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Xanthate

Xanthates are organosulfur compounds comprising salts or esters of xanthic acids, characterized by the [ROCS₂]⁻ anion where R denotes an alkyl group.^[1]^[2] These reagents exhibit a heteropolar structure with nonpolar hydrocarbon and polar dithiocarbonate moieties, rendering them effective collectors in froth flotation for sulfide mineral separation.^[3] In mineral processing, xanthates adsorb onto valuable sulfide particles such as those of copper, lead, zinc, and nickel, imparting hydrophobicity that facilitates their concentration via air bubbles in aqueous slurries.^[4]^[5] Developed in the early 20th century, they remain the predominant collectors for base metal sulfides due to their selectivity and efficiency.^[6] Beyond mining, xanthates are essential intermediates in viscose rayon manufacturing, where alkali cellulose reacts with carbon disulfide to form soluble cellulose xanthate, which is subsequently regenerated into fibers.^[7]^[8] Their instability in acidic environments leads to decomposition into carbon disulfide and other volatiles, posing toxicity risks that necessitate stringent handling and wastewater treatment protocols.^[1]^[2]

History

Discovery and Early Development

Xanthates were first synthesized in 1823 by Danish chemist William Christopher Zeise during his investigations into organosulfur compounds. Zeise prepared these esters of dithiocarbonic acid (xanthic acids) by reacting alcohols with carbon disulfide in the presence of a base, yielding salts such as potassium ethylxanthate.^[9] He named the class "xanthates" from the Greek xanthos, meaning yellow, reflecting the characteristic color of many such compounds.^[4] Zeise's work represented an early empirical exploration of thioester chemistry, building on contemporaneous advances in sulfur-organic reactions amid limited understanding of molecular structures.^[9] Throughout the mid-19th century, xanthates received sporadic attention in basic characterization studies, primarily as part of broader organosulfur research. Researchers noted their solubility in water and organic solvents, as well as their tendency to decompose under acidic conditions, releasing carbon disulfide and alcohol—observations that aligned with the compounds' thio-carbonate linkage.^[4] These efforts, though qualitative, established xanthates as distinct from simpler thiols or sulfides, with Zeise's initial formulations serving as a foundational reference for subsequent inorganic and organic chemists probing sulfur's reactivity.^[9] A significant advancement in xanthate chemistry occurred in 1899 when Russian chemist Lev Aleksandrovich Chugaev identified their thermal decomposition pathway. Chugaev observed that heating xanthate esters, particularly methyl esters derived from secondary alcohols, led to elimination of xanthic acid and formation of olefins, a process later termed the Chugaev reaction or elimination.^[10] This discovery arose from his studies on the optical properties and stereochemistry of xanthates, revealing a stereospecific syn-elimination mechanism without rearrangement, which provided early insights into cyclic transition states in organic decompositions.^[11]

Adoption in Industrial Processes

Xanthates were adopted in froth flotation processes for mineral processing starting in the mid-1920s, marking a pivotal advancement in sulfide ore beneficiation. In 1925, H. Keller introduced water-soluble xanthates as collectors into flotation circuits, replacing less effective oil-based reagents and enabling selective recovery of metals like copper, lead, and zinc from complex ores.^[12] This innovation facilitated the transition from laboratory-scale experiments to large industrial operations, with xanthates' strong affinity for sulfide minerals driving recovery yields upward; for example, copper sulfide flotation efficiencies improved to over 85-90% in early implementations, compared to 50-70% with prior methods, due to enhanced froth stability and mineral attachment.^[13]^[4] By the 1930s, xanthates had become standard in mills processing polymetallic ores, scaling output to millions of tons annually and supporting global metal supply growth amid rising demand.^[14] In the cellulose industry, xanthation's industrial uptake accelerated post-World War II, primarily through the viscose process for rayon fiber production. Developed commercially in the early 1900s but limited by wartime disruptions, the method—dissolving cellulose in alkali to form sodium cellulose xanthate for extrusion and regeneration—expanded rapidly from 1945 onward to meet surging textile needs.^[15] This period saw production yields rise through process optimizations, such as improved xanthate ripening and coagulation controls, achieving fiber conversion efficiencies of 90-95% from cellulose pulp and linking xanthate chemistry to the burgeoning synthetic polymer sector.^[16] Adoption was causally tied to economic recovery, with rayon output in major producers like the U.S. and Europe doubling by the 1950s, as xanthation enabled cost-effective, scalable alternatives to natural fibers.^[17] These parallel adoptions underscored xanthates' role in efficiency gains: in mining, they reduced processing losses by prioritizing hydrophobic mineral attachment, while in viscose manufacture, they streamlined dissolution-regeneration cycles, minimizing waste and boosting throughput from batch to continuous operations. Empirical scaling data from 1920s flotation trials to 1950s rayon plants demonstrated consistent yield uplifts of 20-30% over legacy techniques, driven by xanthates' tunable reactivity under industrial conditions.^[18]^[19]

Chemical Structure and Properties

Molecular Structure

The xanthate anion possesses the general formula ROC(S)S⁻, where R denotes an alkyl group, characterizing it as an O-alkyl dithiocarbonate species.^[1] The core structural motif centers on a carbon atom linked to an oxygen from the alkoxy moiety (RO), a sulfur atom involved in resonance delocalization, and a terminal thiolate sulfur, yielding the connectivity RO–C–S–S with partial double-bond character distributed across the C–S bonds.^[20] Resonance stabilization arises from the contributing forms RO–C(=S)–S⁻ ↔ RO–C(–S⁻)=S, wherein the negative charge on the terminal sulfur conjugates with the thiocarbonyl group, resulting in a planar geometry around the CSC fragment and equivalent partial double-bond lengths for the C–S linkages as determined by electron density distribution.^[21] This delocalization enhances the anion's stability and predisposes it to bidentate coordination through the two sulfur atoms. Crystal structures of alkali metal xanthate salts, including sodium and potassium derivatives, reveal ionic lattices where the planar xanthate anions engage in bidentate chelation with metal cations, often forming polymeric chains or discrete complexes, as observed in crown-ether solvates of lithium through cesium methyl xanthates.^[20] Infrared spectroscopy corroborates the resonance-hybrid structure with a C=S stretching vibration appearing at 1020–1070 cm⁻¹, shifted from typical thioketone values due to the conjugative effects.^[22]

Synthesis and Preparation

The primary laboratory synthesis of sodium alkyl xanthates proceeds via the nucleophilic addition of an alkoxide ion to carbon disulfide, followed by association with the sodium cation. An alcohol (ROH) is deprotonated by sodium hydroxide to form the alkoxide (RO⁻), which attacks the electrophilic central carbon of CS₂, yielding the dithiocarbonate anion RO–C(=S)–S⁻ stoichiometrically in a 1:1:1 molar ratio of alcohol:CS₂:NaOH.^[23] This exothermic reaction is typically conducted at 5–20°C in solvents such as tetrahydrofuran or the alcohol itself to control kinetics and minimize side reactions like trithiocarbonate formation.^[24] For sodium ethyl xanthate specifically, ethanol reacts with CS₂ and aqueous NaOH in a batch process, often yielding 97% under optimized conditions of 10–20°C for 2 hours.^[25] Variations in alkyl chain length are achieved by substituting the alcohol: isopropanol yields sodium isopropyl xanthate, while amyl alcohol produces sodium amyl xanthate, with longer chains generally enhancing stability in non-aqueous media but reducing aqueous solubility due to increased hydrophobicity.^[24] These adaptations maintain the core mechanism while tuning product properties, with reaction times of 0.5–5 hours and molar ratios near 1:1.05:1 (alcohol:CS₂:NaOH) to ensure complete conversion.^[24] In industrial routes, particularly for froth flotation reagents, excess CS₂ functions as both reactant and solvent to facilitate mass and heat transfer, enabling scale-up to reactors like 4000 L vessels.^[26] For sodium isobutyl xanthate, commercial caustic soda reacts with isobutanol and excess CS₂ at approximately 25°C, achieving yields >95% and purity >90%, surpassing traditional kneader methods (91% yield, 84% purity) by reducing diffusion limitations in the product layer.^[26] The apparent activation energy is 15 kJ/mol, supporting ambient-temperature operation for kinetic control.^[26] Purity is evaluated via iodometric titration, in which xanthate quantitatively reduces I₂ to I⁻, allowing precise quantification against standards with molar absorptivities such as 17,750 L/mol·cm at 301 nm.^[27] Empirical yields from laboratory procedures consistently range 96–99% based on alcohol consumption, verified post-distillation of solvents.^[24] Integrity is further confirmed by acid-induced decomposition, liberating CS₂ gas as a diagnostic test for undecomposed xanthate.^[27]

Physical and Spectroscopic Properties

Xanthate salts, such as sodium ethylxanthate, appear as pale yellow amorphous powders with a disagreeable odor attributable to trace carbon disulfide impurities.^[28] These compounds exhibit high water solubility, exemplified by sodium ethylxanthate at 450 g/L at 10°C, and are also soluble in polar solvents like ethanol while showing low solubility in nonpolar hydrocarbons due to their ionic character.^[28] Density for sodium ethylxanthate measures 1.263 g/cm³.^[28] Alkali metal xanthates possess melting points in the range of 182–256°C and decompose upon heating without reaching a boiling point, with decomposition accelerated above approximately 200°C.^[28] ^[29] Vapor pressures remain low at ambient temperatures, though handling requires precautions against volatile decomposition byproducts.^[29] Ultraviolet-visible spectra of xanthates display characteristic absorption maxima near 227 nm and 300 nm, arising from n–σ* transitions associated with the C–S and thiocarbonyl functionalities.^[30] Infrared spectra reveal C–H stretching bands at 2800–3300 cm⁻¹, C–O–C asymmetric and symmetric stretches at approximately 1200 cm⁻¹ and 1110–1140 cm⁻¹, respectively, and C=S stretching vibrations in the 1020–1070 cm⁻¹ region.^[22] ^[31] Nuclear magnetic resonance data for ethylxanthate ions include ¹H signals for the alkyl protons and ¹³C shifts diagnostic of the thiocarbonate carbon around 200–220 ppm.^[32]

Chemical Reactivity

Acid-Base Behavior

Xanthic acids, represented as ROC(=S)SH where R is an alkyl group, function as weak acids due to the dissociable proton on the thiol group, with pKa values generally ranging from 1.4 to 2.2.^[33]^[34] This acidity arises from the stabilization of the conjugate base [ROC(=S)S]^- by resonance involving the sulfur atoms and the alkoxy substituent.^[28] Specific examples include ethylxanthic acid with a pKa of approximately 1.6 and butylxanthic acid with a pKa of 2.23, reflecting minor variations attributable to the inductive effects of the alkyl chain length.^[28]^[34] The protonation equilibrium ROC(=S)S^- + H^+ ⇌ ROC(=S)SH is reversible under acidic conditions, but the protonated form predominates only at low pH values below 2-3. The protonated xanthic acid decomposes rapidly in aqueous media via hydrolysis, yielding the alcohol ROH and carbon disulfide CS_2, with the process often described as unimolecular elimination facilitated by the weak O-C bond.^[35] Kinetic studies indicate first-order rate constants for such decompositions, for instance, on the order of 10^{-4} to 10^{-3} h^{-1} for various alkyl xanthates at neutral to mildly acidic pH and 25°C, though rates accelerate significantly below pH 7 due to increased protonation.^[36]^[37] In neutral water, xanthate salts exhibit greater stability as the low concentration of the acid form limits hydrolysis, with maximum half-lives observed around pH 7-8.^[37] In buffered systems, such as those encountered in mineral processing pulps, pH control via alkaline buffers (typically maintaining pH 9-11) minimizes protonation and thereby enhances xanthate persistence, reducing decomposition rates compared to unbuffered or acidic environments.^[37]^[38] Deviations toward neutrality or slight acidity, even in buffered media, can still promote hydrolysis, underscoring the sensitivity of the acid-base equilibrium to local pH fluctuations.^[38]

Bond Cleavage Reactions

Xanthate esters undergo thermal cleavage of the C-O bond in the Chugaev elimination, a syn-elimination reaction that converts secondary or tertiary alcohols into olefins via pyrolysis at temperatures around 200–300 °C. The mechanism proceeds through a six-membered cyclic transition state where the thiono sulfur abstracts a β-hydrogen, resulting in the extrusion of the alcohol oxygen as part of the dithiocarbonate fragment, yielding the alkene, carbonyl sulfide (COS), and a thiol. This Ei-type process favors cis stereochemistry, as confirmed by deuterium isotopic labeling experiments demonstrating kinetic isotope effects consistent with intramolecular syn abstraction of the β-hydrogen. Empirical studies report yields of 60–90% for simple alkyl xanthates, with side products including trace amounts of alkenes from competing E2 pathways or unchanged starting material due to incomplete decomposition.^[39]^[40] Under oxidative conditions, such as exposure to peroxides or electrochemical oxidation, the C-O bond in xanthates can fragment to generate alkoxy radicals or carbocations, though these pathways are less selective than thermal elimination and often lead to complex mixtures including alcohols and sulfides. Mechanistic investigations using isotopic tracers reveal preferential cleavage at the C-O linkage over C-S in oxygenated media, with oxygen-18 labeling showing migration to byproduct carbonates. Yields vary, with controlled peroxide oxidations achieving 40–70% conversion to olefinic products alongside CS2 and sulfate byproducts from over-oxidation.^[41] Reductive cleavage in the Barton-McCombie deoxygenation targets the C-O bond of xanthate-derived alcohols, employing tributyltin hydride (Bu3SnH) and azoisobutyronitrile (AIBN) initiator to generate alkyl radicals for ultimate hydrogen atom transfer. The mechanism initiates with homolysis of the xanthate C-S bond to form an alkoxy radical intermediate, followed by rapid β-scission of the C-O bond, expelling the dithiocarbonate radical and yielding a carbon-centered radical that abstracts hydrogen from Bu3SnH. Radical trapping experiments and ESR spectroscopy support this fragmentation sequence, with side products limited to stannylated byproducts (5–10%) and recovered xanthate (under 20% in optimized conditions). Reported yields exceed 80% for unhindered secondary xanthates, dropping to 50–70% for tertiary due to competing radical recombination.^[42]^[43] C-S bond scission in xanthates occurs reductively under non-radical conditions, such as heating with di-lauroyl peroxide in 2-propanol, cleaving secondary xanthates to thiols and olefins with equimolar peroxide addition to minimize polymerization. This pathway contrasts with C-O cleavage by preserving the alkoxy fragment initially, though isotopic sulfur-34 studies indicate reversible S-S coupling as a minor side reaction, yielding 70–85% isolated products from alkyl O-ethyl xanthates.^[44]

Interactions with Metals and Electrophiles

Xanthate anions, ROCS₂⁻, coordinate to transition metals primarily through their sulfur atoms, exhibiting monodentate, bidentate chelating, or bridging modes that form four-membered chelate rings in many complexes.^[45] This chelation is evident in complexes with metals such as cadmium(II) and mercury(II), where geometric isomers and varying coordination geometries have been characterized computationally and experimentally.^[46] In the context of froth flotation, xanthates adsorb onto metal sulfide surfaces like those of copper and zinc sulfides via chemisorption, forming surface metal-xanthate species that enhance hydrophobicity; for instance, adsorption of heptyl xanthate on zinc sulfide follows a calculated isotherm, indicating strong affinity driven by dative bonding.^[47] Empirical studies demonstrate selective adsorption kinetics, with heptyl xanthate adsorbing more rapidly on lead sulfide than on zinc sulfide surfaces, as measured by polarized infrared spectroscopy.^[31] On copper-activated zinc oxide, xanthate uptake adheres to a pseudo-first-order kinetic model, with activation enhancing binding through Cu(II)-xanthate intermediates that promote electron transfer and surface complexation.^[48] Binding strengths vary by metal; for example, xanthate coordination to Cu(I) in chalcocite forms stable cuprous xanthate precipitates, contributing to collector efficiency, though quantitative stability constants (log β typically 4-6 for bidentate modes in analogous dithiolates) are inferred from electrochemical data rather than direct solution measurements.^[49] As nucleophiles, xanthate ions react with electrophiles like alkyl halides via SN2 displacement at sulfur, producing unsymmetrical disulfides (ROCSSR') that serve as precursors in organic synthesis; this pathway avoids odorous thiols and proceeds under mild conditions with potassium xanthates.^[50] The reaction's utility extends to reductive sulfuration, where xanthates facilitate thioether formation from halides without direct thiol involvement.^[51] Electrochemical oxidation of xanthates to dixanthogen (ROCSSCOR) occurs at anodic potentials, activating collectors in flotation by generating hydrophobic species; for ethyl xanthate, this process initiates above the mixed potential (approximately -0.1 to 0.2 V vs. SHE, pH-dependent), with adsorption on sulfides like pyrite enhanced under controlled Eh conditions that favor chemisorbed xanthate over physical attachment.^[52]^[53] Pulp potentials optimizing Cu-Zn sulfide flotation align with xanthate oxidation thresholds, minimizing over-oxidation to sulfate.^[54]

Synthetic Applications

Organic Transformations

Xanthates function as versatile precursors for carbon-centered radicals in addition reactions, enabling the formation of new carbon-carbon bonds through intermolecular or intramolecular processes. In these transformations, a peroxide initiator generates a thiocarbonyl radical from the xanthate, which fragments to afford an alkyl radical that adds to an alkene acceptor; the resulting adduct radical then regenerates the xanthate moiety via fragmentation, allowing chain propagation with high fidelity. This methodology, developed extensively by Zard, accommodates unactivated alkenes and tolerates a range of functional groups, though electron-deficient alkenes exhibit reduced efficiency due to unfavorable radical stabilization. Yields for such additions typically range from 60-90%, with intramolecular variants achieving cyclizations to five- or six-membered rings in over 70% yield for many substrates.^[55]^[56] A prominent application is the Barton-McCombie deoxygenation, wherein secondary or primary alcohols are derivatized to xanthate esters (often in 90-95% yield using NaH, CS₂, and alkyl iodide) and then subjected to tributyltin hydride with AIBN, yielding the deoxygenated hydrocarbon via radical fragmentation and hydrogen abstraction. This sequence proceeds with effective retention of configuration at the reacting center for many chiral alcohols, attributed to rapid hydrogen transfer minimizing radical rearrangement, and is particularly selective for hindered secondary alcohols over primaries. Reported yields for the deoxygenation step average 70-90% across diverse substrates, including carbohydrates and steroids, though tertiary alcohols show poor conversion due to steric hindrance in xanthate formation. Scope limitations include sensitivity to competing reductions in polyhydroxylated systems without protection.^[57]^[58] Xanthates also underpin reversible addition-fragmentation chain transfer (RAFT) mechanisms, where the thiocarbonylthio group mediates degenerative exchange between growing radicals and the dormant xanthate, enabling precise control over radical additions in chain extension. This process excels with electron-rich monomers like vinyl acetate, achieving low polydispersity indices (<1.2) and quantitative chain-end fidelity, though styrene polymerization requires optimized xanthate structures to mitigate poor transfer constants. The underlying addition-fragmentation equilibrates radical concentrations, facilitating carbon skeleton assembly via repeated monomer incorporation without altering small-molecule scope.^[59]^[60]

Polymer Chemistry

Xanthates function as thiocarbonylthio chain transfer agents (CTAs) in reversible deactivation radical polymerization (RDRP), particularly within the macromolecular design via interchange of xanthates (MADIX) process, a variant of reversible addition-fragmentation chain transfer (RAFT) polymerization.^[59] This approach enables the synthesis of polymers with controlled molecular weights and low dispersities (typically polydispersity index, PDI, values below 1.5), achieved through efficient chain transfer that maintains living character for sequential monomer additions.^[60] Developed in the late 1990s by researchers at Rhodia, MADIX extended RAFT principles to xanthate derivatives, leveraging their commercial availability from mining applications to provide cost-effective control over radical polymerizations.^[59] The mechanism relies on degenerative chain transfer, where the xanthate group (R-S-C(S)-OR') undergoes rapid exchange with propagating radicals via a reversible homolytic cleavage, rather than the addition-fragmentation cycle dominant in dithioester-based RAFT for more activated monomers.^[61] This exchange equilibrates chain lengths, suppressing termination and enabling predictable growth, with transfer constants (C_tr) often in the range of 10-100 for suitable monomers, as determined from kinetic studies.^[62] Gel permeation chromatography (GPC) analyses confirm linear increases in number-average molecular weight (M_n) with monomer conversion, alongside narrow, monomodal distributions that shift predictably, indicating minimal side reactions like irreversible termination.^[63] Post-2000 advancements expanded xanthate efficacy beyond traditional less-activated monomers (e.g., vinyl acetate, N-vinylpyrrolidone) to acrylics and styrenes via optimized substituents on the xanthate, enhancing addition rates and reducing retardation effects observed in early systems.^[61] For instance, O-ethyl xanthates exhibit moderate C_tr values (around 20-50) for acrylates and styrenes, allowing PDI values as low as 1.2-1.4 in bulk or solution polymerizations at 60-80°C.^[62] This control facilitates block copolymer synthesis, where xanthate-terminated macro-CTAs initiate subsequent blocks in one-pot processes, yielding well-defined architectures like poly(vinyl acetate)-b-polystyrene with retained end-group fidelity verified by NMR and MALDI-TOF. Such precision stems from the thiocarbonyl's stability, preserving ~80-90% end-group integrity even at high conversions (>70%).^[64]

Industrial Applications

Froth Flotation in Mining

Xanthates function as anionic collectors in froth flotation processes for recovering sulfide minerals from ores, primarily through chemisorption onto mineral surfaces such as galena (PbS) and sphalerite (ZnS). This adsorption forms stable metal-xanthate complexes or polymeric dixanthogen layers, which expose non-polar hydrocarbon chains outward, rendering the mineral particles hydrophobic.^[65]^[66] The hydrophobized surfaces promote selective attachment to air bubbles generated in the flotation cell, enabling mineral-laden bubbles to ascend through the pulp and concentrate in the froth phase for skimming, while untreated gangue minerals remain submerged due to their hydrophilic nature. Xanthates demonstrate inherent selectivity for sulfides over non-sulfide gangue, owing to weaker adsorption on oxide or silicate phases under typical alkaline conditions (pH 9-11).^[67]^[68] Selectivity and flotation efficiency vary with the alkyl chain length of the xanthate; shorter chains like ethyl provide moderate collecting power, while longer chains such as in amyl xanthate (C5) yield stronger adsorption and hydrophobicity, favoring recovery of coarser particles (>100 μm) by enhancing bubble-particle adhesion stability.^[69]^[70] Empirical studies on copper-zinc sulfide ores report xanthate-driven recoveries of 80-95% for valuable minerals like chalcopyrite (CuFeS2) and sphalerite, with grades exceeding 20-30% in concentrates, contrasted by <5% recovery of siliceous or carbonate gangue under optimized dosages (10-50 g/t).^[71]^[72]^[73]

Cellulose Derivatization

In the viscose process for producing regenerated cellulose products, purified cellulose, typically from wood pulp or cotton linters, is steeped in 17-20% aqueous sodium hydroxide to form alkali cellulose, which swells and partially dissolves the polymer chains. This alkali cellulose is then treated with carbon disulfide (CS₂) vapor or liquid at around 25-35°C, leading to the formation of sodium cellulose xanthate through nucleophilic attack by the deprotonated hydroxyl groups on the cellulose backbone. The reaction yields a partially substituted xanthate derivative, with a degree of substitution (DS) typically ranging from 0.4 to 0.6 xanthate groups per anhydroglucose unit, rendering it soluble in dilute NaOH (about 5-8%) to produce the viscous orange-brown dope known as viscose, suitable for extrusion into fibers or films.^[74]^[75]^[76] The xanthation step is controlled to achieve optimal solubility and viscosity; excessive CS₂ usage increases DS but can lead to instability, while insufficient substitution results in incomplete dissolution. The resulting viscose solution, with cellulose content of 7-10% and containing residual CS₂ and byproducts like sodium trithiocarbonate, is ripened for 4-5 days to mature the polymer for spinning. This process, discovered by Charles Frederick Cross and Edward John Bevan in 1891, enabled the first commercial production of continuous viscose rayon filaments by 1905.^[77]^[7] Upon extrusion through spinnerets or slits into a coagulation bath of 10-15% sulfuric acid with 20-30% sodium sulfate and zinc sulfate additives at 40-50°C, the sodium cellulose xanthate undergoes rapid decomposition: the xanthate groups protonate to xanthic acid, which decomposes with loss of CS₂ and hydrogen sulfide, regenerating pure cellulose that crystallizes predominantly as the cellulose II polymorph. This acid-induced regeneration solidifies the extruded material into oriented filaments for textile rayon or continuous sheets for cellophane wrapping film, with the cellulose II structure exhibiting altered hydrogen bonding compared to native cellulose I, influencing properties like lower density (1.54 g/cm³ vs. 1.59 g/cm³) and enhanced solubility in certain solvents.^[16]^[78]^[16]

Safety, Health, and Toxicology

Handling Hazards

Xanthates exhibit thermal instability, undergoing exothermic decomposition that can lead to self-heating and spontaneous combustion, particularly in storage. This process is accelerated by exposure to moisture, heat, or acids, releasing flammable carbon disulfide vapors. Incidents of spontaneous combustion have been documented, including boxes of xanthate igniting in confined storage areas due to decomposition buildup.^[79]^[80] Dry forms of xanthates pose flammability risks from vapors and dust. Xanthate dusts are highly ignitable with low ignition temperatures, potentially forming explosive mixtures in air when dispersed finely and exposed to ignition sources. Vapors from decomposition are flammable and can create explosive atmospheres in enclosed spaces, as seen in cases where accidental mixing with reducing agents like sodium metabisulfite produced ignitable gases.^[81]^[82]^[79] Safe handling requires storage in cool, dry conditions away from ignition sources and moisture to mitigate decomposition and fire risks. Adequate ventilation is essential to disperse potentially explosive dust and vapors, while using inert atmospheres such as nitrogen or argon during handling and storage prevents oxidation and self-heating. Non-sparking tools, dust control measures, and separation from incompatibles like acids or oxidizers are recommended based on manufacturer guidelines and incident analyses.^[83]^[84]^[79]

Human Health Effects

Xanthates are primarily irritants upon direct contact, causing redness, rash, and potential blistering on skin, severe conjunctivitis and corneal damage in eyes, and inflammation of the respiratory tract when inhaled as dust or mist.^[3] These effects stem from their alkaline nature and partial decomposition to carbon disulfide (CS₂), a volatile irritant released in moist environments or upon hydrolysis.^[79] Inhalation of xanthate vapors or aerosols can exacerbate respiratory irritation, with symptoms including coughing and throat discomfort at occupational exposure levels.^[14] Systemic toxicity arises mainly from CS₂ liberation, which is neurotoxic via chronic low-level exposure, inducing peripheral neuropathy characterized by sensory loss, motor weakness, and reduced nerve conduction velocity. Electrophysiological studies detect subclinical neuropathy at air concentrations of 10-40 ppm CS₂, with symptomatic cases emerging at 20-60 ppm over months to years of repeated exposure.^[85] Dose-response data from viscose rayon workers show neuropathy prevalence increasing with cumulative exposure, where 8-hour time-weighted averages above 30 ppm correlate with overt clinical signs like tremor and ataxia.^[86] Acute oral toxicity in rodents yields LD50 values of approximately 0.7-1.7 g/kg body weight, depending on the xanthate alkyl chain; for instance, sodium ethyl xanthate has an LD50 of 730 mg/kg in mice and potassium ethyl xanthate around 1.7 g/kg in rats, with effects including gastrointestinal distress and central nervous system depression at higher doses.^[3]^[87] No evidence supports carcinogenicity, as xanthates are not classified as such by the International Agency for Research on Cancer (IARC) or equivalent bodies.^[88] Occupational exposure limits for xanthates are set at 1-2 mg/m³ as 8-hour time-weighted averages to mitigate irritation and CS₂-related risks, with stricter controls recommended in mining contexts where decomposition accelerates.^[89]^[90] Limited human studies emphasize engineering controls and personal protective equipment to maintain exposures below these thresholds, preventing dose-dependent neurotoxic outcomes.^[91]

Environmental Aspects

Fate and Degradation in Ecosystems

Xanthates undergo rapid hydrolytic decomposition in aqueous environments, particularly under acidic conditions, with primary products including carbon disulfide (CS₂), the corresponding alcohol (e.g., ethanol from ethyl xanthate), carbonate ions, and trithiocarbonate.^[28] For sodium ethyl xanthate, the hydrolysis half-life is approximately 260 hours at pH 7 and 25°C, extending beyond 500 hours at pH 8–11, though rates accelerate with higher temperatures, metal ion presence, or lower pH.^[28] In neutral to alkaline waters typical of many ecosystems, degradation proceeds via initial formation of xanthic acid followed by dissociation, yielding a first-order kinetic profile with half-lives generally spanning 2–8 days depending on alkyl chain length and conditions.^[92] Oxidative processes in aerated waters further degrade intermediates like dixanthogen, leading to mineralization products such as CO₂ and sulfate ions through sulfur oxidation pathways.^[92] Photolysis, driven by UV exposure, enhances breakdown rates in surface waters, with laboratory simulations reporting decomposition constants on the order of minutes to hours under direct irradiation, though natural sunlight attenuates this in deeper or turbid systems.^[93] Microbial degradation, mediated by aquatic bacteria, follows first-order kinetics and achieves substantial removal, such as 81.8% of xanthate within 8 days in simulated conditions.^[94] In soils, xanthates exhibit low persistence due to adsorption onto mineral surfaces (e.g., oxides) followed by hydrolytic and oxidative degradation, with ubiquitous soil oxidants like MnO₂ accelerating breakdown via surface-catalyzed reactions.^[95] Unlike persistent organic pollutants, xanthates' inherent instability limits long-term accumulation, with environmental half-lives typically aligning with aqueous kinetics under moist conditions.^[92]

Ecological Impacts and Empirical Studies

Laboratory studies demonstrate acute toxicity of xanthates to aquatic organisms at concentrations typically ranging from 0.1 to 100 mg/L. For instance, 96-hour LC50 values for fish species such as Pimephales promelas (fathead minnow) fall between 0.32 and 5.6 mg/L, while sodium ethyl xanthate exhibits LC50 values of 29–37 mg/L for certain fish and EC50 values of 0.35 mg/L for Daphnia magna (24 hours). Algal species like Pseudokirchneriella subcapitata show EC50 values around 0.5 mg/L, indicating sensitivity in primary producers.^[14]^[96]^[97] In mining contexts, exposure realism tempers these lab findings, as xanthate concentrations in tailing slurries range from 0.2 to 1.2 mg/L before further dilution in receiving waters, often falling below acute lethal thresholds for less sensitive species post-discharge. Empirical bioassays conducted in natural river water yielded LC50 values comparable to those in controlled well water (e.g., 31–47 mg/L for P. promelas), suggesting minimal modulation by environmental matrices, yet rapid dilution in large aquatic systems reduces peak exposures. Xanthates degrade via hydrolysis and oxidation with a half-life of approximately 260 hours at neutral pH, persisting only a few days in nature and producing byproducts like carbon disulfide, though post-treatment effluents frequently register below documented LC50 levels for monitored sites.^[96]^[97] Field and degradation studies indicate limited long-term ecological persistence, with no significant bioaccumulation expected due to the ionic nature of xanthates, contrasting with concerns over heavy metal complexation that could indirectly enhance metal uptake in some fish. Localized impacts near mining discharges, such as elevated toxicity in undiluted tailings, are mitigated by natural attenuation processes, including biodegradation and dilution, as observed in stability tests where lower environmental concentrations (e.g., 10 mg/L) showed substantial degradation over 96 hours. While decomposition products pose secondary risks, empirical evidence from aquatic toxicity assays underscores that real-world risks are often lower than undiluted lab projections, enabling containment through engineered and natural dispersal.^[96]^[14]^[97]

Regulatory Frameworks and Mitigation

Xanthates, such as sodium ethyl xanthate and potassium amyl xanthate, are registered under the European Union's REACH regulation, classifying them as substances requiring risk assessment due to their potential toxicity to aquatic organisms and persistence in wastewater.^[98] ^[34] In the United States, these compounds are listed on the TSCA inventory, mandating reporting and control measures for manufacturing, import, and processing to address environmental and health hazards.^[99] ^[87] Enforceable discharge limits for xanthate residuals in mining effluents are jurisdiction-specific, with thresholds as low as 1 mg/L imposed in certain regions to prevent ecological harm, often monitored over 8-10 hour periods before release into watercourses.^[100] These standards drive the adoption of mitigation protocols, prioritizing source reduction through operational controls alongside end-of-pipe treatments. Key mitigation techniques include oxidative degradation using hydrogen peroxide (H₂O₂), which breaks down xanthate anions via advanced oxidation processes, and adsorption onto activated carbon, both capable of achieving substantial removal rates from process wastewater.^[5] ^[101] Dosage optimization in froth flotation circuits represents a primary engineering control, where empirical monitoring prevents overdosing—typically maintaining collector inputs at levels like 50 g/t for specific ores—to limit residual xanthate carryover into tailings and reduce treatment burdens.^[102] ^[103] Such practices, informed by site-specific flotation data, align with global standards emphasizing minimal environmental release without compromising mineral recovery.^[104]

Economic and Strategic Importance

Global Production and Market Dynamics

Global production of xanthates stands at approximately 150,000 metric tons annually in 2024, with forecasts indicating growth to 400,000 tons by 2034, driven by expanding mining applications.^[105] China dominates supply chains, leading in both production capacity and exports—accounting for over 2,200 shipments in recent trade data—owing to its vast chemical infrastructure in provinces like Shandong and Jiangsu, alongside robust domestic mineral extraction needs.^[106]^[107] India follows as a key producer, supported by its growing mining output and cost-competitive manufacturing, while Asia-Pacific as a region holds over 40% of global market share.^[108] This concentration reflects causal linkages to regional resource abundance and lower production costs, though it exposes global supply to geopolitical and regulatory risks in these hubs. The xanthate market was valued at USD 558 million in 2024 and is projected to reach USD 741 million by 2030, expanding at a CAGR of about 4.9%, fueled primarily by demand in copper and gold mining where xanthates serve as essential collectors in froth flotation to recover metals from increasingly low-grade ores.^[109]^[110] Rising global metal consumption—tied to electrification, infrastructure, and electronics—sustains this trajectory despite environmental scrutiny over xanthate degradation products, as alternatives remain less economically viable for sulfide ore processing.^[111] Xanthate pricing exhibits volatility linked to carbon disulfide (CS₂) feedstock costs, which constitute a major input; spot prices for xanthates surged 10% in Q1 2024 amid CS₂ supply shortages exacerbated by raw material constraints.^[105]^[108] Declining ore grades further amplify demand fluctuations, requiring higher reagent volumes per ton of concentrate and thus heightening price sensitivity to supply disruptions in the CS₂ chain, predominantly derived from sulfur and natural gas.^[112] Trade data underscores this, with export volumes correlating to mining cycles in copper- and gold-rich regions.^[106]

Role in Resource Extraction

Xanthates function as selective collectors in the froth flotation process, a cornerstone of sulfide ore beneficiation in metal extraction. They chemisorb onto the surfaces of sulfide minerals such as chalcopyrite (CuFeS₂), sphalerite (ZnS), and galena (PbS), imparting hydrophobicity that enables attachment to air bubbles and separation from hydrophilic gangue. This mechanism underpins the recovery of base and precious metals from complex, low-grade ores, where physical separation alone yields insufficient concentrates. In industrial applications, xanthates like sodium ethyl xanthate (NaEX) and potassium amyl xanthate (PAX) are dosed at 50-200 g per ton of ore, facilitating metallurgical recoveries typically exceeding 80% for copper sulfides under optimized conditions.^[104]^[113] The efficiency gains from xanthate-based flotation contrast with pre-20th-century methods like gravity concentration or amalgamation, which often limited recoveries to 50-70% for disseminated sulfides, necessitating higher ore volumes for equivalent metal output. Modern flotation circuits, reliant on xanthates, process ores with grades as low as 0.5% Cu, expanding viable reserves and supporting global supply chains for infrastructure metals (e.g., copper for wiring) and technology enablers (e.g., zinc for galvanizing, nickel for batteries). For instance, in chalcopyrite flotation, xanthate supplementation has demonstrated grade enhancements of at least 15% alongside sustained high recovery, underscoring their role in maximizing extractable value per mined ton.^[114]^[115] Economically, xanthates' low unit cost—approximately $1.50-3.00 per kg in bulk—combined with minimal reagent consumption, yields processing expenses far below those of alternative collectors like dithiophosphates or thionocarbamates, which can exceed $5-10 per kg. This affordability reduces the energy and capital intensity per ton of recovered metal, as higher selectivity minimizes tailings volume and downstream refining demands. By enabling precise targeting of thiophilic sulfides, xanthates counteract inefficiencies in bulk processing, ensuring that resource extraction aligns with causal demands for metals in electrification and construction, where supply bottlenecks could otherwise inflate costs and delay deployment.^[116]^[117]

Alternatives and Innovations

Substitute Collectors

Dithiophosphates (DTP), such as sodium diisobutyl dithiophosphate, serve as common alternative collectors to xanthates in sulfide mineral froth flotation, particularly for enhancing selectivity against gangue minerals like pyrite and sphalerite.^[118]^[119] Empirical adsorption studies on chalcopyrite demonstrate that DTP exhibits higher selectivity than xanthates due to the lower electronegativity of phosphorus in its functional group, which reduces non-specific binding to iron sulfides.^[120] However, flotation recovery metrics reveal trade-offs, with DTP typically yielding lower overall collectivity for target sulfides; for instance, in mixed collector systems for copper sulfides, xanthates achieve higher recovery rates (up to 90% in optimized conditions) compared to DTP alone, which prioritizes grade over mass pull.^[121]^[122] Mercaptobenzothiazole (MBT), often combined with dithiocarbamates (DTC), functions as another substitute collector for desulfurization and sulfide separation, adsorbing via its thione group to mineral surfaces.^[123] In pyrite flotation tests, DTC-MBT mixtures achieved recoveries of 66.6-69.9% under alkaline conditions, lagging behind xanthates' approximately 75% efficiency, with notably slower kinetics attributed to weaker hydrophobic induction.^[123] Froth stability represents a key limitation for both DTP and MBT relative to xanthates; while xanthates inherently promote persistent, mineral-laden froths suitable for coarse particle recovery, DTP requires synergistic frother additions to mitigate brittle froth collapse, and MBT hybrids exhibit reduced persistence in high-shear environments, complicating scale-up in industrial circuits.^[124]^[123] Across empirical comparisons for polymetallic sulfide ores, xanthates demonstrate superior versatility and recovery for many systems, such as chalcopyrite and galena, where DTP and MBT's enhanced selectivity fails to compensate for depressed yields (e.g., 10-20% lower in single-collector trials) and elevated reagent dosages, inflating operational costs by 15-30% in some reported cases.^[118]^[121] These alternatives excel in niche applications demanding pyrite rejection but underperform in bulk sulfide flotation, where xanthates' balanced hydrophobization prevails. Emerging biodegradable hybrids, blending DTP or MBT moieties with ester linkages, show promise in lab-scale selectivity but remain unscaled due to inconsistent recovery and stability metrics.^[119]

Recent Developments (2020-2025)

In 2023, a novel photocatalyst designated KL-PIF was synthesized by integrating an organic solar active layer with silicate substrates, achieving efficient degradation of butyl xanthate under photocatalytic conditions, with reported removal efficiencies exceeding 95% in targeted wastewater treatments.^[125] This advance leverages visible-light activation to accelerate xanthate breakdown, minimizing residual toxicity in mining effluents compared to traditional methods. Complementary studies in 2024 demonstrated similar efficacy using AgCl/g-C3N4/Ti-MOFs composites, which degraded butyl xanthate solutions via enhanced charge separation and reactive oxygen species generation under visible light irradiation.^[126] Parallel innovations in collector formulations include the AERO XR series, custom-developed as xanthate replacements for copper sulfide flotation, offering improved safety, handling, and selectivity against pyrite while maintaining comparable recovery yields in empirical tests at copper operations.^[127] These collectors, such as AERO 3739, reduce volatility and decomposition risks associated with xanthates, enabling neat dosing and extended shelf life without compromising metallurgical performance in chalcopyrite-bearing ores.^[128] Biodegradation-focused research progressed with microbial immobilization techniques, such as Pseudomonas sp. on biochar, yielding up to 81.8% xanthate removal over eight days in simulated mine water, following first-order kinetics and highlighting potential for integrated wastewater remediation.^[129]^[94]

Structural Analogs

Dithiocarbamates possess the general formula R₂NC(S)S⁻, featuring a nitrogen atom in place of the oxygen substituent found in xanthates (ROCS₂⁻), thereby maintaining a comparable dithioester framework while altering the heteroatom linkage.^[130] This substitution influences electronic properties, with dithiocarbamates demonstrating enhanced stability in alkaline environments relative to xanthates, which undergo rapid hydrolysis to yield carbon disulfide (CS₂) under similar conditions.^[131]^[132] Trithiocarbonates, represented as RSC(S)S⁻ or related variants with an additional sulfur atom replacing the oxygen, exhibit structural resemblance to xanthates through their shared trithiocarbonate core, differing primarily in the substitution at the terminal position. These compounds display varying hydrolytic behavior, often synthesized alongside xanthates in processes involving carbon disulfide and thiols, but with distinct reactivity profiles due to the sulfur-for-oxygen exchange.^[133] Dithiophosphates, with the formula (RO)₂P(S)S⁻, serve as phosphorus-based analogs to xanthates by substituting the central carbon atom with phosphorus while retaining the dithio and alkoxy functionalities, resulting in a phosphodithioate motif.^[134] This structural modification confers greater chemical stability, as evidenced by di-isobutyl dithiophosphinates resisting decomposition more effectively than xanthates in aqueous media.^[38]

Functional Derivatives

O-aryl xanthates, where the oxygen-bound group is an aryl moiety rather than alkyl, exhibit distinct reactivity profiles compared to alkyl analogs, often leveraging enhanced stability in thermal processes. These derivatives have been employed as stabilizers for polymeric materials, such as polyethylene, by suppressing thermo-oxidative destruction and extending the induction period of oxidation, as demonstrated in studies on aroylethyl(ethyl)xanthates.^[135] In radical polymerization techniques like reversible addition-fragmentation chain transfer (RAFT), O-aryl xanthates mitigate side reactions through the formation of highly energetic aryl radicals, which resist premature termination or elimination pathways observed in O-alkyl variants.^[136] This structural modification influences decomposition kinetics, with metal salts of O-aryl xanthates showing reduced stability relative to alkyl counterparts, yet enabling selective reactivity in synthetic routes to thioethers or heterocycles.^[137] Metal xanthate complexes represent another class of functional derivatives, where the xanthate ligands coordinate to transition metals, altering electronic and steric properties for targeted applications in materials synthesis. These complexes serve as single-source precursors in chemical vapor deposition (CVD) for metal sulfide thin films and nanoparticles, decomposing cleanly to yield phases like CdS, NiS, or Sb2S3 with tunable porosity and morphology.^[138] ^[139] For instance, pyridine-adducted nickel(II) xanthates facilitate aerosol-assisted CVD of nickel sulfide, while sterically hindered variants control nanoparticle size in CdS formation.^[140] The choice of alkyl chain length or adduct influences volatility and decomposition temperature, optimizing precursor efficiency over multi-component systems. Coordination geometry in metal xanthate complexes diverges markedly from that in simple ionic salts, such as alkali metal xanthates, which exist as discrete [ROCS2]- anions without metal-ligand bonding beyond electrostatics. In complexes, xanthate ligands adopt monodentate, anisobidentate, or bridging modes, leading to polymeric or dimeric structures with geometries like distorted square-planar in Ni(II) or tetrahedral in Cd(II) centers.^[141] ^[142] Bridging occurs via asymmetric S-C-S linkages, where each sulfur coordinates to different metals, contrasting the non-coordinating nature of simple salts and enabling unique magnetic or optical properties in the resulting materials. This geometric versatility underpins their utility as precursors, as ligand asymmetry affects decomposition pathways and phase purity compared to the hydrolytic instability of uncoordinated salts.^[45]

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[PDF] Safety Data Sheet Sodium Isobutyl Xanthate (SIBX) - Redox
Sep 23, 2025 · Hazard Statements. H252. Self-heating in large quantities; may catch fire. H302 + H312. Harmful if swallowed or in contact with skin.
[90]
Polyneuropathy induced by carbon disulfide in viscose rayon workers
Aug 7, 2025 · The fixed point air concentrations of CS2 were 150-300 ppm in the cutting areas and 15 to 100 ppm in the spinning areas. The estimated eight ...
[91]
[PDF] review on environmental risk assessment of mining chemicals used ...
Xanthates degrade rather quickly and results of residue analyses have gen- erally shown half-lives (T½) of xanthates in water of 2 to 8 days depending on the ...<|separator|>
[92]
UV185+254 nm photolysis of typical thiol collectors: decomposition ...
May 22, 2019 · The decomposition rate constants decreased in the order SDD > PEX > IET ≫ DDA, and the DDA was the refractory collector. After 120 min of UV185+ ...
[93]
Treatment Technology and Research Progress of Residual Xanthate ...
The results showed that the removal of xanthate reached 81.8% after 8 days of biodegradation, and the treatment process was consistent with the first order ...
[94]
Degradation of amyl xanthate by manganese dioxide - IWA Publishing
Sep 26, 2017 · The objective of this study was to systematically explore the oxidative removal of AX with MnO2 by investigating removal efficiency and ...
[95]
Xanthates in freshwater and marine water - Water Quality Australia
Environmental fate The half-life of SEX at pH 7 (25°C) is around 260 hours and doubles at above pH 8. Xanthates are expected to last a few days in the natural ...
[96]
[PDF] Toxicity of Xanthates to Freshwater Fish and Invertebrates.
Forty-eight hour. LC50's do not appear to be significantly different between the bioassays run in well water and bioassays run in river water. The degradation ...Missing: ecotoxicity aquatic organisms
[97]
Sodium isobutyl xanthate | C5H9NaOS2 | CID 23683691 - PubChem
Sodium isobutyl xanthate ... REACH Registered Substance. Status: Active Update: 12-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15855.
[98]
Sodium xanthate SDS, 140-90-9 Safety Data Sheets - ECHEMI
SECTION 9: Physical and chemical properties and safety characteristics. Physical state. Light yellow powder. Colour. no data available. Odour. no data available.
[99]
Removal of Ethyl Xanthate Anions from Contaminated Aqueous ...
... discharge limit is 1 ppm for a period of 8–10 h. Xanthates can ... Catalytic ozonation of mineral processing wastewater containing Butyl Xanthate.
[100]
Removal of xanthate in flotation wastewater by ultrasound and ...
For dealing with the xanthate simulated wastewater, which concentration is 120 mg·L-1, on the condition of concentration of H2O2 is 20 mg·L-1, concentration of ...<|separator|>
[101]
[PDF] Minimizing Xanthate Impacts on Watercourses in Cold Climate
xanthate degradation. Alternatively, xanthate may also be oxidised by UV light. Oxidation processes aim at degrading the xanthates fully into harmless ...Missing: bioaccumulation | Show results with:bioaccumulation
[102]
Optimization of the Froth Flotation Process for the Enrichment of Cu ...
Aug 6, 2025 · The adsorption of collectors on sulfide minerals occurs through two main mechanisms: chemical adsorption, where chemisorbed metal xanthate forms ...
[103]
Establishing an optimized flotation scheme for a complex Base ...
Sep 15, 2024 · The primary objective of this study was the creation of an optimized flotation procedure using a xanthate-based reagent scheme for a complex, ...Missing: practices | Show results with:practices
[104]
Xanthate Market Size 2023, Forecast By 2034 - Reports and Data
Historical data indicates that the average spot price for xanthates rose by 10% in Q1 2024 due to shortages in key feedstocks like carbon disulfide.Missing: CS2 | Show results with:CS2
[105]
Xanthate Exports from World - Volza.com
Rating 4.7 (1,423) China leads the world in Xanthate exports with 2,213 shipments, followed by India with 275 shipments , and Uzbekistan taking the third spot with 232 shipments .
[106]
Xanthates Market Size ($732.6 Million) 2030
Use of xanthates is declining , especially in the EU, where chemical restrictions, REACH compliance, and water discharge norms are strict. Sweden, Germany ...<|separator|>
[107]
Xanthate Market Size, Growth, Share and Forecast Report 2032
Asia-Pacific dominated the market with 42% share in 2024, driven by strong mining activities in China, India, and Australia. North America held 28% share, ...
[108]
Xanthates - Market Research
Global Xanthates Market to Reach US$741.3 Million by 2030. The global market for Xanthates estimated at US$558.0 Million in the year 2024, is expected to ...<|control11|><|separator|>
[109]
Xanthate Market Size, Share, Trends, Growth Report – 2032
The xanthate market size was valued at USD 563.2 million in 2023 and is estimated to grow at a CAGR of over 5.1% from 2024 to 2032 driven by increasing ...Missing: timeline | Show results with:timeline
[110]
https://www.gminsights.com/industry-analysis/xanthate-market
[111]
Xanthates Market Market Disruption: Competitor Insights and Trends ...
Rating 4.8 (1,980) Jun 17, 2025 · The global xanthates market, valued at approximately $800 million in 2025, is experiencing robust growth, projected to maintain a Compound Annual Growth Rate ( ...Missing: CS2 feedstock
[112]
[PDF] 1 Froth Flotation – Fundamental Principles - Chemical Engineering
Xanthates are highly selective collectors for sulfide minerals, as they chemically react with the sulfide surfaces and do not have any affinity for the common ...
[113]
Innovative study on chalcopyrite flotation efficiency with xanthate ...
Jan 2, 2025 · The purpose of flotation reagents is to impart hydrophobicity to the mineral particles, by preferentially adsorbing at the solid–liquid ...
[114]
The Application of Xanthate in Froth Flotation Process - Cnfree reagent
Apr 11, 2019 · Xanthate is the most commonly used collectors for flotation of sulfide minerals. Low-grade xanthate is generally suitable for the collection of easily ...
[115]
Factory Mining Agent Flotation Reagent Sodium Ethyl Xanthate
Rating 5.0 · Review by MIC_BUYERFactory Mining Agent Flotation Reagent Sodium Ethyl Xanthate ; Transport Package. Iron Drum or Wooden Case ; Specification. 160-170kg/iron drum or 850kg/wooden ...Missing: per | Show results with:per
[116]
Potassium Amyl Xanthate (PAX) - Alpha Grinding Media
Aug 19, 2025 · Water Solubility, Soluble ; pH (1% aqueous solution), 9 to 12 ; Typical Dosage, 100–400 g per ton of mineral ; Packaging, 110 kg metal drum / 25 kg ...
[117]
Adsorption of dithiophosphate and dithiophosphinate on chalcopyrite
Aug 6, 2025 · The latters are less efficient than xanthates but have higher selectivity against iron sulphides and sphalerite, minerals that appear ...
[118]
Alternative flotation collectors for the environmental desulfurization ...
Dithiophosphate (DTP), dithiocarbamate (DTC), and mercaptobenzothiazole (MBT) compounds are some alternative sulfide collectors to xanthates. These collectors ...
[119]
Adsorption behaviour of xanthate and dithiophosphinate from their ...
Aug 6, 2025 · Dithiophosphates are more selective collectors than xanthate, due to the lower electronegativity of the P atom present in the functional group ( ...
[120]
Comparison of single and mixed reagent systems for flotation of ...
Xanthates (R-O-CSSMe) have been shown to have weaker selectivity and better collectivity for sulfide minerals than dithiophosphate [21][22][23] [24] . The ...
[121]
The formulation and use of mixed collectors in sulphide flotation
Mixtures of ethyl xanthate and ethyl dithiophosphate showed smaller improvements in recovery. However, isobutyl xanthate, as a single collector, was ...
[122]
Alternatives to xanthate collectors for the desulphurization of ores ...
In contrast, the performance of DTC-MBT was lower than for xanthate i.e., 69.9% with NaOH and 66.6% with CaO.
[123]
[PDF] The synergistic interaction between dithiophosphate and frothers at ...
Dithiophosphate (DTP) synergistically increases flotation recovery in the presence of frothers, though DTP does not adsorb onto the mineral surface.
[124]
Butyl xanthate photocatalytic degradation using a highly effective ...
A novel photocatalyst, KL-PIF, is synthesized using an organic solar active layer that attaches to silicate substrates to efficiently remove butyl xanthate.
[125]
AgCl/g-C3N4/Ti-MOFs photocatalytic composite for visible light ...
Jun 1, 2024 · In this study, a novel composite material composed of gC 3 N 4 /AgCl/Ti-MOFs was prepared, and the catalytic degradation effect of butyl xanthate solution
[126]
[PDF] AERO® XR Series Collectors: Safer, Custom-Formulated ... - SAIMM
The AERO 3739 xanthate replacement, as with other xanthate replacements, offers benefits such as improved handling, neat dosing, and enhanced SHE properties.Missing: Clariant | Show results with:Clariant
[127]
AERO® Promoters For Diverse Mineralogies - Syensqo
Xanthate replacement solution that is an effective copper collector with selectivity against pyrite. ... AERO® NR Series for Copper-Molybdenum Separations.Missing: Clariant | Show results with:Clariant
[128]
Adsorption and biodegradation of butyl xanthate in mine water by ...
Jan 1, 2025 · This study aimed to evaluate the effectiveness of Pseudomonas sp. immobilized on yak dung biochar (Ps.@YDBC600) for BX degradation.
[129]
The Versatility in the Applications of Dithiocarbamates - PMC - NIH
Dithiocarbamate ligands have the ability to form stable complexes with transition metals, and this chelating ability has been utilized in numerous applications.
[130]
Dithiocarbamates: Properties, Methodological Approaches and ...
Alkyl dithiocarbamates (MDTCs and DMDTCs) are stable in an alkaline medium; the DMDCs are assumed to undergo acid-catalysed hydrolysis as the primary ...
[131]
Chemical stability of xanthates, dithiophosphinates and hydroxamic ...
Jan 1, 2021 · Xanthates are unstable, decomposing into toxic carbon disulfide. Dithiophosphinates and hydroxamic acids are more stable and may be ...
[132]
Selective one-pot synthesis of trithiocarbonates, xanthates, and ...
Feb 16, 2006 · Selective one-pot synthesis of trithiocarbonates, xanthates, and dithiocarbamates for use in RAFT/MADIX living radical polymerizations. Org ...Missing: analogs | Show results with:analogs
[133]
Adsorption of Alkyl Xanthate and Dithiophosphate on a Cleavage ...
XANTHATES and dithiophosphate are the two principal collecting reagents in the flotation for sulphide minerals. They have structural formulæ respectively.
[134]
Synthesis and study of aroylethyl(ethyl)-xanthates as stabilizers of ...
Sep 14, 2021 · It was revealed that aroylethyl(ethyl)xanthates had a stabilizing effect due to the suppression of thermo-oxidative destruction of polyethylene.
[135]
Thiocarbonyl chemistry in polymer science - RSC Publishing
May 4, 2022 · An O-aryl xanthate RAFT agent was shown to prevent this side reaction because the associated aryl sp2-based radical is even more energetic than ...
[136]
(PDF) Synthesis of O-arylxanthates esters and derivatives
Aug 10, 2025 · Metal salts of O-arylxanthates are very unstable as compared to the alkyl analogs. Metal O-aryl dithiocarbonates (xanthates) were reported for ...
[137]
Metal Sulfide Thin Films with Tunable Nanoporosity for ...
Jan 4, 2022 · Metal xanthates are widely used as single-source precursors for the formation of metal ... metal xanthate complexes discussed earlier. On ...
[138]
Pyridine Adducts of Nickel(II) Xanthates as Single-Source ...
Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide. Click to copy article ...<|separator|>
[139]
Investigating the Effect of Steric Hindrance within CdS Single ... - NIH
In this report, we have investigated the effect of increasing steric hindrance of the coordinating ligands of four xanthate-based CdS single-source precursors ...
[140]
Xanthate - an overview | ScienceDirect Topics
The first polymeric xanthate complex cadmium n-butyl xanthate, [Cd(S2COC4H9)2], was reported by Rietveld and Maslen in 1965 [91]. In this complex the central Cd ...Missing: history | Show results with:history
[141]
Insights into the thermal decomposition and conversion mechanism ...
Jun 11, 2025 · For metal xanthates, the design of the xanthate ligand allows to tune the properties of the metal sulfide obtained by their thermal conversion.Missing: tests | Show results with:tests