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Contact process

The Contact process is the primary industrial method for producing sulfuric acid on a large scale, involving the combustion of sulfur to form sulfur dioxide, the catalytic oxidation of sulfur dioxide to sulfur trioxide, and the hydration of sulfur trioxide to yield concentrated sulfuric acid.^[1] This process, which accounts for the majority of global sulfuric acid production, utilizes vanadium pentoxide (V₂O₅) as a catalyst in the key oxidation step to achieve high conversion efficiency under controlled conditions of approximately 450°C and 1–2 atm pressure.^[2]^[1] Sulfuric acid produced via this method is essential for numerous applications, including the manufacture of phosphate fertilizers (the largest use, consuming over 50% of production), petroleum refining, metal processing, and the synthesis of chemicals such as detergents, dyes, and batteries.^[3]^[4] The process begins with the burning of elemental sulfur (sourced primarily from natural deposits or as a byproduct of petroleum refining) in dry air to generate sulfur dioxide gas: S(s) + O₂(g) → SO₂(g).^[1]^[2] The sulfur dioxide is then purified to remove impurities like arsenic and dust before entering the converter, where it reacts with oxygen over multiple beds of V₂O₅ catalyst: 2SO₂(g) + O₂(g) ⇌ 2SO₃(g), achieving 95–99.8% conversion depending on whether single- or double-absorption designs are used.^[1] To avoid the hazardous direct reaction of sulfur trioxide with water, the SO₃ is absorbed into 98–99% concentrated sulfuric acid to form oleum (H₂S₂O₇), which is subsequently diluted: H₂S₂O₇ + H₂O → 2H₂SO₄(aq).^[2]^[1] Developed in the mid-19th century and refined through the 20th century, the Contact process has largely supplanted older methods like the lead chamber process due to its higher yield (up to 99.5% overall efficiency) and ability to produce acid of greater concentration.^[1]

History

Early Invention

The contact process for producing sulfuric acid was first patented in 1831 by British vinegar merchant Peregrine Phillips, who described a method for oxidizing sulfur dioxide to sulfur trioxide using platinum as a catalyst, followed by absorption to yield concentrated acid. This invention offered a more efficient alternative to the lead chamber process, enabling higher acid concentrations essential for industrial applications.^[5] Early implementation faced significant hurdles due to the platinum catalyst's limitations. The metal's high cost made large-scale use prohibitive, while its sensitivity to poisoning by arsenic and other impurities in sulfur dioxide sources caused rapid deactivation, reducing catalytic activity and overall process reliability.^[6] During the 1860s, experimental setups were developed to test the process, but they yielded low conversion efficiencies, with only partial oxidation of sulfur dioxide achieved under the conditions of the time. In the 1870s, commercial attempts were undertaken in the UK by Rudolph Messel, a chemist working with platinum catalysts, yet these efforts failed owing to ongoing issues with catalyst deactivation and insufficient conversion rates, rendering the process uneconomical for widespread adoption.^[7]

Commercial Development

The commercial viability of the Contact process emerged in the late 19th century, overcoming early challenges like catalyst poisoning through innovations in gas purification. In 1876, the firm Spencer Chapman and Messel established the first industrial-scale plant in Silvertown, London, where Rudolph Messel implemented purification techniques to remove arsenic and other impurities from sulfur dioxide gas streams. These steps, involving washing and drying the gases, prevented deactivation of the platinum catalyst and enabled consistent production of concentrated sulfuric acid, marking a pivotal shift from experimental setups to reliable manufacturing.^[8] A significant advancement occurred in the 1910s with the transition from platinum to vanadium pentoxide (V₂O₅) as the catalyst, driven by cost reduction and enhanced resistance to poisoning. BASF patented the use of V₂O₅ supported on silica with alkali metal promoters in 1913, allowing operation at lower temperatures and greater durability in impure feeds. This innovation, adopted widely by German firms, lowered production expenses—platinum costs had previously limited scalability—and facilitated larger plants, such as those operational in Germany by the early 1900s that produced fuming sulfuric acid for dyes and explosives.^[9] World War I accelerated adoption due to surging demand for sulfuric acid in munitions, prompting rapid expansion of Contact process facilities. In Europe, production ramped up to meet needs for fuming acid in high explosives, with German output increasing substantially to support wartime efforts. Post-war, the process gained traction in the United States during the 1920s, where initial plants like those by DuPont adopted V₂O₅ catalysis; the first U.S. contact plant had been built in 1899 at Mineral Point, Wisconsin.^[10]^[11]

Chemistry

Key Reactions

The Contact process for sulfuric acid production begins with the oxidation of elemental sulfur to sulfur dioxide, a highly exothermic reaction that serves as the initial step:

\text{S(s) + O}_2\text{(g) \to SO}_2\text{(g)}

This is followed by the primary reaction, the reversible catalytic oxidation of sulfur dioxide to sulfur trioxide:

$2 \text{SO}_2\text{(g) + O}_2\text{(g)} \rightleftharpoons 2 \text{SO}_3\text{(g)} \quad \Delta H = -198 \, \text{kJ/mol}

The reaction is exothermic, with the forward direction favored thermodynamically at lower temperatures but kinetically slow without catalysis. The stoichiometry can also be expressed on a per-mole basis: \text{SO}_2 + \frac{1}{2} \text{O}_2 \to \text{SO}_3, which remains equilibrium-limited due to the reversible nature of the process.^[12] The final step involves the formation of sulfuric acid through absorption of sulfur trioxide, but direct hydration with water (\text{SO}_3 + \text{H}_2\text{O} \to \text{H}_2\text{SO}_4) is avoided due to the highly exothermic nature of the reaction, which produces a persistent mist of fine sulfuric acid droplets difficult to condense and handle industrially. Instead, sulfur trioxide is absorbed into concentrated sulfuric acid to form oleum (\text{H}_2\text{S}_2\text{O}_7), which is then hydrolyzed: \text{H}_2\text{S}_2\text{O}_7 + \text{H}_2\text{O} \to 2 \text{H}_2\text{SO}_4. This indirect route ensures efficient production while managing heat release.^[12] Thermodynamically, the equilibrium constant K_p for the primary reaction decreases with increasing temperature, consistent with Le Chatelier's principle for exothermic equilibria, as described by the van't Hoff equation. The uncatalyzed forward reaction has a very high activation energy (over 200 kJ/mol), making it kinetically unfeasible at practical temperatures. Vanadium pentoxide reduces the effective activation energy to approximately 85–100 kJ/mol, enabling the process at moderate temperatures around 450°C.^[13]

Catalysis and Equilibrium

The catalytic oxidation of SO₂ to SO₃ in the Contact process utilizes vanadium pentoxide (V₂O₅) as the primary promoter catalyst, supported on a porous carrier such as silica and operating within a molten alkali pyrosulfate salt system at 400–600°C. The mechanism commences with the adsorption of SO₂ onto the catalyst surface, particularly at bridging V–O–M sites (where M denotes alkali metals like potassium or cesium), forming a surface-bound sulfur-oxygen complex. This is followed by oxidation via a Mars–van Krevelen-type redox cycle, in which V⁵⁺ species are reduced to V⁴⁺ while facilitating the incorporation of lattice oxygen into SO₃, with gaseous O₂ subsequently reoxidizing the reduced vanadium sites to regenerate the active V⁵⁺ form; the SO₃ then desorbs, completing the cycle. This redox process ensures efficient turnover, with the molten salt phase (e.g., K₂S₂O₇–V₂O₅) enhancing vanadium mobility and activity while mitigating deactivation from V⁴⁺ accumulation at lower temperatures.^[14]^[15] Given the exothermic nature of the SO₂ + ½O₂ ⇌ SO₃ reaction, equilibrium management is critical to maximize yield while sustaining kinetics. Per Le Chatelier's principle, decreasing temperature shifts the equilibrium toward SO₃ formation by favoring the exothermic direction, yet excessively low temperatures (<400°C) hinder the reaction rate due to reduced catalyst activity and increased SO₃ inhibition. An optimal operating temperature of 400–450°C thus balances high equilibrium conversion (approaching 100% theoretically) with practical kinetics, allowing sufficient SO₃ production without excessive energy input for heating. To further drive the equilibrium forward and counteract O₂ consumption, excess air is introduced, maintaining 7–10% O₂ in the feed gas; this dilutes SO₂ (typically to 7–10% concentration) but promotes conversion by increasing reactant availability.^[14]^[16] Catalyst bed design addresses the reaction's exothermicity and equilibrium limitations through a multi-stage adiabatic converter, typically comprising 4–5 sequential beds with intercooling between stages to remove heat and prevent hotspots that could shift equilibrium reversibly. Incoming gas at ~400°C passes through the first bed, where rapid SO₂ oxidation raises the temperature to ~600°C; intercoolers then reduce it back to ~400–420°C before the next bed, enabling progressive conversion while keeping conditions near the kinetic optimum and avoiding sintering of the V₂O₅ phase. This staged approach, combined with moderate pressure (1–2 atm) to enhance gas throughput without excessive compression costs, achieves overall SO₂-to-SO₃ conversion efficiencies of 99.5–99.8%, influenced by precise control of gas composition (low SO₂ to minimize reversal) and minimal impurities that poison the catalyst.^[16]

Core Process

Sulfur Dioxide Generation

The primary method for generating sulfur dioxide (SO₂) in the Contact process involves the combustion of elemental sulfur in dry air within a dedicated furnace. Molten sulfur, heated to approximately 140°C for fluidity, is atomized using spray nozzles or spinning cups and introduced into the combustion chamber along with excess dried air (typically containing less than 0.05 g/Nm³ water vapor) to ensure complete oxidation via the reaction S + O₂ → SO₂. This produces a hot gas stream with SO₂ concentrations of 9-11% by volume, alongside excess oxygen (about 10-12%) and nitrogen as diluent.^[17]^[1] The combustion reaction is highly exothermic and occurs at temperatures ranging from 850°C to 1100°C, generating gas exit temperatures up to 1127°C in the furnace. To manage these high temperatures and recover energy, the SO₂-laden gases are immediately passed through waste heat boilers, where they are cooled to around 420-450°C while producing high-pressure steam (40-60 bar) at a rate of approximately 3.88 tonnes per tonne of sulfur burned. This energy recovery step enhances the overall efficiency of the sulfuric acid plant. Dry air is preferentially used in this method to minimize moisture introduction, which could otherwise promote premature sulfuric acid formation; in contrast, wet methods may apply to alternative feedstocks where inherent water content is present. Typical gas flow rates from a single sulfur burner unit range from 1000 to 2000 m³/h, scalable based on plant capacity.^[17]^[1]^[18] Elemental sulfur feedstocks, primarily recovered from petroleum and natural gas processing, introduce trace impurities such as arsenic (As), selenium (Se), and mercury (Hg), typically at levels below 1000 ppm total, which can carry over into the SO₂ gas and affect downstream catalysis. These impurities originate from geological deposits and require careful sulfur filtration prior to burning to maintain gas quality.^[19]^[1] Alternative methods for SO₂ generation include roasting sulfide ores, such as pyrite (FeS₂), in fluidized bed reactors at temperatures up to 1200°C, yielding SO₂ through partial oxidation (e.g., 4FeS₂ + 11O₂ → 2Fe₂O₃ + 8SO₂) and producing iron oxide byproducts. Another approach utilizes off-gases from metallurgical smelters, which contain 10-20% SO₂ from the oxidation of metal sulfides during ore processing, directly feeding these streams into the Contact process after initial conditioning. These alternatives are employed when elemental sulfur is scarce or when integrating with mining operations, though they often introduce higher impurity loads compared to sulfur burning.^[20]^[21]

Gas Purification

In the Contact process for sulfuric acid production, gas purification is essential to remove impurities from the sulfur dioxide (SO₂) stream after its generation, preventing catalyst deactivation and ensuring high conversion efficiency. Impurities such as dust, acid mist, arsenic compounds, and other gaseous contaminants can poison the vanadium pentoxide (V₂O₅) catalyst used in the subsequent oxidation step, reducing its activity by forming inactive compounds or blocking active sites.^[22] Additionally, halides (e.g., chlorides) and fluorine must be minimized to avoid corrosion and further catalyst impairment.^[22] Key impurities are addressed through targeted removal techniques. Dust particles are captured using cyclone dust collectors or electrostatic precipitators, achieving dust levels below 10 ppm to safeguard converter beds.^[1] Arsenic, primarily present as arsenious oxide (As₂O₃), is removed via passage through ferric hydroxide filters, where it forms insoluble arsenate compounds, reducing concentrations to less than 1 ppm.^[1] Sulfur mist and fine acid droplets are eliminated using mist eliminators, such as fiber-based vertical tube or dual-pad designs, often in combination with Venturi scrubbers for enhanced separation.^[1] After cooling in waste heat boilers to 420–450°C, the SO₂ gas undergoes purification to remove any residual impurities before entering the converter. The gas is then washed in scrubbing towers with dilute sulfuric acid (typically 1–10% concentration) to remove soluble impurities and further reduce mist.^[1]^[12] Drying follows in packed towers using 93–98% sulfuric acid, which absorbs residual moisture to below 0.1%, preventing hydrolysis of the catalyst and ensuring optimal reaction conditions.^[1] These purification innovations were pivotal in scaling the Contact process commercially, with Rudolf Messel's developments around 1898 enhancing gas cleaning efficiency and enabling reliable large-scale operation by addressing catalyst poisoning challenges.

Catalytic Oxidation

The catalytic oxidation of sulfur dioxide (SO₂) to sulfur trioxide (SO₃) occurs in a multi-bed converter, which serves as the core reaction vessel in the Contact process.^[23] Converters are typically designed as either radial-flow or axial-flow systems to facilitate efficient gas distribution through the catalyst beds. Radial-flow converters, often constructed from stainless steel for enhanced durability, feature a cylindrical shell where gas enters radially and flows inward or outward across the beds, minimizing pressure drop and allowing for larger capacities. Axial-flow designs, more common in conventional carbon steel converters, direct gas linearly through the beds from top to bottom. Both types incorporate 4 to 5 catalyst beds, with inter-bed cooling to manage the exothermic reaction heat, often via external heat exchangers that generate steam for plant energy recovery.^[23]^[16] Operating conditions are optimized to maximize conversion while preventing catalyst deactivation. The inlet gas temperature to the first bed is maintained at approximately 400°C to ignite the reaction, with overall pressure ranging from 1 to 2 atm to keep operations near atmospheric levels and reduce equipment stress. Gas velocity through the beds is controlled at 1 to 2 m/s to ensure uniform flow and avoid channeling, while heat management is critical to prevent hotspots exceeding 600°C, which can sinter the catalyst and reduce its activity.^[16]^[6] The oxidation proceeds in stages across the catalyst beds under adiabatic conditions, with cooling between beds to lower the temperature before subsequent passes. In a standard 4-bed converter, the first bed achieves 60-70% SO₂ conversion, where the temperature rise due to the exothermic reaction is most pronounced. Subsequent beds incrementally increase conversion, reaching a total of 99.7% SO₃ yield by the final bed. In some configurations, unconverted tail gas is recycled to the converter inlet to boost overall efficiency, particularly in plants aiming for higher purity. Equilibrium limitations, influenced by temperature and gas composition, constrain per-bed conversion but are addressed through this staged approach.^[16] The catalyst consists of vanadium pentoxide (V₂O₅), typically 6-9 wt%, supported on a porous silica carrier to provide high surface area and stability. It is formed into shapes such as cylindrical pellets (6-8 mm diameter) or rings (10 mm outer diameter with 4 mm holes) to balance reactivity and pressure drop; ring shapes reduce pressure loss by up to 50% compared to pellets, enabling higher throughput. These forms promote a molten salt film mechanism at operating temperatures, enhancing SO₂ oxidation selectivity.^[6]

Sulfur Trioxide Absorption

The sulfur trioxide (SO₃) generated in the catalytic oxidation stage enters the absorption system after cooling to remove excess heat. This step utilizes a counter-current packed absorption tower, typically a vertical cylindrical vessel constructed from corrosion-resistant materials such as brick-lined carbon steel or specialty alloys, filled with packing like ceramic saddles or rings to maximize gas-liquid contact. Strong sulfuric acid (98-99% H₂SO₄) circulates as the absorbent, introduced at the top of the tower while the SO₃-laden gas rises from the bottom, enabling efficient mass transfer.^[24]^[1] The absorption reaction forms sulfuric acid through the hydration of SO₃, represented as SO₃ + H₂O → H₂SO₄, but direct contact with free water is avoided to prevent the formation of fine acid mist droplets that are difficult to capture. Instead, SO₃ first reacts with concentrated H₂SO₄ to produce oleum (H₂S₂O₇), which is then carefully diluted under controlled conditions. The circulating acid is cooled, often to around 80°C, using heat exchangers to manage the exothermic reaction and optimize solubility and absorption rates, with inlet temperatures typically ranging from 65-85°C depending on regional practices. In the single absorption configuration, gas flows through one primary tower, though some designs employ two towers in series to achieve the desired acid strength while maintaining process efficiency.^[1]^[25]^[24] This setup yields sulfuric acid at 98% concentration, with SO₃ capture efficiency exceeding 99.7% under optimal conditions, minimizing emissions and stack opacity. If higher concentrations are needed, the process can produce oleum as an intermediate, where excess SO₃ forms disulfuric acid (H₂S₂O₇). Mist eliminators at the tower outlet capture any entrained droplets, ensuring clean tail gas.^[1]^[25] Dilution of the absorbed acid generates weaker streams, which are recycled back into the process—often to the drying tower or for controlled water addition—to maintain circulation concentrations and overall material balance, reducing waste and enhancing resource efficiency.^[24]^[1]

Advanced Variants

Double Contact Double Absorption

The Double Contact Double Absorption (DCDA) process represents a key advancement in the Contact process for sulfuric acid production, enabling near-complete conversion of sulfur dioxide to sulfur trioxide through staged oxidation and absorption. In the process flow, sulfur dioxide gas is first oxidized in a multi-bed catalytic converter to achieve approximately 99% conversion to sulfur trioxide, after which the gas enters the first absorption tower where roughly 90% of the SO₃ is absorbed into concentrated sulfuric acid (98-99%), forming oleum. The resulting tail gas, still containing unreacted SO₂ (about 0.3-0.5%), is then reheated and passed through a second converter stage for additional oxidation before entering the second absorption tower, where the remaining SO₃ is captured, yielding an overall SO₂ conversion efficiency of 99.7% or higher.^[26]^[1]^[27] This configuration incorporates two absorption towers and an intermediate converter pass, optimizing equilibrium shifts to maximize yield while minimizing unreacted gases, and is typically employed in large-scale facilities producing over 300 tons of sulfuric acid per day. Developed to address emission limitations, the DCDA process was introduced during the 1950s and 1960s, with the first commercial installation operational in March 1964 by Farbenfabriken Bayer AG in Germany; by 1967, over 20 such plants were in use worldwide.^[27]^[1] Key advantages include elevating SO₂ conversion from 97-98% in single-absorption systems to 99.5-99.8%, which reduces stack SO₂ emissions to 100-240 ppm—about one-tenth of single-absorption levels—and limits overall SO₂ emissions to approximately 2 kg per metric ton of acid produced, positioning DCDA as a best available control technology for environmental compliance. The process also supports higher feed SO₂ concentrations (up to 13%), enhancing throughput and equipment efficiency without increasing plant size proportionally.^[27]^[1]

Wet Sulfuric Acid Process

The Wet Sulfuric Acid (WSA) process, developed by Haldor Topsoe A/S in the early 1980s, serves as a compact alternative to traditional sulfuric acid production methods for handling low-grade or impure sulfur-containing gases, such as those from metallurgical operations or refineries.^[28] Unlike conventional dry absorption techniques that require gas drying and multi-stage absorption towers, the WSA process operates entirely with wet process gas, enabling direct conversion of sulfur compounds like H₂S or SO₂ into commercial-grade sulfuric acid without intermediate purification steps.^[29] The technology combusts sulfur-bearing feed gases to produce SO₂, followed by catalytic oxidation to SO₃, and then hydrolyzes the SO₃ with water vapor present in the gas stream to form sulfuric acid vapor, which is condensed into liquid acid at approximately 98% concentration.^[28] This integrated approach achieves high efficiency, with overall sulfur recovery rates of 98-99.8%.^[28] The key steps of the WSA process begin with preheating the sulfurous feed gas—often containing H₂S, SO₂, or other sulfides—and mixing it with combustion air and fuel if needed. This mixture undergoes oxidation in a combustion chamber or, for certain feeds like H₂S-rich gases, a fluid bed reactor to convert sulfur compounds to SO₂ while maintaining the gas in a wet state.^[28] The SO₂-laden gas is then passed through one to three fixed-bed catalytic reactors containing specialized VK-WSA vanadium-based catalysts, where it is oxidized to SO₃ at temperatures around 400-600°C, achieving conversion efficiencies exceeding 99.7% even for dilute feeds (as low as 0.1-10% SO₂).^[29] The resulting SO₃ reacts with residual water vapor in the wet gas stream to form gaseous H₂SO₄, which enters the proprietary WSA condenser—a heat recovery unit where the acid vapor is cooled to 80-120°C and condensed directly into liquid sulfuric acid without requiring a separate absorption tower or drying equipment.^[28] The process is autothermal for SO₂ concentrations above 3%, generating high-pressure superheated steam (up to 40 bar) from waste heat for plant use or export, while tail gas emissions are minimized to near-zero SOₓ levels.^[29] A primary advantage of the WSA process is its ability to process impure, wet sulfur sources like smelter off-gases or refinery acid gases that are challenging for traditional methods, reducing SOₓ emissions by over 99% and enabling compliance with stringent environmental regulations.^[28] Its compact design results in a smaller plant footprint—typically 50-70% less than double-contact double-absorption systems—along with lower capital and operating costs due to simplified equipment and high energy efficiency (e.g., 45-50 kWh per metric ton of acid produced).^[28] The process also eliminates the need for tail gas treatment units in many cases, as the clean tail gas (with <10 ppm SO₂) can be directly vented or integrated into downstream operations.^[29] The WSA process is widely applied in metallurgical plants for treating off-gases from non-ferrous smelters, such as copper or zinc production, where it recovers sulfur from dilute SO₂ streams that would otherwise be emitted.^[28] It is also integrated into oil refineries for handling H₂S from amine units or spent alkylation acids, and in petrochemical facilities for gasifier off-gases. The first commercial WSA plant was commissioned in 1990 at N.V. Sadaci S.A. in Belgium, processing sulfuric acid plant tail gases, and by 2006, over 55 units had been installed worldwide across 25 countries. As of 2023, the technology has over 170 global references.^[28]^[30] It continues to be licensed for new installations and retrofits as of 2025, supporting sustainable sulfur management in heavy industry.^[29]

Significance and Impacts

Industrial Applications

The Contact process serves as the cornerstone for industrial sulfuric acid production, enabling the manufacture of high-purity acid essential for diverse sectors. Globally, sulfuric acid output via this process exceeds 90% of total production, supporting an annual volume of approximately 270 million metric tons as of 2024.^[31]^[32] The primary application of sulfuric acid lies in fertilizer production, which consumes around 60% of global supply, predominantly through the wet process to convert phosphate rock into phosphoric acid for phosphate-based fertilizers like superphosphate. Petroleum refining accounts for about 15% of usage, where the acid facilitates alkylation processes to produce high-octane gasoline and removes impurities from hydrocarbon streams.^[33] Metal processing utilizes roughly 10%, including applications in pickling steel to remove rust and scale prior to galvanizing, as well as in hydrometallurgical extraction of non-ferrous metals.^[12] Sulfuric acid is often integrated as a captive byproduct in mining operations, such as copper leaching via the solvent extraction-electrowinning (SX-EW) method, where it regenerates during ore processing to enhance metal recovery efficiency.^[34] In chemical synthesis, it supports the production of detergents, dyes, and pigments by acting as a catalyst or dehydrating agent in sulfonation reactions.^[12] Market dynamics reflect robust demand growth in emerging economies, driven by expanding agricultural needs and industrialization in regions like Asia-Pacific and Africa, with projected annual increases of 3-4% through 2030.^[32] Market prices typically range from $100 to $150 per metric ton, influenced by raw material prices and energy inputs, underscoring the process's economic viability at scale.^[35]

Environmental Considerations

Modern sulfuric acid plants employing the Contact process have significantly reduced SOx emissions through advanced designs like double contact double absorption (DCDA), achieving stack gas SO2 concentrations below 50 ppm in compliant facilities. NOx emissions primarily arise from combustion of sulfur or other feedstocks and are typically controlled to levels below 100 ppm via low-NOx burners and selective catalytic reduction where necessary. Continuous stack gas monitoring is mandated to ensure compliance, with real-time sensors tracking SOx and NOx to prevent exceedances.^[36]^[37] Waste management in the Contact process focuses on recycling spent vanadium pentoxide catalysts, from which vanadium is recovered via hydrometallurgical or pyrometallurgical methods, such as roasting and leaching with sodium carbonate or sulfuric acid, yielding over 90% recovery rates and minimizing landfill disposal. Acid mist, formed during SO3 absorption, is controlled using demisters—typically mesh pads or fiber beds—that capture droplets larger than 3-5 microns, reducing emissions to less than 0.075 lb per ton of acid produced. Water usage for cooling process gases and equipment is optimized in modern plants, with closed-loop systems recirculating water to limit consumption to approximately 1-2 m³ per ton of H2SO4, though evaporation in cooling towers requires makeup water treatment to prevent scaling.^[38]^[39]^[1] Sustainability efforts in the Contact process emphasize energy efficiency, with state-of-the-art plants generating approximately 6 GJ of thermal energy per ton of H₂SO₄ through heat recovery from exothermic reactions to generate steam for power or process use. The carbon footprint of conventional production is around 0.14 tons CO₂ equivalent per ton of acid, largely from feedstock combustion, but can be lowered by sourcing "green sulfur" recovered from biogas desulfurization processes that convert H₂S to elemental sulfur via biological oxidation. Post-2010 advancements include SO₂ recycling from industrial flue gases into sulfuric acid via wet gas processes, enabling carbon-neutral production by utilizing waste emissions instead of fossil-derived sulfur; as of 2025, adoption of such integrated systems has increased in Europe and North America to meet stricter emissions targets.^[40]^[41]^[42] Regulatory frameworks enforce these practices, with U.S. EPA New Source Performance Standards limiting SO2 to 2 lb per ton of acid and acid mist to 0.075 lb per ton, while EU Industrial Emissions Directive best available techniques reference documents (BREF) require SO2 emissions below 200 mg/Nm³ (about 70 ppm) for new plants, driving ongoing improvements in emission controls and resource recovery.^[36]^[43]

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A World of Sulfur by AK Tyagi, Nuberg EPC
In the 18th century, the contact process was developed by Rudolf Messel ... The contact process is an improved version for the commercial production of sulfuric ...Missing: Rudolph | Show results with:Rudolph
[31]
Sulfuric Acid Market, Industry Size Forecast [Latest]
The global sulfuric acid market is expected to grow from USD 41.23 billion in 2025 to USD 49.94 billion by 2030, at a CAGR of 3.9% during the forecast period.
[32]
Sulfuric Acid Market Size, Share And Growth Report, 2030
The global sulfuric acid market size was estimated at USD 13.39 billion in 2022 and is projected to reach USD 17.94 billion by 2030, growing at a CAGR of 3.7% ...Market Size & Forecast · Application Insight · Regional Insight<|control11|><|separator|>
[33]
[PDF] sulfur - Mineral Commodity Summaries 2024 - USGS.gov
Elemental sulfur production was estimated to be 8.0 million tons; Louisiana and Texas accounted for about 52% of domestic production. Elemental sulfur was ...
[34]
Sulphuric Acid Prices, Trends, Index, News, Monitor and Demand
The average Sulphuric Acid price for the quarter was approximately USD 79.67/MT, per regional assessment. • Sulphuric Acid Spot Price softened in late September ...Missing: $100-150 | Show results with:$100-150
[35]
Sulfuric Acid Plants: New Source Performance Standards (NSPS)
The New Source Performance Standards (NSPS) for Sulfuric Acid Plants regulate emissions of particulate matter, sulfur dioxide, nitrogen oxides, and sulfuric ...Missing: EU SOx
[36]
[PDF] Pollution Prevention and Control in the European Sulphuric Acid ...
4.1.2.3 Double contact process (double absorption). In the double contact process, a primary conversion efficiency of 80% to 93%, depending on the ...
[37]
Catalysts Recycling - Sulphuric Acid on the Web
Vanadium is recovered from spent catalyst using one of two methods; Hydrometallurgy or Pyrometallurgy. Hydrometallugy. The recovery of vanadium starts with the ...
[38]
Guideline Series Final Guideline Document Control Of Sulfuric Acid ...
1.4 CONTROL OF ACID MIST EMISSIONS FROM EXISTING PLANTS. Good control of sulfuric acid mist emissions from existing contact sulfuric acid plants can be ...
[39]
[PDF] SULPHURIC ACID PRODUCTION
Sulphuric acid is produced using purified liquid sulphur, which is combusted to SO2, then oxidized to SO3, and finally absorbed to create H2SO4.
[40]
Sulfuric acid (H2SO4). E513 · 0.14 kg CO₂e/kg - CarbonCloud
Sulfuric acid (H2SO4). E513 has a carbon footprint of 0.14 kg CO₂e/kg at factories worldwide. Check how it compares to other ingredients in ClimateHub.
[41]
Sulfothane™ | Veolia Water Technologies
Sulfothane is a combination of an alkaline scrubber column combined with a biological alkalinity recovery step including the production of elemental sulfur.
[42]
[PDF] EMEP/EEA air pollutant emission inventory guidebook 2023
Oleum plants also produce mist emissions of sulphuric acid. (3). For sulphuric acid production only SO2 is relevant. Other pollutants may be released from ...Missing: regulations | Show results with:regulations