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Shives

Shives, also known as hurds, shoves, or boon, are the lignocellulosic woody cores separated from the fibers during the mechanical processing of stems from such as (Linum usitatissimum), (), and ( spp.). These rigid, fibrous residues represent the inner structural component of the stem, contrasting with the flexible outer fibers used primarily for textiles like , , and burlap. In the production process, shives are isolated through a series of steps beginning with , where enzymes or microbes break down the binding the fibers to the woody , followed by breaking to the , to scrape away the shives, and hackling to align and clean the remaining fibers. This yields shives comprising 50–70% of the dry weight, positioning them as the primary by-product of the bast fiber industry. Historically underutilized as , shives have gained recognition for their sustainable potential due to their abundance, low cost, and composition rich in (35–45%), (20–30%), and (20–25%). Contemporary applications of shives span multiple sectors, leveraging their absorbent, lightweight, and biodegradable properties. In and , they serve as material for , offering superior moisture absorption compared to traditional options like . In and manufacturing, shives are incorporated into particleboards, fiber-reinforced composites, and for eco-friendly building materials, enhancing mechanical strength while reducing reliance on virgin wood. Additionally, their porous structure enables use as adsorbents for , removing and dyes, and as feedstocks for via or production. Ongoing research emphasizes shives' role in circular economies, with innovations in particle size optimization and chemical modification expanding their viability in and .

Definition and Sources

Definition

Shives are the short, woody core fragments, also known as hurds or shoves, that remain after the mechanical separation of bast fibers from the stems of bast fiber plants such as ( usitatissimum) and (). These fragments consist primarily of the lignified tissue in the plant's inner core, which is shorter and more rigid compared to the elongated bast fibers extracted for use. The term "shives" derives from the Middle English "shif" (plural "shives"), attested in the late to describe particles of husk produced after beating the stems during preparation. This usage traces back to "scheve" or "schif," meaning "," and is possibly connected to an Old English root "*scīfe" denoting a split or fragment. In some contexts, "shives" is used interchangeably with "hurds," particularly in processing, though "hurds" is more specifically applied to the woody core of hemp stems. Shives are conceptually distinct from bast fibers, which form continuous bundles in the phloem layer of the stem's outer and are prized for their length and strength in applications like cordage and fabrics. In contrast, shives represent the brittle, splintered inner woody material that must be removed to isolate the layer, highlighting the anatomical separation between the plant's supportive core and its fibrous exterior. This differentiation is fundamental to bast fiber , where shives emerge as a byproduct of breaking and . The historical naming of shives emerged within medieval fiber industries, particularly in flax cultivation regions like those in the and , where manual and early mechanical beating techniques routinely generated these core splinters as a processing residue. By the , the term was standardized in industrial contexts to denote this specific waste material, reflecting centuries of refinement in separating usable fibers from the plant's structural core.

Plant Sources

Shives are primarily derived from bast fiber plants, including (Linum usitatissimum), (), ( spp.), and (Hibiscus cannabinus). These annual dicotyledonous plants produce fibers in the layer of their stems, with the inner woody core forming the shives after mechanical separation. Botanically, these plants feature slender, upright stems that are typically hollow, consisting of an outer bast layer surrounding a central pithy core that lignifies into shives. Flax stems reach heights of 0.6 to 1.2 meters with a diameter of 1-2 mm, hemp stems grow 1.5 to 5 meters tall and 5-15 mm in diameter, jute stems reach 2.5 to 3.5 meters with basal diameters of about 20-25 mm, while kenaf stems can exceed 3-4 meters with diameters up to 25 mm, all contributing to substantial shive production potential. Shive yields vary by plant but generally constitute the majority of stem dry weight: approximately 70% for , 70-75% for , 60% for , and 60-70% for , with the remainder primarily fibers. These percentages reflect the plants' structure, where the woody core provides structural support while allowing efficient water transport through the hollow lumen. Flax is predominantly cultivated in temperate regions of and , such as , , and , where cool, moist climates favor its growth. Hemp is grown globally, with major production in , , and , particularly emphasizing low-THC industrial varieties following legalization trends in the 1990s and 2000s that expanded for non-drug purposes. Jute thrives in tropical regions, primarily in and , which account for over 90% of global production as of 2023. Kenaf thrives in subtropical and tropical areas, including , , and the , benefiting from warmer conditions that support its rapid biomass accumulation. Shive quality differs by plant variety; for instance, fiber-type cultivars produce taller stems with higher bast-to-core ratios, yielding denser, more uniform shives compared to oilseed varieties, which prioritize seed production and result in shorter stems with potentially finer but lower-volume shives. These variations influence shive suitability for downstream applications, though isolates them from all types.

Production

Decortication Process

The process serves as the primary mechanical method for separating fibers from the woody core, known as shives, in plants such as and . This technique has been central to fiber production since the , when early methods dominated in , involving labor-intensive steps to process retted stems. Industrial scaling occurred in the 20th century, particularly for processing, driven by that enabled large-scale operations and improved economic viability. The process begins with breaking, where dried, retted stems are crushed between fluted rollers or similar mechanisms to fracture the woody core without damaging the outer bast fibers. This is followed by , in which rotating blades or swinging knives scrape away the broken shives and short s, cleaning the longer fiber bundles. The final step, hackling, uses comb-like structures to align and further separate the fibers, removing any remaining woody and producing refined fiber ready for spinning or other uses. Decorticators, the key machinery, were developed in the late , with significant improvements patented in 1917 by George W. Schlichten in the , leading to powered variants for widespread adoption. Common types include roller mills, which use paired rollers to crush and separate, and hammer mills, employing rotating hammers for more aggressive breaking suitable for tougher stems. Modern automated systems integrate these steps into continuous lines, often incorporating for dust removal, enhancing throughput to several tons per hour. Efficiency metrics highlight the process's output: typical yield rates from dry stem weight are 25-30% bast fiber and 70-75% shives for , with yielding slightly higher fiber proportions around 35-40%. varies by scale but averages approximately 90-100 kWh per ton of processed material in contemporary operations.

Alternative Extraction Methods

While mechanical decortication serves as the baseline for shive isolation from bast plants like flax and hemp, alternative methods focus on chemical, biological, and advanced physical treatments to facilitate separation by degrading pectins and other binders in the stem. Chemical retting employs alkali solutions, such as sodium hydroxide (NaOH), or enzymatic treatments to soften plant stems prior to shive separation, yielding fibers with enhanced purity due to reduced lignin and pectin residues. For instance, alkaline retting under controlled conditions (e.g., 1-5% NaOH at 50-80°C) effectively dissolves non-fibrous components, allowing cleaner shive isolation compared to untreated stems. Enzymatic retting uses pectinase-rich mixtures like Flaxzyme or Ultrazym, applied at pH 5-7 and 40-50°C for 4-24 hours, which selectively hydrolyzes pectins for precise fiber-shive demarcation without excessive fiber damage. These approaches improve shive yield by 10-15% in flax through better stem breakdown, though they require neutralization steps to manage effluent. Biological retting relies on microbial action, often involving bacteria such as species, to enzymatically degrade stem binders in a controlled, eco-friendly manner. In water retting variants, stems are submerged for 5-14 days at 25-30°C, where pectinolytic produce enzymes that break down hemicelluloses and pectins, facilitating shive release with minimal mechanical input. This method, common for , achieves uniform retting through microbial succession (e.g., initial dominance followed by ), resulting in shives with lower contamination from epidermal tissues. Its environmental benefits include reduced chemical use and wastewater compared to processes, aligning with practices. Biological methods like microbial retting typically consume 20-30% less energy for the mechanical separation step than traditional mechanical following field retting (e.g., ~70-80 kWh/ton total for ), primarily due to ambient conditions and easier decohesion with no heavy machinery. Emerging technologies like and supercritical CO₂ extraction enable high-purity shive isolation by combining thermal, pressure, and solvent effects. involves saturating stems with steam at 180-220°C and 10-20 bar for 1-5 minutes, followed by rapid , which fragments the core and separates shives from fibers through autohydrolysis of lignocellulosic bonds. This technique, developed in the 1980s-1990s for lignocellulosic materials including , enhances shive accessibility for downstream uses by delignifying up to 20-30% of the core material. Supercritical CO₂ extraction, using CO₂ at 31-40°C and 200-300 bar with co-solvents like , degums stems by penetrating and dissolving pectins, promoting fiber-shive decohesion without water or harsh chemicals; studies from the 2010s show it increases shive purity by improving inter-fiber separation in . In terms of efficiency, chemical and emerging methods offer trade-offs, with achieving faster throughput (seconds per batch) at moderate (100-150 MJ/ton) but requiring specialized equipment, while supercritical CO₂ provides solvent-free purity at higher . Overall, these alternatives prioritize and quality over the speed of traditional approaches.

Properties

Physical Characteristics

Shives are the woody core fragments remaining after the decortication of bast fiber plants like hemp and flax, typically appearing as irregular, elongated particles. These particles generally range in length from 7 to 15 mm and width from 2 to 4 mm, depending on the grade and processing method, with finer grades having median lengths around 7.5 mm and coarser ones up to 15 mm. Their shape is often needle-like for flax shives and more rectangular for hemp hurds, contributing to their irregular woody fragment form. Bulk density varies from 80 to 160 kg/m³ in the dry state, with typical values of 85–90 kg/m³ for hemp shives, making them lightweight aggregates suitable for various applications. The texture of shives features a highly porous structure, with accessible averaging 76.7% in hemp shives, arising from interconnected voids and vessels measuring 50–100 μm in . This enables high absorption, up to 300% by weight or an average of 252% across varieties, allowing shives to absorb several times their dry weight in . Additionally, the porous nature provides effective , with ranging from 0.04 to 0.08 W/m·K and an R-value of approximately 2.5 per inch for loose hemp shives at typical densities. Shives exhibit color variability from light to or light , influenced by the source and processing conditions, as seen in shives displaying a yellow hue and hemp shives a bright tone. Moisture content is typically 8–12%, with averages around 7.8–10% reported for hemp and shives under standard conditions, reflecting their hygroscopic properties. Mechanically, shives demonstrate low , generally in the range of 2–3 at 10% deformation for hemp shive-based materials, though values can reach up to 1.24 in composites depending on particle integration. Their , stemming from the brittle woody composition, makes them amenable to particleboard production, where aspect ratios enhance bending strength by about 60% compared to particles.

Chemical Composition

Shives, the woody inner core of such as and , are primarily composed of lignocellulosic materials, with constituting 44-55%, 15-25%, and 15-25% of their dry weight. Minor components include , typically 2-5%, and content ranging from 1-5%, which contribute to the overall structural integrity and reactivity of the material. These proportions provide shives with a balance of rigidity from and flexibility from , influencing their durability in various applications. The chemical makeup of shives varies depending on the plant source, with shives generally containing higher levels (20-28%) compared to shives (14-24%), which affects their resistance to . Additionally, shives exhibit a pH range of 6.5-7.5 in aqueous suspension, making them compatible with mildly acidic or basic processing environments without significant . This neutrality stems from the balanced ionic content in the lignocellulosic matrix. Analytical verification of shive composition commonly employs Fourier Transform Infrared (FTIR) spectroscopy to detect functional groups associated with , , and , alongside High-Performance Liquid Chromatography (HPLC) for precise quantification of hydrolyzed sugars and . reveals thermal stability up to 250°C, after which begins to degrade around 220-280°C, followed by at 300-350°C and persisting to higher temperatures. Environmental processing, such as , alters shive composition by reducing content by 50-70% through microbial enzymatic action, which loosens the matrix and enhances accessibility of core components without substantially affecting or levels. This degradation, from initial levels of 25-30 g/kg to 7-10 g/kg , improves the material's reactivity for subsequent treatments.

Applications

Agricultural and Animal Uses

Shives, the woody inner core of bast fiber plants such as and , have long been utilized in for their absorbent qualities, particularly in animal bedding applications. In livestock management, hemp shives serve as an effective bedding material for stalls and due to their high and capacity, which can reach up to four times their weight in liquid. This absorbency helps maintain dry conditions and reduces airborne dust compared to traditional options like wood shavings. Studies on horse bedding have shown that hemp shives lower gaseous concentrations by approximately 19% relative to , mitigating respiratory issues in animals from ammonia buildup. In farming practices, shives function as and soil amendments to enhance and crop performance. When applied as a surface layer in gardens and fields, hemp shives suppress weed growth by blocking sunlight and provide insulation against temperature fluctuations, while their structure promotes moisture retention in the . Upon decomposition, shives contribute , improving and fertility; their high carbon-to-nitrogen (C:N) ratio, typically 40–70:1, indicates slow breakdown, which sustains long-term nutrient release without rapid immobilization of . This makes them suitable for organic systems where gradual addition is preferred. Historically, shives were employed in 19th-century farming for practical agricultural purposes, including as bedding and litter to absorb and return nutrients to the upon composting. This utilization aligned with traditional processing in regions like and the , where shives were a of and repurposed to support local and . In the , adoption of shives in organic agriculture has grown since the early 2000s, coinciding with renewed cultivation following regulatory changes that legalized in and ; this shift has promoted shives as a sustainable, low-input alternative in regenerative farming practices. Economically, shives offer cost-effectiveness for agricultural uses, with bulk pricing for hemp shives in applications ranging from approximately 0.20 to 0.45 euros per kilogram in markets as of 2023, making them competitive against or wood-based alternatives. In , where hemp production has expanded, regional examples include the use of locally sourced hemp shives for equine and bedding, leveraging domestic supply chains to keep costs low and support circular farm economies.

Industrial and Composite Uses

Shives, the woody inner core of and similar plants, serve as a sustainable in the production of particleboard and medium-density (MDF). In these products, shives are typically incorporated as a primary filler, comprising 10-25% in core or surface layers when blended with wood particles and resins, though higher contents up to 85% are achievable with starch-based binders for specialized high-strength variants. The resulting boards exhibit mechanical properties suitable for , including a modulus of rupture (MOR) exceeding 15 and often reaching 40 with chemical treatments and compression, meeting European standards such as EN 310 for bending strength. In insulation applications, are utilized to manufacture lightweight thermal and acoustic panels, often in formulations combining shives with lime binders. These materials demonstrate low thermal conductivity values of 0.049-0.052 W/(m·K) at densities of 109-124 kg/m³, providing effective comparable to conventional products. Acoustic performance benefits from the shives' high (around 79%), enhancing sound absorption in building interiors. Fire resistance is improved by the inherent content in shives, rendering relatively low-flammability for non-structural use. Shives also function as reinforcements in biocomposites, particularly bioplastics and automotive components, where they replace synthetic fillers to promote biodegradability. In starch biocomposites produced via , optimal incorporation of 40% hemp shives yields tensile strengths of 11.5 MPa and of 1621 MPa, with improved water resistance for packaging and structural parts. European Union-funded projects in the , such as the MultiHemp initiative (2013-2017), advanced shive-based bioproducts for industrial applications, including automotive interiors, by optimizing processing for enhanced mechanical integration. The lignin's natural binding properties further aids adhesion in these composites. Global production of shives for uses aligns with the expanding hemp sector, with output estimated at over 100,000 tons annually as of 2022, supporting applications in composites and building materials. Since 2015, demand has grown significantly in sectors, driven by mandates and a projected (CAGR) of over 17% for the broader through 2030, reaching approximately USD 6.79 billion globally.

Developments and Research

Water-Repellent Coatings

Research on water-repellent coatings for shives has primarily focused on shives, employing silane-functionalized sol-gel treatments to enhance hydrophobicity while preserving the material's . These coatings typically involve the cohydrolysis and polycondensation of (TEOS) with methyltrimethoxysilane (MTMS) under acidic catalysis, forming a silica-based network with hydrophobic methyl groups on the shive surface. Application methods include dip-coating () or spray techniques, where shives are submerged or sprayed with the precursor, followed by and curing at moderate temperatures around 80–100°C to promote gelation and . Untreated shives exhibit high baseline water absorption, often exceeding 400% mass increase due to their porous structure. Such treatments have been shown to reduce water absorption by up to 75%, with single-layer coatings limiting uptake to approximately 100–250% compared to untreated samples. Initial studies on these hydrophobic modifications emerged between 2015 and 2020, driven by European research institutions seeking to improve shives for sustainable building materials. Pioneering work at and in the UK demonstrated the efficacy of sol-gel coatings in transforming hydrophilic shives into water-resistant aggregates suitable for insulation and composites. By 2018, multiple layers of these coatings were optimized to balance hydrophobicity with moisture buffering, enabling broader adoption in construction applications. Performance evaluations highlight contact angles exceeding 118° on treated surfaces, confirming superhydrophobic behavior that repels droplets effectively. Durability tests indicate that these coatings maintain hydrophobicity for 6–12 months under simulated environmental , including moderate UV , with minimal in contact angle (less than 10° loss) due to the stable silica matrix. Wax-based alternatives, such as or bio-extracted paraffins, have been explored in complementary studies, applied via dry blending or , achieving similar reductions of 70–85% but with potentially lower long-term UV resistance compared to silane-sol-gel systems. These advancements have enabled expanded applications of treated shives in outdoor composites and , such as weather-exposed blocks and facade panels, where untreated shives would degrade rapidly from moisture ingress. Patents filed around 2018, including those for bio-based formulations tailored to lignocellulosic aggregates, underscore the commercial potential of these coatings in eco-friendly building products. Overall, such treatments enhance shive viability in humid environments without compromising their low-density and properties.

Sustainability and Innovations

Hemp shives offer significant environmental benefits as a biodegradable alternative to synthetic plastics, particularly in composite materials and bioplastics where they replace non-degradable fillers. Their use in applications like hempcrete and particleboards reduces reliance on petroleum-based polymers, promoting circular economy principles through natural decomposition at the end of life. Additionally, hemp shives contribute to carbon sequestration; cultivation of industrial hemp, from which shives are derived, sequesters 9 to 15 tonnes of CO₂ per hectare, with shives themselves enabling long-term storage in building materials such as hemp-lime composites that lock away up to 35 kg CO₂ per square meter over a century. The production of one metric ton of hemp shives can sequester 0.219 to 0.763 metric tons of CO₂, depending on farming practices. Lifecycle assessments highlight the lower environmental footprint of shives compared to traditional materials. Hemp-lime bio-composites incorporating shives exhibit of 3.3 to 3.5 MJ/kg, representing a 10 to 50% reduction relative to conventional options like aerated autoclaved (4.0 MJ/kg) or wood particle-based products. This efficiency stems from hemp's low-input cultivation, which requires minimal fertilizers and pesticides while enhancing . Furthermore, shives-based composites demonstrate high recyclability, allowing repeated processing without significant loss of integrity, unlike many synthetic alternatives that contribute to waste accumulation. Recent innovations leverage shives for advanced applications, including extraction. Post-2020 research has developed methods to isolate nanocrystals and nanofibrils from hurds (shives), achieving yields up to 29% after pretreatment and crystallinity levels of 46 to 77%, enabling uses in high-performance . Shives are also integrated into filaments, such as alkali-treated hurd-reinforced () composites, which improve stiffness, tensile strength, and thermal stability for sustainable additive manufacturing. In 2024-2025, further advancements include mineral additives enhancing fire resistance and durability in , and structural optimization of lightweight shive-fiber panels for eco-friendly construction, supporting expanded use in sustainable building practices. Looking ahead, policies like the EU Green Deal are driving adoption by emphasizing hemp's role in carbon storage and , with cultivation areas expanding across to support these goals. The broader industrial hemp market, encompassing shives-derived products, was projected as of 2023 to reach USD 16.82 billion by 2030, growing at a compound annual rate of 17.5% from 2023 levels; more recent 2024 estimates suggest growth to USD 30.24 billion by 2029 at a 22.4% CAGR.

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