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Chiller

A is a designed to remove from a liquid coolant, typically or a water-glycol , through either a vapor-compression or cycle, allowing the chilled liquid to absorb thermal energy from air, processes, or equipment in various systems. Chillers operate on fundamental thermodynamic principles to achieve cooling, with vapor-compression types using mechanical compressors—such as centrifugal, screw, scroll, or reciprocating—to pressurize and circulate refrigerant, which then evaporates to absorb heat, condenses to release it, and repeats the cycle after expansion. In contrast, absorption chillers employ heat as the energy source, typically from steam, hot water, or exhaust gases, to drive a cycle involving a refrigerant like water and an absorbent such as lithium bromide, avoiding mechanical compression and often integrating with cogeneration systems for efficiency. These systems are sized in tons of cooling capacity, where one ton equals the heat removal rate to melt 2,000 pounds of ice in 24 hours, and modern units achieve efficiencies measured by coefficients of performance (COP) often exceeding 5 for water-cooled models. Primarily deployed in heating, ventilation, and air conditioning (HVAC) for large-scale applications, chillers serve commercial buildings, hospitals, data centers, and universities by producing chilled distributed via pumps and coils to cool spaces efficiently. In industrial settings, they support process cooling for , pharmaceuticals, and , where precise is critical to equipment performance and product quality. Water-cooled chillers, which reject heat to cooling towers, dominate large installations due to higher , while air-cooled variants suit smaller or remote sites without access. Notable advancements in chiller technology focus on , refrigerant transitions to low-global-warming-potential options like HFOs amid phase-outs of hydrofluorocarbons, and integration with smart controls for variable-speed operation and . These developments address environmental regulations and operational costs, with chillers often representing the largest consumer in central plants, underscoring their role in sustainable .

Overview

Definition and Purpose

A chiller is a that removes from a liquid , typically or a water-glycol , via a vapor-compression or cycle, thereby producing chilled for subsequent in various systems. This process enables the chiller to achieve temperatures below ambient levels, serving as a central component in cooling applications such as space conditioning and industrial processes. The primary purpose of a chiller is to facilitate controlled cooling for purposes including occupant comfort in , precise in , and protection of sensitive equipment from overheating. Unlike direct-expansion () systems, which circulate directly to cooling coils for , chillers employ a secondary loop where the chilled liquid acts as an intermediary medium, allowing for more efficient distribution over larger areas. At its core, a chiller operates on fundamental principles where is absorbed from the coolant through the evaporation of a refrigerant in the evaporator section, lowering the coolant's temperature, and then rejected to the environment via the condensation of the refrigerant in the condenser section. This cycle effectively moves from a low-temperature source to a higher-temperature sink, defying natural heat flow without violating thermodynamic laws. Chiller capacity is commonly measured in tons of refrigeration (TR), where one ton represents the rate of heat removal equivalent to melting 2,000 pounds (907 ) of ice at 32°F (0°C) in 24 hours, corresponding to 12,000 British thermal units per hour (BTU/hr) or approximately 3.517 kilowatts (kW). This unit provides a standardized for sizing chillers to match cooling demands in practical installations.

Historical Development

The development of chiller technology began in the early with foundational inventions in refrigeration cycles. In 1834, American inventor patented the first practical system in , utilizing as the in a closed cycle that compressed, condensed, expanded, and evaporated the vapor to produce cooling effects. This innovation laid the groundwork for mechanical cooling but saw limited immediate adoption due to the dangers of early refrigerants like ether. Concurrently, absorption-based cooling emerged in the 1850s, pioneered by French inventor Ferdinand Carré, who developed an ammonia-water in 1858, improving on his brother Edmond's 1850 sulfuric acid-water system; Carré's design received a U.S. patent in 1860 and enabled cooling without mechanical compression by using heat to drive the absorption-desorption process. Key milestones in the 20th century advanced chiller scalability and application, particularly for and industry. In 1922, invented the centrifugal chiller, a high-capacity vapor-compression machine that used a to handle large cooling loads efficiently, marking the first major breakthrough in comfort cooling and enabling widespread in buildings. Following , chiller adoption surged in industrial sectors; by 1950, the plastics industry integrated chillers to control molding temperatures and meet rising demand for consistent product quality, while post-war facilitated broader deployment in and commercial facilities worldwide. Technological shifts in the mid-20th century addressed safety and efficiency challenges. During the 1930s, the industry transitioned from toxic ammonia refrigerants to safer chlorofluorocarbons (CFCs) like , introduced by and , which reduced risks in commercial installations and boosted chiller proliferation in urban environments. chillers gained prominence in the for their , with lithium bromide-water systems becoming commercially viable; by that decade, they accounted for about 40% of U.S. chiller , favored for utilizing or in setups. The oil embargo profoundly influenced technology, as soaring led to a sharp decline in U.S. from over 700,000 tons annually to under 50,000 tons by the mid-decade, prompting innovations in hybrid systems and a temporary shift toward electric vapor-compression alternatives amid fuel scarcity concerns. From the 2020s to 2025, chiller advancements have emphasized energy optimization and digital integration. Variable-speed drives (VSDs) have become standard in modern compressors, allowing dynamic adjustment of motor speeds to match cooling demands and achieve up to 30-50% energy savings compared to fixed-speed systems. Smart controls, incorporating sensors and AI-driven analytics, enable real-time monitoring, , and remote optimization, enhancing overall system efficiency in data centers and smart buildings.

Applications

Air Conditioning Systems

Chillers form the core of central HVAC systems in buildings, where they generate chilled water in a dedicated plant and distribute it via piping networks to terminal devices such as air handling units, fan coil units, or radiant panels for space cooling. This hydronic approach allows for centralized production of cooling while enabling decentralized delivery, reducing ductwork complexity compared to all-air systems. In water-cooled configurations, chillers pair with cooling towers to reject heat into a water loop, achieving higher efficiency by condensing at the wet-bulb temperature, which is lower than ambient air temperature; these systems are often installed indoors with supporting pumps and towers. Air-cooled chillers, by contrast, use finned coils exposed to outdoor air for direct heat rejection, simplifying installation without water infrastructure but performing best in moderate climates. Sizing chillers for air conditioning involves calculating the building's peak cooling load—factored by elements like occupancy, solar gain, internal equipment, and local climate—to determine capacity in tons (where 1 ton equals 12,000 BTU/hr of heat removal). For commercial buildings, capacities typically range from 200 to 500 tons, corresponding to structures of 100,000 to 300,000 square feet at a rule-of-thumb load of 1 ton per 400–600 square feet, though hospitals may require higher densities due to medical equipment heat. Part-load efficiency is a key consideration, as buildings rarely operate at full capacity; modern chillers incorporate variable-speed drives and staging to maintain high performance at 25–75% loads, minimizing energy waste during off-peak hours. Selection also accounts for future expansion, with modular designs allowing scalability. Compared to direct expansion (DX) systems, which use directly at each , chiller-based chilled systems excel in for large-scale applications by leveraging 's superior and enabling heat recovery options, potentially reducing operating costs by 20–30% in high-load environments. This efficiency stems from optimized central plant operations, including variable flow pumping and integration, which DX units struggle to match across expansive zones. Additionally, chilled provides superior zoning flexibility, as pumps can modulate flow to specific areas via valves, supporting independent in multi-story or partitioned buildings without the refrigerant piping limitations of DX. In practice, chillers support diverse needs: in office buildings, they deliver consistent comfort cooling to open-plan spaces; hospitals rely on them for precise, reliable in operating rooms and labs to safeguard sensitive equipment and health; data centers employ high-capacity units, often 200–850 tons per chiller, to dissipate heat loads exceeding 100 kW per rack, with increasing integration in high-density facilities using cooling hybrids as of 2025 to manage intensified thermal demands from AI workloads. systems extend this further, with a shared central plant supplying chilled water via insulated pipes to multiple facilities—such as urban campuses or mixed-use developments—boosting overall efficiency through and , as seen in applications serving data centers with 99.99% uptime guarantees.

Industrial Processes

In manufacturing and processing industries, chillers play a critical role in maintaining precise temperatures for temperature-sensitive operations, ensuring product quality, process efficiency, and equipment longevity. These systems provide cooling for a variety of applications, including plastics molding where chillers rapidly cool molds to solidify materials and prevent defects, food processing to preserve perishables during packaging and storage, and pharmaceuticals where they regulate reactor temperatures typically between 5°C and 15°C to support chemical reactions and sterilization processes. Additionally, chillers are essential for cooling high-heat equipment such as lasers in cutting and welding operations and MRI machines in medical facilities, where stable coolant temperatures prevent overheating and maintain operational accuracy, as well as in electric vehicle battery production for thermal management during cell manufacturing and testing to ensure performance and safety as of 2025. Industrial chillers are often customized for demanding environments, featuring high-precision with stability as tight as ±0.5°C to meet exact process requirements in sectors like semiconductors and . In hazardous settings, such as chemical plants or oil refineries, explosion-proof designs incorporate reinforced components and sealed electrical systems to prevent ignition from flammable vapors, complying with Class I, Division 2 standards. These adaptations ensure safe and reliable performance without compromising . Chillers in settings vary by scale, with portable units offering flexibility for smaller or temporary operations—such as cooling individual machines with capacities up to 40 tons—while central systems handle larger loads across entire facilities for greater . For instance, breweries commonly deploy central chillers exceeding 100 tons to control temperatures, circulating chilled glycol through tanks to maintain activity and consistency. enhancements include heat recovery mechanisms that capture from the for heating applications, such as preheating in lines, and with programmable controllers (PLCs) for automated and adjustment of cooling parameters based on .

Types of Chillers

Vapor-Compression Chillers

Vapor-compression chillers are the most prevalent type of chillers, utilizing mechanical compression to drive the refrigeration cycle and providing efficient cooling for a wide range of applications from small systems to large facilities. These systems operate by compressing a vapor to high pressure and temperature, enabling rejection, followed by and to absorb from the chilled or . They are electrically powered, offering reliable performance and scalability, though they require careful consideration of compressor type for optimal efficiency and noise management. The primary subtypes of vapor-compression chillers are distinguished by their compressor technology, which significantly influences , capacity range, and suitability for specific loads. Reciprocating compressors, using pistons to compress , are suited for smaller capacities of 0.5 to 150 s and peak load operations, achieving efficiencies of 0.7–1.3 kW/ but requiring higher due to multiple . Scroll compressors, which employ two spiral elements for , excel in compact, low-capacity systems up to 30 s, providing quiet and low with good overall for spot or make-up cooling. Screw compressors, featuring twin helical rotors, handle medium to large capacities from 70 to 750 s with robust performance and part-load efficiencies up to 7.0 , making them cost-effective for capacities exceeding 200 s. Centrifugal compressors, relying on rotation to impart to the , are for high-capacity applications over 100 s—often exceeding 750 s—with superior full-load efficiencies of 0.5–0.7 kW/, though they risk surging at loads below 25%. These subtypes allow selection based on load requirements, with centrifugal models dominating large-scale installations due to their scalability and energy performance. A vapor-compression chiller's system layout consists of four core components arranged in a closed loop: the , which raises refrigerant pressure; the , where is rejected to the cooling medium (air or ); the expansion valve, which reduces refrigerant pressure to facilitate evaporation; and the , where the refrigerant absorbs from the load fluid, typically producing chilled at 42–45°F (5.6–7.2°C). This configuration ensures continuous circulation of the refrigerant, with auxiliary elements like oil separators and controls integrated for reliability, but the focus remains on these primary parts for basic operation. Performance in vapor-compression chillers is evaluated using the , a measure of cooling output per unit of electrical input, typically ranging from 3 to 6 for water-cooled systems, with air-cooled variants at the lower end (2.4–3.06). Capacity control methods, such as hot-gas bypass, modulate output by diverting high-pressure vapor directly to the inlet, maintaining stable operation during partial loads without excessive cycling, though it slightly reduces overall efficiency. Other techniques include variable-speed drives for screw and centrifugal types, enhancing part-load performance. Vapor-compression chillers offer high efficiency driven by , achieving significant savings in full-load conditions compared to heat-driven alternatives, with low operational costs in regions with affordable . However, they present disadvantages including noise and , particularly from reciprocating compressors, necessitating measures in installations to mitigate structural and ensure occupant comfort. Centrifugal and types mitigate these issues better, but initial costs can be higher for advanced models.

Absorption Chillers

Absorption chillers are thermally driven cooling systems that utilize heat energy, such as waste heat or low-grade thermal sources, to produce chilled water for air conditioning or process cooling, distinguishing them from mechanically driven vapor-compression chillers. These systems operate on an absorption refrigeration cycle, where a refrigerant-absorbent pair replaces the mechanical compressor with thermal separation processes, making them suitable for integration with cogeneration plants or facilities with abundant thermal energy. Absorption chillers are classified into subtypes based on the number of effects, which determines their and required input . Single-effect chillers use a single and are powered by low-pressure (up to 20 psig) or hot water (185–240°F), achieving moderate cooling output from relatively low-grade sources. In contrast, double-effect chillers incorporate two s for higher , requiring higher-temperature inputs like high-pressure (40–150 psig) or direct firing with or oil, which allows them to produce approximately 40% more chilled water per unit of compared to single-effect models. The performance of these chillers relies on specific refrigerant-absorbent working pairs, with water-lithium (LiBr-H₂O) being the most common for applications producing chilled water above 40°F, such as , due to its high affinity for water and non-. Ammonia- (NH₃-H₂O) pairs are used for lower-temperature chilling below 40°F, like in , as ammonia serves as the while acts as the absorbent, offering good but requiring additional components to manage toxicity risks. In terms of system layout, absorption chillers consist of key components including the , where the absorbent bonds with refrigerant vapor to form a dilute ; the , which applies to separate the refrigerant; the and for changes; pumps to circulate the ; and exchangers to recover between streams. Unlike vapor-compression systems, the core absorption has no beyond the pumps, relying instead on and differentials, which contributes to their compact for large capacities and minimal . Performance metrics for absorption chillers show a coefficient of performance (COP) typically ranging from 0.5 to 1.5, with single-effect models around 0.6–0.75 and double-effect up to 1.0–1.35, reflecting their lower efficiency compared to electric chillers but enabling effective use of waste heat that would otherwise be discarded. They are particularly advantageous in applications where electricity costs are high, such as industrial sites with cogeneration, as they can reduce overall energy expenses by leveraging thermal inputs like exhaust steam. Key advantages of absorption chillers include quiet operation due to the absence of compressors, the ability to utilize low-grade for sustainable cooling, and reduced maintenance needs from fewer moving parts, making them ideal for noise-sensitive environments or combined heat and power systems. However, they suffer from lower overall , higher initial (often $1,500–$4,500 per ), and the need for larger cooling towers to handle the exothermic process, along with risks like solution in LiBr systems.

Operating Principles

Vapor-Compression Cycle

The vapor-compression cycle is the fundamental thermodynamic process employed in vapor-compression chillers to achieve cooling by transferring heat from a low-temperature source to a higher-temperature sink, typically using mechanical work to drive the system. This cycle operates on the principle of repeated phase changes in the refrigerant, exploiting its latent heat of vaporization to absorb and reject heat efficiently. Unlike thermally driven cycles, it relies on electrical power for compression, enabling compact and controllable refrigeration suitable for air conditioning and industrial applications. The consists of four primary processes: , , , and . In the step, low-pressure vapor enters the , where it is compressed to high and , increasing its and preparing it for heat rejection; this process requires the majority of the cycle's work input. The high-pressure, superheated vapor then flows to the , where it releases heat to the surroundings, condensing into a high-pressure while maintaining . Next, the passes through an device, such as a throttle , undergoing a sudden that reduces its and partially vaporizes it, creating a low-pressure two-phase . Finally, in the , this absorbs heat from the cooled space, fully evaporating into low-pressure vapor and completing the as it returns to the . These processes are often visualized on a pressure- (P-h) diagram, where the saturation dome separates liquid and vapor regions, and the cycle forms a closed . The compression appears as a near-vertical line from low to , condensation as a horizontal line under the dome from vapor to liquid, expansion as a vertical drop to low pressure, and evaporation as another horizontal line absorbing heat. This illustrates the refrigerant's phase changes and enthalpy differences driving , with the enclosed area representing the net work input. The performance of the vapor-compression is quantified by the (COP), defined as the ratio of absorbed in the to the work supplied to the : \text{COP} = \frac{Q_\text{evap}}{W_\text{comp}} where Q_\text{evap} is the refrigeration capacity and W_\text{comp} is the compressor work. In an ideal assuming isentropic , reversible , and no pressure drops, the COP approaches the Carnot limit for , \text{COP}_\text{ideal} = \frac{T_\text{evap}}{T_\text{cond} - T_\text{evap}}, with temperatures in . Real cycles exhibit lower COP due to irreversibilities like non-isentropic (increasing work input), heat losses, and in the , typically achieving 50-70% of the ideal value depending on operating conditions. Efficiency improvements in real cycles often involve and the . cools the condensed liquid below its at condenser pressure, increasing the density and thus the heat absorption capacity in the without additional work, which raises the by 5-15% in typical systems. heats the evaporator outlet vapor above its , ensuring complete and preventing liquid ingress to the , though it slightly increases compression work; when optimized, it can enhance overall effect and by up to 10%. These modifications shift the cycle points on the P-h diagram, enlarging the enclosed area for heat absorption relative to work input.

Absorption Cycle

The absorption refrigeration is a heat-driven that utilizes to achieve cooling, replacing mechanical with chemical and desorption mechanisms. It operates on the principle of a working fluid pair consisting of a and an absorbent, where the refrigerant is absorbed into the absorbent solution at low pressure and temperature, releasing heat, and then desorbed using external heat input to regenerate the refrigerant vapor for the cooling . This is particularly advantageous for applications where waste heat or low-grade is available, as it minimizes electrical power consumption beyond auxiliary pumping. The cycle proceeds through five main steps. In the absorption step, vapor from the is absorbed into a dilute of absorbent in the absorber, forming a concentrated and releasing of absorption. The concentrated is then pumped to higher . In the generation step, heat is applied to the concentrated , causing desorption of the vapor while the absorbent remains , producing a dilute that is returned to the absorber. The desorbed vapor is condensed in the , rejecting heat to the and forming a high-pressure . This expands through a throttle valve to low and enters the , where it evaporates, absorbing heat from the cooled medium to produce the refrigeration effect. Unlike vapor-compression cycles, the absorption process eliminates the need for a mechanical compressor by leveraging between the and absorbent. Common working pairs for the cycle include lithium bromide-, where serves as the and lithium bromide as the absorbent; this pair is non-toxic and suitable for air-conditioning applications above 5°C temperatures. Another pair is -, with as the and as the absorbent, enabling lower temperatures down to -45°C for industrial . The choice of pair depends on the required cooling temperature and system pressure, with lithium bromide- operating under vacuum to lower the of . The coefficient of performance (COP) for the absorption cycle is defined as the ratio of the refrigeration effect to the total input energy: \text{COP} = \frac{Q_\text{evap}}{Q_\text{gen} + W_\text{pump}} \approx \frac{Q_\text{evap}}{Q_\text{gen}} where Q_\text{evap} is the heat absorbed in the evaporator, Q_\text{gen} is the heat supplied to the generator, and W_\text{pump} is the negligible pump work. This heat-driven COP typically ranges from 0.6–0.75 for single-effect cycles and 1.0–1.2 for double-effect cycles, approaching the Carnot limit for reversible heat-driven refrigeration processes, which is given by \text{COP}_\text{Carnot} = \left( \frac{T_e}{T_g - T_e} \right) \left( \frac{T_g - T_c}{T_c} \right) under ideal conditions with evaporator temperature T_e, generator temperature T_g, and condenser/absorber temperature T_c. Heat sources for single-effect cycles require temperatures of 80–100°C, such as low-pressure steam or hot water, while double-effect cycles demand 150–180°C for efficiency gains through sequential generation stages.

Design and Selection

Key Components

Chillers, whether vapor-compression or types, rely on several core components to facilitate and processes. The and are fundamental shared elements in both systems. The absorbs from the chilled water or process fluid, typically using shell-and-tube or designs to maximize efficiency through contact or indirect heat exchange surfaces. Shell-and-tube evaporators are prevalent in larger industrial units due to their robustness and ability to handle high fluid volumes, while plate types offer compact footprints suitable for space-constrained applications. The , in contrast, rejects absorbed to the , available in air-cooled configurations with finned coils for atmospheric or water-cooled variants using cooling towers for enhanced thermal performance in water-abundant settings. Type-specific components distinguish the operational mechanisms of each chiller category. In vapor-compression chillers, the serves as the primary driver, elevating pressure and temperature to enable the cycle; common variants include screw compressors for variable capacity control in mid-sized systems and centrifugal compressors for large-capacity applications, typically 200 tons and above, leveraging dynamics for efficient compression. Absorption chillers, however, replace the with a generator and absorber assembly, where the generator uses heat—often from or hot —to separate the (typically ) from the absorbent ( solution), and the absorber facilitates reabsorption under conditions; these can employ crystal or falling-film configurations for improved heat and efficiency. Auxiliary components ensure system reliability and precise control. Expansion devices, such as thermostatic expansion valves (TXVs), regulate into the evaporator by sensing superheat levels, maintaining optimal charge and preventing liquid slugging. Pumps circulate chilled water through the and water loops, with variable-speed options enhancing , while control systems integrate sensors for , , and monitoring to enable automated adjustments and fault detection. Material selection and maintenance practices are critical for , as chillers operate in corrosive environments from refrigerants and water treatments. Components often incorporate alloys or for heat exchangers to resist pitting and , with coatings or inhibitors mitigating . Common failures include from mineral deposits or biological growth in and condensers, which reduces rates by up to 30% if unaddressed, necessitating regular cleaning and management.

Selection Criteria

Selecting a chiller involves a thorough to match the system's to the application's cooling requirements. cooling represents the maximum instantaneous load, typically used for initial to ensure reliability during high-demand periods, while average reflects the typical operational load over time, which is often lower and influences considerations. For multi-chiller setups, factors account for the non-simultaneous peaking of loads across zones or units, commonly ranging from 75% to 85%, allowing for optimized total without oversizing the system. Efficiency metrics guide the evaluation of chiller performance under varying conditions. The Integrated Part Load Value (IPLV) provides a weighted average efficiency metric for variable loads, calculated based on operation at 100%, 75%, 50%, and 25% capacities using standard conditions defined by AHRI Standard 550/590, emphasizing part-load performance since chillers rarely operate at full load. Life-cycle cost analysis incorporates initial purchase, installation, energy consumption, maintenance, and replacement costs to determine long-term value, often favoring chillers with high IPLV ratings in applications with fluctuating demands. Site-specific factors significantly influence chiller selection, particularly in settings. Power availability dictates the feasibility of electric vapor-compression chillers versus types that may use or gas, with sites requiring assessment of electrical capacity to avoid upgrades. Space constraints affect chiller footprint and layout, while impacts condenser performance in water-cooled systems, necessitating to prevent or . For applications prioritizing uptime, redundancy configurations such as —providing one additional unit beyond the minimum required—ensure continuous operation during maintenance or failures, supporting high-reliability needs like 99%+ availability. Economic tools aid in comparing chiller options and validating designs. calculations for versus vapor-compression chillers vary widely, often 3-7 years when utilizing sources due to lower operating expenses offsetting higher upfront costs, though longer periods up to 13 years can occur in specialized configurations without free heat sources. like Carrier's Hourly Analysis Program (HAP) models annual energy use, load profiles, and system interactions to simulate performance and support sizing decisions.

Refrigerants and Sustainability

Common Refrigerants

Chillers employ a variety of refrigerants depending on the system type, with vapor-compression chillers primarily using synthetic hydrofluorocarbons (HFCs), hydrochlorofluorocarbons (HCFCs), and natural fluids, while chillers rely on specific refrigerant-absorbent pairs. In vapor-compression chillers, HCFC-22 (R-22) was historically common but has been phased out from production and import by 2020 due to its ozone-depleting properties. R-22 has a of -40.8°C and is classified as by standards, indicating low toxicity and non-flammability. HFCs such as R-134a and are widely used replacements in modern vapor-compression systems. R-134a, with a boiling point of -26.3°C, is classified as and dominates in large centrifugal chillers due to its favorable thermodynamic properties and compatibility with system components. , a blend with a of -48.5°C, also holds an classification and is prevalent in smaller to medium-capacity chillers for its higher efficiency in screw and scroll compressors. Natural refrigerants offer alternatives with distinct properties. (R-717) has a of -33.3°C and is classified as B2L by , signifying higher toxicity and mild flammability, yet it is favored in industrial chillers for its low cost and excellent efficiency. (R-744), with a point of -78.5°C, is A1-rated and used in transcritical cycles for specialized high-pressure applications in chillers. The following table summarizes key properties of selected vapor-compression refrigerants:
RefrigerantType (°C) Safety ClassCommon Usage in Chillers
R-22HCFC-40.8A1Historical, phased out
R-134aHFC-26.3A1Centrifugal, dominant
HFC Blend-48.5A1Screw/scroll, medium capacity
R-717 ()Natural-33.3B2LIndustrial, low-cost
R-744 (CO2)Natural-78.5 (subl.)A1Transcritical, specialized
Absorption chillers utilize working pairs where the refrigerant is absorbed by a non-volatile or less volatile liquid. The lithium bromide-water (LiBr-H2O) pair is common, with water serving as the refrigerant (boiling point 100°C at atmospheric pressure) and LiBr as the non-volatile absorber, enabling operation in air-conditioning applications above 0°C evaporation temperatures. The ammonia-water (NH3-H2O) pair, where ammonia is the refrigerant and water the absorber, supports lower-temperature refrigeration with ammonia's boiling point of -33.3°C, though it requires careful handling due to ammonia's toxicity (B2L classification). These pairs are selected for their compatibility and ability to achieve high absorption efficiency without mechanical compression.

Environmental Regulations and Alternatives

The Montreal Protocol, adopted in 1987, established a global framework to phase out the production and consumption of ozone-depleting substances, including chlorofluorocarbons (CFCs) commonly used in chiller refrigeration systems, leading to their near-complete elimination by the early 2000s and significant recovery of the stratospheric ozone layer. The Kigali Amendment, adopted in 2016 as an extension of the Montreal Protocol, targets hydrofluorocarbons (HFCs)—non-ozone-depleting alternatives to CFCs—with a phasedown schedule aiming to reduce global HFC production and consumption by more than 80% over the next 30 years, directly affecting chiller operations that rely on these potent greenhouse gases. In the European Union, the F-Gas Regulation (EU) No 517/2014 mandates an HFC phase-down to 21% of the 2009-2012 baseline by 2030 through quotas and bans on high-global-warming-potential (GWP) substances in chillers, with further revisions in 2024 accelerating restrictions to support a 95% reduction in F-gas emissions by 2050. Similarly, the U.S. American Innovation and Manufacturing (AIM) Act of 2020 directs the Environmental Protection Agency to phase down HFC production and consumption by 85% by 2036, imposing sector-specific restrictions on chillers to curb emissions from refrigerant leaks and disposal; effective January 1, 2025, new chillers for comfort cooling are prohibited from using HFCs or blends with GWP ≥ 700. These regulations address key environmental metrics: (ODP), which quantifies a substance's capacity to destroy stratospheric relative to a reference (e.g., CFCs have ODP values up to 1.0, while HFCs have ODP of 0), and (GWP), which measures heat-trapping effects over 100 years compared to (e.g., common HFCs like have GWP exceeding 2,000). Chillers contribute to global environmental burdens through energy-intensive vapor-compression cycles and direct releases that amplify climate impacts. To comply with these mandates, low-impact alternatives are gaining traction, including hydrofluoroolefins (HFOs) such as R-1234ze, which offers a GWP below 1 and zero ODP, enabling in centrifugal chillers with minimal efficiency losses. Hydrocarbon refrigerants, such as propane (R-290) blends, provide natural, low-GWP options (GWP of 3) for smaller or industrial chillers, though their flammability requires enhanced safety designs like secondary containment. Advancements in absorption chillers, which use as the refrigerant and as the absorbent, inherently minimize reliance on synthetic refrigerants by eliminating HFCs entirely, with recent innovations in two-stage cycles improving by up to 20% to further reduce operational energy demands. Looking toward 2025, net-zero emission goals are accelerating adoption of chillers, which eliminate oil for frictionless operation, boosting part-load efficiency by 30-50% and reducing indirect emissions in data centers and commercial buildings. Concurrently, integrated refrigerant recovery systems—mandated under updated regulations—are becoming standard, capturing over 95% of leaked or end-of-life refrigerants to prevent atmospheric release and support principles in chiller maintenance.

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