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Yttrium barium copper oxide

Yttrium barium copper oxide (YBCO), with the chemical formula YBa₂Cu₃O₇, is a crystalline ceramic compound belonging to the family of cuprate high-temperature superconductors, capable of conducting electricity with zero resistance at critical temperatures up to 93 K (−180 °C), which exceeds the boiling point of liquid nitrogen (77 K).^[1]^[2] This material revolutionized superconductivity research upon its discovery in January 1987 by independent teams at the University of Houston and the University of Alabama in Huntsville, marking the first demonstration of superconductivity above liquid nitrogen temperatures and enabling practical cooling without expensive liquid helium.^[3]^[4] Structurally, YBCO adopts an orthorhombic perovskite-like lattice, featuring layered copper-oxygen planes that are essential for its superconducting properties, with the oxygen content (often denoted as YBa₂Cu₃O_{7-δ}, where δ varies) critically tuning the transition temperature (T_c) through doping effects.^[1]^[5] As a type-II superconductor, it allows magnetic flux penetration via vortices, supporting high critical current densities (J_c) in applied fields, which is vital for technological use.^[2] YBCO's significance lies in its potential for energy-efficient applications, including power transmission cables that minimize resistive losses, fault current limiters for grid protection, and high-field magnets for fusion reactors and particle accelerators.^[6] Thin-film and coated-conductor forms of YBCO enable compact devices like superconducting motors, generators, and flywheel energy storage systems, while ongoing research explores enhancements for room-temperature superconductivity.^[7]^[8] Despite challenges like material brittleness and fabrication costs, YBCO remains a cornerstone of high-temperature superconductivity, driving advancements in sustainable energy technologies.^[9]

Properties

Chemical Composition

Yttrium barium copper oxide (YBCO), also denoted as Y-123, possesses the chemical formula YBa₂Cu₃O₇₋δ, where δ represents the oxygen non-stoichiometry parameter, typically ranging from 0 to 1 and reflecting deviations from the ideal oxygen content of 7 atoms per formula unit.^[10] This variability arises primarily from partial occupancy of oxygen sites in the crystal lattice, allowing fine-tuning of electronic properties through controlled oxygenation.^[10] The superconducting form of YBCO corresponds to the orthorhombic phase (Y-123), which forms when δ ≤ 0.5, whereas higher δ values (> 0.5) stabilize the non-superconducting tetragonal phase.^[10] A fully deoxygenated composition, YBa₂Cu₃O₆ (δ = 1), exemplifies the tetragonal variant and exhibits insulating behavior due to the absence of charge carriers.^[10] In its layered perovskite-like arrangement, yttrium serves as a trivalent cation positioned between consecutive CuO₂ planes, acting as a structural spacer that maintains layer separation without contributing directly to conduction.^[11] Barium, as a divalent cation, occupies larger sites in the BaO layers flanking the CuO chains, facilitating charge balance in the reservoir layers. Copper atoms play dual roles: forming the square-planar CuO₂ sheets central to pairing mechanisms and linear CuO chains that provide mobile oxygen and dope the system. Oxygen anions coordinate these metals, with chain-site oxygens particularly sensitive to δ, influencing hole doping and overall stoichiometry.^[10] The value of δ profoundly impacts material properties, including a peak superconducting transition temperature near δ ≈ 0.^[12]

Superconducting and Physical Properties

Yttrium barium copper oxide (YBCO), with the formula YBa₂Cu₃O₇₋ₓ, exhibits superconductivity at a critical temperature T_c \approx 93 K, marking the first material to superconduct above the boiling point of liquid nitrogen (77 K) at ambient pressure.^[13] This T_c reaches its maximum for oxygen deficiencies in the range x \approx 0.07–0.15, corresponding to near-optimal doping levels that optimize the hole carrier concentration in the CuO₂ planes. Below T_c, YBCO demonstrates zero electrical resistance and the Meissner effect, expelling magnetic fields from its interior, consistent with its classification as a type-II superconductor.^[13] In this regime, it supports magnetic flux penetration via vortices, with an upper critical field H_{c2} \approx 120 T at low temperatures for optimally doped samples. The superconducting properties of YBCO are highly anisotropic due to its layered perovskite-like structure, which confines charge carriers primarily to the ab-plane (CuO₂ layers) while limiting transport along the c-axis. In the ab-plane, the critical current density J_c can reach values up to $10^6 A/cm² at 77 K and self-field, enabling high-power applications, whereas J_c along the c-axis is significantly lower, often by orders of magnitude.^[14] This directional dependence arises from the weak interlayer coupling, resulting in pronounced differences in electrical and magnetic responses between in-plane and out-of-plane directions. Physically, YBCO appears as a black, brittle ceramic material with a density of approximately 6.3 g/cm³.^[15] It has a high melting point exceeding 1000 °C and exhibits anisotropic thermal expansion, with coefficients \alpha_a = [13](/page/13) \times 10^{-6} K⁻¹ in the ab-plane and \alpha_c = 12 \times 10^{-6} K⁻¹ along the c-axis, reflecting its orthorhombic crystal symmetry.^[16] In the normal state above T_c, YBCO displays metallic-like resistivity that is nearly linear in temperature, accompanied by pseudogap behavior—a partial suppression of the density of states near the Fermi level starting at a temperature T^* > T_c, which manifests as deviations from simple Fermi liquid transport and influences the material's electronic properties.^[17]

History

Discovery

In 1986, J. Georg Bednorz and K. Alex Müller, working at the IBM Zurich Research Laboratory, reported the discovery of superconductivity in an oxide compound of lanthanum, barium, and copper (La-Ba-Cu-O) with a critical temperature (T_c) of approximately 35 K, marking the onset of high-temperature superconductivity research.^[18] Their findings, initially published in a modest journal to allow further verification, demonstrated a sharp drop in electrical resistance and initial signs of the Meissner effect, challenging the prevailing understanding that higher T_c values required metallic rather than ceramic materials.^[19] For this breakthrough, Bednorz and Müller were awarded the 1987 Nobel Prize in Physics. The announcement ignited an intense global race among research groups to identify materials with even higher T_c values, spurring rapid experimentation with copper-oxide-based ceramics worldwide.^[19] In early 1987, independent teams led by Paul C. W. Chu at the University of Houston and Maw-Kuen Wu at the University of Alabama in Huntsville synthesized yttrium barium copper oxide (YBa₂Cu₃O_7–x), achieving a reproducible superconducting transition at T_c = 93 K under ambient pressure conditions.^[20] Wu's team, including Jim Ashburn and C. J. Torng, observed zero resistance on January 29, 1987, at UAH.^[4] The initial preparation involved a solid-state reaction of yttrium oxide, barium carbonate, and copper oxide powders, heated and ground in multiple cycles to form the compound.^[4] Superconductivity was confirmed through resistivity measurements indicating a sharp onset to zero resistance near 93 K and magnetic susceptibility tests revealing the Meissner effect, with diamagnetic expulsion of magnetic fields below T_c. This achievement positioned YBCO as the first practical high-T_c superconductor operable above the boiling point of liquid nitrogen (77 K), enabling easier cooling and broader potential applications.^[21]

Key Developments

Following the discovery of superconductivity in YBa₂Cu₃O₇ (YBCO) at 93 K, early structural analyses in 1987-1988 utilized X-ray diffraction to confirm its orthorhombic crystal structure, revealing that oxygen annealing was essential for ordering oxygen atoms in the Cu-O chains, thereby stabilizing the phase and enabling optimal superconducting properties. In the 1990s, research focused on enhancing flux pinning to improve the critical current density (J_c) in magnetic fields, with studies demonstrating that introducing impurities and defects, such as nanoscale particles, created effective pinning sites for vortices; for instance, later refinements in the 2000s incorporated BaZrO₃ nanoparticles, which formed coherent nanorods aligned with the c-axis, boosting J_c by up to an order of magnitude in applied fields. Theoretical advancements in cuprate superconductivity during the 1990s established d-wave pairing symmetry through angle-resolved photoemission spectroscopy (ARPES) experiments, which revealed an anisotropic superconducting gap with nodes along the diagonal directions in the Brillouin zone, consistent across hole-doped cuprates like YBCO and providing key insights into the unconventional pairing mechanism. The 2000s saw significant progress in thin-film deposition techniques for coated conductors, including the development of rolling-assisted biaxially textured substrates (RABiTS) and ion-beam-assisted deposition (IBAD) for buffer layers, enabling the fabrication of kilometer-long flexible wires with high J_c over 1 MA/cm² at 77 K, paving the way for practical applications. The 1987 Nobel Prize in Physics awarded to J. Georg Bednorz and K. Alex Müller for their pioneering work on high-temperature superconductivity in copper oxides spurred global research efforts, directly catalyzing the rapid identification and optimization of YBCO as the first material to exceed liquid-nitrogen temperatures.^[22]

Synthesis

Solid-State Synthesis

The solid-state synthesis of yttrium barium copper oxide (YBCO), specifically YBa₂Cu₃O₇₋ₓ, begins with the preparation of precursor powders in a stoichiometric ratio corresponding to Y:Ba:Cu = 1:2:3. High-purity yttrium oxide (Y₂O₃), barium carbonate (BaCO₃), and copper oxide (CuO) are thoroughly mixed, typically by ball milling or mortar grinding, to ensure homogeneity and promote uniform reaction.^[23] The mixture is then calcined in air at temperatures between 900–950 °C for several hours (often 10–24 hours), during which the solid-state reaction occurs to form the tetragonal phase YBa₂Cu₃O₆ as the primary product. This step decomposes BaCO₃ and facilitates the diffusion of cations to form the desired perovskite-like structure. The overall reaction for the calcination stage can be represented as:

\mathrm{Y_2O_3 + 4 BaCO_3 + 6 CuO \rightarrow 2 YBa_2Cu_3O_6 + 4 CO_2}

Following calcination, the resulting powder is reground to break up agglomerates, pressed into pellets, and sintered at temperatures of 920–960 °C (1193–1233 K) for 12–24 hours in air or flowing oxygen to densify the material and improve phase formation.^[23] Multiple firing cycles, involving intermediate grinding and recalcination, are commonly required to enhance reaction completeness and achieve better homogeneity. After sintering, the tetragonal YBa₂Cu₃O₆ phase is oxygenated to the orthorhombic YBa₂Cu₃O₇₋ₓ phase by annealing in pure oxygen at 400–500 °C for 12–24 hours, which adjusts the oxygen stoichiometry (x ≈ 0–0.2) critical for superconductivity; the sample is then quenched or slowly cooled to room temperature to preserve this orthorhombic structure.^[23] Despite its simplicity, the solid-state method faces significant challenges in achieving high phase purity. Incomplete decomposition of BaCO₃ can lead to carbon contamination in the form of residual carbonates, which reacts back with the forming YBCO to regenerate impurities like BaCO₃, Y₂O₃, and CuO, thereby reducing the critical current density and overall superconducting performance.^[24] Additionally, the high temperatures promote the formation of secondary phases such as Y₂BaCuO₅ (green phase) or BaCuO₂ if the mixing is inhomogeneous, necessitating careful control of heating rates, atmosphere, and repeated processing steps to minimize these issues and obtain predominantly single-phase material.

Advanced Synthesis Methods

Chemical solution deposition (CSD) using trifluoroacetic acid (TFA) precursors represents a scalable, low-cost method for producing high-quality YBCO thin films, particularly for coated conductors. In this approach, metal trifluoroacetates of yttrium, barium, and copper are dissolved in solvents like methanol or ethanol, spin-coated or dip-coated onto substrates such as buffered metal tapes, and then pyrolyzed to remove organic components, followed by crystallization in a humid oxygen atmosphere at temperatures around 700–800 °C. This process yields epitaxial YBCO films with critical current densities exceeding 1 MA/cm² at 77 K, owing to the controlled nucleation and growth that minimizes defects. The TFA route is advantageous for industrial scalability due to its compatibility with reel-to-reel processing and reduced material costs compared to vacuum-based techniques.^[25] Physical vapor deposition techniques, including pulsed laser deposition (PLD) and metal-organic chemical vapor deposition (MOCVD), enable the fabrication of epitaxial YBCO thin films with precise compositional control and high crystallinity. PLD involves ablating a stoichiometric YBCO target using a pulsed excimer laser (e.g., KrF at 248 nm) in an oxygen ambient (typically 100–300 mTorr), depositing films on heated substrates like SrTiO₃ or LaAlO₃ at 700–800 °C, resulting in c-axis oriented films with smooth surfaces and superconducting transition temperatures near 90 K. This method excels in producing defect-free films for fundamental studies and devices, though it is limited by line-of-sight deposition. MOCVD, conversely, uses volatile metal-organic precursors such as β-diketonates (e.g., Y(thd)₃, Ba(thd)₂, Cu(thd)₂) vaporized and transported in a carrier gas to a heated substrate, allowing uniform deposition over large areas at 650–850 °C under reduced pressure. It has been optimized for coated conductors, achieving critical currents up to 300 A/cm-width at 77 K self-field. Both techniques facilitate oxygen stoichiometry control post-deposition via annealing in oxygen at 400–500 °C to achieve the optimal δ ≈ 0 for superconductivity.^[26]^[27]^[28] Recent innovations as of 2025 have focused on cost-reduced and scalable synthesis routes to enhance material homogeneity for YBCO. Hybrid oxide-nitrate methods, combining metal oxides with nitrate salts in aqueous or alcoholic solutions, followed by gelation and low-temperature calcination (500–700 °C), reduce precursor costs by up to 50% while promoting uniform cation distribution and finer particle sizes (sub-micron range), leading to denser sintered pellets with improved phase purity. Complementing this, advanced sol-gel techniques using acetate or citrate precursors with chelating agents enable precise control over hydrolysis and condensation, yielding homogeneous YBCO powders and films with reduced agglomeration and enhanced microstructural uniformity, as evidenced by narrower XRD peak widths and higher critical current densities in processed materials. These approaches prioritize environmental benignity and lower energy inputs compared to traditional routes.^[29]^[30] Post-2022 developments include additive manufacturing techniques for producing monocrystalline YBCO structures via 3D printing followed by sintering, enabling complex geometries with high critical currents (as of 2025).^[31] Atomic layer deposition (ALD) has emerged for ultra-thin YBCO films with atomic-level thickness control, suitable for quantum devices (as of 2025).^[32] Enhanced PLD variants using off-axis configurations have improved uniformity and critical current densities comparable to conventional methods at 30–70 K (as of 2025).^[33] Techniques for synthesizing doped YBCO variants, such as incorporation of fluorine or silver, target enhanced flux pinning to improve performance in magnetic fields. Fluorine doping via co-precipitation of metal fluorides or post-annealing in HF atmospheres introduces nanoscale defects that act as pinning centers, boosting critical current densities by 20–30% at 77 K and 1 T, particularly along the c-axis, by distorting the lattice and creating oxygen vacancies. Silver doping, achieved by adding AgNO₃ to TFA or sol-gel precursors (0.5–5 mol%), promotes liquid-phase sintering during processing at 700–900 °C, resulting in refined grain boundaries and increased intergranular connectivity, which enhances flux pinning and raises the irreversibility line by up to 10 K in applied fields. These modifications maintain the orthorhombic YBCO structure while optimizing vortex dynamics for practical applications.^[34]^[35]

Structure

Crystal Structure

Yttrium barium copper oxide (YBCO), with the composition YBa₂Cu₃O₇, adopts an orthorhombic crystal structure characterized by the space group Pmmm and lattice parameters of approximately a = 3.82 Å, b = 3.89 Å, and c = 11.68 Å.^[36] This unit cell reflects a slight distortion from cubic symmetry, with the c-axis significantly elongated to accommodate the layered atomic arrangement.^[37] The structure features a distinctive layered configuration, consisting of CuO₂ planes that serve as the primary superconducting layers, interspersed with BaO planes and yttrium atoms positioned between successive CuO₂ layers.^[37] Along the b-axis, copper-oxygen chains form, comprising square-planar CuO₄ units linked by oxygen atoms, which contribute to the orthorhombic distortion by differentiating the a and b directions.^[37] This layering results in strong anisotropy in physical properties, with conductivity predominantly occurring within the ab-plane.^[36] YBCO can be understood as a defect perovskite structure, where the ideal ABO₃ perovskite motif is modified by oxygen deficiencies and the inclusion of apical oxygen atoms coordinated to copper in the CuO₂ planes. In particular, oxygen vacancies occupy sites within the CuO chains along the b-axis, and their presence or ordering influences the material's superconducting behavior by altering the local coordination and valence states.^[37] For the oxygen-deficient variant YBa₂Cu₃O_{7-x}, a structural transition from orthorhombic to tetragonal symmetry occurs around x ≈ 0.5, marking a point where the a and b parameters become equivalent and superconductivity is suppressed. In the orthorhombic phase, this subtle lattice mismatch often leads to {110} twinning, where domains with interchanged a and b axes coexist to minimize strain energy.^[38]

Electronic Structure

Yttrium barium copper oxide (YBCO), with the formula YBa₂Cu₃O_{6+δ}, is fundamentally a hole-doped Mott insulator, where the undoped parent compound (δ=0) exhibits strong electron correlations that localize electrons in the copper 3d orbitals, resulting in an insulating state despite a half-filled band.^[39] Upon oxygen doping (increasing δ), holes are introduced primarily into the CuO₂ planes, transforming the system into a metal with a Fermi surface composed mainly of hybridized Cu 3d_{x²-y²} and in-plane O 2p_σ orbitals, as revealed by angle-resolved photoemission spectroscopy (ARPES) studies.^[40] This band structure features a large Fermi surface in the optimally doped regime (δ ≈ 1), reflecting the Zhang-Rice singlet formation where a hole on oxygen pairs with a Cu d hole to form an effective x²-y²-like band.^[41] The CuO₂ planes serve as the active layers hosting these quasiparticles, with chain contributions playing a secondary role in the overall electronic properties.^[39] The superconducting state in YBCO is characterized by an unconventional d-wave order parameter, Δ(k) ∝ (cos k_x - cos k_y)/2, which vanishes at nodes along the diagonals of the Brillouin zone, leading to gap anisotropy and low-energy excitations near these points.^[42] This pairing symmetry, confirmed through phase-sensitive Josephson junction experiments and ARPES measurements of the superconducting gap, deviates from conventional s-wave BCS theory in its mechanism, likely involving repulsive interactions mediated by antiferromagnetic spin fluctuations rather than phonon attraction.^[43]^[44] Despite the d-wave form, the pairing exhibits BCS-like coherence factors, but the unconventional nature is evident in the absence of a sign change in the gap across the Fermi surface in a simple way, and in the sensitivity to disorder at the nodes.^[42] In the undoped parent compound YBa₂Cu₃O₆, short-range antiferromagnetic correlations dominate, arising from superexchange interactions between neighboring Cu²⁺ spins in the CuO₂ planes, with a Néel temperature suppressed by doping but persisting as dynamic fluctuations.^[45] Above the superconducting transition temperature T_c, a pseudogap phase emerges in underdoped YBCO (δ < 0.16), manifesting as a partial suppression of low-energy states near the antinodal regions of the Brillouin zone, distinct from the full d-wave gap below T_c.^[46] This pseudogap is attributed to precursor pairing or competing orders, with ARPES revealing Fermi arcs in the nodal regions while antinodes show gapped behavior.^[40] In underdoped regimes, spin fluctuations play a central role, enhancing pairing but also competing with superconductivity through stripe-like orders—modulations of charge and spin density with periods of ~4 lattice spacings.^[44] Inelastic neutron scattering experiments detect these dynamic spin fluctuations peaking near the antiferromagnetic wavevector (π,π), with enhanced spectral weight in underdoped YBCO, supporting their role in mediating d-wave pairing.^[45] ARPES further evidences stripe-induced Fermi surface reconstruction, showing pocket-like features and reduced spectral weight in underdoped samples, while charge order observed via X-ray scattering correlates with these spin dynamics.^[47]^[48]

Applications

Established Applications

Yttrium barium copper oxide (YBCO), a high-temperature superconductor, finds established use in superconducting magnets for medical imaging and particle physics research, leveraging its high critical current density to produce stable, high magnetic fields at temperatures above 20 K. In magnetic resonance imaging (MRI) systems, YBCO-based coils facilitate cryogen-free designs operated with cryocoolers, minimizing helium dependency and enabling more compact and cost-effective scanners. A demonstrated 1.5 T prototype MRI magnet using YBCO tapes achieved field uniformity of 40 ppm over a 12 cm diameter spherical volume at 20 K, highlighting its suitability for clinical applications.^[49] In particle accelerators, YBCO coils contribute to high-field magnets that guide particle beams efficiently. For instance, YBCO inserts have enabled all-superconducting magnets to reach record fields of 32 T at 4.2 K, combining with low-temperature superconductors for enhanced performance in facilities like the National High Magnetic Field Laboratory. These applications benefit from YBCO's high J_c in perpendicular fields, allowing compact designs for accelerator upgrades.^[50]^[51] YBCO is also integral to superconducting fault current limiters (SFCLs) in power grids, where its rapid transition from superconducting to resistive state upon exceeding the critical current quenches faults, limiting prospective currents by factors up to 20 while maintaining low impedance under normal operation. Resistive-type SFCLs using YBCO coated conductors have undergone successful full-scale testing, including a 12 kV/400 A device integrated into distribution networks, demonstrating economic viability for grid protection against short-circuit faults. Commercial developments, such as those by American Superconductor Corporation in collaboration with utilities, have deployed YBCO-based SFCLs since the early 2010s to address rising fault levels from grid interconnections.^[52]^[53] Superconducting quantum interference devices (SQUIDs) fabricated from YBCO enable ultrasensitive magnetometry in medical and geophysical sensing, detecting magnetic fields as low as 10 fT/Hz^{1/2}. In medicine, YBCO SQUIDs support non-invasive biomagnetic measurements, such as magnetoencephalography for brain activity mapping, with multichannel systems achieving spatial resolution sufficient for clinical diagnostics of neurological disorders. Geophysically, they are employed in magnetotelluric surveys to probe subsurface structures for mineral exploration, offering noise floors below 10 fT/Hz^{1/2} in field-deployable, liquid-nitrogen-cooled setups.^[54]^[55] Commercial production of YBCO tapes, scaled up since the 2010s by manufacturers like SuperPower Inc. and SuperOx, supports these applications with kilometer-length coated conductors capable of sustaining ~10 T fields at 20–40 K using cryocoolers, with critical currents exceeding 300 A at 77 K self-field.^[56]^[57]

Proposed and Emerging Applications

Yttrium barium copper oxide (YBCO), a high-temperature superconductor with a critical temperature above 77 K, enabling liquid nitrogen cooling, is being explored for advanced applications in fusion energy. In the SPARC tokamak project, developed by Commonwealth Fusion Systems (CFS) and MIT, YBCO-based high-temperature superconducting (HTS) magnets generate magnetic fields up to 20 tesla, allowing for a compact design that aims to achieve net energy gain. These magnets, constructed from REBCO tapes including YBCO formulations, were successfully tested in 2021, demonstrating stability under extreme conditions. SPARC, under construction as of 2025, is expected to begin initial operations by 2027, potentially revolutionizing fusion reactors by enabling smaller, more efficient systems compared to traditional low-temperature superconductors.^[58]^[59]^[60] YBCO is proposed for enhancing high-speed maglev trains through magnetic levitation systems that leverage its zero-resistance properties for stable, low-friction propulsion. Research has shown that optimizing YBCO's critical current density and pinning forces can improve levitation stability at speeds exceeding 500 km/h, reducing energy consumption and enabling lighter vehicle designs. Prototypes using YBCO bulks have demonstrated dynamic stability during high-frequency operations equivalent to rapid transit speeds.^[61] In power transmission, YBCO HTS cables are envisioned as lossless lines capable of carrying bulk power with minimal AC losses, addressing urban grid congestion. A triplex YBCO cable design achieves losses of 0.054 W/m at 1 kA and 50 Hz, significantly lower than conventional copper cables while maintaining equivalent capacity in a compact form factor under 135 mm diameter. This enables underground installations with reduced electromagnetic interference and lower construction costs.^[62] For quantum computing, YBCO serves as a barrier material in Josephson junctions, facilitating the creation of π-loops and qubits with enhanced coherence for annealing-based processors. Grain-boundary YBCO junctions enable silent phase qubits that exploit d-wave superconductivity for low-noise quantum operations, potentially advancing scalable quantum bits beyond conventional niobium systems. Recent studies on MoRe/YBCO junctions demonstrate stable manipulation of π-states, paving the way for hybrid quantum annealing architectures.^[63] Recent developments from 2023 to 2025 highlight YBCO's emerging role in renewable and aviation sectors. Partnerships and research initiatives are integrating YBCO into superconducting generators for offshore wind turbines, aiming for 10-15 MW units with reduced weight and higher efficiency through HTS windings. In electric aviation, YBCO-based partially superconducting motors are under investigation for high-power-density propulsion, with studies showing potential for 2.5 MW designs cooled by liquid nitrogen to support hybrid-electric aircraft. Experimental HTS induction/synchronous motors using YBCO tapes have validated torque outputs suitable for all-electric flight, targeting reduced emissions in regional aviation.^[64]^[65]

Fabrication and Production

Surface Modification

Surface modification of yttrium barium copper oxide (YBCO) thin films is crucial for optimizing performance in superconducting devices, particularly by tailoring surface chemistry and introducing defects to enhance flux pinning and interface properties. One prominent approach involves chemical modification through the deposition of self-assembled monolayers (SAMs), such as those formed from alkylamines or thiols, which can be applied using techniques like cyclic voltammetry to create tunnel junctions. These monolayers adsorb onto the YBCO surface, altering electronic properties at the interface; for instance, in cuprate superconductor films, SAMs of organic molecules have been shown to tune the critical temperature (T_c) by modulating carrier doping near the surface.^[66]^[67] Lewis acid-base interactions play a key role in these chemical modifications, where amine groups act as Lewis bases that coordinate with undercoordinated copper sites on the YBCO surface, forming stable bonds that improve adhesion to overlying layers and mitigate surface oxidation. This coordination enhances charge transfer within the CuO_2 planes, leading to subtle improvements in superconducting properties, such as an increase in the metal-to-superconductor transition temperature by up to 3 K following immersion in solvents like dichloromethane that facilitate chlorine incorporation and surface passivation.^[68]^[69] To further enhance vortex pinning, physical techniques like plasma etching and ion implantation are employed to create artificial pinning centers on YBCO surfaces. Plasma etching, often using argon-oxygen mixtures, patterns the surface to introduce nanoscale defects that act as pinning sites, while focused ion beam implantation with light ions (e.g., He^+) generates controlled defect arrays, enabling tunable pinning landscapes without significantly degrading bulk superconductivity.^[70]^[71] These surface modifications yield measurable improvements in device performance, including increases in critical current density (J_c) in thin films due to enhanced flux pinning, which is particularly beneficial for Josephson junctions where precise control over weak links is required. Such enhancements arise from the combined effects of chemical passivation and defect engineering, supporting applications in high-sensitivity superconducting electronics.^[72] The anisotropic conductivity inherent to YBCO surfaces can be briefly leveraged in these modifications to direct pinning along specific crystallographic directions.^[73]

Mass Production Techniques

Mass production of yttrium barium copper oxide (YBCO) primarily revolves around the fabrication of coated conductors in the form of flexible tapes, which are essential for practical applications requiring long lengths and high current densities. Two dominant processes for producing these biaxially textured substrates are Rolling-Assisted Biaxially Textured Substrates (RABiTS) and Ion Beam Assisted Deposition (IBAD). In the RABiTS approach, a nickel-based alloy tape is mechanically deformed through rolling to achieve biaxial texture, followed by epitaxial deposition of buffer layers and the YBCO superconductor layer using techniques such as metal-organic deposition (MOD) or pulsed laser deposition (PLD), enabling low-cost, high-speed manufacturing suitable for kilometer-scale production. The IBAD method, in contrast, involves depositing a textured buffer layer, typically yttria-stabilized zirconia (YSZ), onto a non-textured metal substrate using an ion beam to induce crystallographic alignment, which then supports the growth of high-quality YBCO films with critical current densities exceeding 1 MA/cm² over meter lengths. A notable milestone in scaling YBCO wire production was achieved by SuperOx in 2021, where over 300 km of 4 mm-wide YBCO tape was manufactured in just nine months using PLD on IBAD-MgO buffered substrates, primarily for fusion applications. These wires incorporated Y₂O₃ nanoparticles for enhanced flux pinning, achieving engineering critical current densities (J_E) greater than 700 A/mm² at 20 K and 20 T for 87% of the production, with record values exceeding 2000 A/mm² at 4.2 K and 20 T.^[56] This large-volume output demonstrated the feasibility of industrial-scale PLD, though it required optimized tension control to mitigate mechanical damage during deposition of thick YBCO layers (up to 3.5 µm) on thin substrates.^[56] Recent advances in additive manufacturing have expanded mass production capabilities beyond traditional tape geometries. In 2025, researchers demonstrated 3D-ink-printing of polycrystalline YBCO (YBa₂Cu₃O₇₋ₓ + Y₂BaCuO₅) precursors, followed by sintering and epitaxial growth to form monocrystalline structures, enabling the fabrication of complex shapes such as toroidal coils and tubes with high shape fidelity.^[31] This method leverages a percolated Y₂BaCuO₅ skeleton to support single-crystal transformation, yielding critical current densities of approximately 2.1 × 10⁴ A/cm² at 77 K self-field—approximately 66 times higher than polycrystalline counterparts—and supporting persistent currents in intricate 3D architectures.^[31] Despite these progresses, mass production of YBCO faces significant challenges, including high costs around $150/kA·m as of 2021 for coated conductors at then-current volumes, inherent brittleness as a ceramic material leading to mechanical fragility in wire form, and performance yields below 90% due to variations in texture uniformity and defect sensitivity.^[74]^[75] Solutions to address these include continuous reel-to-reel processing, which integrates deposition, characterization, and feedback control to ensure uniform performance over long lengths while minimizing waste and improving scalability, as well as emerging low-cost methods like chemical solution deposition (CSD).^[76]^[77]

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Oct 25, 2012 · For YBa2Cu3O7–δ the variation of TC in this case is induced solely by oxygen depletion, which has the notable propensity of creating percolative ...<|control11|><|separator|>
[14]
Superconductivity at 93 K in a new mixed-phase Y-Ba-Cu-O ...
Mar 2, 1987 · ... Superconductivity at 93 K in a new mixed-phase Y-Ba-Cu-O compound system at ambient pressure. M. K. Wu, J. R. Ashburn, and C. J. Torng · P. H. ...Missing: nature. | Show results with:nature.
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https://www.sciencedirect.com/science/article/abs/pii/S0925838821009610
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Thermoelectric properties of Pr-substituted YBCO ceramics
Aug 5, 2021 · The theoretical density of (YBCO-123) is 6.3 g/cm3. The microstructure and the electrical traits of YBCO-123 ceramic can be changed either ...Missing: cm³ | Show results with:cm³
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[PDF] miiw&mm w \m 'M^^^ETA^' ^' "*"^ - OSTI.GOV
Oct 12, 1988 · The thermal expansion coefficient of YBCO (13 xlO ^^ X^l) is larger than most of the oxide materials listed in Table 1, and the phase transition ...Missing: physical cm³
[18]
Peculiarities of pseudogap in Y 0.95 Pr 0.05 Ba 2 Cu 3 O 7−δ ...
Dec 31, 2019 · Pseudogap and its temperature dependence in YBCO from the data of resistance measurements. Phys. Solid State 45, 1223–1232 (2003). Article ...
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Possible highT c superconductivity in the Ba−La−Cu−O system
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April 1986: Bednorz and Müller Trigger Avalanche of High ...
Mar 16, 2023 · Georg Bednorz and K. Alex Müller submitted their paper, “Possible high-Tc superconductivity in the Ba−La−Cu−O system,” to the journal ...
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Milestone-Proposal:Discovery of Superconductivity at 93 K in Yttrium ...
Sep 24, 2018 · YBCO, in turn, tripled that level at 93 K. At the same time, it marked a somewhat unique material in that the layered structure was the ...
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What's so hot about superconductors? - New Scientist
After Bednorz and Muller announced their results, researchers around the world quickly confirmed the discovery. Within a few months, Paul Chu and his ...
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The Nobel Prize in Physics 1987 - NobelPrize.org
The Nobel Prize in Physics 1987 was awarded jointly to J. Georg Bednorz and K. Alexander Müller for their important break-through in the discovery of ...
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[PDF] YBCO Synthesis and Characterization (Electrical Transport Option)
A successfully performed synthesis mixed the chemicals in proportions such that the atomic ratios of yttrium, barium, and copper were 1:2:3: 0.5Y2O3 +. 2BaCO3 + ...Missing: solid calcination 900-950° sintering 1000- 1300K equation
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[PDF] AD - DTIC
Nov 30, 1992 · The optimum sintering treatment for the freeze-dried YBCO powders is thus 890'C for 24 hours, followed by annealing at 550°C. The pellets formed ...Missing: equation | Show results with:equation
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Chemical solution deposition of YBa2Cu3O7−x coated conductors
This paper reviews the most recent work on chemical solution deposition within the IFW Dresden while also considering achievements on this specific research ...
[27]
Pulsed laser deposition and characterization of high-Tc YBa2Cu3O7
The electrical and structural studies performed on laser deposited YBCO films have shown that films produced by PLD are superior than films produced by other ...
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Laser deposition of YBa2Cu3O7−δ films using a pulsed oxygen ...
Mar 18, 1991 · Thin films of YBa2Cu3O7−δ (YBCO) have been grown by pulsed laser deposition in a low‐pressure background (10−4–10−3 Torr) by using a pulsed, ...Missing: seminal | Show results with:seminal
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Metal‐Organic Chemical Vapor Deposition of Oxide Perovskite ...
Apr 15, 2022 · A summary of significant studies on applications of MOCVD techniques of YBCO and LBCO superconducting thin films is reported in Table 2.
[30]
Synthesis of Al2O3 nanoparticles highly distributed in YBa2Cu3O7 ...
Aug 7, 2025 · The auto-combustion reaction has successfully transformed the Al nitrate added YBCO precursor gels to very fine ashes which yielded to Al2O3 and ...
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Synthesis of porous high-temperature superconductors via a ...
Jun 16, 2022 · For better control of macro- and nanomorphology, sol–gel techniques can be employed that utilise the homogeneous nature of solutions for the ...
[32]
Enhanced flux-pinning in fluorine-free MOD YBCO films by chemical ...
Effects of dilute cobalt and zinc doping on biaxial texture, microstructure and flux-pinning properties of YBCO films were investigated. The surface density and ...
[33]
Effect of Silver Doping on the Superconducting and Structural ... - NIH
Aug 3, 2022 · It is currently known that doping silver into YBa2Cu3O6+x (YBCO) improves the growth properties of the films [13] and enhances the incorporation ...
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Orthorhombic YBa 2 Cu 3 O 7 Cleaved Single Crystal by XPS
Dec 1, 1992 · X-ray photoemission spectra from the cleaved surface of a single crystal of the high temperature superconductor, YBa2Cu3O7, are presented.
[35]
None
### Summary of Crystal Structure of YBa₂Cu₃O₇ (Orthorhombic)
[36]
{110} twinning in YBa 2 Cu 3 O 7-x
The orthorhombic ratio (b-a)/a has been shown to vary considerably across a number of twin domains in annealed material from 0.006 to 0.02.
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Doping a Mott insulator: Physics of high-temperature superconductivity
Jan 6, 2006 · This article reviews the physics of high-temperature superconductors from the point of view of the doping of a Mott insulator.
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In situ doping control of the surface of high-temperature ... - Nature
Jun 22, 2008 · Through in situ deposition of potassium atoms on cleaved YBCO, we can continuously control the surface doping and follow the evolution of the Fermi surface.
[39]
[PDF] arXiv:1007.4027v1 [cond-mat.supr-con] 22 Jul 2010
Jul 22, 2010 · YBCO phase diagram. (a) Schematics of the Fermi surface of optimally doped YBCO from band-structure calculations: three sheets of Fermi ...
[40]
[cond-mat/9511130] Superconducting state properties of a d-wave ...
Nov 27, 1995 · YBa_2Cu_3O_7 (YBCO) exhibits a large anisotropy between the a and b axes in the CuO_2 planes because of the presence of CuO chains. In order to ...
[41]
Superconducting Pairing State in YBCO from SQUIDs
Sep 27, 1993 · From the magnetic flux modulation of YBCO-Pb dc SQUIDs, we determine the spatial anisotropy of the phase of the order parameter in single ...
[42]
A common thread: The pairing interaction for unconventional ...
Oct 8, 2012 · It is proposed that spin-fluctuation mediated pairing is the common thread linking a broad class of superconducting materials.
[43]
Intra-unit-cell magnetic correlations near optimal doping in ... - Nature
Jul 3, 2015 · Here we present polarized neutron-scattering measurements of nearly optimally doped YBa 2 Cu 3 O 6.85 , carried out on two different spectrometers, that reveal ...
[44]
[PDF] The pseudogap - arXiv
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[45]
Direct observation of competition between superconductivity and ...
Oct 14, 2012 · X-ray diffraction experiments reveal that spatial charge ordering occurs in the pseudogap state of YBa2Cu3O6 ... YBCO is the pseudogap.
[46]
Competing charge, spin, and superconducting orders in underdoped
Aug 21, 2014 · We present a bulk-sensitive high-energy x-ray study for several oxygen concentrations, including strongly underdoped.
[47]
Conductors for commercial MRI magnets beyond NbTi
In this paper, we analyze conductor requirements for commercial MRI magnets beyond traditional NbTi conductors, while avoiding links to a particular magnet ...
[48]
New World-Record Magnet Fulfills Superconducting Promise
Dec 12, 2017 · One of the two YBCO coils used in the world-record 32-tesla all-superconducting magnet. Stephen Bilenky.
[49]
Magnetization and Creep in YBCO Tape and CORC Cables for ...
Feb 7, 2019 · Magnetization and Creep in YBCO Tape and CORC Cables for Particle Accelerators: Value and Modification Via Preinjection Cycle. Publisher: IEEE.
[50]
Request Rejected
- **Summary**: Insufficient relevant content. The requested URL (https://ieeexplore.ieee.org/document/4275918/) was rejected, and no information about the use of YBCO in fault current limiters for power grids or its commercial status is available from the provided content.
[51]
Development of Resistive Fault Current Limiters Based on YBCO ...
Aug 9, 2025 · In a cooperation between AMSC and Siemens the limiting capability of YBCO CCs has been investigated and was demonstrated in a successful ...
[52]
Superconducting quantum interference device instruments and ...
Oct 11, 2006 · MEDICAL APPLICATIONS OF SQUIDS. Electrical measurements of physiological potentials are well established in clinical diagnostics. Essentially ...
[53]
High-Tc squids - ScienceDirect.com
These devices are now sufficiently sensitive for use in an intriguing variety of applications, including geophysics, magnetocardiology, nondestructive ...Missing: medical | Show results with:medical
[54]
Development and large volume production of extremely high current ...
Jan 22, 2021 · In this article we demonstrate very high engineering current density in practical 2G HTS wires based on a simple YBCO superconductor formulation ...
[55]
[PDF] Examples and Future Prospects of High-Temperature ...
Compared with. BSCCO wire, YBCO wire has good critical current (Ic) versus magnetic field (B) characteristics and low pro- duction cost, because smaller silver ...Missing: statistics | Show results with:statistics
[56]
MIT-designed project achieves major advance toward fusion energy
Sep 8, 2021 · MIT and Commonwealth Fusion Systems scientists have created a 20 tesla magnetic field using a large, high temperature superconducting fusion ...
[57]
HTS magnets | Commonwealth Fusion Systems
HTS magnets are high-temperature superconducting magnets that enable stronger magnetic fields for smaller, high-performing fusion systems, and are the largest ...Missing: YBCO T planned
[58]
(PDF) The Effect of Critical Parameters of High Temperature ...
Aug 15, 2024 · To name one, these technologies, the levitating train operating at speeds exceeding 500 km/h. To study the efficiency and improvement of ...
[59]
Study of an YBCO HTS transmission cable system - ScienceDirect
HTS transmission cables offer an innovative transmission line that differs from conventional technologies because HTS cables can send bulk power with ...Missing: lossless | Show results with:lossless
[60]
MoRe/YBCO Josephson junctions and π-loops - IOPscience
The demonstrated ability to stabilise and manipulate states of π-loops paves the way towards new computing concepts such as quantum annealing computing.Abstract · Introduction · Experimental details · Results and discussion
[61]
Experimental study of a high-temperature superconducting induction ...
This research can be used to optimize the electromagnetic design of superconducting electric motors, as well as other superconducting magnet applications ...
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[PDF] UC Santa Cruz - eScholarship
Sep 2, 2025 · Table 2.1. Power Density Comparison of PM Motors for Electric Aircraft. Reference. Electric Motor. Power Density [kW/kg].
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[PDF] Tuning the critical temperature of cuprate superconductor films using ...
Many of the electronic properties of high-temperature cuprate superconductors (HTSC) are strongly dependent on the number of.
[64]
Controlling the Surface Properties of High Temperature ...
Molecular monolayer-based surface modification chem- istry, often referred to in the literature as "self-assembly", has been developed and used extensively for ...Missing: assembled | Show results with:assembled
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(PDF) Enhancement of YBCO superconductivity by chemical surface ...
Jul 20, 2024 · In our study, we investigated the effects of various solvents on the metal-to-superconductor transition (MST) of YBCO. Additionally, we explored ...Missing: Lewis acid-
[66]
https://arxiv.org/pdf/1401.3603
[67]
[PDF] ION AND PLASMA INDUCED PATTERNING OF YBa₂Cu307
The way to overcome the low selectivities of pure physical etching is to employ a chemical component in order to either increase the etch rate of the YBCO or ...
[68]
1 Introduction - arXiv
Nanopatterning of YBCO thin films by focused-ion-beam irradiation has proven to be a versatile method for fabricating ultradense vortex pinning landscapes and ...Missing: plasma | Show results with:plasma
[69]
Josephson Junctions and SQUIDs Created by Focused Helium-Ion ...
Apr 25, 2019 · To image possible structural modifications induced by He -FIB irradiation in our YBCO films, we use scanning transmission electron microscopy ( ...
[70]
Enhancing the critical current of YBa2Cu3O7 thin films by substrate ...
Dec 20, 2018 · ... Etching, Ion implantation ... Indeed, this process can be potentially damaging to the YBCO from ion implantation, handling, and water exposure.Missing: plasma | Show results with:plasma
[71]
Additively-manufactured monocrystalline YBCO superconductor
Feb 24, 2025 · Wu, M. K. et al. Superconductivity at 93 K in a new mixed-phase Y-Ba-Cu-O compound system at ambient pressure. Phys. Rev. Lett. 58, 908–910 ...Results And Discussion · Single-Crystal Growth · Methods
[72]
YBCO superconductor wire based on IBAD-textured templates and ...
Aug 6, 2025 · Our results indicate that cost of coated conductors can be below $10/kAm already at 5000 km production volume of 4-mm superconductor wire, with ...
[73]
[PDF] Reel-to-reel Characterization towards Feedback Control in ...
Large-scale, high-field superconducting applications raised the demand for accu- rate, non-destructive reel-to-reel characterization in order to assure uniform ...Missing: brittleness | Show results with:brittleness
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[PDF] High Performance HTS Tapes for High Field Magnet Applications
Sep 14, 2015 · • A primary driver of cost is manufacturing yield. • For high yield manufacturing, consistent wire performance is needed. • Uniformity of Ic ...Missing: brittleness | Show results with:brittleness