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Disodium pyrophosphate

Disodium pyrophosphate, also known as sodium acid pyrophosphate (SAPP), is an inorganic compound with the chemical formula Na₂H₂P₂O₇ and a molecular weight of 221.94 g/mol.^[1] It appears as a white, odorless crystalline powder or granules that is highly soluble in water, with a pH of approximately 4 in a 1% solution, and decomposes at around 220°C.^[2] This sodium salt of pyrophosphoric acid is produced industrially by neutralizing phosphoric acid with sodium hydroxide or carbonate followed by thermal dehydration at about 250°C.^[2] In the food industry, disodium pyrophosphate serves multiple functions as a generally recognized as safe (GRAS) additive, including acting as a leavening agent in baked goods like cakes and pancakes by releasing carbon dioxide upon reaction with baking soda.^[1] It also functions as an emulsifier in processed cheeses to prevent separation and as a sequestrant in canned tuna or potatoes to inhibit discoloration and chelate metal ions that could affect quality.^[2] Beyond food, it finds applications in industrial processes such as electroplating, metal cleaning, and as a dispersant in oil well drilling muds, as well as in cosmetics as a chelating and buffering agent.^[1] Disodium pyrophosphate is regulated as GRAS by the U.S. Food and Drug Administration (FDA) for use in human food and animal feeds under good manufacturing practices, with specific limits in standardized foods such as up to 3% in cheese products and 0.5% in canned tuna.^[2] The U.S. Environmental Protection Agency (EPA) exempts it from pesticide residue tolerances when used as an inert ingredient, and it is approved internationally by bodies like Codex Alimentarius (INS 450(i)) and the European Union (E 450(i)), with a recommended phosphorus intake limit of 70 mg/kg body weight per day.^[2] Safety assessments indicate low toxicity, with an oral LD50 of 2650 mg/kg in mice, though it can cause mild irritation to skin, eyes, and respiratory tract upon direct exposure to dust.^[1]

Chemical identity and properties

Nomenclature and identifiers

Disodium pyrophosphate is systematically named disodium dihydrogen diphosphate according to IUPAC nomenclature.^[1] It is commonly referred to as sodium acid pyrophosphate (SAPP) or disodium diphosphate in industrial and food contexts.^[1]^[3] Key chemical identifiers for disodium pyrophosphate include the following:

Identifier	Value
CAS Number	7758-16-9^[1]
EC Number	231-835-0
E Number (food additive)	E450(i)^[3]

The compound has the molecular formula Na₂H₂P₂O₇ and a molar mass of 221.94 g/mol.^[1] It typically appears as a white, odorless crystalline powder.^[1]

Molecular structure and formula

Disodium pyrophosphate has the molecular formula \ce{Na2H2P2O7}, comprising two sodium cations (\ce{Na+}) and the dihydrogen pyrophosphate anion (\ce{H2P2O7^2-}).^[1] The core structural feature of the anion is a P-O-P bridge connecting two \ce{PO3} groups, where each phosphorus atom adopts a tetrahedral coordination geometry with four surrounding oxygen atoms.^[1] This bridging oxygen in the P-O-P linkage is distinct from the terminal oxygens, contributing to the overall diphosphate architecture. The two acidic hydrogen atoms are attached to terminal oxygen atoms, rendering the anion as a partially protonated form of the fully deprotonated pyrophosphate ion \ce{P2O7^4-}. A simplified representation of the structure highlights the pyrophosphate ion as [\ce{O3P-O-PO3}]^{4-}, protonated to \ce{[H2O3P-O-PO3H2]^2-} with sodium counterions.^[1] In Lewis terms, each phosphorus exhibits five valence electrons forming four sigma bonds to oxygen, with the bridge oxygen shared between the two phosphorus centers, and double-bond character often implied in terminal P=O bonds for resonance stability. This configuration arises from the dehydration of two orthophosphate units (\ce{HPO4^2-}), where condensation eliminates water to forge the P-O-P bond.

Physical and chemical properties

Disodium pyrophosphate appears as a white, odorless crystalline powder. Its density is 1.86 g/cm³.^[2] The compound does not have a defined melting point, instead decomposing at approximately 220 °C.^[2] It exhibits moderate solubility in water, with approximately 11.5 g dissolving in 100 mL at 20 °C, and is insoluble in ethanol.^[4] A 0.1 M aqueous solution has a pH of approximately 4.3, reflecting its mildly acidic nature.^[5] Chemically, disodium pyrophosphate functions as a chelating agent, forming stable complexes with divalent metal ions such as Ca²⁺ and Mg²⁺, which helps sequester these ions in solution.^[6] It possesses buffering capacity primarily in acidic pH ranges due to the pKa values of its phosphate groups (around 0.9, 2.1, 6.7, and 9.4).^[7] The compound undergoes slow hydrolysis in water to form orthophosphate ions, with the rate increasing with temperature and decreasing pH.^[8] Thermally, it decomposes above 220 °C to yield sodium metaphosphate.^[9] Disodium pyrophosphate is non-flammable and non-explosive under standard conditions.^[10]

Synthesis and production

Laboratory preparation

Disodium pyrophosphate, also known as sodium acid pyrophosphate, is commonly prepared in laboratory settings through the thermal dehydration of monosodium dihydrogen phosphate (NaH₂PO₄). This method involves heating the dihydrogen phosphate to temperatures between 200 and 250 °C, facilitating the condensation reaction represented by the equation:

$2 \mathrm{NaH_2PO_4} \rightarrow \mathrm{Na_2H_2P_2O_7} + \mathrm{H_2O}

The process requires careful control of heating to prevent over-dehydration, which may result in the formation of higher polyphosphates such as sodium trimetaphosphate.^[11]^[12] Under optimized laboratory conditions, this reaction typically yields 80-90% of the desired product, depending on the purity of the starting material and precise temperature regulation. Following synthesis, the crude product is purified by recrystallization from hot water or ethanol. The mixture is dissolved in the minimum amount of boiling solvent, filtered to remove impurities, and then cooled slowly to promote crystal formation, yielding colorless, odorless crystals suitable for analytical or experimental use.^[1]

Industrial manufacturing

Disodium pyrophosphate, also known as sodium acid pyrophosphate (SAPP), is primarily produced on an industrial scale through a two-step process involving partial neutralization followed by thermal dehydration. In the first step, food-grade phosphoric acid, typically derived from the thermal process to ensure high purity and minimize impurities like heavy metals, is partially neutralized with sodium hydroxide or sodium carbonate (soda ash) to form monosodium phosphate (NaH₂PO₄). This reaction is carried out in aqueous solution under controlled conditions to achieve the desired pH, often around 4.5, yielding a solution or slurry of monosodium phosphate.^[13] The monosodium phosphate is then dehydrated in the second step via calcination, where two molecules condense to form disodium pyrophosphate: 2 NaH₂PO₄ → Na₂H₂P₂O₇ + H₂O. This thermal treatment occurs in a rotary kiln or furnace at approximately 250°C, with residence times adjusted to promote dehydration while limiting side reactions. The process is energy-intensive, requiring precise temperature control to avoid excessive formation of byproducts such as sodium trimetaphosphate. Spray-drying may precede calcination to produce a dry feed for efficient heating.^[13]^[14]^[15] Feedstocks for this production are sourced from wet-process phosphoric acid (purified for food-grade applications) and soda ash, which is obtained from natural trona deposits or synthetic processes. Global demand for disodium pyrophosphate was approximately 120,000 metric tons as of 2022, driven primarily by demand in the food and industrial sectors, with major manufacturing hubs in the United States, China, and Europe.^[16] Process variations enhance efficiency and scalability, including continuous furnace heating systems for steady-state operation and fluidized bed reactors, which improve heat transfer and uniformity by suspending the material in a gas stream. These methods reduce energy consumption compared to batch processes and allow for higher throughput in large-scale facilities.^[17]^[15] Quality control is critical, particularly for food-grade material, which must meet purity standards exceeding 98% disodium pyrophosphate content, with limits on impurities such as heavy metals (e.g., arsenic <3 ppm) and insoluble matter. Analytical techniques like ion chromatography and titration ensure compliance, while process monitoring minimizes byproducts through optimized calcination conditions.^[18]

Applications

Food and beverage uses

Disodium pyrophosphate, also known as sodium acid pyrophosphate (SAPP), serves multiple functional roles in food and beverage processing, primarily as a leavening agent, sequestrant, emulsifier, and acidity regulator. It is recognized as generally safe (GRAS) by the U.S. Food and Drug Administration for use in various edible products at specified levels. In the food industry, it constitutes a significant portion of phosphate additives employed to enhance product quality, texture, and shelf life without altering nutritional profiles substantially.^[2] As a leavening agent, disodium pyrophosphate is commonly incorporated into double-acting baking powders, where it reacts with sodium bicarbonate (NaHCO₃) to produce carbon dioxide gas. This reaction occurs in two stages: an initial release at room temperature during mixing and a slower release at higher baking temperatures, contributing to uniform rise and tender crumb in products like cakes, muffins, and refrigerated doughs. The key reaction is:

\mathrm{Na_2H_2P_2O_7 + NaHCO_3 \rightarrow Na_3HP_2O_7 + CO_2 + H_2O}

^[19] In meat and seafood processing, disodium pyrophosphate acts as a color and texture stabilizer by chelating metal ions that cause oxidation and discoloration. It is added to canned tuna at levels up to 0.5% by weight to inhibit struvite crystal formation, maintaining product clarity and appearance.^[20] Similarly, in processed ham and other cured meats, it is used at a maximum of 0.5% in the finished product to enhance moisture retention and prevent darkening. For frozen potato products, such as hash browns and French fries, it functions as a sequestrant at typical levels around 0.1-0.5%, binding iron and other metals to preserve natural color during storage and cooking.^[2]^[2] Disodium pyrophosphate also serves as an emulsifier in dairy-based foods, particularly processed cheeses, where it is limited to 3% of the finished weight to promote smooth melting and prevent fat separation by dispersing casein proteins. It is similarly applied in instant puddings to stabilize emulsions and achieve creamy textures. As an acidity regulator, it adjusts pH in beverages and other formulations, ensuring consistent flavor and stability without excessive sourness.^[21]^[2]^[22]

Industrial and other applications

Disodium pyrophosphate serves as a key ingredient in detergents and cleaners, functioning as a chelating agent that softens water by binding calcium and magnesium ions, thereby enhancing cleaning efficiency and preventing scale buildup.^[23] It also acts as a corrosion inhibitor in formulations for dairy equipment and metal surfaces, protecting against degradation in hard water environments.^[1] These properties make it valuable at low concentrations in industrial cleaning solutions, where it helps maintain equipment integrity without excessive foaming.^[24] In chemical processing, disodium pyrophosphate stabilizes hydrogen peroxide solutions by chelating metal ions that catalyze decomposition, extending shelf life in bleaching and disinfection applications.^[25] It is similarly employed in electroplating baths as a buffering agent to control pH and prevent metal ion precipitation, ensuring uniform deposition during metal finishing processes.^[26] Beyond these roles, disodium pyrophosphate finds use as a tanning auxiliary in the leather industry, where it removes iron stains from hides and aids in the sulfitation of tanning extracts to improve preservation and flexibility.^[27] In petroleum extraction, it disperses clays in drilling muds, reducing viscosity and gel strength to facilitate smoother operations in oil wells. Additionally, it controls tartar formation in toothpastes by inhibiting calcium phosphate crystallization on dental surfaces, contributing to oral hygiene products.^[28] In pet food manufacturing, it enhances palatability, particularly in feline formulations, by improving texture and flavor perception without altering nutritional profiles.^[29]

Safety, health, and regulation

Toxicity and health effects

Disodium pyrophosphate demonstrates low acute toxicity via oral exposure, with a reported LD50 of 2,650 mg/kg in mice.^[1] Dermal absorption is minimal, as evidenced by an LD50 greater than 2,000 mg/kg in rabbits, though the compound can act as an irritant to skin and eyes in its powder form, potentially causing redness or discomfort upon direct contact. At high doses, primary effects are limited to gastrointestinal irritation, including nausea, vomiting, or diarrhea, due to its phosphate content and solubility in aqueous environments.^[1] Chronic exposure primarily occurs through dietary sources, where exposure to phosphorus from phosphate additives, including disodium pyrophosphate, contributes to overall phosphate consumption. EFSA's 2019 re-evaluation estimated mean exposure to phosphorus from phosphate additives at 71–537 mg P/day for adults, with high chronic exposure (95th percentile) up to 1,071 mg P/day, generally below the group acceptable daily intake (ADI) of 40 mg/kg body weight (expressed as phosphorus) for healthy individuals. In vulnerable groups, such as those with chronic kidney disease, excessive phosphate intake from additives like disodium pyrophosphate may contribute to phosphate overload, potentially leading to hyperphosphatemia, which can exacerbate cardiovascular risks and mineral imbalances.^[30]^[31] With no evidence of genotoxicity or carcinogenicity in available studies, the compound shows low concern for tumor promotion.^[30] Animal studies indicate no reproductive or developmental toxicity associated with disodium pyrophosphate at doses up to the group ADI for phosphates of 40 mg/kg body weight expressed as phosphorus.^[30] Human data from comprehensive food additive reviews, including those by the European Food Safety Authority (EFSA) and the U.S. Food and Drug Administration (FDA), affirm its safety when used at approved levels in food, with no observed adverse effects in general populations under typical exposure scenarios.^[30]

Regulatory status and environmental impact

Disodium pyrophosphate, known as E450(i) in the European Union, is authorized as a food additive with maximum permitted levels varying by food category, typically ranging from 500 to 20,000 mg/kg depending on the product.^[32] In the EU, it is permitted in baked goods such as bread and fine bakery wares at levels up to 2,500 mg/kg expressed as phosphorus, either alone or in combination with other phosphates, to function as an acidity regulator, raising agent, and sequestrant.^[33] The Codex Alimentarius General Standard for Food Additives permits its use in baked goods up to 5,000 mg/kg in certain bakery wares, with provisions for up to 9,300 mg/kg in specific formulations under good manufacturing practice.^[34] In the United States, disodium pyrophosphate holds Generally Recognized as Safe (GRAS) status under 21 CFR 182.1087, allowing its use in food in accordance with good manufacturing practice without specified numerical limits.^[35] Globally, the Joint FAO/WHO Expert Committee on Food Additives (JECFA) has established a maximum tolerable daily intake (MTDI) of 70 mg/kg body weight for phosphorus from all sources, including pyrophosphates like disodium pyrophosphate, based on evaluations of phosphate safety.^[36] Environmentally, disodium pyrophosphate undergoes rapid hydrolysis in aqueous environments to orthophosphate, rendering it biodegradable but contributing to phosphorus loading in wastewater.^[37] This phosphorus release can exacerbate eutrophication in receiving waters by promoting algal blooms when discharged from food processing or municipal effluents.^[38] However, it exhibits low bioaccumulation potential, as neither the compound nor its dissociated ions are expected to concentrate in organisms due to their ionic nature and solubility.^[39] Regulatory restrictions on disodium pyrophosphate stem from broader phosphate controls to mitigate environmental impacts. In the EU, phosphate bans in detergents, including phosphorus compounds like pyrophosphates, were implemented progressively, with a limit of 0.3 g phosphorus per standard dosage in dishwasher detergents and 0.5 g per standard dosage in laundry detergents effective from January 2013 and 2017, respectively, under Regulation (EU) No 259/2012.^[40] This phase-out targets eco-detergents to reduce eutrophication risks, though exemptions apply for industrial uses.^[41] In water treatment applications, its use is monitored to prevent excessive phosphorus discharge, with ongoing assessments by bodies like the European Commission to evaluate cumulative environmental loading.^[42]

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Sodium acid pyrophosphate used as a general purpose food additive in animal drugs, feeds, and related products is generally recognized as safe when used in ...
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Disodium dihydrogen diphosphate, disodium dihydrogen pyrophosphate, acid ... C.A.S. number. 7758-16-9. Chemical formula. Na2H2P2O7. Formula weight. 221.94.
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When it is heated to above 220℃，it can be decomposed and form sodium metaphosphate. In general, it is packed with outer woven bag and inner bag, the net ...
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Not flammable. 6. ACCIDENTAL RELEASE MEASURES. Personal precautions, protective equipment and emergency procedures: Wear protective clothing.
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Heat sodium dihydrogen phosphate (NaH2PO4) to a certain temperature (such as 200 ℃) to dehydrate it and generate disodium dihydrogen pyrophosphate. Collect the ...
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SAPP is manufactured by partially neutralizing food grade phosphoric acid with sodium hydroxide or sodium carbonate to form monosodium phosphate. Dehydration of ...
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Sodium acid pyrophosphate (SAPP) is manufactured with double drying process like other Pyrophosphates due to heating needed at a high temperature. Sodium ...
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(b) Conditions of use. This substance is generally recognized as safe when used in accordance with good manufacturing practice.Missing: Disodium FDA
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DISODIUM DIHYDROGEN DIPHOSPHATE; DISODIUM DIHYDROGEN PYROPHOSPHATE; ACID SODIUM PYROPHOSPHATE. CAS number. 7758-16-9. INS. 450i. Functional Class.Missing: EC | Show results with:EC
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