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ECTFE

ECTFE, or ethylene chlorotrifluoroethylene, is a semi-crystalline, melt-processable fluoropolymer formed by the copolymerization of ethylene and chlorotrifluoroethylene in a 1:1 alternating structure, offering a unique balance of chemical inertness, thermal endurance, and robust mechanical performance.^[1]^[2] First commercialized by DuPont in 1974 under the trade name Halar, it has since become a staple in industries requiring high-performance materials for corrosion resistance and electrical insulation, with production later acquired by Solvay (now Syensqo) in 2001.^[3]^[2] The development of ECTFE addressed limitations in earlier fluoropolymers like PTFE, providing improved processability while retaining strong carbon-fluorine bonds that confer exceptional stability.^[3] Its chemical structure—[-CH₂-CH₂-CF₂-CFCl-]ₙ—enables hydrogen bonding for enhanced mechanical integrity alongside fluorine's electronegativity for resistance to degradation.^[1] Over the decades, innovations such as sustainable powder coating formulations have extended its use, with applications in corrosion protection dating back over 40 years in chemical processing and semiconductor sectors.^[4]^[5] Key properties of ECTFE include outstanding chemical resistance to strong acids, bases, and oxidants, surpassing PVDF and rivaling PTFE, though it may swell in certain solvents like esters at elevated temperatures.^[6]^[1] Thermally, it operates continuously from -80°C to 150°C, with a melting point of 242°C, and demonstrates low thermal expansion and high heat deflection temperature.^[7]^[1] Mechanically, it exhibits tensile strength of 30-57 MPa, elongation at break of 250-300%, and Shore D hardness of 70-75, contributing to its impact resistance and durability.^[1] Additionally, ECTFE offers low gas and vapor permeability—superior to ETFE and PFA—excellent UV and weather resistance, inherent flame retardancy (UL 94 V-0, LOI of 52), and superior electrical insulation properties, making it ideal for harsh environments.^[7]^[6] Its purity, with minimal extractables and fluoride leach-out, suits ultra-pure applications in semiconductors and pharmaceuticals.^[6] ECTFE finds broad applications as linings, coatings, and extruded products in corrosive settings, including chemical processing equipment, flue gas treatment systems, and acid storage tanks.^[1]^[5] In the semiconductor and pharmaceutical industries, it lines ultra-pure water systems and exhaust ducts compliant with FM 4922 fire safety standards.^[6] For electrical uses, it serves as insulation for wires and cables in automotive, aerospace, and critical fluid transfer applications, benefiting from its sterilizability via gamma irradiation.^[7] Other notable uses include thin films for photovoltaic modules, filter membranes, and protective barriers where low permeation and weather resistance are essential.^[3] Compared to PTFE, ECTFE provides easier processing via extrusion, injection molding, or powder coating at 260-280°C melt temperatures, though with a lower maximum service temperature of 150°C versus PTFE's 260°C.^[1]^[3]

Overview

Definition and Composition

ECTFE (ethylene chlorotrifluoroethylene) is defined as an alternating copolymer derived from the monomers ethylene (C₂H₄) and chlorotrifluoroethylene (CTFE, CF₂=CFCl), typically in a 1:1 molar ratio.^[8]^[9] This polymer is classified as a semi-crystalline, partially fluorinated thermoplastic fluoropolymer, belonging to the broader family of fluoropolymers that incorporate fluorine atoms for enhanced chemical stability.^[10]^[1] Unlike some fully fluorinated fluoropolymers such as PTFE, which cannot be processed by conventional melting techniques due to their high molecular weight and crystallinity, ECTFE exhibits melt-processability as a key characteristic, enabling standard thermoplastic fabrication methods.^[1]^[11] The repeating chemical structure of ECTFE is represented by the formula (C₂H₄·CF₂CFCl)_n.^[11]

History and Commercial Development

Ethylene chlorotrifluoroethylene (ECTFE) was developed in the late 1960s to early 1970s as a partially fluorinated semi-crystalline polymer aimed at enhancing the processability of polytetrafluoroethylene (PTFE) while maintaining strong chemical resistance.^[12]^[13] Researchers at DuPont pioneered the initial polymerization process using a 1:1 molar ratio of ethylene and chlorotrifluoroethylene monomers, addressing limitations in PTFE's melt-processability for industrial applications.^[14] DuPont first commercialized ECTFE in 1974 under the trade name Halar, marking its entry into the market for corrosion-resistant materials.^[2] This launch positioned ECTFE as a melt-processable alternative suitable for demanding environments, with early adoption in chemical processing equipment due to its superior barrier properties against acids and solvents.^[12]^[15] In 2001, the Solvay Group acquired Ausimont, an Italian firm that had been producing Halar ECTFE, thereby becoming the sole global producer of the material.^[3]^[16] Under Solvay's stewardship, production continued to expand, with Halar ECTFE coatings applied for over 40 years in corrosion prevention across various industries by the late 2010s.^[4] In December 2023, Solvay spun off its specialty chemicals division into Syensqo, which now oversees Halar ECTFE manufacturing and further capacity enhancements to meet rising demand.^[17] Key milestones include the 1970s introduction of ECTFE for chemical resistance applications, such as in pulp and paper bleaching towers and acid storage, leveraging its low permeability to harsh substances.^[12]^[18] During the 2000s, adoption grew significantly in the semiconductor and pharmaceutical sectors, driven by ECTFE's suitability for high-purity systems and anti-corrosion needs in fabrication processes.^[19]^[20] As of 2025, the global ECTFE market is valued at approximately US$211 million, reflecting steady growth fueled by expansions in electronics and healthcare applications, with projections to reach US$297 million by 2032 at a compound annual growth rate of 4.4%.^[21]

Chemical Structure and Synthesis

Monomers and Polymerization Process

ECTFE is produced through the copolymerization of ethylene, an inexpensive and readily available non-fluorinated monomer, and chlorotrifluoroethylene (CTFE), a fluorinated monomer that confers essential properties such as thermal stability and chemical resistance to the resulting polymer. The synthesis yields a strictly alternating copolymer with a 1:1 molar ratio of the two monomers, which is critical for achieving the desired semi-crystalline structure and performance characteristics.^[22]^[14] The primary industrial method for ECTFE production is aqueous free radical suspension polymerization, a process that disperses the monomers in water to form polymer particles. This reaction is initiated by free radical generators, typically organic peroxides such as benzoyl peroxide, and proceeds under elevated temperatures ranging from 60°C to 150°C and pressures of 5 to 100 MPa to ensure effective monomer incorporation and alternation. The suspension environment facilitates heat dissipation and easy separation of the polymer product post-reaction.^[22]^[14] Molecular weight is regulated during polymerization using chain transfer agents, including chlorinated compounds, alcohols, and ketones, to achieve values typically between 100,000 and 500,000 g/mol, which influence processability and end-use properties. The process is conducted in batch or continuous stirred-tank reactors on an industrial scale, yielding the polymer in pellet or powder form for downstream melt processing. Variations in the core suspension method include minor incorporation of additional comonomers, such as perfluoroalkyl vinyl ethers, to tailor specific grades for enhanced performance, though the alternating ethylene-CTFE backbone remains central.^[9]^[23]^[1]

Molecular Characteristics

ECTFE is an alternating copolymer composed of ethylene and chlorotrifluoroethylene (CTFE) monomers, resulting in a repeating unit of -[CH₂-CH₂-CF₂-CFCl]-. This 1:1 alternation arises from the differing reactivities of the monomers during copolymerization, leading to a highly regular backbone structure.^[22] The semi-crystalline morphology of ECTFE, with crystallinity typically ranging from 50% to 55%, stems from this ordered alternating chain configuration, which allows for efficient packing in crystalline domains while amorphous regions provide flexibility and contribute to the polymer's overall toughness. The high degree of chain regularity ensures a uniform molecular architecture, minimizing defects and enhancing structural consistency across the material.^[22]^[14] With approximately 40% fluorine content by weight, ECTFE exhibits significant hydrophobicity and low surface energy, attributes primarily due to the strong carbon-fluorine bonds along the chain. The presence of the chlorine atom in the CFCl unit plays a key role in improving processability relative to fully fluorinated analogs like PTFE, as it reduces overall crystallinity and facilitates melt processing. Additionally, the polar C-Cl and C-F bonds introduce dipole moments that influence the material's electrical properties and intermolecular interactions.^[22]^[24]

Properties

Physical and Mechanical Properties

ECTFE exhibits a density in the range of 1.6–1.7 g/cm³, which contributes to its lightweight yet robust profile compared to other fluoropolymers.^[1]^[25] This density allows for efficient material use in structural applications without compromising durability. The polymer has a melting point of 242°C, enabling processing at relatively moderate temperatures while maintaining structural integrity.^[1] It supports continuous use over a broad temperature range from -80°C to 150°C, demonstrating exceptional thermal versatility from subzero conditions to elevated operational environments.^[1] Mechanically, ECTFE displays tensile strength of 40–57 MPa and elongation at break of 200–300%, indicating a balance of strength and ductility that resists fracture under deformation.^[1] Its Young's modulus ranges from 1.4–2.1 GPa, providing stiffness suitable for load-bearing components.^[1] The material offers high impact strength, with no break in notched Izod at 23°C and 50–110 J/m at −40°C, ensuring toughness even at low temperatures.^[1] Its abrasion resistance surpasses that of PTFE, making it ideal for wear-prone surfaces.^[26] Electrically, ECTFE features a dielectric strength of 80–100 kV/mm and volume resistivity greater than 10¹⁵ Ω·cm, underscoring its excellence as an insulator in high-voltage settings.^[27]^[1] Optically, ECTFE appears translucent in bulk form, while thin films exhibit high UV transparency and light transmission up to 95%, supporting applications requiring visibility or UV passage.^[1] These attributes stem from its alternating molecular structure of ethylene and chlorotrifluoroethylene units, which influences chain packing and light interaction.^[1]

Chemical and Thermal Properties

ECTFE exhibits exceptional chemical resistance, remaining inert to a wide range of substances including strong and weak inorganic acids such as hydrochloric acid (up to 150°C) and sulfuric acid (up to 121°C), bases like sodium hydroxide (up to 121°C), salts, aliphatic hydrocarbons, alcohols, and oxidants.^[1]^[28] It also demonstrates good resistance to many solvents, though limited swelling occurs with ketones (e.g., acetone at 100°C causing 3.5% weight gain) and amines.^[1]^[28] The material serves as an effective barrier against permeation, with low gas permeability rates; for instance, oxygen permeation is approximately 10.2 cm³·mm/m²·atm·day at 25°C, which is 10 to 100 times lower than that of PTFE or FEP.^[29] It also provides strong resistance to water vapor, with absorption below 0.01% and permeability around 750 cm³·mm/m²·atm·day at 23°C.^[29]^[1] Thermally, ECTFE maintains stability across a broad range, with continuous use temperatures from -80°C to 150°C and decomposition occurring above approximately 400°C as measured by thermogravimetric analysis.^[1] Its limiting oxygen index (LOI) exceeds 52%, contributing to self-extinguishing behavior in fire conditions.^[1] Regarding flammability, ECTFE achieves a UL 94 V-0 rating at thicknesses as low as 0.18 mm and complies with FM 4910 standards for low smoke generation.^[1] Additionally, it shows excellent radiation resistance, retaining mechanical and electrical properties after exposure to gamma radiation up to 200 Mrad.^[1]

Processing and Fabrication

Melt-Processable Techniques

ECTFE is a melt-processable fluoropolymer, distinguished by its relatively low melting point of 225–242°C, which enables processing at temperatures between 230°C and 280°C without significant thermal degradation.^[1] Its melt flow index, typically ranging from 1 to 20 g/10 min at 275°C under a 2.16 kg load, facilitates standard thermoplastic shaping methods while maintaining molecular integrity.^[30] Extrusion is a primary technique for producing ECTFE pipes, sheets, films, and wire coatings, leveraging its pseudoplastic flow behavior.^[1] Optimal melt processing temperatures for extrusion are 270–295°C, using a single-flight screw with a compression ratio of 2.5:1 to 3:1 and an L/D ratio of 20:1 to 30:1 to accommodate its shear sensitivity and prevent excessive degradation from prolonged residence times.^[1] Injection molding suits the fabrication of complex components such as fittings, where the material is processed at cylinder temperatures of 230–275°C and mold temperatures of 90–150°C.^[1] Cycle times vary from 20 to 150 seconds based on part thickness, with shot sizes recommended at 40–70% of machine capacity to ensure uniform filling and minimize voids.^[1] Rotational molding employs ECTFE in powder form, such as grades with particle sizes of 300–500 microns, to create large tanks and linings through biaxial rotation in heated molds.^[31] The process involves oven temperatures of 250–288°C, achieving peak internal air temperatures of 255–275°C, with total heating cycles of 50–80 minutes followed by controlled cooling over 20 minutes to control wall thicknesses from 0.038 to 0.953 cm.^[31] A key advantage in melt processing is ECTFE's low moisture sensitivity, with water absorption below 0.1% after 24 hours at 23°C, eliminating the need for pre-drying and reducing preparation time.^[30]^[1]

Secondary Fabrication Methods

Secondary fabrication methods for ECTFE encompass techniques applied after initial melt processing or as alternative shaping processes to form coatings, linings, and finished components. These methods leverage ECTFE's thermoplastic nature to achieve precise geometries and enhanced performance in corrosion-resistant applications. Powder coating involves electrostatic application of ECTFE powder onto preheated metal substrates, forming durable corrosion barriers. The process typically uses a corona gun with 30-50 kV voltage and 20-25 μA amperage to apply a primer layer (75-150 μm thick) followed by topcoats (150-250 μm each), building thicknesses up to several millimeters through multiple passes. Curing occurs at 260-280°C, with residence times minimized to ensure fusion without thermal degradation; for high-build coatings exceeding 1 mm, 5-6 coats are common, followed by ambient cooling to avoid stresses.^[32]^[33] Rotolining and sheet lining produce seamless internal linings for vessels, pipes, and chemical processing equipment. In rotolining, ECTFE powder is charged into the hollow article, which is then rotated (typically at 2:1 to 8:1 ratios) and heated in stages to 250-302°C, achieving a peak internal air temperature of 255-275°C for fusion into pinhole-free layers 0.038-0.953 cm thick; cycle times range from 10-20 minutes per stage in two-stage processes or 50-80 minutes overall. Adhesion promoters, such as ECTFE-compatible primers, are applied post-surface preparation (degreasing and grit blasting) to enhance bonding to metal substrates. Sheet lining follows similar heating and fusion but uses preformed ECTFE sheets welded into place for larger structures.^[31] Machining ECTFE components employs carbide tools to achieve tight tolerances, capitalizing on the material's machinability akin to nylon. Turning uses tools with 30-40° rake angles, 5° side clearance, and 8-10° end cutting edges, while drilling requires sharp bits oversized by 0.1-0.5 mm and coolants to prevent heat buildup. Post-machining annealing at 150°C relieves internal stresses, with durations scaling by thickness: 15 minutes for 12.5 mm parts up to 4 hours for 25 mm sections.^[33] Welding joins ECTFE parts using hot gas or infrared methods to maintain structural integrity. Hot gas welding employs guns rated at 800 W or higher, with gas temperatures of 380-425°C and welding speeds of 0.1-0.5 cm/s, producing joints with tensile strength equivalent to 100% of the base material. Infrared welding offers similar results through controlled non-contact heating.^[33] Film extrusion and lamination create thin ECTFE films for membranes and laminates. Extrusion often utilizes thermally induced phase separation (TIPS) at 200-240°C with diluents like dibutyl phthalate to form porous structures, followed by extraction and stretching for controlled thicknesses of 10-500 μm. Lamination bonds these films to substrates via heat and pressure, ensuring uniform adhesion for barrier applications.^[33]

Applications

Industrial Corrosion Protection

ECTFE is widely employed as a lining material for piping and tanks in industries handling aggressive chemical media, such as chlor-alkali production and pharmaceutical processes, where it provides robust protection against corrosion from halogens, oxidizers, acids, and alkalis.^[34] These linings, typically applied in thicknesses ranging from 1 to 5 mm, ensure long-term integrity by forming a smooth, impermeable barrier that minimizes permeation and maintains equipment durability under harsh conditions.^[34] In chlor-alkali facilities, ECTFE linings safeguard vessels and conduits exposed to chlorine and caustic solutions, preventing degradation that could compromise safety and efficiency.^[35] For valves and pumps in chemical plants, ECTFE coatings are applied to impellers, housings, and other components to withstand continuous exposure to corrosive fluids and mechanical wear.^[36] These coatings leverage ECTFE's inherent chemical resistance to protect against a broad spectrum of solvents, acids, and bases, extending service life in demanding operational environments.^[1] In the semiconductor industry, ECTFE is utilized in wet benches and wafer processing tools, where its resistance to hydrofluoric acid (HF) and photoresists prevents contamination and corrosion during etching and cleaning operations.^[37] The material's low extractables and surface smoothness make it suitable for high-purity systems, ensuring reliable performance in environments requiring precise chemical handling.^[1] For pharmaceutical applications, ECTFE serves as sterile linings in reactors and processing equipment, offering compliance with FDA standards under 21 CFR 177.1380 for food-contact materials up to 120°C.^[1] Grades such as ECTFE DA are specifically formulated to meet these regulatory requirements, enabling safe containment of sensitive formulations without risking leaching or degradation.^[5] ECTFE is used in oil and gas applications, where it lines pipes and internals to resist hydrogen sulfide (H₂S) corrosion at elevated temperatures.^[38] For instance, ECTFE barriers have proven effective in high-temperature gas lines, providing smooth, durable protection that outperforms traditional materials in aggressive hydrocarbon environments over decades of service.^[34]

Electrical and Specialty Uses

ECTFE serves as an effective insulation material for wires and cables, particularly in demanding aerospace and nuclear environments where high-voltage performance and radiation resistance are essential. Its superior dielectric properties, including a dielectric constant of 2.55 at 1 MHz and a dielectric strength of 728 V/mil, allow for the application of thin coatings that maintain electrical integrity while reducing weight and material usage.^[7] In aerospace applications, ECTFE-insulated cables provide flame resistance (UL 94 V-0) and operate reliably from -70°C to 148°C, protecting wiring harnesses from abrasion and harsh thermal conditions.^[7] In 2025, companies like 3M introduced advanced ECTFE coatings for aerospace applications focusing on weight reduction and improved corrosion resistance.^[39] For nuclear settings, ECTFE's ability to withstand high-energy radiation makes it suitable for instrumentation and control cables exposed to ionizing environments.^[40] In filtration applications, ECTFE-based nonwoven fabrics, produced via melt-blowing techniques, offer robust performance in harsh conditions due to their thermal stability up to 150°C and chemical resistance. These materials exhibit hydrophobic properties with water contact angles around 128°, enabling efficient separation in oily or contaminated environments, and demonstrate high mechanical strength for repeated use.^[41] While primarily developed for oil-water separation with efficiencies exceeding 99%, their structure supports potential extension to hot gas filtration in industrial settings.^[41] ECTFE membranes, fabricated using the thermally induced phase separation (TIPS) method, find utility in advanced separation processes such as fuel cells and gas purification. The TIPS process involves dissolving ECTFE in high-boiling diluents like acetyl tributyl citrate (ATBC) above its melting point, followed by controlled cooling and diluent extraction to form porous structures with tunable pore sizes typically in the microporous range (0.1–0.6 µm).^[2] In proton exchange membrane fuel cells (PEMFCs), modified ECTFE membranes grafted with sulfonated polystyrene (ECTFE-g-PSSA) deliver high proton conductivity and durability, maintaining performance for over 450 hours at 75°C.^[42] For gas separation, these membranes excel in vacuum membrane distillation (VMD), achieving water fluxes up to 22.3 L/m²·h and near-complete salt rejection (99.9%), making them suitable for recovering humidified gas streams in energy-efficient processes.^[43] ECTFE's low surface energy and FDA-compliant grades enable its use in anti-stick coatings for food processing equipment and medical devices, where non-adhesive surfaces prevent buildup and facilitate cleaning. In food service applications, ECTFE coatings withstand processing temperatures up to 150°C while resisting acids, bases, and sanitizers, ensuring hygienic operation.^[44] For medical devices, its biocompatibility and sterilizability support components like pharmaceutical handling tools and implants, providing barrier protection without promoting microbial adhesion.^[44]

Comparisons and Considerations

Relation to Other Fluoropolymers

ECTFE, or ethylene chlorotrifluoroethylene copolymer, distinguishes itself from other fluoropolymers through a balance of mechanical robustness, processability, and cost-effectiveness, though it trades off some chemical inertness compared to fully fluorinated variants. Relative to polytetrafluoroethylene (PTFE), ECTFE provides superior abrasion resistance and impact strength, with a tensile strength of approximately 48 MPa versus PTFE's 17 MPa, enabling greater durability in dynamic environments.^[45] Additionally, ECTFE's lower melting point of 240°C allows for straightforward melt processing techniques like extrusion and injection molding, in contrast to PTFE's higher sintering temperature of 327°C, which limits it to compression molding or sintering. However, PTFE exhibits broader chemical inertness, particularly against molten alkali metals and certain aggressive solvents where ECTFE shows reduced resistance due to its chlorotrifluoroethylene component.^[46]^[1] In comparison to perfluoroalkoxy (PFA) and fluorinated ethylene propylene (FEP), ECTFE demonstrates enhanced mechanical strength, boasting a flexural modulus of 1.7 GPa against PFA's 0.9 GPa and FEP's lower values around 0.5 GPa, making it suitable for applications requiring structural integrity. Its limiting oxygen index (LOI) of over 52% provides good fire resistance, though this is lower than FEP's >95%, indicating FEP's superior non-flammability in oxygen-rich settings; nonetheless, ECTFE's easier melting at 240°C facilitates broader fabrication options than FEP's 270°C or PFA's 305°C. The incorporation of ethylene in ECTFE's structure reduces reliance on costly fluorinated monomers, positioning its price at approximately $25–30 per kg as of 2023, comparable to or slightly lower than PFA and FEP which range $20–35 per kg as of 2025.^[1]^[45]^[47]^[48] Compared to ethylene tetrafluoroethylene (ETFE), ECTFE's chlorine content enhances fire resistance, with an LOI of >52% surpassing ETFE's 32%, contributing to its UL 94 V-0 rating for low flammability. However, this chlorination slightly compromises UV stability, as ETFE's fully fluorinated backbone offers better long-term resistance to ultraviolet degradation without additives. Both materials share similar tensile strengths around 48 MPa, but ECTFE's broader chemical resistance to bases like sodium hydroxide provides an edge in corrosive settings.^[1]^[8] Overall, ECTFE occupies a higher cost position among fluoropolymers at $25–40 per kg as of 2023, exceeding PTFE's $12–18 per kg as of November 2025 for standard grades while far exceeding polyvinyl chloride (PVC) at under $2 per kg, reflecting its specialized fluoropolymer attributes. Selection criteria for ECTFE emphasize scenarios demanding a combination of chemical and thermal stability (up to 150°C continuous use) alongside melt processability, such as in linings or wires where extreme inertness like PTFE's is unnecessary but mechanical performance exceeds that of softer options like FEP.^[47]^[49]^[1]

Environmental Impact and Safety

The production of ECTFE involves copolymerization of ethylene and chlorotrifluoroethylene (CTFE), with processes designed to minimize volatile organic compound (VOC) emissions through efficient filtration and scrubbing systems. Handling of the CTFE monomer, which is toxic and requires careful ventilation to prevent exposure, contributes to controlled emissions during manufacturing.^[50] ECTFE's exceptional durability significantly reduces environmental impact over its lifecycle, as components coated or fabricated with the material often achieve service lives exceeding 20 years under outdoor exposure to sunlight and atmospheric conditions, thereby minimizing waste from frequent replacements. This long-term stability stems from its resistance to weathering and chemical degradation, lowering the overall material demand and associated production emissions.^[34] As a thermoplastic fluoropolymer, ECTFE can be reprocessed by melting and regrinding, with up to 15% regrind material incorporable without substantial loss of properties, supporting potential recycling in manufacturing. However, commercial recycling remains limited due to risks of contamination from its high-purity applications, such as in semiconductors, which necessitate separation to avoid performance degradation. Some ECTFE thin films are recyclable, enabling weight reductions in applications like construction by replacing heavier materials.^[1]^[34] In solid form, ECTFE is non-toxic and poses no significant health hazards under normal conditions. During processing or overheating above 300°C, thermal decomposition can release hazardous fumes including hydrogen fluoride (HF), hydrogen chloride (HCl), and fluorophosgene, potentially causing polymer fume fever with flu-like symptoms; adequate ventilation and personal protective equipment (PPE) such as safety goggles, nitrile gloves, and respiratory masks are essential to mitigate exposure. ECTFE exhibits low flammability, with a UL 94 V-0 rating and an NFPA 704 flammability classification of 1, indicating minimal fire risk.^[51]^[1]^[52] ECTFE complies with RoHS Directive 2011/65/EU, as it contains none of the restricted substances like lead or mercury. As a partially fluorinated polymer due to its ethylene-chlorotrifluoroethylene structure, ECTFE falls under broader PFAS classifications but benefits from ongoing debates in 2025 regarding exemptions for essential fluoropolymers, with its partial fluorination seen as reducing persistence concerns compared to fully fluorinated alternatives. Regulatory proposals, such as ECHA's updated PFAS restrictions under REACH, continue to evaluate sector-specific uses, potentially allowing continued application in critical industries.^[1]^[53]^[54]

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ECTFE is essentially a 1 :1 alternating copolymer of ethylene and chlorotrifluoroethylene. It contains about 80% by weight of chlorotrifluoro-ethylene, ...
[33]
[PDF] ectfe (halar®) as a new material for primary sample containment of
This is interpreted to be C – F stretching which typically ranges from 1000 to 1400 cm-1. The peak at 752 cm-1 is most likely C – Cl stretching. A comparison ...
[34]
[PDF] Halar® ECTFE - Nevicolor
Physical properties. Density at 23 °C/73 °F g/cm3. (lb/ft3). 1.68. (105) ... Melting point. °C. (°F). 225. (436). 242. (468). 242. (468). 242. (468). Heat of ...
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[PDF] Halar® ECTFE - Rotational Molding Processing Guide
Halar® ECTFE is a melt-processable fluoropolymer with excellent impact strength, used in rotomolding by melting in a heated mold. It is also used for ...
[36]
[PDF] Halar ECTFE Electrostatic Powder Coating
Coatings greater than 1 mm are termed “High Build” coatings. The Halar powder application bake temperatures are 250-290°C.<|control11|><|separator|>
[37]
[PDF] Halar® ECTFE - Kurt J. Lesker Company
One of the principal advantages of Halar® fluoropolymer is the ease with which it can be processed . Halar® fluoropolymer is a true thermoplastic that can ...Missing: fully | Show results with:fully
[38]
Halar® ECTFE - Applications - Syensqo
Halar ECTFE is used in semiconductor ductwork, chemical processing, oil & gas, construction, and energy solutions, including PV modules.
[39]
ECTFE/Halar®Coatings Review - Engineers Edge
ECTFE is resistant to the permeation of oxygen, carbon dioxide, chlorine ... corrosive environments such as chloro-alkalis facilities. In many ways the ...
[40]
Halar® Applications - Plas-Tech Coatings
Halar® ECTFE has superior chemical resistance and high temperature ... Available in FDA 21 CFR 177.380(a)(4) compliant grade. Additional Halar ...
[41]
Wet Bench for Semiconductor & Other FM4910 Applications
Since wet bench equipment is made from highly customizable materials like polypropylene, stainless steel, PVDF, PVC-C as well as Teflon®, PFA, and ECTFE (HALAR®) ...
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[PDF] Reliable Performance in O&G Extreme Environments | Solvay
For high temperature gas lines, Halar® ECTFE is an effective, smooth corrosion barrier for pipe internals and other assets. Both of these polymers are well ...
[43]
The Fluoropolymers Family: ECTFE, ETFE, FEP, Fluoroelastomers ...
Dec 26, 2024 · ECTFE is also used in the electronics industry due to its insulation properties and ability to withstand high-energy radiation, making it ideal ...
[44]
https://plastechcoatings.com/halar-applications-aerospace-food-service-industrial-medical-packaging-industries/
[45]
https://www.fluorotherm.com/technical-information/materials-overview/material-comparison/
[46]
https://www.makeitfrom.com/compare/Ethylene-Chlorotrifluoroethylene-ECTFE/Polytetrafluoroethylene-PTFE
[47]
Halar Applications for Aerospace, Food Service, Industrial, Medical ...
Mar 2, 2023 · ECTFE's resistance to high temperatures, hazardous chemicals, and ultraviolet radiation makes it an effective coating material for aerospace ...Missing: HF | Show results with:HF<|separator|>
[48]
All Material Comparison - Fluorotherm™
All Material Comparison. Typical Properties of Fluoropolymers. Property, Method No. Units, PTFE, FEP, PFA, ETFE, ECTFE, PCTFE, PVDF. Specific Gravity, D792, - ...
[49]
ECTFE vs. PTFE - MakeItFrom.com
Both ECTFE and PTFE are thermoplastics. They share 16 material properties, but 14 are unique to each. Properties are compared with top bar for ECTFE and bottom ...
[50]
None
### Comparison of ECTFE, FEP, and PFA Fluoropolymers
[51]
Ethylene Chlorotrifluoroethylene (ECTFE) Price Trend - Chart
Ethylene Chlorotrifluoroethylene (ECTFE) Prices Q4 December 2023 United States: 28907 USD/MT, China: 26914 USD/MT, Germany: 24920 USD/MT.Missing: kg | Show results with:kg
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Polytetrafluoroethylene (PTFE) price index - businessanalytiq
Polytetrafluoroethylene (PTFE) price October 2025 and outlook (see chart below) · North America:US$13.73/KG, unchanged · Europe:US$15.42/KG, 0.3% up · Northeast ...
[53]
[PDF] REGULATORY MANAGEMENT OPTION ANALYSIS FOR ...
Nov 4, 2021 · Therefore, FPG continues to advocate for the segmentation of the PFAS family of substances before performing any grouping-based assessment, ...
[54]
None
### Safety Information for Halar® 901S (ECTFE)
[55]
Solvay Solexis Halar® E-CTFE Fluoropolymer Coatings
The dielectric strength is 80 kV/mm (2000V/mil) in 1 mil (.025 mm) thickness. Flammability: Halar ECTFE has received a UL 94 V-O rating in thicknesses as ...Missing: volume resistivity
[56]
Information about the PFAS restriction | Röchling EN
The PFAS restriction involves a prohibition of over 10,000 substances, including fluoroplastics like PVDF, E-CTFE, PFA, and PTFE, which are essential for ...Missing: RoHS compliance
[57]
ECHA publishes updated PFAS restriction proposal - European Union
Aug 20, 2025 · The European Chemicals Agency (ECHA) has published the updated proposal to restrict per- and polyfluoroalkyl substances (PFAS) under the EU's ...Missing: ECTFE | Show results with:ECTFE