovar alloy is a vacuum melted, iron-nickel-cobalt, low expansion alloy whose chemical composition is controlled within narrow limits to assure precise uniform ...
[51]
Low Expansion 42 - Specialty Alloys - Carpenter Technology
Low Expansion 42 is a 42% nickel-iron alloy with a consistently low rate of thermal expansion at temperatures up to approximately 650°F (343°C).
[52]
Effect of Cobalt on Microstructure and Mechanical Properties of Invar ...
The CTE decreased with the addition of cobalt, especially when the content of cobalt was 0.2 wt%. Compare to the sample without cobalt the microhardness with ...<|control11|><|separator|>
[53]
(PDF) Strengthening of Super Invar Cast Steel by Precipitation of ...
Aug 9, 2025 · Fig. 1. Various types of cryo-an nealing process to improve mechanical properties of super invar cast steel. Tab le 1.
[54]
Phase stability and thermal expansion properties of additive ...
May 16, 2025 · These 21 invar alloys have a metastable austenite phase at ambient temperatures, and their low thermal expansion 22 arises from the ...
[55]
[PDF] invar and related nickel steels - GovInfo
standard of steel containing some 22 per cent nickel and 3 per cent chromium, discovered that the linear coefficient of thermal expansion at ordinary ...
[56]
Modern Large Telescope Design* - Optica Publishing Group
The purpose of the telescope tube is to hold the mirrors and the various attachments in alignment. ... For special purposes a tube of aluminum or of invar might ...
[57]
Fabrication of low thermal expansion coefficient electrodeposited ...
An electrodeposited Invar alloy film was prepared with near-zero inclusions and near-zero thermal expansion, which will advance its application in OLED fine ...Missing: 2020s | Show results with:2020s
[58]
What is Invar? A Comprehensive Definition and Overview - Domadia
Dec 20, 2024 · Discovered in 1896 by Swiss physicist Charles Edouard Guillaume, this alloy emerged from his meticulous studies on the thermal expansion ...
[59]
INVAR® SFD, your material of choice for OLED and display ...
INVAR® SFD provides the controlled expansion required by the tools used for the fabrication of OLED displays. This alloy has also expansion and mechanical ...Missing: substrates semiconductors 2020s
[60]
A New Alloy is Enabling Ultra-Stable Structures ... - NASA Science
Jul 1, 2025 · Invar was bonded to the mirrors and flexures made of Ti6Al4V—a titanium alloy commonly used in aerospace applications—were attached to the Invar ...
[61]
The Advanced Super Invar Alloys with Zero Thermal Expansion for ...
Aug 9, 2025 · Invar alloys with low thermal expansion are often used in the structural and optical components of space telescopes and sensors, ...Missing: OLED 2020s
[62]
An Optical Acoustic Detection System Based on Fabry Pérot Etalon ...
Dec 16, 2021 · The protective structure of the confocal stabilized FPE is composed of an invar tube, copper sheath, Bakelite sheath and aluminum housing to ...<|separator|>
[63]
[PDF] stability of materials for use in space-based interferometric
... instruments [30]. Invar alloys are commonly used in clocks, scientific instruments, bimetal strips in thermostats, and many other applications where ...
[64]
CNC Machining Invar: A Complete Guide - DEK
Aug 26, 2024 · MRI machines comprise Invar components, which allow the maintenance of the alignment of magnetic fields in a precise way. Also, the surgical ...