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Molybdenite

Molybdenite is a molybdenum sulfide mineral with the chemical formula MoS₂, recognized as the primary ore of molybdenum and characterized by its soft, greasy texture resembling graphite.^[1] It crystallizes in the hexagonal system, typically appearing as black to lead-gray hexagonal plates or foliated masses with a metallic luster, perfect basal cleavage, and a Mohs hardness of 1 to 1.5.^[1] Molybdenite occurs worldwide in hydrothermal vein deposits associated with granitic intrusions, porphyry copper deposits, and pegmatites, often forming in low- to medium-temperature environments.^[1] As the chief source of molybdenum, a refractory metal essential for strengthening alloys, molybdenite is mined extensively for industrial applications, including steel production where molybdenum enhances hardenability, corrosion resistance, and high-temperature performance.^[2] Beyond metallurgy, molybdenum derived from molybdenite serves as a catalyst in petroleum refining, a component in lubricants, pigments, and fertilizers, and is under investigation for semiconductor uses due to its layered structure and electronic properties.^[2]^[1]^[3]

Etymology and History

Name Origin

The name molybdenite derives from the ancient Greek term molybdos, meaning "lead," a reference to the mineral's metallic luster and superficial resemblance to lead-bearing ores such as galena, with which it was frequently confused in antiquity.^[4]^[5] This etymological root reflects early misunderstandings of the mineral's composition, as its soft, gray-black appearance and streak led miners and naturalists to group it among plumbiferous substances.^[1] Historical nomenclature for molybdenite included variations like "molybdæna" and "black lead ore," terms employed by classical authors such as Dioscorides (c. 50–70 CE) and Pliny the Elder (c. 79 CE) to describe similar soft, dark minerals, often encompassing galena or even graphite.^[1] These names persisted into the Renaissance, as seen in Georgius Agricola's 1556 work De Re Metallica, where "molybdæna" still denoted lead ores without distinguishing molybdenite's unique chemistry.^[1] Such terminological overlap contributed to centuries of misidentification, delaying recognition of its molybdenum content. Molybdenite was first described as a distinct mineral in 1778 by Swedish chemist Carl Wilhelm Scheele, who analyzed samples and identified molybdenum as a novel element within its structure, separate from lead or carbon.^[6]^[4] Scheele's work marked a pivotal shift, highlighting the mineral's sulfide nature rather than a lead compound. This standardization solidified molybdenite's identity as molybdenum disulfide (MoS₂), paving the way for its recognition as the primary ore of the element.^[1]

Discovery and Early Uses

Molybdenite, the primary ore of molybdenum, played a pivotal role in the discovery of the element molybdenum in the late 18th century. In 1778, Swedish chemist Carl Wilhelm Scheele analyzed samples of molybdenite obtained from Swedish deposits and decomposed them using hot nitric acid, identifying the mineral as a sulfide containing a previously unknown metal rather than lead or graphite as previously thought.^[4] This breakthrough clarified the mineral's composition and laid the foundation for further chemical investigations. Scheele's work was conducted using specimens from early Swedish occurrences, such as those in the Gruvåsen mining district in Värmland, which were among the first documented sources of molybdenite in Europe.^[7] Building on Scheele's findings, Swedish chemist Peter Jacob Hjelm successfully isolated impure molybdenum metal from molybdenite in 1781 by reducing molybdic acid with carbon, marking the first production of the element in metallic form.^[8] Hjelm's method involved heating the acid derived from molybdenite with charcoal, yielding a gray powder that he named molybdenum after the ancient Greek term for lead-like minerals. This isolation confirmed Scheele's earlier observations and enabled initial studies of the metal's properties.^[9] By the mid-19th century, practical applications expanded into metallurgy, where molybdenite-derived molybdenum was noted for enhancing steel's hardness and strength; French metallurgists observed these benefits in small alloy additions, leading to early patents for molybdenum-steel compositions in armor plating by 1891.^[10]^[11]

Chemical Composition and Structure

Molecular Formula and Composition

Molybdenite, the primary ore mineral of molybdenum, has the chemical formula MoS₂, consisting of one molybdenum (Mo) atom bonded to two sulfur (S) atoms.^[12] This composition reflects a simple binary sulfide where molybdenum is in the +4 oxidation state and each sulfur in the -2 state, forming the basis for its role in molybdenum extraction.^[13] The molar mass of pure MoS₂ is 160.07 g/mol, calculated from the atomic weights of molybdenum (95.95 g/mol) and sulfur (32.06 g/mol × 2).^[14] In terms of mass percentage, molybdenum accounts for 59.94% and sulfur for 40.06%.^[15] Natural molybdenite samples frequently exhibit stoichiometric variations due to lattice defects, such as vacancies or substitutions, which can result in slight deviations from the ideal Mo:S ratio of 1:2 and influence its reactivity and trace element incorporation.^[16] Common impurities in molybdenite include rhenium (Re), which substitutes for molybdenum in the lattice and can reach concentrations up to 1-2% (10,000-20,000 ppm) in certain deposits, though typical values range from tens to thousands of ppm.^[17] Iron (Fe) and copper (Cu) sulfides, often as inclusions like pyrite or chalcopyrite, are also prevalent, with iron contents varying from 0.05% to over 1% by weight in some ores.^[18] The isotopic composition of molybdenum in molybdenite, particularly when coupled with rhenium's decay to osmium (Re-Os system), enables precise geochronology, as molybdenite incorporates significant Re (ppm levels) but negligible common osmium, yielding robust formation ages for ore deposits.^[19]

Crystal Structure

Molybdenite, the mineral form of molybdenum disulfide (MoS₂), crystallizes in the hexagonal crystal system with the space group P6₃/mmc (No. 194). This structure is characteristic of the 2H polytype, which is the most abundant form found in nature. The atomic arrangement features molybdenum atoms coordinated to six sulfur atoms, forming distorted trigonal prismatic units that define the basic building block of the lattice.^[20]^[21] The crystal exhibits a layered structure where sheets of molybdenum atoms are arranged in a hexagonal pattern, each sandwiched between two layers of sulfur atoms. Within each layer, strong covalent bonds link the molybdenum and sulfur atoms, while the layers themselves are held together by weak van der Waals forces. This anisotropic bonding results in a highly stable intralayer configuration but facile interlayer sliding. The experimental lattice parameters for the 2H polytype at room temperature are a = 3.160 Å and c = 12.298 Å, reflecting the compact in-plane arrangement and the expanded out-of-plane dimension due to the interlayer spacing.^[20]^[22] Molybdenite displays polytypism, with variations arising from different stacking sequences of the S-Mo-S layers. The predominant 2H polytype follows an AbAb... sequence, where "A" and "B" denote distinct layer positions relative to the hexagonal lattice. In contrast, the less common 3R polytype adopts an ABCABC... stacking, corresponding to the rhombohedral space group R3m. These polytypes can coexist in natural samples, influenced by growth conditions, but the 2H form dominates due to its thermodynamic stability.^[21]^[23] The weak van der Waals interactions between layers enable perfect cleavage along the basal (0001) planes, producing thin, flexible sheets with a metallic sheen. This cleavage is a direct consequence of the minimal energy required to separate the layers, making molybdenite resemble graphite in its mechanical behavior despite differing chemical compositions.^[22]^[24]

Physical and Optical Properties

Appearance and Morphology

Molybdenite possesses a distinctive metallic luster and is characteristically lead-gray or bluish-gray in color, frequently leading to confusion with graphite due to these superficial similarities.^[25]^[26] The mineral is opaque, with a bluish-gray streak that aids in its identification.^[25]^[1] In terms of morphology, molybdenite typically forms in massive, foliated, or tabular habits, often appearing as scaly aggregates or disseminated grains.^[26]^[1] Common crystal forms include hexagonal plates, sometimes slightly curved or barrel-shaped, and rosettes composed of thin, platy blades; these structures can reach up to 15 cm in size.^[26]^[27] The mineral exhibits perfect cleavage along the basal plane {0001}, enabling it to separate into thin, flexible sheets.^[1]^[26] Twinning is rare but can produce pseudo-hexagonal forms through composition planes on {10̄11}.^[26] This cleavage, resulting from the mineral's layered structure, contributes to its sectile nature and ease of handling in thin sections. In thin section, molybdenite appears nearly opaque but translucent in very thin flakes, showing pale green-yellow to yellow-green pleochroism.^[25]^[26]

Density and Hardness

Molybdenite exhibits a density ranging from 4.62 to 4.73 g/cm³, equivalent to a specific gravity of 4.7 to 4.8, with minor variations attributable to impurities such as rhenium or other trace elements incorporated during formation.^[1] This density positions it as a moderately heavy mineral, denser than common sulfides like pyrite but lighter than galena, aiding in its gravitational separation during mineral processing. On the Mohs scale, molybdenite registers a hardness of 1 to 1.5, classifying it among the softest minerals and allowing it to be readily scratched by a fingernail or even softer materials.^[1] This low hardness stems from its weak interlayer van der Waals bonds in the hexagonal crystal structure, contributing to its high compressibility and flexibility, much like graphite. Along the basal planes, the Young's modulus measures approximately 238 GPa, reflecting stiffness within layers while permitting easy cleavage and deformation perpendicular to them.^[28] The thermal conductivity of molybdenite is markedly anisotropic, with in-plane values of 85–110 W/m·K significantly exceeding the cross-plane conductivity of about 2.5 W/m·K at room temperature, a consequence of efficient phonon transport parallel to the layers versus scattering across them.^[29] Electrically, it behaves as a semiconductor with n-type characteristics, exhibiting an in-plane resistivity of approximately 0.0028 Ω·m at ambient conditions, though this can vary with purity and doping levels.^[30]

Geological Occurrence

Natural Deposits

Molybdenite serves as the primary ore mineral for molybdenum in porphyry copper-molybdenum deposits, where it occurs as disseminated crystals and veinlets associated with copper mineralization.^[31] Notable examples include the Chuquicamata deposit in Chile, one of the world's largest open-pit copper mines with significant molybdenite by-product, and the Bingham Canyon mine in Utah, USA, a major porphyry system yielding substantial molybdenum alongside copper.^[32] These deposits typically form in subduction-related volcanic arcs and account for the majority of global molybdenum supply from such settings.^[33] Molybdenite also occurs in porphyry molybdenum deposits hosted in granitic and metamorphic terranes, such as the Climax mine in Colorado, USA, a high-grade example with ore in Precambrian gneisses intruded by Tertiary rhyolite porphyry stocks, featuring stockwork quartz-molybdenite veinlets. It represents one of the richest molybdenite concentrations globally.^[34] Common associated minerals in these deposits include pyrite, chalcopyrite, and quartz, which form the gangue and accompany molybdenite in hydrothermal veins.^[35] Additionally, molybdenite appears as an accessory mineral in granitic pegmatites, though these rarely contribute significantly to global molybdenum supply.^[1] Major producing countries for molybdenum, primarily derived from molybdenite-bearing ores, include China as the world's largest producer with an estimated 110,000 metric tons in 2024, followed by Peru, Chile, and the United States.^[36] These nations host diverse molybdenite deposits, from large-scale porphyry operations to smaller vein systems, contributing over 90% of global output. Global identified molybdenum resources are estimated at about 25 million metric tons, with molybdenite serving as the source for roughly 80% of recoverable molybdenum.^[36]

Formation Processes

Molybdenite primarily forms through hydrothermal processes in which molybdenum is transported and precipitated from hot, sulfur-rich aqueous fluids associated with magmatic systems. These fluids, derived from the exsolution of volatiles during the crystallization of intermediate to felsic intrusions, typically operate at temperatures ranging from 180 to 600°C, with common mineralization occurring between 250 and 400°C.^[31] The precipitation of molybdenite (MoS₂) occurs as these fluids cool and interact with host rocks, leading to supersaturation and deposition in veins, stockworks, or disseminated forms within porphyry systems.^[37] High sulfur concentrations in the fluids, often linked to magmatic sources with δ³⁴S values near 0‰ indicative of mantle derivation, facilitate molybdenum transport primarily as thiomolybdate complexes such as MoS₄²⁻ or HSMoS₃⁻ under reducing conditions.^[31]^[38] These formation processes are closely tied to tectonic settings involving subduction zones and continental arcs, where hydrous magmas generated in the mantle wedge above subducting slabs undergo differentiation to produce metal-enriched felsic melts. Magma differentiation, including fractional crystallization, concentrates incompatible elements like molybdenum in the residual melt and exsolved fluids, promoting molybdenite saturation at depth (typically 4–7 km).^[31] Geochemical signatures of these systems include elevated sulfur fugacity (fS₂), which enhances molybdenum solubility in bisulfide-dominated complexes, and reducing conditions that favor sulfide precipitation over oxide phases.^[31]^[39] In such environments, molybdenite often associates with quartz, potassic alteration, and other sulfides like pyrite and chalcopyrite, reflecting the fluid's evolution from magmatic to potentially mixed meteoric influences peripherally.^[31] Secondary enrichment of molybdenite can occur via supergene processes in oxidized zones near the surface, where downward-percolating meteoric waters leach molybdenum from primary sulfides and redeposit it as secondary molybdenite, jordisite, or ferrimolybdite at the water table or in reducing horizons.^[40] This enrichment is limited compared to primary hydrothermal deposition and typically forms thin blankets or irregular zones, driven by fluctuating redox conditions and pH in weathered profiles.^[31] The timing of molybdenite formation spans from the Proterozoic to the recent, as determined by Re-Os isotope dating of the mineral itself, which provides precise ages due to its high rhenium content and lack of common osmium. Examples include Paleoproterozoic deposits dated to approximately 1.68 Ga and Miocene formations in the Andes around 10 Ma, such as the Brahma porphyry Cu-Mo prospect in Chile, highlighting episodic mineralization linked to long-lived subduction dynamics.^[41]^[42]

Extraction and Processing

Mining Techniques

Molybdenite, the primary ore mineral for molybdenum, is predominantly extracted from large-scale porphyry deposits, which account for approximately 90-95% of global production.^[43] These deposits are typically amenable to open-pit mining methods due to their low-grade, bulk-tonnage nature, allowing for the removal of vast quantities of overburden and ore using large-scale equipment such as excavators, haul trucks, and drills.^[31] Open-pit operations involve sequential drilling and blasting to fragment the rock, followed by loading and hauling to surface processing facilities, enabling efficient extraction from near-surface deposits.^[44] For deeper or higher-grade vein-type deposits, underground mining techniques are employed, particularly where open-pit methods become uneconomical. Common approaches include room-and-pillar mining for tabular or flat-lying veins, which involves excavating rooms while leaving pillars for support, and cut-and-fill stoping for irregular, steeply dipping veins, where ore is extracted in slices and backfilled with waste to maintain stability.^[45] In select cases, such as the Climax deposit, block caving is used for massive underground orebodies, where the ore is undercut to induce controlled collapse under its own weight.^[44] Ore grades in these operations typically range from 0.05% to 0.2% molybdenum, necessitating selective mining to optimize recovery.^[31] A significant portion of molybdenite—around 60% globally—is recovered as a byproduct from porphyry copper mines, where it occurs disseminated alongside copper sulfides.^[46] In these operations, the ore is processed through crushing, grinding, and froth flotation to separate molybdenite into a concentrate, often after initial copper recovery.^[47] Recent advancements in molybdenite mining, as of 2024, include the adoption of automated haulage systems to enhance safety and efficiency in both open-pit and underground settings, as implemented by major producers like Freeport-McMoRan.^[48] Additionally, drone-based surveying has improved site mapping and monitoring, reducing manual labor risks and enabling real-time data collection for operational optimization.^[49]

Refining Methods

The primary refining of molybdenite (MoS₂) begins with froth flotation of the crushed ore, where the mineral is separated from gangue materials by introducing air bubbles into a slurry, allowing MoS₂ particles to attach to froth and rise to the surface for collection. This process typically yields a concentrate containing 85–92% MoS₂, which serves as the feedstock for subsequent steps.^[50] The concentrate is then roasted in air at temperatures between 500–650°C to convert MoS₂ to molybdenum trioxide (MoO₃), a key intermediate, while releasing sulfur dioxide gas. The primary reaction is:

$2\text{MoS}_2 + 7\text{O}_2 \rightarrow 2\text{MoO}_3 + 4\text{SO}_2

This roasting also involves intermediate steps to manage oxidation, resulting in a product with at least 57% Mo and less than 0.1% sulfur.^[50] Purification of the MoO₃ follows, often through dissolution in an alkaline medium followed by solvent extraction or ion exchange to remove impurities such as rhenium, copper, and other metals. Solvent extraction uses organic reagents to selectively bind and separate molybdenum from rhenium-bearing solutions, while ion exchange employs resins to adsorb and elute contaminants like rhenium for its recovery. These methods produce high-purity molybdenum chemicals suitable for further processing.^[50]^[51] The purified MoO₃ is reduced to metallic molybdenum using hydrogen gas in a two-stage process, with the overall reaction:

\text{MoO}_3 + 3\text{H}_2 \rightarrow \text{Mo} + 3\text{H}_2\text{O}

The first stage partially reduces MoO₃ to MoO₂ at 450–650°C, followed by complete reduction to metal at 1,000–1,100°C, yielding powder or pellets of 99.9% purity.^[50] Global molybdenum production reached an estimated 260,000 metric tons of contained molybdenum in 2024, primarily from molybdenite refining, with approximately 25% of supply derived from recycling sources such as spent catalysts.^[36]^[52]

Industrial Applications

Lubricants and Catalysts

Molybdenite, primarily in the form of molybdenum disulfide (MoS₂), exhibits exceptional dry lubricant properties attributable to its hexagonal layered crystal structure, where individual S-Mo-S layers are bound by weak van der Waals forces that facilitate interlayer sliding and minimize friction. This structure enables MoS₂ to serve as an effective solid lubricant in greases, oils, and protective coatings, particularly in demanding conditions such as high temperatures up to 350°C in air and extreme vacuum environments where conventional liquid lubricants fail.^[53]^[54] When incorporated as nanoadditives in engine oils, MoS₂ forms a durable boundary layer that reduces friction coefficients by 20-30% and enhances anti-wear performance, making it a staple in high-performance applications. Its efficacy is especially pronounced in aerospace sectors, where NASA has employed MoS₂-based formulations for mechanisms in spacecraft and satellites to ensure reliable operation under vacuum and thermal extremes.^[55]^[56] In catalysis, MoS₂ plays a pivotal role in hydrodesulfurization (HDS) processes within petroleum refining, where it removes sulfur compounds from fuels to meet environmental standards; the active phase is generated by sulfidation of molybdenum oxide (MoOₓ) precursors, creating coordinatively unsaturated edge sites on MoS₂ nanoclusters that promote hydrogenation and C-S bond cleavage.^[57]^[58] Non-metallurgical applications account for approximately 21% of global molybdenum consumption as of 2023, including about 15% for catalysts in the chemical and petrochemical industries and around 1-2% for lubricants, underscoring their industrial significance beyond metallurgical uses.^[59] Synthetic MoS₂, produced via chemical vapor deposition (CVD) methods such as metalorganic CVD or plasma-enhanced variants, achieves enhanced purity and uniformity compared to natural molybdenite-derived material, enabling tailored properties for advanced lubrication and catalysis.^[60]

Electronics and Semiconductors

Molybdenite, or molybdenum disulfide (MoS₂), in its two-dimensional (2D) form as a monolayer or few-layer structure, serves as a prototypical transition metal dichalcogenide (TMD) material for advanced electronics due to its atomic-scale thickness and tunable electronic properties.^[61] Unlike bulk MoS₂, which exhibits an indirect bandgap of approximately 1.2 eV, the monolayer variant transitions to a direct bandgap of 1.8 eV, enabling efficient light-matter interactions and semiconducting behavior suitable for device integration. In field-effect transistors (FETs), 2D MoS₂ has demonstrated exceptional performance, with devices achieving on/off current ratios exceeding 10⁸ and room-temperature carrier mobilities around 200 cm²/V·s when gated with high-k dielectrics like HfO₂.^[61] These metrics position MoS₂ as a viable channel material for low-power, high-speed logic circuits, surpassing traditional silicon in scalability for sub-5 nm nodes.^[61] The direct bandgap in thin-film MoS₂ enables applications in optoelectronics, including photovoltaics where it acts as an efficient charge separator in heterojunction solar cells, enhancing power conversion efficiencies through improved light absorption in the visible range.^[62] Similarly, in light-emitting diodes (LEDs), monolayer MoS₂ facilitates radiative recombination, with vertical homojunctions exhibiting low turn-on voltages and bright electroluminescence for flexible displays.^[63] Integration of 2D MoS₂ into flexible electronics and sensors leverages its mechanical robustness and piezoresistive properties, enabling bendable transistors and gas/strain sensors with high sensitivity on polymer substrates.^[64] Research in these areas surged post-2010, positioning MoS₂ as a bandgap-endowed analog to graphene for overcoming zero-bandgap limitations in 2D electronics.^[65] Since the 2020s, MoS₂ nanomaterials have transitioned toward commercialization in electronics, with wafer-scale chemical vapor deposition enabling prototype FET arrays and optoelectronic devices; as of 2025, ongoing research has improved the reliability of monolayer MoS₂ field-effect transistors using ultra-thin dielectrics, advancing toward practical integration, though bulk lubricants derived from molybdenite remain ancillary in semiconductor fabrication.^[66]^[67]^[68]

Health and Environmental Considerations

Toxicity and Safety

Molybdenite, the primary ore of molybdenum consisting mainly of molybdenum disulfide (MoS₂), poses low acute toxicity risks, with an oral LD50 exceeding 5,000 mg/kg in rats for insoluble molybdenum compounds, underscoring its relative safety in single, high-dose scenarios.^[69] However, inhalation of molybdenite dust can irritate the respiratory tract, leading to symptoms such as coughing, wheezing, and dyspnea, particularly in occupational environments like mining and processing.^[70] Chronic inhalation exposure to molybdenum dust has been associated with pneumoconiosis and reduced lung function in workers handling fine particulate matter, though evidence is stronger for mixed-metal dusts including molybdenum trioxide.^[71] Contact with MoS₂ may also cause mechanical irritation to the skin and eyes due to its particulate nature and sulfur content, potentially resulting in redness or discomfort upon prolonged exposure.^[72] Prolonged exposure to molybdenum from molybdenite handling is linked to systemic health effects, including gout-like symptoms referred to as molybdenosis, which manifest as joint pain, fatigue, and elevated serum uric acid levels, often exacerbated by inadequate dietary copper.^[73] These symptoms arise from disruptions in purine metabolism and have been documented in populations with chronic occupational or environmental molybdenum intake above 0.2 mg/kg/day.^[71] In ruminants such as cattle and sheep, bioaccumulation of molybdenum from mine tailings contaminated with molybdenite residues induces secondary copper deficiency, interfering with copper absorption via thiomolybdate formation in the rumen and causing clinical signs including diarrhea, poor growth, anemia, and lameness.^[74] This antagonism is particularly pronounced when molybdenum levels in forage exceed 5 mg/kg dry matter alongside sulfur content above 0.33%.^[75] To mitigate risks, occupational handling of molybdenite requires strict adherence to safety standards, including the OSHA permissible exposure limit (PEL) of 5 mg/m³ for the respirable fraction of insoluble molybdenum compounds (as Mo), with a total dust limit of 15 mg/m³ over an 8-hour workday.^[76] Personal protective equipment, such as NIOSH-approved respirators for dust, gloves, and eye protection, is essential during mining, crushing, or refining processes to prevent inhalation and dermal contact.^[71] Engineering controls like local exhaust ventilation further reduce airborne concentrations.

Environmental Impact

Molybdenite mining and processing pose significant environmental risks primarily through the generation of acid mine drainage (AMD) from the oxidation of sulfide minerals like MoS₂. This process produces sulfuric acid and mobilizes heavy metals, resulting in highly acidic tailings with pH levels often below 4, which can persist for decades and degrade surrounding soil and water quality.^[77] Roasting of molybdenite concentrate to produce molybdenum trioxide releases sulfur dioxide (SO₂) emissions, contributing to acid rain formation when SO₂ reacts with atmospheric moisture. Modern desulfurization technologies, such as sulfuric acid plants and lime scrubbers, can reduce these SO₂ emissions by up to 99%, mitigating atmospheric pollution from processing facilities.^[50]^[78] Water contamination is a key concern, as molybdenum exhibits high mobility in alkaline soils (pH >7), where it exists primarily as the soluble molybdate anion (MoO₄²⁻), facilitating its transport into groundwater and surface waters. Elevated molybdenum levels in aquatic environments can harm fish and other organisms, with chronic toxicity thresholds as low as 0.073 mg/L for freshwater species like rainbow trout.^[3]^[79] As of 2025, the EPA lifetime health advisory for molybdenum in drinking water remains 0.04 mg/L.^[80] Reclamation efforts at molybdenum mine sites increasingly employ phytoremediation, utilizing hyperaccumulator plants such as certain grasses and legumes that uptake and stabilize molybdenum in their biomass, reducing soil and water contamination over time.^[81] The carbon footprint of molybdenum production is notable, with mining and concentration of molybdenite emitting approximately 5.7 kg CO₂-equivalent per kg of molybdenum metal, driven largely by energy-intensive ore extraction and transport. Industry efforts are shifting toward green refining techniques, including renewable energy integration and low-emission roasting processes, to reduce this impact.^[82]

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van der Waals Epitaxy of MoS2 Layers Using Graphene As Growth ...
We present a method for synthesizing MoS 2 /Graphene hybrid heterostructures with a growth template of graphene-covered Cu foil.Missing: perfect basal cleavage
[25]
Molybdenite: Mineral properties, uses, geologic occurrence
Molybdenite is a rare mineral composed of molybdenum and sulfur, with a chemical composition of MoS 2. It occurs in igneous and metamorphic rocks.Missing: appearance morphology
[26]
[PDF] Molybdenite MoS2 - Handbook of Mineralogy
Molybdenite (MoS2) is hexagonal, with a hardness of 1-1.5, lead-gray color, metallic luster, and a greasy feel. It has a bluish-gray streak.
[27]
Molybdenite - Saint-Hilaire
Crystal System is hexagonal; mmc (-2H) and (-3R). Crystal Habits include sharp hexagonal, thin-foil plates forming attractive rosettes or spherical ...Missing: twinning pseudo-
[28]
Young's Modulus of Molybdenum Disulphide (MoS2)? - ResearchGate
Sep 17, 2014 · The Young's modulus we obtained for ultrathin MoS2 flakes (E = 0.33 ± 0.07 TPa) should be compared with the value for bulk MoS2, Ebulk = 0.24 ...Missing: molybdenite | Show results with:molybdenite
[29]
Measurement of the anisotropic thermal conductivity of molybdenum ...
We use pump-probe metrology based on the magneto-optic Kerr effect to measure the anisotropic thermal conductivity of (001)-oriented MoS2 crystals. A ≈20 nmAnalysis · Through-plane thermal... · In-plane thermal conductivity...Missing: molybdenite | Show results with:molybdenite
[30]
Spreading resistance and conductance anisotropy in multilayer MoS2
Mar 25, 2024 · Based on the scaling theory for conduction in anisotropic materials, the model yields an in-plane resistivity of 0.28 ± 0.07 Ω cm and an ...
[31]
[PDF] Arc-Related Porphyry Molybdenum Deposit Model
Anomalous metallic trace constituents found in arc- related porphyry molybdenum deposits include copper, lead, silver, tin, and zinc. Molybdenite in porphyry ...
[32]
By-Products of Porphyry Copper and Molybdenum Deposits
Jan 1, 2016 · Molybdenite is the primary ore mineral in porphyry Mo deposits, and there is no metal zoning of various Mo-bearing minerals. Molybdenum ...
[33]
[PDF] Low-fluorine Stockwork Molybdenite Deposits
Low-fluorine stockwork molybdenite deposits are closely related to porphyry copper deposits, being similar in their tectonic setting (continental volcanic arc) ...Missing: global | Show results with:global
[34]
[PDF] THE CLIMAX MOLYBDENUM DEPOSIT COLORADO
The Climax molybdenum deposit is the largest single metal-mining operation in Colorado, with a reserve sufficient for 2,000 tons daily for 3 years.
[35]
[PDF] Investigations of Molybdenum Deposits in the
About half of the molybdenite deposits examined are quartz veins that include some pyrite and, less commonly, chalcopyrite.
[36]
[PDF] Molybdenum - Mineral Commodity Summaries 2024 - USGS.gov
Molybdenum is a refractory metallic element used principally as an alloying agent in cast iron, steel, and superalloys and is also used in numerous chemical ...
[37]
Molybdenum speciation in magmatic-hydrothermal fluids
Apr 15, 2025 · Magmatic-hydrothermal ore deposits are the world's major source of molybdenum (Mo), yet the speciation of Mo in magmatic-hydrothermal fluids is still uncertain.
[38]
[PDF] The role of sulfur in molybdenum transport in hydrothermal fluids - HAL
Nov 4, 2021 · Molybdenum (Mo) is mainly mined from magmatic hydrothermal deposits (e.g., porphyry Cu-Mo-Au deposits), where the metals including Mo are ...
[39]
Molybdenite Saturation in Silicic Magmas - Oxford Academic
Mar 31, 2011 · Abstract. We identified molybdenite (MoS2) as an accessory magmatic phase in 13 out of 27 felsic magma systems examined worldwide.Missing: bisulfide | Show results with:bisulfide
[40]
Behavior of molybdenum during weathering of the Ceresco Ridge ...
Where these conditions apply there may be supergene enrichment of Mo in the form of molybdenite, jordisite or ferrimolybdite at the water table. There was ...
[41]
[PDF] Summary of results. Re–Os molybdenite dating of the Hit or Miss ...
Molybdenite was dated to determine an absolute age for tungsten mineralisation at the deposit. The Re–Os molybdenite model ages obtained were 1677 ± 10 Ma and ...Missing: Andes | Show results with:Andes
[42]
The Miocene Brahma porphyry Cu-Mo prospect in Central Chilean ...
Mineralization ages of ~ 14 Ma, 12 Ma, and 10 Ma were obtained by Re-Os determinations on molybdenite from samples of different paragenetic stages. These ...
[43]
[PDF] molybdenum mineralization with emphasis on porphyry systems ...
Supergene enrichment ... The trend of the self-potential response follows a major negative potential centre over the oxidized zones of the porphyry systems.
[44]
[PDF] Climax-Type Porphyry Molybdenum Deposits
Climax-type deposits are mined by large-scale underground block caving or aboveground open- pit methods. Surface areas of open pits and associated waste dumps ...
[45]
10.3.1: Room and Pillar Method | MNG 230 - Dutton Institute
The majority of underground production comes from room and pillar mines, and the majority of underground mines, by number, employs the room and pillar method!
[46]
Molybdenum processing | Extraction, Applications & Uses - Britannica
During the 19th century, the German chemist Bucholtz and the Swede Jöns Jacob Berzelius systematically explored the complex chemistry of molybdenum, but it ...
[47]
Molybdenum Ore Processing by Flotation - 911Metallurgist
May 5, 2016 · It is usually present as the sulphide, molybdenite, which is readily recovered in the copper flotation concentrate. Copper sulphide flotation ...Regrind Circuit · Flotation of Molybdenite from... · The Copper/Moly Separation...
[48]
[PDF] 2024-annual-report-on-sustainability.pdf - Freeport-McMoRan
Apr 23, 2025 · The implementation of new and innovative technologies and practices, such as our leaching initiatives and the advancement of autonomous haulage ...Missing: automated | Show results with:automated
[49]
I, Robot. Mining's Automated Future - K-MINE
Nov 1, 2024 · One of the most significant advancements is the implementation of autonomous haulage systems (AHS). ... Drone surveying a large mining area for ...
[50]
Molybdenum Processing
Some of the by-product molybdenite concentrates from copper mines contain small quantities (<0.10%) of rhenium. Molybdenum roasters equipped to recover rhenium ...
[51]
Hydrometallurgical separation of Mo and Re from Rhenium ...
Aug 14, 2025 · Ion exchange involves the adsorption of rhenium using resins followed by its elution to obtain a high-purity rhenium solution [11]. The ...Missing: refining | Show results with:refining
[52]
[PDF] MOLYBDENUM - USGS.gov
... production of molybdenum concentrate decreased by 3% to 33,000 tons of molybdenum content in 2024 compared with 34,000 tons in 2023. Molybdenum concentrate.
[53]
Global Molybdenum Production: Key Players & Market Trends
Apr 18, 2025 · Approximately 25% of global molybdenum supply comes from recycled sources, primarily from spent catalysts and high-grade steel scrap. The ...
[54]
https://shop.nanografi.com/blog/dry-lubricants-and-their-use-in-machinery/
[55]
Dry Lubricants and Their Use in Machinery - Nanografi
Jul 30, 2021 · MoS2 of 1–100 µm size is a common dry lubricant. In oxidizing environments, few alternatives confer stability and high lubricity at up to 350 °C ...
[56]
MoS2 Nanomaterials as Lubricant Additives: A Review - MDPI
Dec 11, 2023 · The results of four-sphere machine tests showed that the addition of OA-MoS2 nanosheets significantly improved the friction reduction, anti-wear ...Missing: NASA | Show results with:NASA<|separator|>
[57]
[PDF] solid lubricants - NASA Technical Reports Server (NTRS)
The signifi- cant growth in solid-lubricant technology has led NASA to look seriously at the potential for nonaerospace applications.
[58]
https://ifp.hal.science/hal-03650986v1/document
[59]
[PDF] Genesis of MoS2 from Model-Mo-Oxide Precursors Supported on
Apr 25, 2022 · 23.20. Page 3. 2. ABSTRACT: The molecular-scale understanding of the genesis of the MoS2 phase from Mo- oxide precursors by sulfo-reduction ...<|control11|><|separator|>
[60]
Synthesis Methods of Two-Dimensional MoS 2 : A Brief Review - MDPI
With plasma-enhanced chemical vapor deposition (PECVD), the growth temperature of MoS2 can be lowered to 150–300 °C, making it possible to directly deposit ...
[61]
Single-layer MoS2 transistors | Nature Nanotechnology
Jan 30, 2011 · Cite this article. Radisavljevic, B., Radenovic, A., Brivio, J. et al. Single-layer MoS2 transistors. Nature Nanotech 6, 147–150 (2011).
[62]
(PDF) A Review on MoS2 Energy Applications - ResearchGate
Oct 15, 2025 · In this work, we present MoS2 as a future material for energy storage and generation applications, especially solar cells, which are a ...
[63]
The highly-efficient light-emitting diodes based on transition metal ...
Jul 22, 2020 · The ultimate thickness of the MoS2 vertical homojunction is 3 nm and the depth of chemical doping is 1.5 nm. To expand the application range of ...
[64]
Flexible integrated circuits and multifunctional electronics based on ...
Feb 24, 2015 · Two-dimensional materials, such as graphene and its analogues, have been investigated by numerous researchers for high performance flexible ...
[65]
Two-dimensional MoS2: Properties, preparation, and applications
Aug 7, 2025 · In this Review, we attempt to provide the latest development of optical and electronic properties, synthesis approaches, and potential applications of 2D MoS2.
[66]
[PDF] From lab to fab: path forward for 2D material electronics
May 17, 2023 · For ICs, recent breakthroughs include the 1-bit MoS2 microprocessor unit [18], the first 2D MoS2 analog ampli- fiers [19], and other logic ...
[67]
Batch Production of Wafer-Scale Monolayer MoS 2 - MDPI
Aug 18, 2023 · Here, a significant breakthrough in the batch production of wafer-scale monolayer MoS 2 via chemical vapor deposition is reported.
[68]
[PDF] Thompson Creek Metals SAFETY DATA SHEET MOLYBDENUM ...
May 29, 2015 · Acute Toxicity Level: Insoluble Mo compounds exhibit low toxicity LD50 (rat) >5000 mg/kg. No specific data available for MoS2. Skin corrosion/ ...
[69]
HEALTH EFFECTS - Toxicological Profile for Molybdenum - NCBI
Of the 92 identified toxicity publications, 84% evaluated health outcomes in laboratory animals; most (74%) were conducted by the oral route of exposure.
[70]
[PDF] ATSDR Molybdenum Tox Profile
This profile reflects ATSDR's assessment of all relevant toxicologic testing and information that has been peer-reviewed.
[71]
[PDF] SAFETY DATA SHEET
Oct 21, 2022 · Molybdenum Sulfide. Appearance (physical state, color, etc.) black, lustrous powder. Molecular Formula. MoS2. Molar Mass (g/mol). 160.06. Odor.
[72]
Molybdenum - Health Professional Fact Sheet
Mar 30, 2021 · The affected individuals experienced achy joints, gout-like symptoms, and abnormally high blood levels of uric acid [14]. Given the absence of ...
[73]
Molybdenum Toxicity in Animals - Toxicology
Molybdenum toxicity, often from copper-molybdenum imbalance, causes poor growth, diarrhea, and lameness in ruminants, especially cattle and sheep. It is a herd ...Missing: molybdenite hazards<|separator|>
[74]
Copper and health status of cattle grazing high-molybdenum forage ...
Animals appeared healthy and no signs of Cu deficiency were observed. Key words: Molybdenum, molybdenosis, copper, mine tailings, reclamation, animal health ...
[75]
https://cdnsciencepub.com/doi/10.4141/A02-084
[76]
[PDF] HARDROCK MINING: ACID MINE DRAINAGE
Acid mine drainage is considered one of mining's most serious threats to water resources.1 A mine with acid mine drainage has the potential for long-term ...
[77]
SO2 Removal and Acid Gas Control - Babcock & Wilcox
Current designs can achieve more than 99% SO2 removal, with system availability greater than 99.5%. Our absorber design also provides reduced operating and ...
[78]
The Role of Molybdenum in Agricultural Plant Production - PMC - NIH
... soil colloids. In alkaline soils, molybdenum becomes more soluble and is accessible to plants mainly in its anion form as Inline graphic . In contrast, in ...
[79]
[PDF] Molybdenum Water Quality Guidelines for the Protection ... - Gov.bc.ca
The Mo WQG for the protection of freshwater aquatic life is 0.073 mg/L. This WQG was derived by multiplying the lowest chronic toxicity value for rainbow ...
[80]
[PDF] Molybdenosis and Land Reclamation Strategies for Prevention
If the metal in the soil is abundant and hyperaccumulators are used for phytoremediation, there is sometimes the option to ... of molybdenum in mining-affected ...
[81]
[PDF] Summary Report 2024 - International Molybdenum Association
Mining ores containing molybdenum may be carried out by way of underground mining or surface/open pit mining. Data for both mining methods were collected ...