Fact-checked by Grok 2 weeks ago

Tortuosity

Tortuosity is a dimensionless that quantifies the deviation of actual pathways from a straight line in complex structures, particularly in porous media, where it represents the ratio of the effective path length through the material to the (straight-line) between endpoints. This measure, typically denoted by τ and always greater than or equal to 1, captures the and interconnectedness of pore spaces, influencing the hindrance to transport processes such as , fluid flow, and conduction. Originating from geometric considerations, tortuosity extends beyond simple length ratios to include hydraulic, electrical, and diffusive variants, each tailored to specific physical phenomena in the medium. In porous media like soils, rocks, and engineered materials, tortuosity plays a pivotal role in determining effective transport properties, as it accounts for the increased resistance caused by tortuous paths around solid obstacles, thereby reducing and permeability relative to free-space values. For instance, the effective D* relates to the free D by D* = D / τ in simple models, though more advanced formulations incorporate (φ) as D* = φ D / τ. This parameter is essential for modeling phenomena such as in geosciences, where higher tortuosity correlates with lower , and in , where it helps predict reservoir performance. Beyond geosciences, tortuosity is critical in electrochemical devices like batteries and fuel cells, where it governs mass and charge transport through porous electrodes, directly impacting device efficiency and polarization losses. In biological contexts, such as the (ECS) of the , tortuosity (often denoted λ) quantifies hindrance around cellular structures, with typical values around 1.6 that increase during pathological conditions like ischemia, affecting delivery and waste clearance. Applications also span thermal conductivity in insulators and sound absorption in acoustic materials, underscoring tortuosity's interdisciplinary relevance in optimizing material design for energy, environmental, and biomedical technologies. Tortuosity is calculated through diverse methods, including geometric approaches that trace shortest paths via imaging techniques like micro-computed tomography (μCT), flux-based simulations solving equations like Laplace's for transport fields, and empirical models relating it to (e.g., τ = 1 / √φ for some media). Experimental measurements often employ real-time or integrative optical imaging in biological systems, while numerical tools like the Lattice Boltzmann Method enable predictions in complex microstructures. These approaches reveal that tortuosity values typically range from 1 to over 4, depending on the medium's heterogeneity and the definition used, highlighting ongoing challenges in across fields.

Definition and Fundamentals

Geometric Interpretation

Tortuosity, in its geometric sense, quantifies the deviation of a pathway from a straight line within a medium, defined as the ratio of the actual tortuous path length L_e to the straight-line L between endpoints, expressed as \tau = \frac{L_e}{L}. This formulation captures the inherent in structures like porous materials, where particles or fluids must navigate around obstacles, elongating their travel compared to direct traversal. As a dimensionless , tortuosity satisfies \tau \geq 1, with equality holding only for perfectly straight paths; values exceeding 1 reflect increasing or meandering, which impede efficient by extending effective distances. In conceptual terms, a value of \tau = 1 corresponds to unobstructed , while higher \tau indicates progressively more convoluted routes, such as those in fractal-like or irregularly shaped voids. To illustrate, consider a simple two-dimensional curved line connecting two points: if the line arcs gently, \tau slightly exceeds 1, but a highly sinuous elevates it further, emphasizing how geometric complexity amplifies path relative to . Similarly, in three dimensions, a coiled exemplifies tortuosity, where the helical winding multiplies the centerline against the axial straight-line , mimicking pathways in fibrous or packed without requiring intricate networks. Geometric tortuosity represents an intrinsic property of the medium's microstructure, determined solely by its spatial configuration, whereas apparent tortuosity incorporates observer-dependent or process-specific effects, such as interactions that alter perceived path efficiency. This distinction underscores tortuosity's role as a pure morphological descriptor, independent of external influences like or measurement techniques.

Historical Development

The concept of tortuosity originated in the early within and , where it was introduced to quantify the deviation of fluid paths from straight lines in porous media. In , Josef Kozeny proposed the term in the context of modeling permeability, drawing on a capillary tube to describe conduction in and emphasizing the geometric lengthening of flow paths due to pore structure. This geometric interpretation laid the groundwork for understanding tortuosity as a factor influencing in hydrological applications. By the late , Philip C. Carman advanced the Kozeny model, extending it to predict permeability in granular beds such as saturated sands, soils, and clays. A pivotal development occurred in 1942 when G.E. Archie introduced in , relating the formation factor to (F = a/φ^m), which in subsequent interpretations accounts for the tortuous nature of conduction paths in porous rocks alongside effects. This empirical relation marked tortuosity's shift toward quantitative application in reservoir characterization, influencing subsequent studies in fluid and electrical transport. Following , in the post-1950s era, tortuosity gained broader adoption in for analyzing and in engineered porous materials, such as catalysts and filters, where it became essential for scaling microscopic to macroscopic properties. The 1980s saw further refinements in porous media theory, with Jacob Bear and collaborators integrating tortuosity into comprehensive models of and transport, emphasizing its and dependence on in macroscopic averaging techniques. A key milestone in the involved the advent of computed , which enabled three-dimensional visualization and direct computation of tortuosity in real porous samples like sandstones, revolutionizing the shift from idealized models to image-based analysis. In the post-2010 period, approaches have emerged for predicting tortuosity, particularly in design, where convolutional neural networks analyze microstructural images to forecast transport properties and optimize performance.

Mathematical Formulations

Two-Dimensional Cases

In two-dimensional cases, tortuosity quantifies the deviation of transport paths from straight lines in planar structures, such as slices of porous media or curved channels. The basic geometric formulation expresses tortuosity \tau as the ratio of the effective path length to the straight-line distance, given by \tau = \frac{\int ds}{L}, where ds is the differential arc length element along the curved path and L is the Euclidean distance between endpoints. This integral form captures the elongation due to path curvature in 2D geometries, such as those encountered in thin-layer porous materials or vascular networks viewed in cross-section. For simple 2D paths, tortuosity can be computed analytically to illustrate its value. Consider a semicircular path of radius r, where the arc length is \pi r and the straight-line distance is $2r, resulting in \tau = \pi/2 \approx 1.57. Similar calculations apply to sinusoidal curves, which model undulating flow paths in layered media; for a sine wave with amplitude a and wavelength \lambda, the path length approximates \int_0^\lambda \sqrt{1 + (2\pi a / \lambda)^2 \sin^2(2\pi x / \lambda)} \, dx, yielding \tau \approx 1.216 for moderate amplitudes where a / \lambda = 0.2. In fractal-like 2D patterns, such as self-similar pore networks, tortuosity follows power-law relations with porosity \phi, often \tau \sim \phi^{-\epsilon} where \epsilon \approx 0.5 to 1, reflecting increased path complexity at lower porosities. A vector-based approach in leverages velocities to estimate tortuosity, particularly for hydraulic contexts, as \tau = \langle \mathbf{u} \rangle / \langle u_x \rangle, where \mathbf{u} is the velocity vector, \langle \mathbf{u} \rangle its average, and \langle u_x \rangle the component along the principal direction. This formulation, derived from Boltzmann simulations, approximates the path elongation via discretized sums over grid points, \tau \approx \sum |\mathbf{u}(\mathbf{r})| / \sum u_x(\mathbf{r}), and is useful for irregular porous structures like overlapping circles with \phi = 0.85, yielding \tau \approx 1.13. Despite their simplicity, 2D models for tortuosity have limitations, as they often underrepresent the interconnectivity and branching observed in real three-dimensional media, leading to underestimation of effective path resistances in . For instance, at low porosities below 0.5, 2D approximations struggle to capture viable paths, resulting in geometric tortuosity values lower than hydraulic ones due to idealized .

Three-Dimensional Cases

In three-dimensional structures, geometric tortuosity quantifies the elongation of pathways within the volumetric network relative to a straight-line . It is defined as \tau = \frac{L_e}{L}, where L_e is the effective path length through the pores and L is the straight-line across the medium. This scalar measure generalizes to by averaging over multiple paths in the , often computed using volume integrals that integrate the local path lengths weighted by the , such as \tau = \frac{1}{V_p} \int_{V_p} \frac{ds}{dx} \, dV, where V_p is the volume, ds is the differential along the path, and dx is the along the principal direction. For anisotropic media, tortuosity is represented as a second-order tensor \boldsymbol{\tau}, capturing direction-dependent path complexities. Derived from volume-averaged Fick's law, \mathbf{J} = -\mathbf{D}_{\text{eff}} \nabla c, where \mathbf{J} is the diffusive flux and c is concentration, the effective tensor relates to the \mathbf{D}_0 = D_0 \mathbf{I} (with \mathbf{I} the tensor) via \mathbf{D}_{\text{eff}} = \varepsilon D_0 \boldsymbol{\tau}^{-1}, or equivalently, the components satisfy \tau_{ij} = \varepsilon \frac{D_0 \delta_{ij}}{(D_{\text{eff}})_{ij}} in principal coordinates, where \varepsilon is , \delta_{ij} is the , and inversion accounts for the hindrance in each direction. This formulation arises from averaging microscopic fluxes over a , incorporating the tortuosity tensor to adjust for non-uniform path orientations and lengths. In isotropic random media, such as overlapping spheres, tortuosity approximates \tau \approx 1 / \sqrt{\varepsilon}, reflecting reduced due to path meandering in disordered structures; this follows from the Bruggeman relation D_{\text{eff}} / D_0 = \varepsilon^{3/2}, implying \tau = \varepsilon / (D_{\text{eff}} / D_0) = \varepsilon^{-1/2}. Computation in voxel-based representations often employs shortest- algorithms like A-star on grids to estimate \tau by averaging geodesic distances between boundary nodes, enabling quantification in digitized porous volumes. Challenges in 3D tortuosity arise from distinguishing connected transport pathways from dead-end pores, as the former dominate effective transport while the latter inflate geometric estimates without contributing to flux; this requires separating percolating networks via graph theory or diffusion simulations to isolate relevant volumes.

Measurement and Computation

Experimental Methods

One common experimental approach to measure electrical tortuosity involves saturating a porous sample with an electrolyte solution and determining the effective electrical conductivity (σ_eff) relative to the bulk fluid conductivity (σ_bulk) using impedance spectroscopy over a frequency range, typically from 1 Hz to 1 MHz, to minimize electrode polarization effects. The sample, often a cylindrical core of 1-2 cm diameter and length, is placed between non-polarizing electrodes in a conductivity cell, and resistivity is recorded under controlled temperature (e.g., 25°C) to ensure ionic mobility consistency. Porosity (φ) is measured independently, e.g., via gravimetric methods. Tortuosity (τ) is then calculated as τ = √(φ σ_bulk / σ_eff), assuming a simplified geometric model where the formation factor approximates the square root relation for many granular media. This method has been applied to sandstones, yielding τ values around 1.5-3 for Berea samples with porosities of 15-20%. Diffusion-based experiments quantify diffusional tortuosity by tracking the self-diffusion of tracer molecules, such as or like , within a fluid-saturated porous sample using pulsed field (PFG-NMR). The setup typically employs a benchtop NMR spectrometer with strengths up to G/cm and diffusion times (Δ) of 10-100 ms to probe length scales of 100-2000 μm, allowing observation of the long-time diffusion limit where the effective (D_eff) stabilizes. (ε) is independently measured via NMR relaxation or gravimetric methods, and τ is derived from D_eff = D_0 ε / τ, where D_0 is the free-fluid calibrated against bulk samples at the same temperature and . For bead packs or pellets, this yields τ ≈ 1.2-1.6, with higher values in heterogeneous rocks due to restricted pathways. Recent applications as of 2025 include refined PFG-NMR for assessing tortuosity in fast-charging supercapacitors. Hydraulic permeability tests infer hydraulic tortuosity from steady-state fluid flow through a saturated porous under controlled gradients, adhering to : Q = -(k A / μ) (ΔP / L), where Q is the , A the cross-sectional area, μ the fluid , ΔP the , L the sample length, and k the intrinsic permeability. The setup involves a holder with upstream and downstream reservoirs maintaining constant ΔP (e.g., 0.1-1 ) using a syringe pump for low- fluids like or , with flow rates measured via effluent collection or flow meters over 10-30 minutes to ensure . and characteristic pore size are determined separately (e.g., via mercury intrusion), allowing τ to be estimated by relating k to models like Kozeny-Carman, where higher τ reduces k for given ε; typical results for packs show τ increasing from 1.1 at ε=0.8 to 2.0 at ε=0.4. Accuracy in these methods relies on calibration against samples with known geometries, such as uniform glass bead packs (τ ≈ 1.4), to validate instrument response and fluid properties, with errors typically below 5% for homogeneous media but rising to 20-30% in heterogeneous samples due to local variations in pore connectivity and partial saturation effects. Post-2000 advancements, including higher-resolution impedance analyzers (sub-mHz frequencies) and multi-gradient NMR sequences, have improved microscale resolution to 10-50 μm, reducing artifacts from sample heterogeneity by enabling shorter diffusion times and better separation of bulk versus restricted diffusion signals. Common error sources include incomplete saturation, temperature fluctuations (±0.1°C control recommended), and surface interactions altering effective pathways, necessitating replicate measurements on multiple core orientations.

Numerical and Image-Based Techniques

Numerical and image-based techniques provide computational frameworks for estimating tortuosity in complex porous structures using digital representations derived from advanced imaging, such as micro-computed tomography (μCT) or (MRI). These methods are essential for analyzing irregular geometries where direct measurement is challenging, enabling the quantification of tortuosity through algorithmic processing of voxelized data. By segmenting the pore space from solid phases in the images, tortuosity can be computed as a structural descriptor that informs transport behavior without relying on physical experiments. A prominent approach involves voxel-based shortest path algorithms applied to segmented 3D images, where tortuosity τ is calculated as the ratio of the average geodesic distance (actual length along connected pores) to the across the domain. , an efficient graph-search method, is commonly used to identify these shortest paths between boundary points or random pairs within the pore network, with τ obtained by averaging over numerous paths to account for heterogeneity. This technique has been implemented in open-source tools like the TORT3D code, which processes 3D images of unconsolidated porous media and demonstrates accuracy comparable to analytical benchmarks for simple structures. For instance, in μCT scans of samples, this method yields τ values around 1.2–1.5, reflecting the winding nature of pore channels. Finite element modeling (FEM) offers an alternative by simulating transport processes, such as steady-state , to derive tortuosity indirectly through effective medium theory. In this method, the governing ∇·(D ∇c) = 0 is solved on a meshed representation of the imaged microstructure, where D is the local (set to D_0 in pores and 0 in solids), yielding the effective diffusivity D_eff from the across the domain; tortuosity is then extracted as τ = ε (D_0 / D_eff), with ε as the . Commercial software like supports these simulations by importing segmented image data and handling anisotropic meshes for high-fidelity results, particularly in fibrous or granular media. Representative applications in show τ values of 2–4, aligning with enhanced path complexity in . Since 2015, approaches, especially convolutional neural networks (CNNs), have gained traction for rapid tortuosity prediction from microstructure images, bypassing iterative simulations. These models are trained on large datasets of synthetic porous media generated via random obstacle placement, learning to map 2D or 3D image features directly to τ values, often alongside and permeability. A seminal CNN implementation achieves prediction errors below 5% for tortuosity in granular packs, enabling inference in seconds on GPU hardware compared to hours for traditional methods. Such techniques are particularly effective for high-throughput analysis of μCT-derived datasets in heterogeneous rocks. Recent extensions as of 2025 include neural networks for thermal tortuosity prediction using macroscopic geometric parameters. Validation of these techniques typically involves cross-comparison with experimental data, such as mercury intrusion porosimetry or NMR diffusion measurements, confirming that numerical τ estimates match within 10% for diverse porous materials like soils and composites. Computational costs, however, escalate with resolution; for grids exceeding 256³ voxels, Dijkstra-based methods may require 1–10 hours on multi-core CPUs due to path enumeration, while FEM simulations on equivalent meshes can demand 24–48 hours or more, necessitating optimizations like or reduced-order modeling for practical use.

Applications

Transport in Porous Media

In porous media such as rocks and soils, tortuosity plays a crucial role in governing flow and mass transport by accounting for the elongated and convoluted nature of pore pathways, which increases flow resistance compared to straight-line distances. The Kozeny-Carman equation integrates tortuosity with to predict permeability, expressed as k = \frac{\varepsilon^3}{(1-\varepsilon)^2} \cdot \frac{d^2}{180 \tau}, where k is the permeability, \varepsilon is the , d is the particle , and \tau is the tortuosity. This formulation highlights how higher tortuosity reduces permeability by lengthening effective flow paths, making it essential for hydraulic modeling in geological formations. For diffusive transport, tortuosity modifies Fick's law through the effective diffusion coefficient D_{\text{eff}} = D_0 \cdot \frac{\varepsilon}{\tau}, where D_0 is the diffusion coefficient, thereby explaining the slowdown of in tortuous pores due to increased path lengths and reduced cross-sectional area availability. This adjustment is particularly important in low-permeability media where dominates over , influencing solute rates. Tortuosity can be estimated from electrical conductivity measurements, as outlined in experimental methods. In geosciences, tortuosity informs predictions of and oil recovery in reservoirs, where typical values range from approximately 2 to 4, reflecting moderate complexity that balances and resistance. For instance, in formations, higher tortuosity correlates with reduced recovery efficiency during operations, guiding to optimize injection strategies. Recent models from the incorporate tortuosity into simulations for CO2 sequestration, using techniques like the Lattice Boltzmann Method to evaluate its effects on injection dynamics and plume migration in heterogeneous aquifers. These simulations demonstrate that tortuosity influences optimal pulsatile injection frequencies, enhancing CO2 displacement by up to 16% in water-saturated media.

Electrochemistry and Energy Storage

In electrochemical systems such as lithium-ion batteries, tortuosity significantly influences and charge within porous electrodes by extending the effective path length for species . In Newman's concentrated solution , the effective ionic in the electrolyte phase of porous electrodes is expressed as D_{\text{eff}} = \frac{\epsilon}{\tau} D, where \epsilon is the electrode porosity, \tau is the tortuosity, and D is the ; this adjustment accounts for the tortuous structure, leading to higher concentration gradients and overpotentials that limit overall cell performance. This framework, foundational to porous electrode modeling, underscores how elevated tortuosity impedes lithium-ion migration, particularly in high-rate operations where rapid charging exacerbates limitations. Quantification of tortuosity in porous electrodes reveals typical values of 3 to 5 for anodes, depending on microstructure and levels around 30-40%; these values arise from the random of active particles and binders, which increase ionic and reduce the effective by factors of 6 to 20. Higher tortuosity directly impairs rate capability by amplifying , resulting in diminished at currents above 1C, and accelerates capacity fade through mechanisms like uneven solid electrolyte interphase (SEI) formation and plating during cycling. Optimization strategies focus on reducing tortuosity through engineered microstructures, particularly in solid-state batteries where ionic transport is more constrained. Post-2020 research has demonstrated that vertically aligned architectures, such as carbon nanotube scaffolds in polymer-based cathodes, can lower the tortuosity factor to 1.5 from typical values of 4-5, enhancing Li⁺ conductivity to 4.25 × 10⁻⁴ S/cm at 40°C and enabling stable cycling at low stack pressures with minimal fade over 100 cycles. These alignments, achieved via 3D printing or shear-induced orientation, create straight ion pathways that mitigate diffusion bottlenecks and improve energy density in all-solid-state systems. In fuel cell applications, tortuosity in gas diffusion layers (GDLs) critically governs oxygen transport to the catalyst layer, where values typically ranging from 2 to 4 in carbon fiber-based GDLs elongate gas diffusion paths and elevate mass transport resistance. The effective oxygen diffusivity follows D_{\text{eff, dry}} = \frac{\epsilon}{\tau} D_{\text{bulk}}, with dry GDLs showing D_{\text{eff}} \approx 0.038 cm²/s at 30°C; under humid operation, water saturation further increases effective tortuosity, reducing diffusivity to 30% of dry values and causing performance losses up to 100 mV at 1 A/cm² due to oxygen starvation. This highlights tortuosity as a key factor in mitigating flooding-related inefficiencies in polymer electrolyte fuel cells.

Biological and Medical Contexts

In biological systems, tortuosity quantifies the deviation from straight-line paths in natural structures such as vascular and neural networks, influencing and physiological . In vasculature, it measures vessel winding, which elevates and impairs ; for instance, coronary tortuosity can increase hemodynamic by up to 92% during exercise, contributing to myocardial ischemia. This effect is pronounced in pathological conditions like tumor , where elevated vessel tortuosity disrupts uniform blood distribution and hinders therapeutic by increasing interstitial pressure and reducing convective . Quantitative vessel tortuosity metrics, such as those derived from , serve as biomarkers for assessing vascular normalization in response to anti-angiogenic therapies. In neural tissues, tortuosity describes the meandering of axonal paths within tracts, which can be quantified using to evaluate microstructural integrity. These MRI-derived measures reveal axonal tortuosity variations linked to neurodegeneration, where increased undulation correlates with axonal loss and demyelination in conditions like . Such assessments help track disease progression by highlighting deviations in fiber orientation and . Physiologically, higher tortuosity in structures like vessels correlates with reduced and tissue hypoxia, elevating metabolic demands for oxygen delivery. In sickle cell retinopathy, for example, increased vessel tortuosity is associated with lower vascular oxygen content, potentially exacerbating energy costs for maintaining in oxygen-sensitive tissues. Advancements in the have integrated computational anatomy for tortuosity quantification in medical diagnostics, particularly for risk prediction. vascular tortuosity features, analyzed via AI-driven imaging, enhance predictive models for incident beyond traditional risk factors, with metrics like arterial inflection count showing significant associations. Similarly, intracranial vessel tortuosity assessments via predict procedural challenges in and correlate with ischemic outcomes.

References

  1. [1]
    Tortuosity in electrochemical devices: a review of calculation ...
    Tortuosity is the fraction of the shortest pathway through a porous structure, vital for mass and charge transport in electrochemical devices.
  2. [2]
    Tortuosity: A brief review - ScienceDirect.com
    Tortuosity describes the sinuosity of the pore space, influencing flux transport in porous media and affecting the flow of diffusion.
  3. [3]
    A Model of Effective Diffusion and Tortuosity in the Extracellular ...
    Tortuosity of the extracellular space describes hindrance posed to the diffusion process by a geometrically complex medium in comparison to an environment ...
  4. [4]
    Evaluation of geometric tortuosity for 3D digitally generated porous ...
    Nov 14, 2022 · Geometric tortuosity plays an important role in characterizing the complexity of a porous medium. The literature on several occasions has ...
  5. [5]
    Tortuosity of porous media: Image analysis and physical simulation
    In contrast to geometrical tortuosity that exclusively depends on the porous microstructure, physical tortuosities are related to both the porous microstructure ...
  6. [6]
    [PDF] Tortuosity and Microstructure Effects in Porous Media - OAPEN Library
    Tortuosity is an important morphological characteristic, which describes the limiting effects of the pore structure on the transport properties of porous media.
  7. [7]
    Review of Theories and a New Classification of Tortuosity Types
    Aug 1, 2023 · In this chapter, a thorough review of all relevant tortuosity types is presented. Thereby, the underlying concepts, definitions and associated theories are ...
  8. [8]
    Permeability of saturated sands, soils and clays
    Mar 27, 2009 · Permeability of saturated sands, soils and clays. Published online by Cambridge University Press: 27 March 2009. P. C. Carman.
  9. [9]
    The Electrical Resistivity Log as an Aid in Determining Some ...
    Journal Paper| December 01 1942. The Electrical Resistivity Log as an Aid in Determining Some Reservoir Characteristics Available. G.E. Archie. G.E. Archie.Missing: URL | Show results with:URL
  10. [10]
    Tortuosity in Porous Media: A Critical Review - ACSESS - Wiley
    Sep 20, 2013 · The concept of tortuosity is used to characterize the structure of porous media, to estimate their electrical and hydraulic conductivity, and to study the ...
  11. [11]
    [PDF] Advances in Transport Phenomena in Porous Media
    This volume contains the lectures presented at the NATO. ADVANCED STUDY INSTITUTE that took place at Newark, Delaware, U.S.A.,. July 14-23, 1985.
  12. [12]
    Microscopic Imaging of Porous Media With X-Ray Computer ...
    Sep 1, 1993 · This paper presents a new method for imaging the 3D microstructure of porous media. The method is based on high-resolution X-ray computer ...
  13. [13]
    Simulation to estimate the correlation of porous structure properties ...
    Highlights. CNN predicts tortuosity from cross-sectional images of lithium-ion batteries. SVR model predicts tortuosity from porosity and particle aspect ratio ...
  14. [14]
    An Alternative Methodology to Compute the Geometric Tortuosity in ...
    Apr 2, 2022 · This study proposes an alternative method to estimate the geometric tortuosity of digitally created two-dimensional porous media.
  15. [15]
    (PDF) How to Calculate Tortuosity Easily? - ResearchGate
    Aug 7, 2025 · Tortuosity, defined as the ratio of the average length of real flow paths to the system length, is another important parameter describing ...
  16. [16]
    Tortuosity of unsaturated porous fractal materials | Phys. Rev. E
    Jul 18, 2008 · It is found that the variation of tortuosity 𝛼 with filling fraction 𝜙 is found to follow a power law of the form 𝛼 ∼ 𝜙 − 𝜖 for both ...
  17. [17]
    Suitability of 2D modelling to evaluate flow properties in 3D porous ...
    Jul 23, 2020 · The limitations of such approaches are often overlooked. Here, we assess to which extent 2D flows in porous media are suitable representations ...
  18. [18]
    [1203.5646] How to Calculate Tortuosity Easily? - ar5iv - arXiv
    Figure 5: Hydraulic tortuosity, T , computed using Eq. (5) in a U-shaped channel as a function of the relative step depth b / H 𝑏 𝐻 b/H for two channel heights ...
  19. [19]
    Tortuosity and the Averaging of Microvelocity Fields in Poroelasticity
    The fabric tensor, a 3D measure of the architecture of pore structure, was introduced in the expression of the tortuosity tensor for anisotropic porous media.
  20. [20]
  21. [21]
    (PDF) Tortuous Flow in Porous Media - ResearchGate
    Aug 7, 2025 · Hydraulic tortuosity in porous media is typically defined as the ratio of the average length of the actual flow path (L a ) to the geometric ...
  22. [22]
    TORT3D: A MATLAB code to compute geometric tortuosity from 3D ...
    In this paper, an algorithm was developed and implemented as a MATLAB code to compute tortuosity from three-dimensional images.
  23. [23]
    Prediction of the Effective Diffusion Coefficient in Random Porous ...
    Aug 7, 2025 · A finite-element-based method is presented for evaluating the effective gas diffusion coefficient of porous solids.
  24. [24]
    Predicting porosity, permeability, and tortuosity of porous media from ...
    Dec 8, 2020 · It is shown that the CNNs can be used to predict the porosity, permeability, and tortuosity with good accuracy.Missing: post- | Show results with:post-
  25. [25]
    [PDF] 1 KOZENY-CARMAN EQUATION REVISITED Jack Dvorkin
    The Kozeny-Carman equation is often presented as permeability versus porosity, grain size, and tortuosity. When it is used to estimate permeability ...
  26. [26]
    Critical review of the impact of tortuosity on diffusion - ScienceDirect
    In this paper we present a review of theoretical and empirical models that incorporate tortuosity in the diffusion coefficient.
  27. [27]
    [PDF] 1999: A Systematic Study for Selecting an Adequate Tortuosity Model
    With the exception of Faris model (Perkins, 1963), and Dogu and Smith's (1975), tortuosity values for sandstone rocks seem to range between approximately 2 and ...
  28. [28]
    Isothermal CO2 injection into water-saturated porous media
    Aug 1, 2023 · The Lattice Boltzmann Method (LBM) is used to simulate the isothermal injection of CO2 into a water-saturated, homogeneous porous medium.
  29. [29]
    The electrode tortuosity factor: why the conventional ... - Nature
    Aug 14, 2020 · The tortuosity factor of porous battery electrodes is an important parameter used to correlate electrode microstructure with performance through numerical ...
  30. [30]
    Quantifying Tortuosity of Porous Li-Ion Battery Electrodes
    Aug 22, 2018 · This paper compares two experimental methods that determine tortuosity based on diffusivity or conductivity.
  31. [31]
    Tortuosities of porous graphite electrodes without conductive carbon...
    They reported tortuosity factor values of approximately 2.8 for 1.5 wt%, around 3.1 for 3 wt%, and 5.2 for 10 wt%. ...
  32. [32]
    Enhancing rate capability of graphite anodes for lithium-ion batteries ...
    Dec 1, 2021 · Tortuosity (τ) can be calculated as follows [19](3) τ = R i o n · A · k · ε 2 d where A, d, and ε are the surface area, thickness, and porosity ...
  33. [33]
    Effect of Porosity, Thickness and Tortuosity on Capacity Fade of Anode
    The impact of porosity of a negative electrode containing a silicon/carbon/graphite composite on the cycling performance of 18650 cells with a NMC-based cathode ...
  34. [34]
    Increasing the Discharge Rate Capability of Lithium-Ion Cells with ...
    May 23, 2018 · This particle orientation implies a strong tortuosity anisotropy within the graphite anodes ... anodes already showed a capacity fade toward 65%.
  35. [35]
    Enhancing cathode composites with conductive alignment synergy ...
    Jan 3, 2025 · Enhancing transport and chemomechanical properties in cathode composites is crucial for the performance of solid-state batteries.
  36. [36]
    [PDF] Tailored Cathode Composite Microstructure Enables Long Cycle ...
    Jan 25, 2025 · Moreover, the composite features reduced tortuosity, which enhances Li ion conduction. These microstructural advantages result in significantly ...
  37. [37]
    Determination and Engineering of Li‐Ion Tortuosity in Electrode ...
    May 22, 2024 · This article delves into why understanding and controlling tortuosity is essential for improving battery performance.
  38. [38]
    Insights into Oxygen Transport Properties of Partially Saturated Gas ...
    Apr 28, 2023 · The oxygen transport performance in PEFCs is mainly limited by the catalyst layer (CL) and the gas diffusion layer (GDL). The local oxygen ...
  39. [39]
    On Tortuosity and Water Management in Hydrophobic ... - IOP Science
    Mar 27, 2025 · To improve mass transport limitations in proton exchange membrane fuel cells (PEMFCs), a detailed analysis of the gas diffusion layer ...
  40. [40]
    Effects of gas-diffusion layer properties on the performance of the ...
    Aug 19, 2023 · The primary objective of this research is to determine the impact of GDL transport characteristics on the performance of HT-PEMFCs cathode.
  41. [41]
    (PDF) In-Plane Effective Diffusivity in PEMFC Gas Diffusion Layers
    Aug 6, 2025 · This method was based on the transient diffusion of oxygen from air into an initially nitrogen purged porous sample and has proven to be ...
  42. [42]
    Impact of coronary tortuosity on the coronary blood flow - PubMed
    Jul 26, 2013 · The resistance of the coronary arteries increased up to 92% due to the CT during exercise. A maximum increase of 96% was observed in the mean ...
  43. [43]
    A tumor vasculature–based imaging biomarker for predicting ...
    Nov 25, 2022 · We present a new imaging biomarker, quantitative vessel tortuosity (QVT), and evaluate its association with response and survival in patients ...Results · Materials And Methods · Vascular Feature Extraction<|separator|>
  44. [44]
    [PDF] Diffusion distinguishes between axonal loss and demyelination in ...
    In this work, we establish for the first time that the AWF is most sensitive to axonal loss, while the EAS tortuosity is most sensitive to demyelination. For ...Missing: path τ 1.1-1.5
  45. [45]
    Relationship between retinal vessel tortuosity and oxygenation in ...
    Nov 18, 2019 · Reduced retinal vascular oxygen (O2) content causes tissue hypoxia and may lead to development of vision-threatening pathologies.Image Acquisition And... · Vascular Oxygen Content · Vessel Tortuosity IndexMissing: costs | Show results with:costs
  46. [46]
    Retinal vascular fingerprints predict incident stroke - Heart
    Tortuosity. Among 30 parameters extracted using 10 extraction methods, only arterial inflection count tortuosity was found to be associated with stroke risk. ...
  47. [47]
    Impact of intracranial vessel tortuosity on mechanical thrombectomy ...
    Aug 13, 2025 · Conclusions: Intracranial vessel tortuosity reduces recanalization success and increases procedural challenges. Its impact on complications and ...