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Citronella oil

Citronella oil is a pale yellow to brownish extracted through from the leaves and stems of lemongrass species, primarily Cymbopogon nardus (Ceylon citronella) and Cymbopogon winterianus (Java citronella), which are native to tropical regions of and cultivated in areas such as and the . The name "citronella" derives from the "citronnelle," meaning "little ," referring to its citrus-like scent. It has been used traditionally in for centuries as an and in medicinal practices, with commercial production beginning in the late . This volatile oil possesses a strong, fresh, lemon-like aroma and serves as a natural , with primary applications as an , fragrance ingredient, and flavoring agent. Chemically, citronella oil is a complex mixture of monoterpenes, with key constituents including (typically 25–45%), (15–30%), (10–20%), and (3–10%), varying by grass variety and growing conditions. These compounds contribute to its , antibacterial, and insecticidal properties, enabling it to mask scents that attract pests like mosquitoes and body lice without directly killing them. In the United States, it has been registered as a minimum-risk since 1948 and is classified as (GRAS) by the FDA for use in foods, beverages, and cosmetics at low concentrations. Beyond —where it provides short-term protection (up to 2 hours at 10% concentration in topical formulations)—citronella oil is incorporated into household products such as candles, lotions, sprays, and pet collars, as well as in perfumery and soaps for its uplifting . While generally low in , with oral and dermal LD50 values exceeding 4,000 mg/kg in animal studies, it can cause mild or allergic reactions in sensitive individuals, and its use is not recommended for children under 6 months without medical advice.

Overview

Definition and Botanical Sources

Citronella oil is an extracted primarily through from the leaves and stems of specific species in the family. This process yields a volatile product valued for its aromatic qualities, with the oil serving as a key ingredient in various natural formulations. The primary botanical sources are (L.) Rendle, native to and tropical regions of and , which produces the Ceylon type of citronella oil, and Cymbopogon winterianus Jowitt, a cultivated hybrid variety originating from southern or and introduced to , , used for the Java type. These perennial, tufted grasses thrive in tropical climates, reaching heights of up to 2 meters, with aromatic leaves that contain glandular structures rich in oil-producing compounds. Physically, citronella oil presents as a pale to brownish liquid possessing a fresh, citrusy, lemon-like aroma. Its density typically ranges from 0.89 to 0.93 g/cm³, while the falls between 1.47 and 1.49 at 20°C, characteristics that aid in assessing its purity and quality. Citronella oil is distinct from related essential oils such as lemongrass oil, derived from (DC.) Stapf, due to its unique composition that enhances its profile as an effective natural .

History and Etymology

The term "" derives from the French word citronelle, a form of meaning "," reflecting the oil's characteristic citrus-like aroma. This nomenclature first appeared in European documentation around 1858, referring to the fragrant oil extracted from Asiatic grasses used in perfumes and soaps. Citronella oil has been employed in traditional and for centuries to treat rashes, , and , often as an aromatic tea or topical remedy. In Southeast Asian folk practices, it served as a natural and remedy for conditions, while in Ayurvedic traditions, it was valued for alleviating digestive issues. The oil was introduced to in the through colonial trade routes from Ceylon (modern-day ) as a novel and fragrance ingredient. Commercial production commenced in () in the late , leveraging the region's tropical climate for large-scale cultivation of the grasses. During the (1837–1901), citronella gained adoption in European perfumery for its fresh, uplifting scent in soaps and colognes. Its role expanded significantly as a mosquito repellent during , earning a reputation in military applications for protecting troops from insect-borne diseases. This usage intensified in , where citronella-based formulations were standard in repellents before more advanced synthetics emerged, contributing to a post-war surge in household products like candles and sprays.

Chemical Composition

Primary Constituents

Citronella oil consists predominantly of volatile monoterpenoids and sesquiterpenes, including aldehydes, alcohols, and , with no fixed oils present. These compounds contribute to its characteristic aroma, , and bioactivity. The oil exhibits optical activity, with a typically ranging from -5° to +5°. The primary constituents are , , and . , the main , comprises 25-48% of the oil and provides its distinctive lemony scent while enhancing repellent action. , an making up 15-30%, imparts floral notes and supports properties. , another at 10-20%, contributes to the oil's overall . Minor constituents include (up to 10%), a responsible for additional citrus aroma; trace amounts of , adding subtle woody undertones; and methyl isoeugenol in some variants, which introduces spicy notes. The chemical profile is analyzed using gas chromatography-mass spectrometry (GC-MS) for precise identification and quantification of components. International standards, such as ISO 3848 for Java-type citronella oil, ensure quality by specifying minimum levels of total alcohols and aldehydes (at least 80%) and key individual compounds like citronellal.

Variations Between Types

Citronella oil derived from the Ceylon type, obtained from , typically exhibits an oil yield of 0.8-1.5% from fresh leaves, with key constituents including at 5-15%, at 18-20%, and below 10%. This composition results in a milder, more balanced aroma compared to other variants, making it suitable for applications where subtlety is preferred, though its lower concentrations of active aldehydes contribute to reduced overall potency. In contrast, the Java type, sourced from Cymbopogon winterianus, offers a higher oil yield of 1-2% from leaves, featuring elevated levels of at 32-45%, at 21-24%, and at 11-15%. These proportions account for a sharper, more pungent scent and greater total active compound content, enhancing its commercial value for industrial extraction and formulation. The differences in chemical profiles significantly influence suitability: the Java type's higher geraniol and citronellal levels make it preferable for insect repellents due to enhanced efficacy, while the Ceylon type's more equilibrated makeup suits perfumery for its softer profile. The Java type originated as a hybrid from crosses involving Ceylon varieties introduced to Java in the late 19th century by Dutch cultivators, leading to selective breeding for superior oil quality. Quality grading for citronella oil primarily relies on content, with Indonesian regulations mandating a minimum of 35%. Adulteration risks are notable, particularly with synthetic added to boost apparent aldehyde levels and reduce costs, necessitating analytical verification for authenticity.

Types of Citronella Oil

Ceylon Type

The Ceylon type of citronella oil is derived from , a , clump-forming, evergreen grass native to (formerly Ceylon) and belonging to the family. This species typically grows to a height of up to 1.5 meters, featuring long, narrow, bright green leaves that arise from a stout , with a characteristic citrus-like aroma emanating from its foliage. Unlike faster-maturing hybrids, C. nardus exhibits relatively slower growth, thriving in tropical climates with well-drained, sandy soils and requiring 1,800–2,500 mm of annual rainfall. Production of Ceylon citronella oil is centered primarily in , with significant cultivation also occurring in and parts of tropical , where the plant is grown on marginal, infertile coastal soils. Historically, served as the epicenter during the colonial era, with large-scale plantations established in the early to meet export demands for essential oils, marking the region's role as a key supplier since the 1900s. Distinct from other varieties, the Ceylon type possesses a softer, more lemony aroma with subtle woody undertones, attributed to its chemical profile rich in (up to 60%) and (about 15%), lending it a fresher, less pungent scent suitable for delicate applications. It generally yields lower oil quantities—typically 0.5–1% from —compared to higher-output types, yet this results in a purer, more refined composition ideal for fine fragrances and therapeutic uses. Traditionally, in , the oil has been incorporated into local and oils for its aromatic and insect-repelling properties. In the market, Ceylon citronella oil holds a niche preference in for formulating soaps, candles, and perfumes, where its milder profile enhances subtle scent blends without overpowering other notes. Export-quality production adheres to international standards such as ISO 3849:2003, which specifies characteristics like a pale yellow to brownish-yellow color, relative density of 0.888–0.908, and a to ensure consistency and purity for global trade.

Java Type

The Java type of citronella oil is derived from winterianus, a robust, perennial, clump-forming grass in the family that reaches heights of up to 2-3 meters, featuring long, linear, leathery, light green leaves that are broader and more vigorous than those of the Ceylon type. This hybrid variety originated from crosses between (Ceylon citronella) and related species, developed through selective cultivation in , , in the early to enhance yield and aroma potency. The plant exhibits faster maturation and greater hybrid vigor, allowing for denser planting and quicker harvests compared to the milder Ceylon variant. Production of Java citronella oil is dominated by , where it originated from pre-1900 plantations, alongside major contributions from and , which together account for a significant portion of global output. These regions leverage the plant's adaptability to tropical climates for large-scale cultivation, with and producing over 40% of the world's supply. The variety's establishment in Indonesian estates post-1900 facilitated its spread to other areas, emphasizing its role in . Distinctive traits of the Java type include its intense, camphoraceous scent—characterized by fresh, lemony, and slightly woody notes—that arises from elevated levels of key compounds, making it more pungent than the sweeter, grassy profile of Ceylon oil. It offers higher yields, typically 1-2% by fresh weight, and greater concentrations of active components like (35-45%) and (20-30%), enhancing its efficacy for applications. These attributes render it particularly suited for industrial-scale production of repellents, where its robust growth and superior extraction efficiency provide economic advantages over the Ceylon type. In the market, Java citronella oil holds a prominent niche in , particularly for pesticides, cosmetics, and perfumery, driven by its higher purity and versatility in formulations. Its elevated active compound levels contribute to greater export value, with the type commanding about 57% of global due to efficiency and in repellent products.

Production

Cultivation Practices

Citronella grass thrives in tropical and subtropical climates with temperatures ranging from 20°C to 38°C and annual rainfall of 2000 to 2500 mm, though it can tolerate lower rainfall with supplemental irrigation. High humidity above 70% supports optimal growth, while frost or prolonged dry spells can hinder development. The plant prefers well-drained sandy loam soils rich in organic matter, with a pH between 5.0 and 7.0; heavy clay or waterlogged soils should be avoided to prevent root rot. Practices are similar for both Ceylon (Cymbopogon nardus) and Java (Cymbopogon winterianus) types, though the Java type often produces higher biomass under optimal conditions. Propagation occurs primarily through slips from mature clumps containing 2-3 tillers, though can be used less commonly; planting is ideally done at the onset of the monsoon season or under irrigated conditions in early . Slips are spaced at 60 cm x 45 cm (or 45 x 45 cm in fertile soils) to allow for tillering, accommodating about 30,000-40,000 plants , and planted 5-8 cm deep in prepared beds. The crop establishes within 1-2 months, achieving full ground cover in 30-40 days, and remains productive as a for 4-6 years before replanting is necessary. Harvesting begins 4-6 months after planting with the first cut at 15-20 cm above ground, followed by subsequent harvests every 2-3 months to maintain oil quality; typically, 3-4 cuts occur annually in the first year, increasing to 5-6 in subsequent years. Regular fertilization with , , and (e.g., 200:80:75 kg/ha/year) and every 10-15 days during dry periods enhance vigor and leaf production. Citronella grass is susceptible to fungal diseases like (caused by spp.) and , as well as pests including stem borers, mites, and nematodes that damage and foliage. management is preferred in sustainable systems, utilizing applications to deter by disrupting feeding and growth cycles, while with improves soil nitrogen and reduces pest incidence through . Chemical controls like for borers or fungicides for are alternatives but less favored for environmental reasons. Annual fresh leaf yields range from 20 to 30 tons per , varying with , , and management; the Java type (Cymbopogon winterianus) typically produces higher biomass and oil content compared to the Ceylon type (Cymbopogon nardus).

Extraction Methods

The primary method for extracting citronella oil is , which accounts for approximately 93% of global production, including citronella. In this process, fresh or dried leaves and stems of the Cymbopogon plant are placed in a distillation apparatus where at 100–120°C is passed through the plant material for 2–4 hours, volatilizing the essential oils that are then condensed and collected. This method yields 0.8–2% oil by weight from the plant material, depending on factors such as plant variety and processing conditions. Alternative extraction techniques are used less frequently but offer advantages in specific scenarios. Water distillation, a traditional hydro-distillation variant, involves the plant material directly in water, though it is less efficient due to longer extraction times and potential of volatile compounds. Solvent , employed rarely for producing absolutes, uses organic solvents like to dissolve the oils, followed by solvent evaporation, but it may introduce impurities unsuitable for therapeutic applications. Supercritical CO2 represents a approach, utilizing under high pressure and moderate temperatures to selectively extract heat-sensitive components while preserving their integrity, though it requires specialized equipment and is not yet widespread for . Following , the crude oil mixture, which includes water and hydrosol, undergoes separation through or to isolate the oil layer. The oil is then dried using to remove residual moisture, ensuring stability. For long-term preservation, the dried oil is stored in dark containers at 10–20°C to minimize oxidation and light-induced degradation. Quality control in extraction focuses on optimizing parameters to maximize retention of key components like , as efficiency variations can reduce its concentration by up to 20–30% in suboptimal conditions. Additionally, post-extraction , such as leaf residues, is often utilized as organic mulch to suppress weeds and enhance retention in subsequent cultivations.

Uses and Applications

As an Insect Repellent

Citronella oil serves as a natural primarily through its volatile compounds, which mask human scents attractive to pests and interfere with their olfactory receptors. The key active ingredients, and , evaporate readily, creating a scent barrier that confuses ' sensory detection of hosts. Common formulations include topical lotions and creams at concentrations of 5-10%, which are applied directly to the skin for personal protection. Sprays and aerosols disperse the oil into the air or onto surfaces, while candles and torches release vapors through burning, providing area-wide repellency in outdoor settings. For enhanced duration, citronella oil is often combined with , which slows evaporation and prolongs the masking effect. It targets a range of pests, proving effective against mosquitoes such as and species, as well as flies and moths. However, its efficacy is reduced against ticks and bees, where it offers limited deterrence compared to other . Historically, citronella oil has been incorporated into candles since the for outdoor . In modern applications, it holds EPA-registered status as a minimum-risk under 25(b), allowing its inclusion in over-the-counter repellent products without full registration requirements.

Other Commercial and Therapeutic Uses

Citronella oil serves as a base note in perfumes due to its fresh, citrusy aroma, and is incorporated into cosmetics such as soaps and shampoos at dilutions typically ranging from 1% to 5% to provide fragrance without causing irritation. Its strong scent also helps mask odors in household detergents, enhancing their fresh profile. In , citronella oil is employed for relief, with reported to lower and while refreshing mood, though clinical evidence remains preliminary. Topically, when diluted, it is used for oily and , leveraging the properties of its geraniol component to soothe and reduce . Limited evidence supports its and antibacterial effects, attributed to compounds like , making it suitable for minor applications in diluted form. The U.S. recognizes citronella oil as (GRAS) for use as a agent, permitting its addition in small amounts to impart a citrus-like note in foods such as candies and beverages. Typical concentrations range from 3 to 35 parts per million, including in liqueurs where levels below 0.1% enhance flavor without overpowering other ingredients. Industrially, citronella oil functions as a natural fragrance in candles, contributing to their aromatic appeal. Its properties enable use as a in films to extend by inhibiting microbial growth. In , it acts as an to protect crops from pests. Residues from citronella production show potential, with of spent waste yielding up to 37.7% bio-oil, offering a pathway.

Efficacy and Safety

Scientific Studies on Efficacy

Scientific studies have extensively evaluated the efficacy of citronella oil, particularly its primary use as an , with s confirming moderate short-term protection against mosquitoes. A 2011 of 11 controlled laboratory studies found that citronella oil provided protection times of at least 1.5 hours against Aedes spp., 3 hours against Anopheles spp., and 5 hours against Culex spp., with citronella plus extending protection up to 6 hours in some cases. Citronella was less effective in duration than . At concentrations of 10%, citronella oil provided around 60 minutes of protection against Anopheles stephensi in laboratory settings. Field trials have shown variability, achieving 50-90% reduction in bites for 1-2 hours depending on formulation and environmental factors. In comparison, formulations consistently offered longer protection, up to 5 hours or more, highlighting citronella's relative inferiority in duration. Beyond repellency, research supports citronella oil's properties, including activity against . A 2022 study on reported minimum inhibitory concentrations () of 256 µg/mL against C. albicans, with significant inhibition of formation. Earlier work in 2016 identified , a key component, with an MIC of 1000 µg/mL against C. albicans strains, demonstrating dose-dependent growth suppression without notable at effective concentrations. In contexts, of citronella oil has shown promise for reducing anxiety. A 2012 clinical study found that of citronella oil increased pleasant (e.g., feeling relaxed and calm) per the Geneva and Scale, with effects within minutes, and increased alpha and wave activity indicating relaxation. These findings align with broader evidence for essential oils in stress modulation. As of 2023, reviews continue to support citronella's role as a natural alternative, though with calls for more field studies on long-term use. The efficacy of citronella oil is influenced by its high , which contributes to its short protection duration as an repellent; studies indicate rapid limits topical applications to under 2 hours without stabilizers. Synergistic formulations, such as those incorporating p-menthane-3,8-diol (PMD)—a derived from citronella-related terpenoids—can extend protection to 4-6 hours by reducing rates and enhancing adherence. PMD-based products, often comprising 64-72% PMD in commercial formulations, provide comparable efficacy to in some trials while maintaining a natural profile. Despite these findings, limitations persist in the research on citronella oil's efficacy. Protection varies significantly by mosquito species, with reduced performance against compared to in some studies, and there are few long-term human trials assessing repeated exposure effects. The recognizes plant-based repellents like citronella as viable natural alternatives for prevention in resource-limited settings, but recommends them as supplements to primary methods like rather than standalone solutions.

Health Risks and Precautions

Citronella oil is classified as (GRAS) by the U.S. (FDA) for use as a agent and in external applications, such as in and repellents, under 21 CFR 182.20 for oils. It exhibits low , with an oral LD50 greater than 5 g/kg in rats, indicating minimal risk from incidental ingestion in small amounts. Dermal LD50 values exceed 4.7 g/kg in rabbits, further supporting its low toxicity profile for topical use when properly diluted. Potential adverse effects include skin irritation and , reported in approximately 1-2% of tested individuals in with 2% concentrations, though higher rates up to 5% may occur in sensitive populations; a is recommended prior to widespread application. Undiluted citronella oil can cause serious eye irritation upon contact. is not advised, as it may lead to , , or more severe gastrointestinal distress, potentially fatal in large doses. Use is not recommended during due to insufficient data. For children, topical application is possibly safe over 6 months old when diluted and avoiding eyes or mouth; oral use is unsafe in children. Precautions include diluting citronella oil to 1-2% in a or for safe topical application to minimize irritation risks, as recommended by guidelines. Although not highly phototoxic like certain oils, direct exposure after skin application should be limited to prevent potential mild sensitization. Citronella oil may interact with sedative medications, such as , by enhancing drowsiness through modulation, so caution is advised for individuals on such treatments. Regulatory guidelines affirm its safety for approved uses: the U.S. Environmental Protection Agency (EPA) exempts citronella oil from federal insecticide tolerances as a minimum-risk biopesticide under 40 CFR 152.25(f), allowing its use in over-the-counter repellents without residue limits. In the European Union, citronella oil (CAS 8000-29-1) is registered under the REACH regulation (EC) 1907/2006, ensuring compliance with chemical safety assessments for cosmetic and pesticide applications. Product labels must include warnings for asthma sufferers, as inhalation of citronella oil vapors may trigger bronchoconstriction or exacerbate respiratory symptoms in sensitive individuals.

Global Production and Market

Major Producing Regions

Indonesia is a leading producer of citronella oil globally, alongside , with the two countries together accounting for approximately 40% of worldwide supply, primarily through cultivation of the Java type (Cymbopogon winterianus). The country's volcanic soils, particularly in regions like , provide rich mineral content that enhances plant growth and oil yields. Export activities are facilitated through major ports such as , supporting shipments to international markets. China ranks as a significant producer, with production concentrated in southern provinces like where hybrid cultivation practices are employed to improve resilience and yield. Sri Lanka serves as the origin of the Ceylon type (Cymbopogon nardus), supported by monsoon climates that enable organic farming methods in southern areas. The island's port acts as a key export hub for raw oil. In , cultivation is prominent in and , where the crop benefits from tropical conditions suitable for both Java and Ceylon varieties and contributes significantly to global supply. Emerging production occurs in , which focuses on regional supply chains to meet local demand and reduce import reliance, and , where limited cultivation persists despite historical declines. Citronella oil production predominantly involves smallholder farmers across , providing essential income and bolstering rural economies through . However, challenges such as climate change-induced variations in rainfall threaten yield consistency in monsoon-dependent areas. Trade in citronella oil is largely export-oriented, with around 80% shipped as raw material for processing abroad; primary importers include the , countries, and , which utilize the oil in repellents, perfumes, and pharmaceuticals. Global production of citronella oil stands at approximately 4,000 metric tons annually as of 2025, with the market valued at around USD 520 million. The industry has experienced a (CAGR) of about 5.3% in recent years, fueled by rising consumer preference for natural and plant-based products in repellents and personal care applications. Key trends include a notable shift toward , driven by demand for sustainable and eco-friendly alternatives, with variants showing accelerated growth in major markets. The Java type of citronella oil accounts for roughly 57% of total output, primarily sourced from . Additionally, post-2020 supply chain disruptions from the , including lockdowns and transportation delays, led to reduced availability and price increases of approximately 15-20% in key producing regions. Projections indicate the market will reach USD 871.5 million by 2035, maintaining a CAGR of 5.3%, supported by expanding use in eco-friendly repellents and . However, competition from synthetic alternatives poses ongoing challenges to growth. Major producing countries contribute significantly, with and together accounting for about 40% of global output, equating to roughly 1,600 metric tons combined annually.

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