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Dynode

A dynode is an in an , such as those used in s and other detectors, that functions to produce secondary emission of s when struck by primary s or ions, thereby enabling the amplification of weak signals through a . The dynode was first conceptualized in 1930 by Soviet-Russian physicist Leonid Aleksandrovich Kubetsky, who proposed its use in a novel device to amplify weak photocurrents by integrating a photocathode with multiple secondary-emission stages, marking the invention of the . Kubetsky's design achieved gains of up to 10⁴ by 1933–1934 through the use of materials like Ag-O-Cs for the emitting surfaces and magnetic focusing to direct paths, though his contributions were initially overlooked in Western literature. In 1936, V.K. Zworykin and colleagues at Laboratories developed and published a similar multi-stage multiplier, which popularized the technology globally and led to widespread adoption in devices. In a typical discrete-dynode electron multiplier, several dynodes—often 12 to 24 in number—are arranged sequentially within a envelope, with each subsequent dynode maintained at a progressively higher positive potential relative to the previous one via a resistive . When an incoming ion or strikes the first dynode, it liberates multiple due to the secondary (typically 3–5 electrons per incident particle), which are then accelerated toward the next dynode, repeating the process to generate an exponential cascade and overall gains ranging from 10⁴ to 10⁸ depending on the number of stages and operating voltage. Dynode surfaces are coated with materials like beryllium-copper alloys, cesium-activated , or oxides to optimize secondary efficiency while minimizing noise from dark current (often below 1 pA at moderate gains). Dynodes are essential in applications requiring high-sensitivity detection of charged particles or photons, including positive and negative ion detection in and field-ion , where they provide rapid response times and enable photon-counting modes for trace analysis. They also feature prominently in photomultiplier tubes for vacuum ultraviolet spectroscopy, (such as ESCA and ), and soft detection, offering gains up to 10⁸ with low noise for precise measurement of low-light or low-flux signals. Variations like conversion dynodes, which apply high voltages (around 10 kV) to enhance ion-to-electron conversion, extend their utility to detecting heavy ions in .

History

Invention and Early Development

The concept of the dynode originated in the context of early experiments focused on through secondary . In 1918, Albert W. Hull at invented the dynatron oscillator, a circuit that exploited secondary from a to produce effects, enabling oscillation without external components. This marked the first practical use of a dynode-like structure for multiplication, though initially applied to generation rather than light detection. During the early , researchers began exploring secondary emission more systematically for amplification in vacuum tubes, building on Hull's work to enhance gain in triodes and early tetrodes, well before its adoption in applications. These developments addressed limitations in signal amplification for radio and early electronic circuits, where secondary emission from grids or plates was harnessed to boost currents, paving the way for multi-stage designs. By 1922, Albert W. Hull introduced the term "dynode" for the secondary-emitting in his work on vacuum tubes. The integration of dynodes into photomultiplier tubes (PMTs) for light detection began in the 1930s. On August 4, 1930, Soviet physicist Leonid Aleksandrovich Kubetsky proposed the first , integrating a photocathode with multiple secondary-emission stages (dynodes) to amplify weak photocurrents. By 1933–1934, Kubetsky developed practical tubes using Ag-O-Cs materials for emitting surfaces and magnetic focusing, achieving gains of up to 10⁴. These "Kubetsky tubes" were demonstrated in the USSR, though his contributions were initially overlooked in Western literature. In September 1934, Vladimir Zworykin visited Leningrad and observed Kubetsky's work. Independently, in 1935, Harley Iams and Bernard Salzberg at Laboratories developed the first practical prototype of a single-stage , combining a photocathode with a dynode to achieve amplification factors of around 6 through secondary emission, significantly improving sensitivity for weak optical signals. This was followed in 1936 by Zworykin, George Morton, and Louis Malter at , who introduced multi-stage dynode chains in , enabling gains up to 10⁶. This design led to the first commercial , the Type 931, introduced in 1941. Post-World War II research from 1949 to 1956 brought key refinements to dynode chains in , with contributions from engineers like G.A. Morton focusing on optimizing voltage distribution and geometries for higher and reduced in multi-stage amplification. These improvements enhanced overall PMT performance, making them more reliable for scientific and increasing stability across dynode stages.

Naming and Terminology

The term "dynode" was coined by Albert W. Hull in 1922 while working at the General Electric Research Laboratory, to designate the in vacuum tubes that emits for purposes. Derived from "dynatron"—a device Hull had previously invented—the name combines the prefix "dyn-" (rooted in "dynamic," from the Greek dunamis meaning power) with the suffix "-ode" (indicating an ). The distinction between "dynatron" and "dynode" is important: the former refers to the complete structure, patented by in 1921, which exhibits through secondary electron emission for use in oscillators and amplifiers, whereas the latter specifically identifies the amplifying within such devices. The evolution of the terminology began with Hull's foundational 1918 paper describing the dynatron invention as a precursor device, but without employing the term "dynode," which received its formal introduction in his 1922 proceedings contribution to the (AIEE). In early literature on electron multipliers and vacuum tube technology, the dynode was often described using alternative nomenclature such as "multiplier electrode" or "secondary emission electrode" to emphasize its role in electron amplification.

Physical Principles

Secondary Electron Emission

Secondary electron emission is the process by which low-energy electrons are released from the surface of a solid material upon bombardment by higher-energy primary electrons or ions, resulting from the transfer of kinetic energy that excites and liberates bound electrons within the material. This phenomenon occurs when incident primary electrons penetrate the material, undergoing inelastic collisions that generate internal secondary electrons through excitation processes, such as the creation of electron-hole pairs in semiconductors or free electrons in conductors. The emitted secondary electrons typically have kinetic energies below 50 eV, often less than 5 eV, and their escape from the surface is governed by the probability of overcoming the material's surface potential barrier. The key parameter characterizing secondary electron emission is the secondary emission yield, denoted as \delta, defined as the ratio of the number of emitted secondary electrons (N_s) to the number of incident primary electrons (N_p): \delta = \frac{N_s}{N_p} For materials commonly used in dynodes, \delta typically ranges from 2 to 10 under operational conditions. The yield \delta(E) depends strongly on the energy E of the primary electrons, exhibiting a characteristic curve that rises from near zero at low energies (due to insufficient penetration), reaches a maximum at around 500–1000 eV (where the generation and escape probabilities are optimized), and then declines at higher energies as primaries penetrate deeper than the escape depth of secondaries. This energy dependence arises from the balance between secondary electron generation via inelastic scattering and their transport to the surface, where factors like the material's work function and band structure influence escape efficiency. The escape probability of secondary electrons is particularly sensitive to surface properties, including the (the minimum energy required to remove an from the surface) and the band structure, which determine how effectively excited electrons can reach and surmount the vacuum barrier without retrapping. In the three-step model of secondary emission, generation occurs through cascading inelastic events within ~10 of the surface, followed by diffusion and potential backscattering during transport, with only a fraction (~0.1–1%) ultimately escaping. Secondary electron emission was first observed in 1902 by L. H. Austin and H. Starke during experiments on interactions with metal surfaces. Its application to emerged in the 1910s, notably with Albert W. Hull's invention of the dynatron in 1918, which exploited secondary emission from the to produce for oscillatory and purposes. This process underpins the multiplication stages in dynode chains, where each emission event contributes to signal enhancement.

Gain Mechanism

In photomultiplier tubes, the gain mechanism begins when a primary photoelectron emitted from the photocathode is accelerated toward the first dynode by an electric potential difference of approximately 90-300 V, striking its surface and inducing secondary electron emission with a yield of δ secondary electrons per incident primary. These secondary electrons are then accelerated to the subsequent dynode, where each emits δ additional secondaries, creating a cascading multiplication effect across multiple dynode stages, typically 10-14 in number. This staged process results in an exponential increase in electron count, with the total gain G theoretically given by G = δ^n, where n is the number of dynode stages. The voltage configuration plays a critical role in maintaining efficient , with inter-dynode potentials progressively increasing—often around 100 V per stage—to ensure high exceeding 95% by directing electrons accurately to the next dynode. Key factors influencing gain include the uniformity of , which must be optimized to prevent electron loss; dynode spacing of 1-2 mm, which minimizes time and enhances collection; and the inherent of each dynode (typically 10-100 MΩ), which allows for even current distribution across the dynode surface to avoid localized overloads. These elements collectively enable stable amplification while adapting to varying operational conditions. However, the mechanism has limitations, such as gain saturation at high input currents due to space charge effects, where accumulated electrons repel incoming ones, reducing efficiency; overall gains typically range from 10^5 to 10^8 electrons per input photoelectron under normal conditions. A more precise expression for the overall gain accounts for collection efficiency ε (ranging from 0.9 to 0.99), yielding G ≈ (δ ε)^n; this arises from the single-stage multiplication factor of δ · ε (emitted secondaries times the fraction collected at the next stage), which compounds across n identical stages to produce the total. G \approx (\delta \varepsilon)^n

Design and Materials

Types of Dynode Structures

Dynode structures in electron multipliers, particularly photomultiplier tubes (PMTs), are designed to optimize secondary electron emission while balancing gain, timing, and efficiency. Discrete dynode configurations consist of multiple staged electrodes, each shaped to direct electrons toward the next stage for multiplication. These structures vary in geometry to address trade-offs such as electron path length, focusing precision, and uniformity. The Venetian blind structure employs multi-slotted plates arranged in parallel, providing a large secondary surface area for moderate to high but resulting in longer trajectories that lead to poorer timing . In contrast, the box-and-grid type uses box-like enclosures with intervening grids to enhance focusing and collection, offering improved and stable at the cost of similar timing limitations to the Venetian blind. Linear-focused dynodes feature curved plates that generate uniform , enabling shorter, more direct paths for superior timing and high in compact designs. The circular-cage arranges dynodes in a cylindrical cage-like formation, achieving compact geometry with fast response and good uniformity, though it may require higher voltages for optimal . Continuous dynode structures, such as microchannel plates (MCPs), function as arrays of millions of tiny parallel channels, each approximately 6-12 μm in diameter, acting like numerous independent dynodes in a thin plate (typically 0.4-1 mm thick). Electrons enter the channels and generate along the walls via a , yielding gains up to 10^4 per single plate and up to 10^6-10^7 when stacked, with excellent due to the parallel operation. Other variants include transmission dynodes, which use thin foils or meshes where incident electrons pass through the material, emitting secondaries from both surfaces to enable bidirectional multiplication and compact layouts with high linearity. Magnetic-focused dynodes incorporate external magnetic fields to control electron trajectories, reducing spread and improving focusing in early designs from the 1940s, though modern implementations often integrate this with other structures for enhanced stability in magnetic environments. Performance trade-offs across these structures are evident in key metrics: collection efficiency, the ratio of electrons reaching the effective dynode area, typically ranges from 90-99% in well-focused designs, minimizing losses between stages. Transit time spread (TTS), measuring , varies from 0.3-1 ns in linear-focused and circular-cage types to 4-9 ns in Venetian blind and box-and-grid configurations, influencing overall response speed. Spatial uniformity, reflecting consistent output across the active area, is generally high (20-40% variation or better) in head-on dynodes and exceptional in MCPs due to their distributed channels.

Materials Used

Dynodes in photomultiplier tubes and other electron multipliers typically employ surface coatings optimized for high secondary electron emission yields (δ), with materials selected for their ability to produce multiple secondary electrons per incident primary electron. Common materials include metal oxides such as and , which provide δ values of approximately 3.4 at 2000 eV for BeO and up to 24.3 at 1300 eV for MgO, enabling efficient electron multiplication. Alkali antimonides, such as Na-K-Sb or Cs-Sb, are also used as dynode coatings, offering stable gain at lower operating voltages compared to oxide-based alternatives, though they are more commonly associated with photocathodes. Alloys like copper-beryllium (Cu-Be) serve as structural substrates, often coated with thin layers such as to enhance while providing mechanical support and durability under ion bombardment. For specialized applications, including activated with cesium (GaP(Cs)) are employed on dynode surfaces to achieve high sensitivity in the range, with yields exceeding those of standard oxides in low-energy regimes. Early dynode materials in the , such as silver-magnesium (Ag-Mg) alloys, relied on selective oxidation to form MgO films for , marking a transition to more advanced and coatings by the that improved overall yield and stability. These materials are prepared via , , or to form thin films typically 10–100 nm thick, which achieve low work functions of 1–2 to facilitate the escape of . Such preparation ensures high δ across primary electron energies of 100–2000 , with durability against repeated ion impacts essential for long-term operation in environments. Despite their effectiveness, these coatings face challenges including aging from gas adsorption on , which reduces over time, and to , particularly for MgO which exhibits high yields but degrades under exposure to residual gases. processes, such as baking the device at around 400°C in to desorb contaminants and restore surface properties, are routinely applied to mitigate these issues and maintain performance.

Applications

In Photomultiplier Tubes

In photomultiplier tubes (s), dynodes serve as the core amplification stage, where secondary electron emission multiplies photoelectrons generated at the photocathode into a detectable electrical signal. The typical PMT structure begins with a photocathode that emits photoelectrons upon absorbing incident photons, achieving a of 10-30% depending on the photocathode material and wavelength. These photoelectrons are then electrostatically accelerated toward the first dynode in a chain of 10-14 stages, each producing multiple through impact, resulting in an overall gain of 10^6 to 10^8. The amplified electron cascade is finally collected at the as a current pulse, enabling single-photon detection with . Dynode configurations in PMTs are tailored to specific optical geometries and applications. Head-on PMTs feature a flat, circular photocathode at the tube's end, paired with uniformly arranged dynodes to provide even illumination and , making them suitable for imaging tasks. In contrast, side-on PMTs employ a curved photocathode along the tube's side, with a more compact dynode chain, which facilitates efficient coupling to spectroscopic instruments where space constraints are critical. These designs leverage the gain mechanism from secondary to maintain consistent amplification across the path. PMTs exhibit exceptional performance for low-light detection, including timing better than 1 ns for single- events, allowing precise of arrival times. They offer to individual photons across the ultraviolet-visible-near-infrared (180-900 nm), with spectral response determined by the photocathode. arises primarily from dark current, typically manifesting as a pulse rate of 1-10 Hz under dark conditions, which can be minimized through cooling. In modern applications, PMTs with dynode amplification are integral to detectors, such as Cherenkov counters that identify charged particles via their emitted light. They also enable high-resolution imaging in medical (PET) scanners by detecting light from gamma-ray interactions. In astronomy, PMTs support low-light observations in telescopes, capturing faint signals from distant celestial sources. Advancements in technology include hybrid designs, where silicon photodiodes replace traditional dynode chains in later stages to enhance and reduce noise, achieving up to 50% higher detection rates in the visible range compared to conventional . These photomultiplier tubes (HPDs) combine vacuum photocathodes with amplification for improved performance in demanding environments.

Other Electron Multipliers

Dynodes find extensive use in electron multipliers beyond photomultiplier tubes, particularly in devices designed for direct amplification of charged particles such as ions and electrons. One prominent example is the channeltron, also known as an electron multiplier horn, which employs a continuous dynode channel typically constructed from semiconductive glass (such as lead silicate glass) with a resistive inner surface to enhance secondary electron emission. These devices are widely utilized in mass spectrometry for ion detection, where incoming ions strike the channel wall, initiating a cascade of secondary electrons that achieves gains ranging from 10^4 to 10^6, enabling sensitive detection of low-abundance species. Modern variants often use semiconductive glass channels for improved durability, maintaining high gain while resisting degradation in vacuum environments. In image intensifiers, particularly those employed in night vision systems, multi-dynode chains or microchannel plate (MCP) structures amplify images generated from photocathodes. Each microchannel in an MCP functions as a continuous dynode, where photoelectrons enter and trigger secondary emission along the channel walls, producing intensified clouds that are subsequently converted to visible on a screen. This configuration allows for real-time amplification of faint images in low-light conditions, with overall system gains often exceeding 10^4, making it essential for and observational applications. Historical applications include vidicons and image orthicons in early video cameras, where dynode multipliers amplified signals from scanned targets to produce images under varying illumination. In image orthicons, a series of dynodes progressively accelerates and multiplies from the photocathode, enabling low-light sensitivity comparable to candlelight levels. Similarly, residual gas analyzers (RGAs) incorporate dynode arrays or continuous-dynode electron multipliers to measure partial pressures of gases in systems, where ions from the sample are directed onto the dynode surface for amplification, facilitating detection down to 10^-14 mbar. Contemporary uses extend to space instrumentation, such as analyzers on satellites, where rugged dynode-based multipliers detect charged particles in harsh orbital environments. For instance, continuous-dynode multipliers (CDEMs) in missions like those from the select and amplify particle energies using electrostatic analyzers, providing critical data on and radiation. In , dynode-based multipliers enable direct detection of charged particles from radioactive decays, leveraging secondary emission to enhance signal-to-noise ratios in high-radiation settings. Compared to photomultiplier tubes, these dynode electron multipliers offer advantages for inputs, including without intermediate photocathode conversion, which simplifies design and improves efficiency, alongside greater ruggedness in extreme environments like or chambers due to the absence of fragile light-sensitive components. This direct amplification mechanism underscores their role in signal enhancement across diverse non-photonic detection scenarios.

References

  1. [1]
    DYNODE Definition & Meaning - Merriam-Webster
    The meaning of DYNODE is an electrode in an electron tube that functions to produce secondary emission of electrons.
  2. [2]
    [PDF] On the history of photoelectron multiplier invention - arXiv
    In the next year 1936, Zworykin et al. developed a photomultiplier tube having multiple dynode stages.” [6]. “… the first photomultiplier tube was invented by.
  3. [3]
    [PDF] ELECTRON MULTIPLIERS FOR MASS SPECTROMETRY
    A typical discrete-dynode electron multiplier has between 12 and 24 dynodes and is used with an operating gain of between 104 and 108, depending on the ...
  4. [4]
    Structure of Electron Multiplier (Discrete-Dynode Type) - Shimadzu
    An electron multiplier consists of many dynodes. Negative voltage is applied to each one by dividing the high voltage applied to the first dynode with ...Missing: component | Show results with:component
  5. [5]
    [PDF] electron multipliers [2.5 mb/pdf] - Hamamatsu Photonics
    Electron multipliers are mainly used as positive/negative ion detectors. They are also useful for detecting and measuring vacuum. UV rays and soft X-rays.
  6. [6]
    Albert W. Hull - Engineering and Technology History Wiki
    Apr 3, 2023 · In the 1918 issue of the Proceedings of the IRE he published a paper on a vacuum tube which he had invented called the dynatron.
  7. [7]
    [PDF] Untitled - World Radio History
    6 A. W. Hull, "The Dynatron," Proc. LR.E., Vol. 6 ... The second dynode is an ... tion may be the secondary emission and electron reflection that comes.
  8. [8]
    [PDF] PHOTOMULTIPLIER TUBES - Hamamatsu Photonics
    The electron trajectories from the photocathode to the first dynode must be carefully designed in consideration of the photocathode shape (planar or ...
  9. [9]
    [PDF] The Challenges of Low-Energy Secondary Electron Emission ... - DTIC
    Nov 25, 2019 · In August of 1915, Albert W. Hull patented the dynatron while working for the. General Electric Research Laboratory (Figure 5) [10]. This was ...
  10. [10]
  11. [11]
    Secondary electron emission and vacuum electronics - AIP Publishing
    Feb 6, 2023 · Secondary electron emission is produced when a beam of energetic electrons impacts a solid surface. As a result, it occurs to some degree in any ...
  12. [12]
    [PDF] Secondary Electron Emission - DigitalCommons@USU
    Secondary electron emission (SEE) discovered in 1902 by. Austin and Starke, is the proces s by which electrons are emit- ted from the surface of a solid as a ...Missing: observation | Show results with:observation
  13. [13]
    [PDF] Photomultiplier Tubes - Basics and Applications
    In 1935, Iams et al.23) succeeded in producing a triode photomultiplier tube with a photocathode combined with a single-stage dynode (secondary emissive ...
  14. [14]
    Photomultipliers - RP Photonics
    The electrons are subsequently accelerated with a high voltage (hundreds of volts) to a first dynode (an electrode), where they generate several secondary ...
  15. [15]
  16. [16]
    Surface Characterization and Secondary Electron Emission ... - MDPI
    Ag-Mg alloy is used as a dynode material in electron multiplier tubes due to the high secondary electron yields (δ) of the surface of MgO film.<|control11|><|separator|>
  17. [17]
    [PDF] Photomultiplier tube basics
    A photomultiplier tube converts light into a measurable current using a photocathode, electron multiplier, and anode. It has a large sensing area, fast ...
  18. [18]
    Lesson 8.1 - Photomultiplier Tubes (PMTs) | Berkeley Nucleonics
    There are a number of PMT dynode structures, each with their typical characteristics. Important PMT parameters are: Amplification as a function of voltage.<|control11|><|separator|>
  19. [19]
    [PDF] Signal Recovery with PMTs - thinkSRS.com
    A PMT base provides bias voltages to the PMT's photocathode and dynodes from a single, negative, high-voltage power supply. The simplest design consists of a ...
  20. [20]
    Photomultiplier Tubes - an overview | ScienceDirect Topics
    A photomultiplier tube (PMT) is defined as a device that converts light into electrical signals, functioning as a sensitive detector for low-intensity ...
  21. [21]
    [PDF] Large Area Hybrid Photodiodes
    Hybrid Photodiodes (HPD) represent one of the most promising options for high granularity single photon detection. HPD's are photodetectors consisting of a ...
  22. [22]
    Electron Multiplier - an overview | ScienceDirect Topics
    In discrete dynode electron multipliers, a series of dynodes are used to amplify the initial signal, thereby generating an electron cascade. After an ion ...
  23. [23]
    Mass Spectrometer: The Detector - NASA
    The GCMS uses a continuous dynode electron multiplier, also known as a channel electron multiplier. It is comprised of "the channel," a hollow, cornucopia- ...
  24. [24]
    Channel electron multipliers - Exosens
    A Channeltron is an electron multiplier that is comprised of a hollow, semiconductive glass “channel” which has an ability to conduct (or transmit) electricity.
  25. [25]
    US5883380A - Night vision device, improved image intensifier tube ...
    Thus, the channels 32 of the microchannel plate 22 are each a dynode, emitting a shower of secondary electrons in response to receipt at face 28 of ...
  26. [26]
    Image Intensification: The Technology of Night Vision
    Image intensification, the basis of night vision, is a complex conversion of energy particles that occurs within a vacuum tube. An image-intensifier s.
  27. [27]
    The Application of Image Orthicon Techniques to Auroral Observation
    ... dynode multiplier section. (See Figure 1.) (a) Image ... Vidicon and Intensifier Image Orthicon are largely combinations or permutations of earlier types.
  28. [28]
    Residual Gas Analyzer - thinkSRS.com
    This state-of-the-art macro multi-channel continuous-dynode electron multiplier (CDEM) offers increased longevity and stability and can also be replaced by the ...
  29. [29]
    ESA - Description - European Space Agency
    TED uses eight programmed swept electrostatic curved-plate analysers with continuous dynode electron multipliers (CDEM) to select the particles type and energy.
  30. [30]
    [PDF] ELECTRON MULTIPLIER - NASA Technical Reports Server (NTRS)
    -Bare electron multipliers with a dynode structure similar to a photo- multiplier tube have been used to detect directly charged particles allowed to strike ...
  31. [31]
    [PDF] Application Note Number 50: Advantages of an Electron Multiplier
    Abstract: An electron multiplier converts the charge of an ion into a much larger electron current. This increase in signal intensity allows for faster scan ...