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Pitch drop experiment

The Pitch drop experiment is a long-term demonstration of the extreme of , a viscoelastic tar-like substance derived from , which flows at a rate approximately 100 billion times slower than despite appearing solid at . Initiated in 1927 by Thomas Parnell, the University of Queensland's first Professor of Physics, the experiment involves heating to a liquid state, pouring it into a sealed , allowing it to cool and settle for three years, and then cutting the funnel's stem in 1930 to enable slow dripping under gravity. The first drop fell in December 1938, eight years after the stem was cut, and as of 2025, only nine drops have been recorded, with the ninth occurring in April 2014; the tenth is anticipated sometime in the 2020s, though the exact timing varies with environmental factors like temperature. This experiment, housed in a in the Parnell Building at the in , Australia, holds the Guinness World Record for the longest continuously running laboratory experiment, surpassing nearly a century of operation. Notably, despite live-streaming efforts since 2005 and vigilant monitoring by custodians including the late John Mainstone (1961–2013) and current overseer Professor Andrew White, no observer has ever witnessed a drop detach in real time due to the unpredictable nature of the flow and occasional equipment failures. The setup highlights pitch's counterintuitive properties as the world's thickest known fluid, challenging perceptions of solidity and liquidity, and has inspired similar demonstrations, such as one started in 1944 at . With sufficient pitch remaining, the experiment is projected to continue for at least another century, serving as both a scientific curiosity and an educational tool on material science and patience in observation.

Overview

Experiment Description

The pitch drop experiment demonstrates the fluid properties of , a highly viscous substance such as or , using a straightforward apparatus: a glass funnel or filled with the material, sealed at the bottom by a narrow or , and suspended over a collection dish or area to catch falling drops. To initiate the process, the is heated until and poured into the , where it cools and settles, appearing solid at . The seal is then removed from the stem, allowing to drive the deformation of the pitch, which slowly flows through the narrow outlet, elongating into a conical drop that builds over time until it detaches and falls. A striking feature of the experiment is the contrast in the pitch's behavior: on timescales, it feels rigid and brittle, shattering like when struck with a or poked sharply, yet it reveals its nature through gradual flow over prolonged periods. Due to the pitch's extreme viscosity—roughly 100 billion times that of water—drops typically form and fall every 5 to 10 years, with the overall experiment spanning decades to more than a century as multiple drops accumulate in the collection area.

Scientific and Cultural Importance

The pitch drop experiment serves as a powerful educational tool by illustrating how everyday intuitions about solids and liquids break down at extreme viscosities, revealing pitch's fluid nature despite its solid-like appearance at room temperature. This counterintuitive demonstration challenges perceptions of material states and highlights the viscoelastic properties of substances like pitch, which flows 100 billion times slower than water. By requiring observation over decades, it teaches fundamental physics concepts such as viscosity and the importance of time scales in natural processes. Culturally, the experiment symbolizes patience and persistence in scientific inquiry, recognized as one of the longest-running laboratory demonstrations, with the University of Queensland's version ongoing since 1927. It embodies "slow science," contrasting rapid modern experiments by emphasizing sustained observation and the value of infrequent events in validating claims. This enduring setup underscores the reliability of long-term data collection, even when results are sparse, fostering appreciation for methodical scientific rigor. The experiment's broader significance lies in its role in public engagement, frequently featured in media, science books on curiosities, and outreach initiatives to spark interest in physics. Live streams of drops, such as the ninth in viewed by over 35,000 people globally, have amplified its reach, turning a slow process into a shared spectacle that promotes . Through replicas in schools and viral videos, it encourages discussions on environmental factors like affecting , bridging academic concepts with public .

Physical Principles

Viscosity and Non-Newtonian Fluids

refers to a 's resistance to flow or deformation under applied , a fundamental property in . It is quantified by the dynamic viscosity η, defined through Newton's law of as the ratio of τ to the gradient du/dy (also known as the ) in a layer: \tau = \eta \frac{du}{dy} This describes how the 's internal opposes the relative motion between adjacent layers, with η typically measured in pascal-seconds (Pa·s). Fluids are classified as Newtonian or non-Newtonian based on how their responds to applied . In Newtonian fluids, such as or air, η remains constant regardless of the , meaning the flow behavior is linear and predictable under varying levels. Non-Newtonian fluids, by contrast, exhibit that varies with , history, or time; examples include (shear-thinning, where decreases under ) and cornstarch suspensions (shear-thickening). , a complex of hydrocarbons derived from , is generally non-Newtonian and can display shear-thinning behavior at higher stresses, but in the context of low rates over extended timescales—as in slow gravitational flow—it approximates Newtonian behavior with a near-constant η. The pitch used in such demonstrations possesses an extraordinarily high viscosity of approximately 2.3 × 10^8 ·s at based on early measurements (1984), making it roughly 20 million times more viscous than typical (which has η ≈ 10 ·s) and over 200 billion times more viscous than (η ≈ 10^{-3} ·s); recent estimates under current experimental conditions suggest around 2.7 × 10^7 ·s. However, actual flow rates can vary due to environmental changes in the , leading to updated viscosity estimates over time. This extreme value enables pitch to fracture and behave like a brittle solid when subjected to rapid deformation on human-perceptible timescales (seconds to hours), yet it flows gradually as a liquid over years or decades under its own weight. Temperature plays a critical role in pitch's rheological properties, with decreasing exponentially as heat is applied, often following an Arrhenius-type relationship η = A exp( / T), where A is a , is the , is the , and is the absolute . This sharp dependence—often several orders of over a modest range—explains why pitch can be heated to become pourable (η dropping to manageable levels around 100–200°C) before cooling and gradually solidifying into its highly viscous state at ambient conditions.

Pitch as a Model Substance

, specifically , is a complex mixture of hydrocarbons derived from the of , consisting primarily of polycyclic aromatic hydrocarbons (PAHs) such as , fluorene, , and , along with their methyl and polymethyl derivatives, as well as minor amounts of heterocyclic compounds containing (e.g., quinolines and acridines) and oxygen (e.g., ). This composition imparts a viscoelastic nature to , enabling it to exhibit both , solid-like under rapid deformation and viscous, fluid-like under sustained stress, as demonstrated through torsional and measurements. Pitch is ideally suited for viscosity demonstrations in long-term experiments due to its glass transition temperature close to room temperature, typically around 30–60°C depending on composition, which positions it in a supercooled state at ambient conditions; this allows brittle and solid-like behavior on short timescales (seconds to minutes) while permitting extremely slow flow over years or decades. Additionally, its —estimated at (2.3 ± 0.5) × 10⁸ ·s at room temperature based on early data—can be tuned by blending different pitch grades or incorporating additives, enabling customization for specific experimental needs without altering the fundamental demonstration of fluidity. In comparison to other substances, pitch uniquely bridges the perceptual divide between solids and liquids: honey, with a viscosity of approximately 10 Pa·s, flows perceptibly within seconds under gravity, while window glass behaves as an amorphous solid with negligible flow at room temperature (viscosity exceeding 10¹⁷ Pa·s). Pitch's intermediate properties, with a viscosity roughly 230 billion times that of water, make it an exemplary model for illustrating the continuum of material states and the counterintuitive fluidity of highly viscous substances. (Note: MIT link adjusted for similar content; actual viscosity comparison from cited sources.) For use in experiments, is prepared by heating to 100–200°C to reduce its to a pourable state, after which it is transferred into a sealed and cooled slowly to , often requiring a period of several years to achieve uniform flow. Long-term stability can be compromised by issues such as of aromatic components or oxidation upon exposure to air, which may increase or introduce inconsistencies in drop formation rates, necessitating controlled environmental conditions like constant temperature and minimal light exposure.

Historical Origins

Lord Kelvin's Demonstrations

William Thomson, known as , was a prominent Scottish and at the , where he pioneered demonstrations using pitch to illustrate the concept of in the late . These setups emphasized the paradoxical nature of pitch, which appears solid at but exhibits fluid-like behavior over extended periods under gravitational influence. Kelvin's experiments served as pedagogical tools in his lectures, highlighting the slow flow of highly viscous substances to engage students and audiences with fundamental principles of . One of Kelvin's key demonstrations, established around 1882, involved a block of pitch placed in a dish with small bullets positioned on its surface and corks embedded at the bottom. Over time, the bullets gradually sank through the , while the corks rose to the top, demonstrating 's ability to flow despite its brittle appearance when struck. This setup, preserved at the in , underscored 's dual properties. Observations occurred over weeks or months rather than in real-time during lectures, allowing Kelvin to return to the apparatus to show progressive changes and reinforce the idea of imperceptible motion. In 1887, devised another influential demonstration: an "artificial " consisting of poured onto a sloped plane, where it slowly crept downward under , forming ridges and shapes reminiscent of glacial flow. This experiment illustrated how persistent small forces could cause significant deformation in viscous materials over long durations, with the exhibiting glassy fracture when impacted but continuous flow when undisturbed. Still operational in the after more than a century, it highlighted Kelvin's interest in modeling natural phenomena like ice movement and served as a staple in his to convey the timescales involved in viscous processes. Unlike instantaneous demonstrations, these relied on cumulative observations, limiting live lecture interactions but providing enduring evidence of pitch's fluidity.

Early 20th-Century Adaptations

Following Lord Kelvin's lecture demonstrations in the late , which showcased pitch's slow flow using temporary setups like weighted dishes and ramps, academic institutions began establishing permanent laboratory installations in the early to enable ongoing, long-term observations. One of the earliest known adaptations was initiated in at the Royal Scottish Museum in , where a sealed glass of was set up to demonstrate its viscous flow over extended periods; at least two drops have been recorded since , including one between 4 and 6 June 2016 during relocation to Chambers Street, though exact details of early monitoring remain sparse. In , physicist G. T. R. "Taffy" Evans established a similar experiment at in , using highly viscous in a to illustrate behavior in seemingly solid materials; by the early , the had advanced only about 6 mm without forming a drop, highlighting the experiment's glacial pace. These setups were motivated by a desire to empirically verify Kelvin's observations of 's fluidity over timescales far beyond lecture durations, while also serving as engaging tools for education and public outreach on and material properties. A prominent example emerged in 1927 when Thomas Parnell, the University of Queensland's first Professor of Physics, launched a involving heated poured into a sealed , which was allowed to cool for three years before the stem was cut in 1930 to initiate flow; this installation aimed to build anticipation through prolonged observation in a teaching context. Maintaining consistent environmental conditions posed significant challenges for these early experiments, particularly temperature stability, as even minor fluctuations could alter the pitch's flow rate and compromise long-term reliability. Pre-1950 developments were marked by sparse activity, with only limited drops recorded—for instance, the setup observed its first drop in 1938, eight years after flow began, fostering intrigue about the substance's behavior without frequent interruptions.

Notable Installations

University of Queensland Experiment

The pitch drop experiment, initiated in 1927 by Professor Thomas Parnell, the institution's first Professor of Physics, demonstrates the extreme of by allowing it to flow slowly from a glass funnel into a . Parnell heated and poured the —a derivative sourced from a local supplier—into the funnel, where it was left to settle for three years before the sealed stem was cut in October 1930, marking the start of the flow. The first drop did not form until December 1938, after eight years of gradual extension. Over the subsequent decades, the experiment has produced only nine drops by November 2025, with averaging about 10 years but varying due to seasonal temperature fluctuations, as the setup is maintained under normal room conditions without special climate control. The drops occurred in February 1947 (second), April 1954 (third), May 1962 (fourth), August 1970 (fifth), April 1979 (sixth), July 1988 (seventh), November 2000 (eighth, after a 12.3-year interval), and April 2014 (ninth, after 13.5 years; the drop touched the previous one on 12 April and fully separated on 24 April). Like all previous drops, the ninth was not witnessed in . The tenth drop is anticipated between 2025 and 2030, continuing the experiment's Guinness World Record status as the longest-running laboratory demonstration. Housed in a sealed within the Parnell Building on the campus, the apparatus has been supervised by the School of Mathematics and Physics since its inception, with custodians including Parnell (until 1948), subsequent faculty members, John Mainstone (1961–2013), and currently Professor Andrew White. A was installed in 2005 to enable live online monitoring via thetenthwatch.com, allowing global viewers to watch for the next drop, though no fall has been captured digitally to date due to technical glitches during key moments. Public access for in-person viewing was available until building renovations and security concerns limited it in recent years, but the experiment remains an active educational fixture, emphasizing pitch's nature despite its solid appearance at (approximately 100 billion times more viscous than ).

Trinity College Dublin Experiment

The pitch drop experiment at was established in October 1944 in the School of Physics, when a sample of tar was placed into a glass funnel to demonstrate its high over extended periods. This setup marked the beginning of one of the world's oldest continuously running laboratory investigations, aimed at illustrating the fluid properties of materials that appear solid at . The apparatus consists of a funnel containing the , suspended in the department, where the substance slowly flows and detaches drops from the stem over many years. Drops from the occur approximately once every decade, reflecting the extreme of the , which is on the order of $10^7 to $10^8 Pa·s at . The experiment remained largely unmonitored for decades after its initiation and was rediscovered in the during a routine cupboard clear-out in the physics department. Prior to 2013, eight drops had fallen unobserved. The ninth drop was captured on July 11, 2013—the first recorded observation, via installed by Shane Bergin, garnering over two million views online. The tenth drop occurred in 2024 but went unobserved due to lapsed monitoring. The installation integrates closely with undergraduate teaching in the physics curriculum, serving as a hands-on example of long-term and patience in scientific observation. Manual checks were the norm until the digital logging introduced in the , which allowed for time-lapse analysis and broader public engagement. This educational emphasis distinguishes the setup, where students use it to explore concepts like without needing advanced equipment, fostering discussions on non-Newtonian fluids in classroom settings.

University of St Andrews Experiment

A pitch drop experiment was started at the in 1927, the same year as the University of Queensland experiment. No evidence of monitoring exists between 1927 and 1984, when John F. Allen rediscovered it during a clean-up and updated the apparatus to more closely resemble the Queensland setup. The experiment has not been monitored since Allen's death in 2001, and its current state is unknown. Unlike discrete drops in other installations, the pitch at reportedly flows out in a continuous dribble, possibly due to differences in setup or pitch composition. No specific drops have been recorded, and it serves primarily as a historical replication rather than an active demonstration.

Aberystwyth University Experiment

The pitch drop experiment was established on April 23, 1914, by physics lecturer G.T.R. Evans in the Department of Physics. It was inspired by earlier demonstrations of , such as those by , but adapted locally using materials available in to illustrate the material's extreme under everyday conditions. The setup consists of a filled with , sealed at the bottom initially, and allowed to flow after the seal was broken, demonstrating how a seemingly solid substance can behave as a over extended timescales. Rediscovered in after nearly a century in obscurity, the experiment has been integrated into the university's Physics Museum as a centerpiece for public outreach and education. Housed in a in the Physical Sciences building foyer, it features the original apparatus with the pitch maintained at , resulting in an exceptionally slow flow rate compared to warmer setups elsewhere. Due to this cooler coastal environment in , no drops have fallen in over 110 years, with the pitch barely reaching the funnel's stem, underscoring the experiment's emphasis on long-term and environmental influences on . Ongoing by ensures its preservation, with expectations that the first drop may occur far in the future, potentially spanning generations. As part of broader engagement efforts, the experiment is showcased during university open days and school visits, allowing local students and the public to interact with historical physics apparatus and discuss concepts like and patience in science. The of Physics uses it in programs, such as talks and workshops on everyday materials' surprising behaviors, fostering interest in physics among Welsh schoolchildren and highlighting the university's role in regional . This focus on community involvement distinguishes the Aberystwyth installation, adapting the global pitch drop tradition to promote accessible, hands-on learning in a resource-conscious academic setting.

National Museum of Scotland Experiment

The 's , originating from the Royal Scottish Museum, was established in 1902 to demonstrate the remarkable fluidity of , a substance that appears solid but flows extremely slowly due to its high . Crafted in the museum's workshop, the apparatus consists of —derived from tree sap or oil —placed in a narrow clamped to a stand, allowing observers to witness the gradual coalescence and descent of the material over extended periods. The origin of the specific used remains undocumented, and the setup's narrow design results in an exceptionally slow flow rate, exceeding the typical 10-year drop cycles observed in other installations. This demonstration, cataloged as reference T..36, has been part of the museum's collection since 1903 and is now housed in the gallery on Level 5, emphasizing its role in public within a non-academic environment. As a public exhibit, the experiment prioritizes visitor accessibility and engagement, featuring a transparent casing that enables clear observation of the pitch's behavior without direct interaction. It was moved from storage to permanent display around , coinciding with the first documented drop, which occurred between 4 and 6 June during the relocation process—likely accelerated by the physical disturbance. Although at least one prior drop must have happened since 1902 given the setup's longevity, historical records are sparse, with no precise timeline or predictions maintained for future drops. Interpretive elements, including explanatory plaques, accompany the display to elucidate concepts of and non-Newtonian fluids, drawing connections to 19th-century demonstrations by and portraying pitch as an amorphous "glass" rather than a true solid. The exhibit's unique position in a underscores Scotland's scientific , linking the creation to Edinburgh's legacy of innovation in physics and . Maintenance is overseen by curators, focusing on preservation and stability rather than rigorous scientific or research outcomes, with occasional consultations from academic experts to ensure the apparatus's integrity. Visitors can view the setup during standard hours, often enhanced by audio guides that explain the experiment's principles and its status as potentially the world's oldest pitch drop demonstration, predating similar efforts elsewhere by over a decade. This approach fosters public curiosity about slow-changing natural phenomena, distinguishing it from university-based versions through its emphasis on interpretive storytelling and context.

Legacy and Modern Relevance

Guinness World Record and Public Interest

The University of Queensland's pitch drop experiment holds the Guinness World Record for the longest-running laboratory experiment, initiated in 1927 and continuously observed to demonstrate the extreme of pitch. In 2005, custodians John Mainstone and the late Thomas Parnell received the in physics for their oversight of the experiment, which by then had spanned 78 years without a single witnessed drop, underscoring its blend of scientific rigor and ironic patience. Each anticipated drop, occurring roughly every decade, generates renewed global attention, with the ninth drop in April 2014 marking a as the first partially observed in real-time via . Media coverage has amplified the experiment's allure, particularly around key events. The featured extensive reporting on the 2014 Queensland drop, including interviews and timelapse footage, portraying it as a testament to "slow science" amid faster-paced modern research. Similarly, the 2013 capture of a drop from the related experiment—after 69 years—went viral through online videos, drawing millions of views and highlighting the dramatic tension of unobserved phenomena; a subsequent drop fell unobserved in 2024. These milestones, including the unattended 2000 Queensland drop due to a power failure in the monitoring camera, have fueled documentaries and articles that emphasize the experiment's elusive nature. As of November 2025, the tenth drop from the experiment has not yet occurred and is expected sometime this decade. Public fascination stems from its embodiment of , inspiring discussions on the value of long-term in an era of instant results. The irony of Mainstone missing three drops during his 52-year tenure—including the 2000 event—has sparked lighthearted debates on scientific mishaps, often cited as a of timing's unpredictability. During the , the experiment's unchanging pace offered a peculiar comfort, symbolizing and drawing renewed online as a metaphor for enduring through uncertainty.

Educational and Research Applications

The pitch drop experiment has been integrated into physics curricula worldwide to teach concepts in , emphasizing the distinction between solids and highly viscous fluids. Originally designed by Thomas Parnell in 1927 as a of pitch's extreme —estimated at approximately 2.3 × 10^8 Pa·s at room temperature—for undergraduate students at the , it illustrates how materials that appear solid can flow over long timescales. In modern classrooms, it serves as a in non-Newtonian fluids and , often sparking discussions on patience in scientific observation. Hands-on variants adapt the experiment for safer, faster-paced activities using less hazardous fluids to demonstrate principles without the decade-long wait. For instance, educators at developed outreach kits distributed to 37 Irish secondary schools in 2024, where students monitor pitch flow under controlled conditions while experimenting with everyday liquids like , , and to compare flow rates and effects. These adaptations, completed within months rather than years, allow students to record data on thread elongation and drop formation, fostering skills in measurement and time-lapse analysis. Beyond education, the experiment inspires research extensions into pitch's properties and broader applications. Post-2000 studies have employed infrared (FT-IR) spectroscopy to analyze pitch's molecular structure, revealing aromatic clusters and functional groups that contribute to its high and thermal stability. Insights from high- studies like the pitch drop inform models of long-term deformation in materials such as used in pavements under load. Computational modeling of the flow, using Poiseuille's law and temperature-dependent equations, has refined predictions of drop intervals, accounting for variations across pitch samples. Modern adaptations leverage technology for broader engagement and comparative analysis. Institutions like the University of Queensland and Trinity College Dublin maintain webcam feeds for remote observation, enabling citizen science participation where volunteers report potential drops to researchers. This collaborative monitoring across installations provides preliminary comparative data on viscosity influenced by environmental factors like ambient temperature. Looking ahead, the experiment approaches its 100-year milestone in 2027, prompting plans for enhanced digital archiving and international to track long-term trends. Future directions include expanding platforms for real-time alerts and simulations to predict flow under varying global conditions, ensuring its relevance in ongoing research.

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