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Firedamp

Firedamp is a highly flammable of gases, primarily (CH₄) at 90–98% concentration, that occurs naturally in seams and poses severe hazards in underground mining environments. Originating from the coalification process of ancient vegetable matter over millions of years, firedamp is released under as is extracted, diffusing from seams and surrounding strata into workings, where it accumulates in pockets or galleries due to its lighter-than-air density (0.55 relative to air). The gas typically includes 90–98% hydrocarbons (mainly ), 0.2–6% (CO₂), up to 6% , and trace amounts of oxygen, , , , and , making it colorless, odorless, and highly combustible when mixed with air. The primary danger of firedamp lies in its potential within a 4–16% concentration range in air, with 9.5% being the most volatile threshold; ignition from open flames, , or frictional can trigger devastating deflagrations or explosions, often leading to asphyxiation from oxygen (below 6% oxygen levels causing ) and secondary fires that have historically caused thousands of fatalities in mines.

Definition and Composition

Definition

Firedamp is a term historically and specifically used in the context of underground to describe a flammable of gases, primarily consisting of diluted in air, that poses a significant risk when ignited. This gas occurs naturally within seams and surrounding strata during operations, accumulating in pockets or along workings where may be inadequate. Unlike other non-flammable mine gases, firedamp's ignitability makes it a primary in mines, requiring vigilant monitoring and control measures to prevent catastrophic events. Firedamp is distinctly different from other dangerous mine gases such as , which is an oxygen-deficient atmosphere primarily composed of and that causes asphyxiation without flammability, or afterdamp, a toxic blend of gases including and that lingers after an or . These distinctions are critical in protocols, as firedamp's explosive potential stems from its ability to form ignitable concentrations in air, whereas and afterdamp primarily threaten through suffocation or poisoning. The term "firedamp" thus encapsulates the unique peril of combustible gas pockets in extraction environments. In underground , firedamp's relevance is confined to environments where is released during mechanical disruption of seams, emphasizing its role as a geological rather than a generalized atmospheric gas. Effective of firedamp through and detection has been essential to mitigating risks in these specific subterranean settings.

Chemical Composition

Firedamp is predominantly composed of (CH₄), which typically accounts for 93% to 99% of the gas released from seams in mines. This high content distinguishes it as a primarily hydrocarbon-based gas, with the remaining fraction consisting of trace hydrocarbons and inert components. In addition to , firedamp often includes small amounts of other alkanes such as (C₂H₆), (C₃H₈), and (C₄H₁₀), usually at concentrations below 5% combined. Minor quantities of (CO₂), (N₂), oxygen (O₂), and occasionally (H₂) or (He) may also be present, depending on the geological conditions of the formation. These trace elements do not significantly alter the overall flammability driven by . The hazardous nature of firedamp arises when it mixes with air, forming an explosive at methane concentrations of 5% to 15% by volume. Below 5%, the is too lean to ignite, while above 15%, it becomes too rich in and lacks sufficient oxygen for propagation. Unlike oxygen-displacing gases such as (primarily CO₂ and N₂), firedamp's composition preserves adequate oxygen in the air , enabling rapid rather than simple asphyxiation.

History and Etymology

Historical Discovery

The earliest documented observation of firedamp-related hazards in European mines dates to 14 October 1621, when a miner named Richard Backas was fatally burned in a pit in , , as recorded in the register of . This incident marked the first known attribution of an underground explosion to what miners would later term "fire damp," a flammable gas emanating from seams. During the , such events were sporadic but increasingly noted in 's burgeoning , particularly in the northeast, where deeper workings released pockets of the gas, leading to sudden ignitions from open flames used for illumination. Miners initially viewed these outbursts through a lens of superstition, often blaming them on ethereal phenomena like will-o'-the-wisps—ghostly lights believed to lure workers to peril—rather than recognizing the natural emission of from geological processes. By the late 17th and early 18th centuries, scientific inquiry began to demystify firedamp, transitioning from to empirical understanding. In 1675, William Jessop of Broomhall, , published detailed accounts in the Philosophical Transactions of the Royal Society, describing firedamp as a distinct "damp" that ignited with a candle's , producing a sharp crack like gunfire, and recounting multiple explosions at Wingfield's coal pit that injured workers. Jessop classified mine gases, including firedamp, , and poisonous gases such as hydrogen sulphide, noting its lighter-than-air properties and ignition risks from naked lights or friction, based on observations from affected sites. Early 18th-century miners, building on such reports, empirically acknowledged firedamp's dangers by ventilating workings to disperse accumulations, a practical measure that reduced immediate risks without yet identifying its chemical nature. This period saw growing documentation in mining treatises, shifting attributions from supernatural causes to hazardous subterranean vapors, though explosions persisted due to inadequate detection. The pivotal scientific breakthrough came in 1815 through Humphry Davy's experiments, which conclusively identified firedamp as primarily (CH₄) and led to transformative safety innovations. Prompted by a series of deadly explosions, including the 1812 Felling Colliery disaster that killed 92, Davy traveled to Newcastle in August 1815 to collect gas samples from mines like . In laboratory tests at the Royal Institution, he determined 's ignition thresholds—exploding in air mixtures between 5% and 14% concentration—and its lower flammability compared to or . By November 1815, Davy presented findings to the Royal Society, demonstrating that narrow metal tubes or could contain flames without propagating explosions, as the gauze's conductivity dissipated heat rapidly. This culminated in the , tested successfully in mines by January 1816, where an enclosed oil flame behind fine wire mesh allowed safe illumination without igniting surrounding firedamp. Davy's work not only pinpointed as the culprit but also established foundational principles for explosion-proof mining technology, fundamentally advancing the field's safety.

Etymology and Naming

The term "firedamp" originates from the combination of "fire," denoting its highly flammable and properties, and "damp," derived from the damp or ultimately Proto-Germanic dampaz, meaning or , with the mining-specific usage first recorded in the 1670s to describe noxious, ignitable gases in seams. This nomenclature highlights the gas's vaporous nature and capacity for when mixed with air, primarily consisting of . Early mining texts employed "damp" as a broad category for various harmful mine gases, encompassing both toxic and flammable varieties, but by the in English-speaking regions, "firedamp" had evolved into a precise designation for the explosive methane-rich variant, distinguishing it from other "damps" like the suffocating . Regional linguistic adaptations reflect localized encounters with mine gas hazards across . In French-speaking mining areas, particularly in , the term "grisou" emerged around 1706 as a Walloon form of "grégeois," referencing "feu grégeois" () owing to its flammable nature. It became widely used in coal mines to denote the same flammable mixture. In mining contexts, the equivalent was "Schlagwetter," literally "striking weather" or "flash weather," a term capturing the sudden, violent explosions akin to a , which arose from historical incidents of gas ignitions in 18th- and 19th-century collieries. These variations underscore how cultural and experiential factors shaped nomenclature, with each drawing from indigenous languages to convey the peril of underground vaporous explosions.

Physical and Chemical Properties

Physical Properties

Firedamp, consisting mainly of , is a colorless and odorless gas at , rendering it undetectable by senses without specialized equipment. This lack of perceptible characteristics contributes significantly to its hazardous nature in confined mine environments, where it can accumulate unnoticed. Additionally, firedamp is non-toxic at low concentrations, exhibiting no adverse physiological effects on s below levels that pose asphyxiation risks due to oxygen displacement. The density of firedamp is approximately 0.717 kg/m³ at 0°C and 1 atm, which is about 55% that of air (1.293 kg/m³), causing it to rise and accumulate in roof crevices, headings, and other elevated areas of coal mines. This buoyancy-driven behavior influences ventilation strategies and gas monitoring practices, as pockets of firedamp can form in poorly ventilated upper strata despite overall airflow. Firedamp exhibits low in , with a value of about 22 mg/L at 25°C and 1 atm, limiting its in aqueous mine environments. However, in seams, it migrates through the porous matrix primarily via rather than or , facilitating its release during operations. This diffusive transport mechanism underscores the gradual emanation of firedamp from beds, affecting emission prediction models in assessments.

Chemical Properties and Reactivity

Firedamp, consisting mainly of (CH₄), exhibits low chemical reactivity under normal ambient conditions due to the stability of its carbon-hydrogen bonds, remaining inert in the absence of strong oxidizers or high-energy initiators. This inertness stems from methane's high , approximately 439 kJ/mol for the C-H bond, which prevents spontaneous reactions with common atmospheric components like or at . However, in the presence of oxygen, firedamp becomes highly reactive upon ignition, undergoing exothermic that releases significant heat and forms mixtures when concentrations range from 4% to 16% in air. The primary combustion reaction for with oxygen is: \ce{CH4 + 2O2 -> CO2 + 2H2O} This process liberates approximately 890 /mol of energy under standard conditions, primarily as , and requires an external ignition such as an open flame, electrical spark, or frictional exceeding the mixture's ignition threshold. Without such a , the reaction does not initiate, underscoring firedamp's dependence on external energy input for reactivity. The of methane-air mixtures, marking the point of self-sustaining without an external spark, is 537°C (999°F) at . This temperature can vary slightly with mixture composition and confinement, but it establishes a critical threshold for ignition risks in oxygen-containing environments like mine airways.

Occurrence and Detection

Natural Occurrence in Mines

Firedamp, consisting predominantly of , originates during the coalification process, in which buried plant matter undergoes chemical transformation into under elevated temperatures and pressures over geological timescales, simultaneously generating hydrocarbons that become adsorbed onto the 's organic structure. This is then trapped within coalbed reservoirs, where it remains sorbed to the matrix or dissolved in formation , forming a significant portion of coal seam gas. These reservoirs typically occur at burial depths of 300 to 1500 meters, where conditions favor gas retention without excessive escape to the surface. The release of firedamp into mine environments is triggered by mining activities that disturb the seams, such as mechanical cutting, hydraulic fracturing, or longwall extraction, which fracture the and reduce confining pressure, prompting rapid desorption and of the gas. In particularly gassy formations, these disturbances can elevate emission rates to 10-20 cubic meters of per ton of extracted, depending on seam characteristics and extraction intensity. Firedamp is most commonly encountered in bituminous and coal seams, which exhibit higher methane storage capacities due to their increased carbon content and micropore structure compared to lower-rank s. Prominent occurrences are documented in the Appalachian Basin of the , historic coalfields of the , and major production regions of , where these coal types dominate underground mining operations.

Detection Methods

Early detection of firedamp in coal mines relied on rudimentary yet effective biological and mechanical indicators to alert miners to the presence of gas before it reached dangerous concentrations. One such method involved the use of canary birds, which were carried in cages by miners starting in the late 19th century; these birds, more sensitive to low oxygen levels and toxic gases than humans, would stop singing or exhibit distress when accumulated, signaling the need for evacuation. Another pivotal early technique was the flame safety lamp, invented by Sir Humphry Davy in 1815, which enclosed an oil flame in a to prevent ignition of firedamp while allowing visual detection; the flame would develop a distinctive blue "cap" or elongate when was present, indicating concentrations as low as about 1.25%, well below the lower explosive limit of 5%. In contemporary operations, advanced electronic detectors have largely supplanted these historical approaches, providing precise, real-time quantification of levels to enhance . Catalytic sensors, in use since the 1920s and still widely employed, operate by oxidizing on a heated (typically at 400–500°C), generating heat proportional to gas concentration that is measured via a circuit; these sensors are robust for underground environments but require frequent calibration to account for drift and . spectroscopy-based detectors represent a more modern alternative, detecting through its absorption of light at specific wavelengths such as 3.3 μm, enabling non-contact, selective measurement without oxygen dependency or degradation; these systems, including tunable laser variants, offer high sensitivity down to parts per million and are integrated into portable or fixed units. Both types are typically calibrated against known standards (e.g., 2.5% mixtures) every 31 days and programmed to issue audible or visual alarms at 1% by volume, well below the flammable threshold to allow preventive action. Monitoring protocols in coal mines emphasize continuous and periodic surveillance to maintain below statutory limits, typically 1–2% in return airways across jurisdictions like the and . In the U.S., federal regulations (30 CFR 75.342) mandate permanently mounted monitors on mining equipment, positioned to sample air from the roof or face, providing a warning at 1.0% and an automatic power cutoff at 2.0%; portable detectors supplement this with checks every 20 minutes at working faces and return airways. Similar protocols in other regions require continuous sampling in return paths to detect accumulations early, with immediate of personnel and enhanced if levels exceed 1.25–2.0%, ensuring compliance through daily inspections and record-keeping.

Hazards and Risks

Explosion Mechanisms

Firedamp explosions initiate when an ignition source, such as an electric spark, frictional heat, or open flame, encounters a methane-air mixture within its flammable concentration range of approximately 5% to 15% by volume. At these concentrations, the mixture is combustible, with the most severe explosions occurring near the stoichiometric ratio of about 9.5% methane, where the reaction proceeds rapidly as \ce{CH4 + 2O2 -> CO2 + 2H2O}, releasing significant heat and pressure. The ignition energy required is low, as little as 0.3 mJ for sparks, allowing common mine activities like machinery operation to trigger the event. The initial manifests as a , with propagation speeds starting below 10 m/s in quiescent conditions but accelerating due to and expansion. In coal mine galleries, confinement and obstacles such as roof supports or irregular walls generate , causing the front to wrinkle and speed up to over 100 m/s, often transitioning to a if the surpasses the in the mixture (around 300-400 m/s). waves propagate supersonically at 1,000-1,800 m/s, producing shock pressures up to 20 times the initial , which can shatter rock and propagate through interconnected tunnels. Propagation is amplified in narrow, elongated mine workings, where reflected pressure waves from walls and bends intensify the blast, leading to structural collapse and further fuel entrainment. Roadway geometry, such as bifurcations or blockages, enhances flame distortion and overpressure peaks exceeding 0.5 MPa, sustaining the explosion over distances of hundreds of meters. Incomplete combustion during this rapid process generates carbon monoxide (CO) as a byproduct, alongside heat and unburned hydrocarbons, increasing post-explosion toxicity and complicating survivor rescue efforts.

Historical Impact on Mine Safety

Firedamp, primarily gas, played a devastating role in numerous mine disasters throughout the 19th and early 20th centuries, often igniting to cause catastrophic explosions that claimed hundreds of lives in single incidents. One of the most tragic examples was the on March 10, 1906, in northern , where an underground explosion triggered a fire that killed 1,099 miners, making it Europe's deadliest at the time. Similarly, the on October 14, 1913, in , , resulted from the ignition of firedamp by an electrical spark, leading to an explosion that killed 439 miners and a rescuer, marking the worst mining disaster in British history. These events highlighted the explosive potential of firedamp in poorly ventilated, deep seams, where gas accumulation was common. The cumulative impact of firedamp-related incidents was profound, contributing significantly to the high fatality rates in during this era. In the , underground accidents, including those from gas explosions, resulted in over 1,000 deaths annually in the late , with rates reaching approximately 2.75 fatalities per 1,000 miners around amid a of about 351,000. Firedamp and explosions, along with roof and ground falls, accounted for 55% of the 10,891 fatalities in mines during peacetime years between 1900 and 1938, with explosions being a major cause in regions like . Globally, such explosions were responsible for a substantial share of disasters, exacerbating the overall toll estimated at tens of thousands in alone during the industrial expansion. These repeated tragedies spurred critical regulatory reforms to address firedamp hazards. In the , the Coal Mines Act of 1850 was enacted in response to mounting public outcry over deaths, establishing a system of government inspectors to enforce basic safety measures like improved and restrictions on child labor underground, though enforcement remained limited initially with only four inspectors nationwide. Subsequent legislation built on this foundation, but the persistent dangers underscored the need for better detection and prevention. By the early , fatality rates began to decline due to these evolving regulations, alongside technological advancements in lamps and . Underground death rates in mines dropped to about 1.34 per 1,000 miners by , reflecting a expansion to around 770,000 and similar annual losses overall (around 1,000 deaths per year), with firedamp incidents decreasing as inspections and mandatory protocols took hold. This shift marked a gradual improvement in , though firedamp remained a persistent until more comprehensive reforms in the mid-20th century.

Prevention and Mitigation

Ventilation Techniques

Ventilation techniques in coal mines are essential for diluting and removing firedamp, a mixture primarily consisting of , to prevent its accumulation in hazardous concentrations within mine workings. These systems ensure that methane levels remain below the lower explosive limit of 5% by , typically targeting dilution to under 1% in active areas, thereby maintaining safe atmospheric conditions for workers. Natural ventilation relies on pressure differences created by thermal gradients or density variations between surface and underground air to induce airflow. In this method, warmer air in the mine rises and exhausts through upcast shafts, drawing in cooler via downcast openings, which helps carry firedamp upward and out of the workings. Historically employed in early mines, natural ventilation was often augmented by simple controls like trap doors or brattices to direct flow, but it provides limited volume and reliability, making it insufficient for modern gassy operations where consistent dilution is required. Mechanical ventilation systems, predominant in contemporary , use powered fans to generate controlled airflow that actively dilutes and evacuates firedamp. Axial fans, commonly installed at the surface or underground, produce air velocities of 0.5-1 m/s in working areas to sweep away from faces and entries, ensuring concentrations in intake air remain below 1%. These systems deliver minimum quantities such as 3,000 cubic feet per minute (cfm) to each working face and 9,000 cfm to the last open crosscut, effectively reducing inflow from coal seams by mixing it with large volumes of exhausted to the surface. Design principles for effective ventilation emphasize targeted airflow distribution, such as split ventilation, which divides fresh air into separate streams to prioritize high-gas emission zones like working faces. In split systems, overcasts or undercasts separate and return airways, directing at least one dedicated split of air—minimum 9,000 cfm—to mechanized sections, preventing layering and ensuring uniform dilution across the mine. This approach, mandated in U.S. regulations for gassy mines, enhances safety by isolating contaminated air for prompt removal while minimizing recirculation.

Modern Safety Technologies

Gas drainage represents a key modern strategy for managing firedamp risks in mines by proactively extracting from coal seams prior to mining activities. This pre-extraction method involves drilling —such as vertical wells from the surface or in-seam —to apply pressure that draws out , typically achieving removal rates of 70-90% of the in-situ gas content depending on seam permeability and borehole design. By reducing concentrations below thresholds before excavation begins, gas drainage minimizes the influx of firedamp into working areas, complementing efforts and significantly lowering hazards in gassy mines. Intrinsic safety equipment forms another cornerstone of contemporary firedamp safety, designed to prevent ignition sources in atmospheres. These devices, including battery-powered cap lamps and methane monitors, limit electrical energy to levels incapable of sparking, ensuring compliance with international standards like ATEX (for European use) and IECEx (for global certification). For instance, ATEX-certified mining lamps and sensors are engineered for Category equipment, suitable for mines prone to firedamp, where they provide continuous monitoring without risking ignition even under fault conditions. Such explosion-proof tools enable miners to detect levels promptly while operating in hazardous zones, integrating seamlessly with broader safety protocols. Regulatory frameworks enforce these technologies through mandatory standards that prioritize real-time monitoring and rapid response. In the United States, the Mine Safety and Health Administration (MSHA) requires methane monitors on face equipment under 30 CFR §75.342, with operations ceasing and evacuation initiated if concentrations exceed 1.5-2% in working faces or returns to prevent explosive mixtures. Similarly, the European Union's Regulation (EU) 2024/1787 mandates comprehensive monitoring, reporting, and verification of methane emissions in coal mines, including real-time systems for active sites and evacuation protocols at thresholds around 2% to align with ATEX safety directives. These regulations ensure widespread adoption of gas drainage and intrinsic safety measures, fostering a proactive approach to firedamp mitigation across jurisdictions.

References

  1. [1]
  2. [2]
    Drainage and Utilisation of Firedamp - Durham Mining Museum
    Jan 17, 2023 · Origin and composition of firedamp. Most of the firedamp emitted in the workings of a coal mine comes from the seams of coal and carbonaceous ...
  3. [3]
    The Most Dangerous Gases In Mining - Chart Industries
    Nov 9, 2023 · Firedamp is a mining term for a set of explosive gases found in mines. It's mostly made up of methane and methane is often an interchangeable ...Missing: composition | Show results with:composition
  4. [4]
    The life-saving lamp: Humphry Davy's fight against firedamp
    Dec 15, 2022 · Firedamp is a term for flammable gases (commonly methane) found in mines. The gases would leak from coal-bearing rocks and spread to the areas ...Missing: definition composition
  5. [5]
    None
    Below is a merged response that consolidates all the information from the provided summaries into a single, comprehensive overview of mine gases based on the 2024 Underground Mine Foreman’s Study Guide. To maximize detail and clarity, I’ve organized the information into a table in CSV format, followed by a narrative summary and a list of useful URLs. This ensures all details are retained and presented efficiently.
  6. [6]
    [PDF] MSHA - IG7 - Advanced Mine Rescue Training (Coal Mines)
    Afterdamp is toxic to breathe, and it may also be oxygen-deficient. Carbon monoxide is the most poisonous of the gases in afterdamp. Blackdamp. Blackdamp ...
  7. [7]
    Mining Terms | Department of Environmental Protection
    Auxiliary ventilation - Portion of main ventilating current directed to face of dead end entry by means of an auxiliary fan and tubing. ... Fire damp - The ...
  8. [8]
    [PDF] Glossary of Coal Mining Terms (June 2008)
    Jun 24, 2008 · Methane mixtures are called "firedamp." Methane monitor - an electronic detector mounted or a piece of mining equipment that detects and ...
  9. [9]
    Firedamp - an overview | ScienceDirect Topics
    Firedamp is defined as a mixture of gases, primarily methane (93 to 99%), found in coal seams, which can lead to dangerous explosions in mines.
  10. [10]
    [PDF] The Composition of Coalbed Gas - CDC Stacks
    Until about the middle of the 20th century coalbed gas was considered a mixture of methane (firedamp) and carbon dioxide (blackdamp).
  11. [11]
    Mines Rescue Service - Fife Pits
    The earliest recorded accident caused by firedamp is believed to have taken place in a pit in Gateshead. In the register of St Mary's Church, under the date 14 ...
  12. [12]
    27 Jun 1896 - The Perils of the Pit. - Trove
    mining, the miners attributed explosions to super ... that the phenomenon known as will-o'-the-wisp is ... of fire-damp the flame becomes elongated and dull.
  13. [13]
    History of Factory and Mine Hygiene 9780231883672 - dokumen.pub
    T h e r e are special articles on miners and gases in mines by Jessop (Philosophical ... " Philosophical Transactions, X (1675), No. 117. Jones, D. C. Coal Mining ...
  14. [14]
    [PDF] FLAMMABLE GAS DETECTION IN COAL MINES - Envirotech Online
    Its main component is methane, although other hydrocarbons can be present at lower concentrations.Missing: composition | Show results with:composition
  15. [15]
    Sir Humphry Davy and the coal miners of the world - NIH
    Davy quickly ascertained the nature of the problem, and he acquired, for his return to the RI, bulk samples of fire-damp from various sources in the mines. In ...
  16. [16]
  17. [17]
    Fire-damp - Etymology, Origin & Meaning
    If not, probably from Middle Low German damp; ultimately in either case from Proto-Germanic *dampaz (source also of Old High German damph, German Dampf "vapor;" ...Missing: mining | Show results with:mining
  18. [18]
    Damp - Oxford Reference
    In the mining industry, “damp” (from German dampf, steam) means smoke, fumes, or gas. Thus, for instance, firedamp is the methane gas that causes explosions ...
  19. [19]
    Flammable gas detection in coal mines – a historical perspective
    Oct 3, 2018 · Naturally occurring hydrocarbon gases that appear in underground coal mines have historically been given the name “firedamp”, derived from the ...Missing: definition composition
  20. [20]
    FIREDAMP - Translation in German - Bab.la
    Find all translations of firedamp in German like Schlagwetter, Grubengas, Grubengase and many others.
  21. [21]
    Methane | CH4 | CID 297 - PubChem - NIH
    Methane is the principal constituent of natural gas(1,3); natural gas from America is approximately 85% methane(4). Emissions of geothermal steam may release ...
  22. [22]
    Methane: Health and Safety Hazards Fact Sheet - MineARC Systems
    Jan 5, 2021 · Methane occurs naturally in the atmosphere; however, it has not been shown to have adverse effects on human life at low concentrations.
  23. [23]
    Does methane pose significant health and public safety hazards?
    Sep 1, 2015 · There is no evidence that low to moderate levels of exposure to methane in air have any toxic effect on humans, and evidence for such effects ...Missing: non- | Show results with:non-
  24. [24]
    Methane (CH₄): Thermophysical Properties and Phase Diagram
    Methane, CH4 , is a colorless odorless gas. It is also known as marsh gas or methyl hydride. The vapors are lighter than air. Methane is easily ignited.
  25. [25]
    [PDF] J"4l - NM.gov
    Methane, gas weighs 0.000717 gram per cubic centimeter or 0.717 kilgram per cubic meter, i.e. density of methane, gas is equal to 0.717 kg/m3; at. 0°( (32°F ...
  26. [26]
    [PDF] UNDERGROUND FIRE BOSS - Utah Labor Commission
    Methane is a colorless, odorless, flammable gas. It is lighter than air, having a specific gravity of 0.554 and is often found near the mine roof (ceiling ...
  27. [27]
    Experimental Study on Methane Diffusion Characteristics of Different ...
    Sep 21, 2023 · The diffusion coefficient (D) is a key parameter that characterizes the gas transport occurring in coal seams. Typically, D is calculated ...
  28. [28]
    Apparent and True Diffusion Coefficients of Methane in Coal and ...
    The diffusion coefficient of methane in coal is a key parameter for the prediction of coalbed methane production. The apparent diffusion coefficient is ...
  29. [29]
    [PDF] The Role of Methane in Tropospheric Chemistry - DSpace@MIT
    While methane is chemically quite inert to reactions with atmospheric molecular species, it does react with atomic species and molecular radicals.
  30. [30]
    Hydrocarbons - Autoignition Temperatures and Flash Points
    Autoignition temperatures and flash points (°C and °F) of different types of hydrocarbons with varying carbon numbers up to C12.
  31. [31]
    Calorimetry: Heat of Combustion of Methane
    Calorimetry. Enthalpy of Combustion of Methane. The combustion reaction for methane is. CH4 (g) + 2 O2 (g) → CO2 (g) + 2 H2O (l).
  32. [32]
  33. [33]
    [PDF] Autoignition temperature determinations and their ... - IChemE
    Developments in the measurement of autoignition temperature values are reviewed and the differences between various methods noted. For certain applications ...
  34. [34]
    [PDF] Coal Mine Methane Recovery - U.S. Environmental Protection Agency
    Coal mine methane (CMM) is gas released from coal or surrounding rock strata during and after coal mining. As such, it is considered a mining hazard, a ...
  35. [35]
    Coalbed Methane Reservoir - an overview | ScienceDirect Topics
    CBM is a significant resource of unconventional gas in the world. Natural gas, chiefly methane, is trapped in coal seams and micropores of coal and is extracted ...
  36. [36]
    Coal-Bed Methane Enhancement with CO2 Sequestration ...
    Mar 2, 2017 · Normally, coal seams at depths of 300–1500 m are considered to be appropriate for CBM. Coal geometry: Concentrated coal deposits (few, thick ...
  37. [37]
    [PDF] Handbook for Methane Control in Mining - CDC Stacks
    Face ventilation in underground bituminous coal mines. Washington, DC: U.S. Department of the Interior, Bureau of Mines, RI 7223. McNider T, Grygiel E ...
  38. [38]
    [PDF] Feasibility Study for Coal Mine Methane Drainage and Utilization
    This yields a 17.5 m3/mton mined total gas emission rate, which is about the in-situ gas content of the mined coal. At Ha Sha Tu, where longhole drilling ...
  39. [39]
    [PDF] Coal Mine Methane Country Profiles, Chapter 21, Updated March ...
    Aug 22, 2025 · Internationally, the accepted standard for a. “gassy” mine is approximately 10 m3 per tonne. • Mexico's 2015 Biennial Update Report to the ...
  40. [40]
    Assessment of coal mine methane (CMM) and abandoned mine ...
    Assessment of coal mine methane (CMM) and abandoned mine methane (AMM) resource potential of longwall mine panels: example from Northern Appalachian Basin, USA.
  41. [41]
    [PDF] Coalbed Methane (CBM) - North Sea Transition Authority
    (CBM) produced via boreholes from virgin coal seams. Methane trapped in coal and surrounding strata are released as a result of mining, and because this gas ...
  42. [42]
    [PDF] Coal Mine Methane Country Profiles, Chapter 20, Updated March ...
    Mar 3, 2020 · • In 2017, Chinese coal production was 66.0 percent bituminous, 16.7 percent coking,. 11.8 percent anthracite, and 5.5 percent lignite (EIA, ...
  43. [43]
    History in gas detection: Coal Mine Canaries & Flame Safety Lamps
    Apr 15, 2021 · In the early 19th century we have the first recorded gas detector or gas tester. They enlisted a person to wear a wet blanket and carry a wick ...
  44. [44]
    Safety Lamps | Smithsonian Institution
    The flammable gas (firedamp) consisted mainly of methane and was most often found in coal mines. ... mining explosions. In 1813 Clanny revealed his first ...
  45. [45]
    Optical Methods of Methane Detection - PMC - PubMed Central
    Mar 5, 2023 · Catalytic sensors have been used since the 1920s to detect methane in mines and have remained the most popular type of sensor used in mining.
  46. [46]
    Methane Sensing for Coal Mining Applications - Edinburgh Sensors
    In recent years, the traditional shielded lamps have been replaced with Methane detectors based upon Infrared absorption sensors to detect the build-up of Mine ...
  47. [47]
    Guidelines for the Control and Monitoring of Methane Gas on ... - CDC
    Methane is monitored using permanently mounted monitors on machines and portable detectors for periodic checks. Monitors provide warnings at 1.0% and alarms at ...
  48. [48]
    30 CFR 75.323 -- Actions for excessive methane. - eCFR
    (1) When 1.0 percent or more methane is present in a return air split between the last working place on a working section and where that split of air meets ...
  49. [49]
    [PDF] Methane management in underground coal mines
    In some, more than one gas detector exceeded 2.5%. ❖ Only 15 of these were reported to the Inspectorate. ❖ One occurrence lasted 157 minutes. ❖ Methane levels ...
  50. [50]
    [PDF] A review on understanding explosions from methane-air mixture
    When methane build-up in an underground coal mine reaches a certain concentration range, explosion can be initiated by the presence of a small heat source. The ...
  51. [51]
    Characteristics of Methane Explosion and Dynamic Response of ...
    Nov 27, 2023 · The results showed that the flame propagation time is shortest when the ignition position is located at the center of the H-type roadway ...
  52. [52]
    Study on the propagation characteristics of methane-air explosion ...
    Jan 24, 2024 · The results show that coal gangue can cause significant disturbances to the flame front, resulting in a violent acceleration of the explosion flame.
  53. [53]
    [PDF] CHAPTER ONE MINE GASSES
    It is produced from the incomplete combustion or explosion of substances containing carbon such as coal, natural gas or gasoline. Large quantities of CO are.
  54. [54]
    Courrières -- Europe's worst ever mining disaster and its ... - LWW
    Background and Goal of Study: On 3rd March 1906 Courrières colliery in northern France was devastated by a methane explosion. About 1100 miners died -- the ...
  55. [55]
    Remembering Senghenydd, the UK's worst mining disaster - BBC
    Oct 14, 2013 · The explosion, probably caused by the ignition of highly-flammable firedamp (or methane), was made worse by the dry coal dust on the pit ...Missing: 1913 | Show results with:1913
  56. [56]
    Full article: 'Dancing in the halls of the rich'? Fatal mine explosions ...
    Aug 13, 2023 · Coal miners. Deaths per 1,000 employees from all explosions of fire damp or coal dust (excludes pure blasting accidents). Series 3 ...
  57. [57]
    Forgotten fatalities: British military, mining and maritime accidents ...
    In coal mining, during peacetime years between 1900 and 1938, roof or ground falls and firedamp or coal dust explosions accounted for 55% of 10 891 fatalities ...
  58. [58]
    Underground Mine Ventilation - 911Metallurgist
    Oct 26, 2016 · The hazards which are controlled by proper ventilation in underground mines include; low oxygen content, toxic gases, flammable gases, fumes, ...
  59. [59]
    [PDF] LECTURE NOTES ON MINE VENTILATION
    Air flows from a region of high pressure to a region of low pressure. • The difference of pressure may be caused by – Purely natural means: called natural.
  60. [60]
    30 U.S. Code § 863 - Ventilation - Law.Cornell.Edu
    Each mechanized mining section shall be ventilated with a separate split of intake air directed by overcasts, undercasts, or the equivalent, except an extension ...
  61. [61]
    Ventilation and Cooling in Underground Mines
    Mar 13, 2011 · An air velocity of 0.25 m/s is the minimum normally allowed in mining and 0.5 m/s would be required where the wet bulb temperature exceeds 25 °C ...<|separator|>
  62. [62]
    Explosion protection - Phoenix Contact
    Equipment group I includes mining equipment liable to be endangered by firedamp and/or dust. Equipment group II includes all other Ex areas not related to ...
  63. [63]
    Standards - IECEx
    IECEx uses international standards like IEC and ISO for equipment in areas with fire or explosion risk, such as IEC 60079-0 for general requirements.
  64. [64]
    [PDF] Regulation (EU) 2024/1787 of the European Parliament ... - EUR-Lex
    Jun 13, 2024 · Rules for accurate measurement, monitoring, reporting and verification of methane emissions in the oil, gas and coal sectors, as well as for the ...