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Flour

Flour is a finely ground produced by milling grains, , nuts, seeds, or , serving as a fundamental ingredient in baking, cooking, and food manufacturing due to its ability to provide , , and thickening properties. Most commonly derived from , it consists of particles from the , , and of the , with processing separating these components to yield different varieties based on refinement level and intended use. The production of flour begins with harvesting grains, followed by cleaning to remove impurities, tempering to adjust moisture content for optimal milling, and grinding through roller mills or stone mills to break down the kernels into flour streams. This process, which dates back over 10,000 years to the of in the , has evolved from manual stone grinding to modern industrial methods that ensure consistency and nutritional enrichment. Flour is a raw agricultural commodity that may contain harmful , so it must be cooked or baked to ensure safety. In contemporary milling, is sifted into various grades, with the primarily used for white flour while and are often reincorporated for whole-grain types or processed into by-products like . Key types of flour are classified by grain source and protein () content, which determines their functionality in recipes: all-purpose flour, a blend of hard and soft with 10-12% protein, suits general ; bread flour from hard varieties (12-14% protein) excels in yeast-leavened products for strong development; cake and pastry flours from soft (under 10% protein) produce tender textures in sweets and crusts; and durum flour, from hard , is ideal for due to its high strength. Alternative flours from , corn, , or chickpeas cater to gluten-free or specialty diets, offering varied nutritional profiles like higher or protein. In the , flour's primary uses include forming the base for baked goods such as breads, cakes, , and pastries, where its proteins form networks for elasticity and rise when hydrated and kneaded. It also thickens sauces, gravies, and batters, and serves in non-baked applications like noodles, tortillas, and extruded snacks. Global production exceeds 800 million metric tons annually as of the 2024/25 marketing year, with approximately 570 million tonnes milled into flour worldwide. Enrichment with vitamins and minerals, mandated in many countries, addresses nutritional deficiencies, making flour a vital contributor to alongside its culinary versatility.

Etymology and History

Etymology

The word "flour" derives from the Latin flos, meaning "flower," which metaphorically referred to the finest, most delicate portion of ground , akin to the bloom of a . This association arose because early milling processes separated the powdery, high-quality part of the meal, evoking the idea of a flower as the best or purest element. The term evolved through Old French flur or flor, which carried dual meanings of "flower" and "the best part of meal," entering Middle English as flour around the mid-13th century. In this period, flour first appeared in documented texts from the 1200s, initially interchangeable with flower due to their shared origin and pronunciation as homonyms. Over time, to avoid confusion, English speakers distinguished the two by respelling flower with an "e" while retaining flour for the product, a solidified by the . Related English terms highlight gradations in grinding: "" denotes a coarser grind of grain, stemming from melu rather than the floral metaphor. In other languages, equivalents often trace to distinct roots; for instance, harina derives from Latin farīna ("" or "flour"), itself from far meaning "" or , emphasizing the material rather than fineness.

Ancient and medieval milling

The earliest evidence of flour production dates to the period, around 30,000 years ago, when hunter-gatherers used simple stone tools to process wild s and plants into edible forms. Archaeological findings from sites such as Bilancino II in (dated to approximately 28,300 BCE), Kostenki 16 in (30,000–32,000 BCE), and Pavlov VI in the (29,000 BCE) reveal residues of grasses, ferns, and cattail on stones and pestles, indicating the use of mortars and early quern-like tools for pounding and ing. These handheld implements, often made of or , allowed small-scale processing of wild cereals like Brachypodium and Botrychium, marking the beginnings of human manipulation of s for . In , milling evolved into a more systematic practice by the period, with saddle querns becoming the primary tool for grinding wheat, a key staple crop. Dating back to at least 4000 BCE, these elongated stone basins paired with rubbing stones enabled women to produce coarse flour for , as depicted in reliefs and confirmed by archaeological remains from sites like the pyramids. wheat flour, often mixed with , formed the basis of flatbreads central to the ian diet, supporting agricultural surplus from floods. By the (around 2000 BCE), while saddle querns remained dominant, early experiments with more efficient rotary hand-mills appeared in the broader , though full adoption in Egypt occurred later during the Ptolemaic era. Roman engineering advanced milling on a grand scale in the 2nd century CE, introducing water-powered mills that revolutionized production capacity. The Barbegal complex near Arles, France, exemplifies this innovation: a series of 16 overshot waterwheels along an aqueduct gradient, capable of grinding up to 25 tons of flour daily to feed around 27,000 people. Built around 140–250 CE, these mills processed wheat into fine flour for urban distribution, reducing labor demands and enabling surplus for military and civilian needs across the empire. Such hydraulic systems, powered by aqueducts, marked a shift from manual to mechanized grinding, influencing Mediterranean economies. During the medieval period in , from the onward, windmills emerged as a vital complement to watermills, powering processing in feudal societies where underpinned daily sustenance. First documented in around 1185 CE and spreading rapidly across and by the early 1200s, vertical-axis windmills ground and into for , which constituted up to 70% of caloric by 1000 CE in diets. Lords often monopolized these mills, charging tolls that reinforced and economic hierarchies, while the technology's adoption in low-water regions like the boosted agricultural output and trade in milled goods. By the 13th century, windmills symbolized feudal prosperity, processing staples that sustained growing populations amid the .

Industrial revolution and modern processing

The marked a pivotal shift in flour production, transitioning from labor-intensive, water- or wind-powered mills to mechanized systems that dramatically scaled output and efficiency. In , engines began powering flour mills in the , with the Mills in —designed by Samuel Wyatt and equipped with a 50-horsepower rotary by —representing the first major application in 1786. This innovation allowed mills to operate continuously and independently of natural water flows, significantly boosting production capacity; for instance, the Mills could grind enough to produce thousands of bags of flour weekly, far exceeding traditional stone mills that relied on intermittent power sources. A key advancement came in 1865 with the introduction of steam-powered roller mills in , where metal rollers replaced stone grinding to progressively break kernels, effectively separating the and from the endosperm to yield purer white flour. These mills automated the separation process, enabling higher yields of refined flour that met growing demand for consistent, high-quality products in urban markets. By the late , roller milling had spread across Europe, supplanting older methods and reducing overall processing times from multi-day batch operations in traditional mills to mere hours in continuous roller systems. In the , roller milling achieved global dominance as the standard for commercial flour production, with refinements in roller design and further enhancing precision and throughput. This era saw mills evolve into large-scale facilities capable of processing thousands of tons of daily, supporting the rise of industrialized and industries. The technology's efficiency minimized waste and standardized flour characteristics, making it indispensable for modern supply chains. The global dissemination of roller milling accelerated after the , where Hungarian-inspired designs were adopted to handle the influx of hard spring wheat from the Midwest. Pioneering mills like the Washburn Crosby operation in installed roller systems by 1878, enabling that supplied burgeoning urban centers with affordable, uniform flour. This adoption not only fueled America's emergence as a leading flour exporter but also transformed milling into a of the national economy, with output surging to meet domestic and international needs by the early 1900s.

Degermed and heat-processed innovations

In the early , the degerming process emerged as a key innovation in U.S. flour milling, particularly for corn, with John Beall patenting the Beall degerminator in 1901 to mechanically separate the oily from the and pericarp. This removal prevented rancidity caused by the 's high oil content, which oxidizes rapidly and shortens , allowing degermed flours to remain stable for 6-12 months under proper storage conditions compared to just 1-3 months for whole-grain varieties containing the . By the , degerming techniques had been refined and widely adopted in industrial milling for both corn and , building on roller milling foundations to produce refined white flour with extended usability for commercial and distribution. Heat-processing methods advanced in as an alternative to chemical treatments, employing up to 150°C to inactivate enzymes like and pathogens in flour without additives, thereby improving stability and performance. These thermal processes, often using dry heat or , denatured proteins and partially gelatinized starches, enhancing flour's and crumb structure in products like cakes while extending by reducing microbial risks. Such innovations addressed quality degradation in refined flours, supporting the growth of mass-produced baked goods during the era. For corn flour specifically, —a Mesoamerican involving alkaline cooking of kernels to loosen hulls and boost nutrition—was industrially adapted post-1940s through innovations like the 1949 development of dry harina by in , enabling scalable production of nixtamalized corn flour for tortillas. This process cooked corn in lime solution, steeped it, and dried it into flour, preserving cultural flavors while allowing mass manufacturing that reached 150 tons monthly initially and expanded globally by the 1970s via patented pre-cooking systems. Despite these benefits, degerming and refining stripped natural vitamins like thiamin, riboflavin, niacin, and iron from the germ and bran, contributing to deficiency diseases observed in the 1930s-1940s. To counter this, the U.S. FDA established enrichment standards for flour in 1941, requiring addition of these nutrients at specified levels, with a 1943 War Food Order mandating enrichment for all interstate flour sales—a policy that became voluntary nationwide by 1946 but was required in 26 states by 1952.

Production

Raw materials and sourcing

Flour production primarily relies on (Triticum aestivum) as the dominant , accounting for the vast majority of global output due to its versatile properties for and . varieties are broadly classified as hard or soft based on kernel texture and protein content, which typically ranges from 10% to 15%; hard , with higher protein levels (often 12-15%), is preferred for bread-making due to its stronger formation, while soft (around 10-12% protein) suits pastries and cakes for its tender crumb. Other cereal grains serve as important alternatives, including (Secale cereale), valued for its robust flavor in breads; (Hordeum vulgare), used in flatbreads and malting; corn (maize, Zea mays), ground into for tortillas; and (Oryza sativa), milled into fine flour for gluten-free applications. Non-cereal sources expand flour diversity, such as nuts like almonds (Prunus dulcis) for low-carb baking, legumes including chickpeas (Cicer arietinum) for protein-rich batters, and roots like (Manihot esculenta) for starchy, -free options in tropical regions. Sourcing decisions hinge on climate suitability, with wheat thriving in temperate zones featuring cool winters and moderate summers (average temperatures of 15-25°C during growth), enabling cultivation in regions like and . Since the , debates over genetically modified (GMO) versus organic wheat have intensified, with organic methods emphasizing and but yielding 20-30% less than conventional varieties in some studies, influencing consumer preferences and regulatory standards. As of 2024, GMO wheat varieties like HB4 have received regulatory approval in the and some countries for , though commercial planting remains limited. Global production reached approximately 801 million metric tons as of 2024/25, reflecting steady output in the , with and as the leading producers at 140 million and 113 million tons, respectively.

Milling techniques

Milling techniques for flour involve mechanical processes that reduce kernels into fine powders, varying from traditional methods that retain whole-grain to modern systems optimized for refinement and specialization. These techniques differ in their mechanisms of grinding, resulting in distinct flour characteristics such as , nutrient retention, and suitability for specific applications. Stone milling, a longstanding traditional method, grinds whole kernels between two rotating stones, typically made of or , using , , and to produce a coarse whole-grain . This process achieves a theoretical 100% rate, preserving all kernel components including , , and , which maintains higher nutrient levels compared to refined methods, though it generates frictional that can degrade sensitive components like and unsaturated fatty acids. The resulting flour has an uneven , with a higher proportion of fine particles below 85 μm alongside coarser ones up to over 363 μm, often yielding a broad range of 96–180 μm after sieving. Roller milling, the dominant industrial technique since the , employs a series of sequential rollers—corrugated for initial breaking and smooth for reduction—to separate the from and before grinding and sifting the endosperm into refined flour. This multi-stage process, involving up to 20–30 roller pairs and intermediate sifting, produces a flour with an extraction rate of approximately 70–75% for white flour, discarding bran and germ for higher purity and longer . The is more consistent, with recombined streams showing about 55% of particles larger than 85 μm, enabling efficient production of standardized flours for . Impact milling, also known as milling, utilizes high-speed rotating s within a chamber to strike grains against a perforated screen or wall, shattering them into flour through rapid impact forces. This method is particularly suited for gluten-free grains such as , , and , as it effectively processes non-wheat cereals without requiring separation of components, and is common in small-scale operations due to its simplicity and lower cost. It produces coarser, polygonal particles with median sizes around 100–200 μm and lower damaged levels (3–4%), though it may attach more to , affecting water absorption. Air classification serves as a complementary post-grinding , using controlled air currents to separate flour particles by and after initial milling, allowing for the of specialty flours with tailored protein content. Introduced commercially in the United States by the Pillsbury Company in 1957, it enables the of fine protein-rich particles from coarser starch-dominant ones, facilitating applications like high-protein flours from soft varieties. By the , it accounted for about 6% of U.S. milling capacity, enhancing versatility in flour types without additional grinding.

Post-milling treatments

After milling, flour undergoes various treatments to improve its color, nutritional profile, baking performance, and stability. These processes, known as post-milling treatments, address limitations in freshly milled flour, such as its yellowish tint from natural pigments and potential nutrient losses during processing. Common treatments include bleaching for whitening, enrichment for nutritional enhancement, and chemical maturation for better dough handling. Bleaching agents are applied to accelerate the natural oxidation that whitens flour by breaking down carotenoid pigments. Benzoyl peroxide, introduced in the early 1900s and approved by the U.S. FDA in 1921, oxidizes these pigments through free radical reactions, achieving a whiter appearance in 24-48 hours compared to weeks or months naturally. Chlorine gas was a historical method used before the 1940s to bleach and mature flour simultaneously, but it has been phased out in the European Union due to health concerns over chlorinated residues and is now prohibited there. In the U.S., benzoyl peroxide remains permitted at levels up to 50 mg/kg as a generally recognized as safe (GRAS) substance, though it can degrade nutrients like vitamin E. Enrichment involves adding essential nutrients lost during milling to combat dietary deficiencies. , standards established by the FDA in 1941 require to contain specific levels of thiamin (2.9 mg/lb), (1.8 mg/lb), , and iron (20 mg/lb), with folic acid added since 1998. This practice, prompted by nutritional concerns during , became effectively mandatory for labeled enriched products to prevent conditions like beriberi and , though unenriched flour remains available. Aging treatments mature flour by oxidizing proteins to enhance properties, either ly or chemically. aging occurs over 1-2 months through exposure to air, gradually improving elasticity and color without additives. Chemical aging, historically using as an to strengthen and increase volume, has been largely discontinued due to its classification as a possible by the International Agency for Research on Cancer in 1999, leading to bans in the (1990), (1994), (2005), and other countries. Safer maturation agents, such as ascorbic acid, are now widely used to mimic aging effects by promoting disulfide bond formation in proteins, thereby strengthening the network, improving gas retention, and enhancing loaf volume by up to 20% at dosages of 20-200 . Added directly to flour during processing or to , ascorbic acid oxidizes sulfhydryl groups into stable cross-links, reducing mixing times and increasing dough tolerance, and is approved in the U.S. at up to 200 with no residues remaining after .

Quality control and standards

Quality control in flour production involves rigorous testing protocols to ensure consistency in physical, chemical, and microbiological properties, as well as adherence to international and regional standards for safety and quality. These measures help maintain flour's suitability for , nutritional labeling, and consumer health by preventing spoilage and verifying compositional accuracy. Mills typically implement analyses at various stages, from raw intake to final packaging, to classify flour types and comply with regulatory requirements. Moisture content is a critical parameter, with ideal levels for maintained between 12% and 14% to prevent growth and ensure stability. Testing is performed using the method, where a flour sample is heated at 130°C for 60 minutes in an air , and the is calculated from the weight loss. Levels exceeding 14.5% increase the risk of microbial proliferation, while excessive can affect milling efficiency. Protein and content analyses are essential for flour , such as distinguishing flour (high protein) from flour (low protein). Protein is determined via the Kjeldahl nitrogen method, which digests the sample in to convert to , followed by and to quantify total , then multiplied by a factor of 5.7 for to estimate crude protein. content, indicating levels and rate, is measured by incinerating a sample at 550–600°C and weighing the residue, with refined white flour typically below 0.55% and whole wheat above 1.2%. ISO 22000 provides a globally recognized framework for management systems in flour production, integrating prerequisite programs and principles to control contamination risks throughout the . It incorporates and Critical Control Points (HACCP) plans, which emerged in the 1990s as a systematic approach to identifying and mitigating biological, chemical, and physical hazards in milling processes. HACCP implementation in flour mills, formalized through guidelines in the early 1990s, requires monitoring critical points like cleaning and to ensure product integrity. Regional standards vary, with the U.S. (FDA) enforcing standards of identity under 21 CFR Part 137 for flours, specifying limits on additives, moisture, and labeling for types like . Globally, the Commission sets harmonized guidelines, including a 20 ppm threshold for in certified gluten-free flours derived from non-gluten grains or processed to remove . This threshold, adopted in the Codex Standard for Foods for Special Dietary Use for Persons Intolerant to (CODEX STAN 118-1981, revised 2008), aligns with FDA rules and enables international trade compliance.

Composition

Chemical components

Flour's primarily consists of carbohydrates, proteins, , and minor components such as minerals and fibers, with variations depending on the type and processing method. In , the predominant component is carbohydrates, which constitute approximately 70-75% of the dry weight, mainly in the form of starches that serve as the reserve. These starches are composed of (about 25%) and (about 75%), where is a linear of glucose units linked by α-1,4 glycosidic bonds, and is a branched with additional α-1,6 linkages, influencing flour's gelatinization and properties. Proteins make up 8-15% of wheat flour's composition, with the majority (over 75%) being storage proteins known as , specifically and . are polymeric proteins that provide elasticity and strength to through bonds, while contribute and extensibility; together, account for roughly 30% and 50% of the total protein content. These proteins are concentrated in the and are crucial for the viscoelastic network formed during and mixing. Lipids comprise 1-2% of , primarily as polar and nonpolar fractions including glycolipids, , and triglycerides derived from the and . A significant portion of these are unsaturated fats, such as (approximately 60%) and (14%), which originate from germ oils but are substantially reduced in refined flours due to the removal of the and during milling. Minerals and fibers represent trace but essential elements, with present at about 0.36% in , often bound in phytates within the . Insoluble fibers, mainly and from the , contribute to the structural integrity and are more abundant in whole-grain flours, where total (primarily insoluble) comprises up to 10-15% of the dry weight in unrefined varieties.

Nutritional content

Flour serves as a of carbohydrates in the human diet, contributing significantly to caloric intake with approximately 350-364 kcal per 100 grams, predominantly from complex carbohydrates such as , while containing low levels of at 1-2 grams per 100 grams. This caloric density makes flour an efficient provider, though its varies based on . The component, a of glucose, forms the bulk of these carbohydrates, supporting sustained release when consumed in balanced diets. Refining into white flour results in substantial losses, with up to 80% of thiamin (B1), riboflavin (B2), and removed during the milling process that separates the and from the . These deficiencies historically contributed to conditions like beriberi and in populations reliant on , prompting mandatory enrichment programs. To counteract this, enriched flours in the United States must add specific levels of vitamins and minerals per FDA standards, including 4-6 mg of iron per 100 grams (equivalent to 20-26 mg per pound), along with thiamin, riboflavin, , and folic acid, restoring key micronutrients to prevent widespread deficiencies. Dietary fiber content differs markedly between , which provides about 12 grams per 100 grams primarily from , and refined flour at around 2.5 grams per 100 grams, influencing digestive health. The higher fiber in promotes regular bowel movements, reduces absorption, and supports , offering protective effects against and cardiovascular issues. In contrast, low-fiber refined flours may contribute to digestive challenges if not balanced with other high-fiber foods. Gluten-free alternative flours, such as those derived from nuts, often exhibit elevated profiles compared to cereal-based options; for instance, flour contains approximately 270 mg of magnesium per 100 grams, aiding muscle function, energy metabolism, and bone health in diets avoiding wheat . These alternatives can enhance overall nutrient density for individuals with celiac disease or gluten sensitivity, though their higher fat content requires portion control to manage caloric intake.

Variations by grain type

Flour derived from typically contains around 12% protein, primarily in the form of , which provides elasticity and structure in , while exhibiting low levels of damage (typically 5-7%) that supports optimal absorption and performance. In contrast, flour has approximately 8% protein and a higher concentration of pentosans (up to 8-10% of dry matter), non- that contribute to stickiness by binding and increasing during mixing. Corn flour generally features 6-9% protein, with limited formation, but undergoes —a process involving treatment—to enhance the of () from bound forms, reducing the risk of and improving nutritional absorption. , at about 7% protein, is notable for its properties due to the absence of proteins like , making it suitable for sensitive populations, though it lacks the balance found in other grains. Legume flours, such as flour, offer significantly higher protein levels at around 20%, enriched with essential like (1.2-1.4 g/100 g dry matter), which complements cereal deficiencies and boosts overall in blends. Non-grain sources like flour are characterized by very low protein content (approximately 2%), rendering them primarily starch-based, but they pose a high risk of toxicity if not properly processed to remove cyanogenic glycosides present in the raw root.

Types

Wheat-based flours

Wheat-based flours are primarily classified by their protein content, which influences development and texture in baked goods, as well as by size and intended culinary applications. Protein levels typically range from 7% to 14%, with higher contents yielding stronger networks suitable for chewy breads, while lower levels produce tender pastries and cakes. fineness also varies, affecting absorption and crumb structure, with finer particles used for delicate items. These flours are derived from hard or soft varieties, milled to remove and in refined types, and are widely used in worldwide. All-purpose flour, with 10-12% protein, serves as a versatile option for general baking tasks such as cookies, muffins, and quick breads, balancing strength and tenderness without requiring substitutions. Bread flour, containing 12-14% protein, develops high gluten levels that support robust yeast rises and chewy structures in loaves and pizza doughs. In contrast, pastry flour at 8-9% protein promotes a tender crumb ideal for pie crusts and biscuits, while cake flour, with 7-9% protein and a finely milled texture (approximately 80-100 mesh), ensures light, fluffy results in cakes and delicate confections. Whole wheat flour, around 13% protein, retains the bran and germ for added nutrition and nutty flavor but can result in denser textures unless blended with refined flours. Bleached flour undergoes chemical treatment to accelerate oxidation, yielding a whiter color, finer , and softer texture compared to unbleached flour, which ages naturally for a denser and tougher feel; this bleaching, often referenced in post-milling processes, enhances handling but is optional in many recipes. In many markets, including the , refined flours are standardly enriched to restore nutrients lost during milling, adding specified levels of iron, thiamin, , , and folic acid per federal regulations to support .

Other cereal flours

Rye flour, derived from the grain (Secale cereale), is characterized by its dark color and nutty , resulting from higher levels of pentosans and compared to other cereal flours. It has a relatively low content, typically ranging from 3% to 8% on a dry basis, which limits its ability to form a strong elastic network and often requires blending with for leavened breads. This low-gluten property makes rye flour particularly suitable for dense, hearty breads like , where fermentation enhances and through . Rye flour is classified into types based on extraction rate and content: light rye flour, milled from the inner with minimal for a milder and finer ; medium rye, incorporating more for added color and fiber; and dark or rye, a whole-grain variety ground coarsely from the entire kernel, yielding a robust, earthy taste ideal for traditional pumpernickel . Corn flour, produced by finely grinding dried maize kernels (Zea mays), is a versatile staple with a neutral flavor and smooth texture, valued for its fine that contributes to crumb in baked goods. As a naturally gluten-free flour, it serves as a key ingredient in products for those avoiding , such as tortillas and . A specialized variant, harina, is made from nixtamalized corn—kernels soaked and cooked in an alkaline solution of —which improves nutritional by increasing calcium content and absorption while imparting a distinctive corn aroma and pliability to doughs. This process, rooted in Mesoamerican traditions, results in a flour that hydrates readily and is essential for authentic masa-based foods. Barley flour, milled from hulled or hull-less ( vulgare), offers a mild, slightly sweet profile with approximately 10% protein content, providing moderate structure in without strong development. It is notably rich in beta-glucans, soluble fibers that form viscous gels in the digestive tract, supporting benefits such as lowered levels and improved glycemic control when consumed regularly. These beta-glucans, concentrated in the and , contribute to barley's role in functional foods, enhancing and cardiovascular without altering the flour's utility. Rice flour, obtained by grinding rice grains (Oryza sativa), varies significantly by variety, influencing its texture and application in both savory and sweet preparations. Long-grain rice flour, high in (up to 25-30%), yields a drier, less sticky product suitable for crisp coatings and lightweight batters due to its lower water-binding capacity. In contrast, sticky or short-grain rice flour, dominated by (over 90% of ), produces a cohesive, glutinous texture ideal for chewy noodles and mochi-like desserts, as the branched starch structure promotes gelation upon heating. Both types are gluten-free, enabling their use in allergen-friendly recipes. Oat flour, created by grinding rolled or (Avena sativa), retains the grain's creamy consistency and wholesome flavor, often used in gluten-free for its binding qualities from natural gums. It contains high levels of soluble , approximately 5 g per 100 g, primarily as , which aids in reduction and blood sugar stabilization. Rolled oat flour, from flattened groats, offers a coarser texture for heartier breads, while finely ground versions mimic all-purpose flour in smoother applications like pancakes.

Non-cereal and alternative flours

Non-cereal and alternative flours are derived from sources outside the grass family (), including nuts, , roots, tubers, and pseudocereals, offering gluten-free alternatives that cater to dietary restrictions, nutritional needs, and specialized diets. These flours provide diverse textures, flavors, and health benefits, such as higher protein or content compared to traditional flours, making them popular in , cooking, and processed foods. Their use has expanded due to rising awareness of celiac disease, gluten sensitivity, and interest in plant-based . Nut flours, such as flour, are produced by grinding blanched or whole s into a fine powder, resulting in a composition high in (approximately 50%), moderate protein (around 25%), and low carbohydrates (about 20%). This profile makes almond flour particularly suitable for low-carbohydrate and ketogenic diets, where it serves as a base for baked goods like muffins and cookies without spiking blood sugar levels. Additionally, almond flour is rich in , providing about 25 mg per 100 g, which acts as an supporting and immune function. Legume flours, including (also known as besan or garbanzo bean flour), are milled from dried and offer a nutty with significant nutritional value, containing around 20-22% protein by weight, which exceeds that of . This high protein content enhances and supports muscle repair, making it a staple in flatbreads, batters, and savory dishes. flour, ground from or lentils, is valued in gluten-free baking for its binding properties, which help mimic the structure of by forming a cohesive in items like breads and cakes, while contributing additional fiber and iron. Root and tuber flours provide starch-rich options for thickening and gluten-free applications. Cassava flour, derived from the whole root of the cassava plant (), is nearly pure (over 80% ), with minimal , , or , making it ideal for creating chewy textures in pancakes and , though it requires careful processing to remove natural cyanogenic compounds. Yam flour, processed from white or yellow yams ( species), retains the tuber’s natural and content, offering a mild flavor suitable for swallows in and gluten-free porridges, with added benefits from potassium and for digestive health. Pseudocereal flours, such as flour, come from seeds of plants like Chenopodium quinoa and stand out for their balanced nutrition, with approximately 14% protein content and a profile that includes all nine essential , qualifying it as a source for vegetarians and vegans. This completeness supports comprehensive needs, aiding in tissue repair and hormone production, while its earthy taste works well in muffins, pancakes, and . The market for gluten-free flours, including these non-cereal alternatives, has seen substantial growth, reaching about $6.4 billion globally in 2022, approximately $7.2 billion as of 2025, and projected to reach $9.4 billion by 2031 at a CAGR of 4% due to increasing demand for allergen-free and health-focused products.

Specialty and blended flours

Specialty flours are designed for particular dietary needs, functional properties, or enhanced nutritional profiles, often through blending or to achieve specific textures, rises, or health benefits. These include self-rising varieties for convenience in , gluten-free options to replicate wheat-based doughs, high-extraction flours retaining more and for , and functional blends incorporating bioactive ingredients. Blended flours combine multiple grains or additives to optimize or , such as high-fiber mixes that boost dietary intake without altering traditional recipes significantly. Self-rising flour consists of all-purpose flour combined with approximately 1 to 1.5 percent and a small amount of , typically 0.25 percent, to provide leavening and in one convenient product. This formulation allows for quick breads and biscuits without separate additions of leavening agents. It was invented and patented in by English Henry Jones in , , initially to improve quality for the by simplifying the process at . Gluten-free flour blends aim to mimic the elasticity and structure of wheat flour for those with celiac disease or gluten sensitivity, commonly using a mix of rice flour, tapioca starch, and potato starch in proportions such as 40-50 percent rice flour, 25-30 percent each of tapioca and potato starch, often with xanthan gum for binding. These ingredients provide a neutral flavor from rice, chewiness from tapioca, and tenderness from potato starch, enabling similar rise and crumb in baked goods. University extension resources highlight such blends as effective for everyday gluten-free baking, emphasizing superfine milling for better incorporation. High-extraction flours, which retain a higher proportion of the and compared to refined varieties, offer increased and nutrients; , a coarse high-extraction flour milled from , typically contains about 12 percent protein, contributing to its strength and suitability for production where it forms a firm, chewy texture. 's high glutenin content supports the extrusion and drying processes in commercial manufacturing. and ancient grain flours, such as those from einkorn—an early domesticated —boast even higher protein levels, averaging 18 percent, along with elevated minerals like and , appealing to consumers seeking heritage varieties with potential digestibility advantages. Functional flours incorporate bioactive compounds to enhance outcomes, such as with omega-3 fatty acids from sources like flaxseed or , which emerged prominently in the to address deficiencies in diets and support cardiovascular . Studies on omega-3-fortified infant flours demonstrate improved lipid profiles and growth in animal models, indicating potential for broader applications in blended baking mixes. Probiotic-enriched flours, often through of grains like or with strains such as Lactobacillus plantarum, introduce live beneficial bacteria to promote gut , with research showing viable incorporation into formulations since the mid-2010s. High-fiber blended flours combine refined with ingredients like or whole grains to deliver up to 10 times the of standard flour, aiding and blood sugar control while maintaining functionality. Commercial examples, such as those from milling companies, blend with isolates to achieve 6-17 grams of per serving, allowing in recipes for muffins or cakes without compromising .

Uses and Applications

Baking and bread-making

Flour serves as the foundational in and bread-making, where its proteins interact with to form , enabling the structure necessary for both leavened and unleavened products. In leavened breads, levels typically range from 60-65% relative to flour weight, allowing the to absorb and develop a cohesive during . This process aligns and glutenin proteins through mechanical agitation and the formation of disulfide bonds, creating an elastic matrix that provides strength and extensibility to the . During yeast fermentation, the high protein content of bread flour, often 12-14%, facilitates the trapping of carbon dioxide (CO₂) gas produced by yeast, which causes the dough to rise. After initial mixing and bulk fermentation, the shaped dough undergoes proofing for 1-2 hours at room temperature, allowing further expansion and flavor development before baking. This gluten network not only retains the CO₂ bubbles but also contributes to the bread's crumb structure and chewiness upon baking. Sourdough bread-making leverages natural with (LAB), particularly in flour, which achieves an acidity of around 4.5 during the process. The LAB produce lactic and acetic acids that enhance flavor complexity, imparting tangy notes while improving extensibility and compared to commercial alone. flour's pentosan content further aids water retention, supporting the slower, more flavorful fermentation typical of artisan loaves. Unleavened breads, such as , rely solely on and water without any leavening agents, resulting in a flat, crisp product that does not rise. Prepared by rapid mixing and baking within 18 minutes to prevent natural , holds significant cultural importance in Jewish traditions, symbolizing the haste of the ' from .

Pastry and

In and , flour plays a crucial role in creating tender, delicate textures by minimizing development, which can otherwise result in tough or chewy results. Low-protein flours are preferred to achieve flaky, light structures in items like pie crusts, cakes, and layered , where the focus is on , incorporation, and steam generation rather than structural strength. Pastry flour, typically with a protein content of 8-9%, is ideal for crusts and similar tender doughs, as its lower gluten-forming potential allows for a crumbly when are incorporated. The shortening method involves cutting cold , such as or , into the flour using a pastry blender or fingers until the mixture resembles coarse crumbs; this coats the flour particles with , inhibiting strands from forming during mixing and rolling, which ensures flakiness upon . For cake baking, cake flour—finely milled with even lower protein (around 6-8%)—is sifted with to aerate the mixture and remove lumps, promoting even distribution and a lighter batter. The creaming follows, where and are beaten together to incorporate air bubbles for lift and tenderness; chemical leavening agents like are then added to the dry ingredients (including the sifted flour) to release during baking, further contributing to the cake's volume without relying on . Puff pastry relies on a process, where made from low-protein flour is repeatedly folded around thin layers of cold , creating hundreds of alternating sheets that separate during . As the pastry bakes, the butter melts and its moisture turns to , expanding the layers for dramatic lift and flakiness without added leavening agents. In confectionery, powdered sugar—milled to a fineness about 10 times that of granulated sugar (with particles around 10-60 microns)—is used for dustings on finished pastries, providing a smooth, non-gritty finish that adheres lightly without altering texture. Cultural applications highlight flour's versatility: French pâtisserie often employs Type 45 (low-protein, finely milled at 8-9%) for delicate items like éclairs and tarts, emphasizing precision and minimal for elegance, while Asian confections like use glutinous rice flour, which develops intense stickiness and chewiness due to its high content when steamed or boiled, yielding a gluten-free, elastic texture distinct from wheat-based pastries.

Cooking and thickening

Flour plays a central role in cooking as a thickener for sauces, gravies, and soups, primarily through that absorbs and binds liquids. One of the most common techniques is the , a cooked mixture of equal parts fat (such as or ) and flour by weight, typically in a 1:1 . The mixture is gently heated to develop flavors and eliminate the raw taste of flour, progressing from a white roux for subtle thickening to a blonde roux (lightly cooked for pale sauces) or brown roux (deeper cooked for robust soups and stews). When liquid is incorporated, the roux's starch granules swell and trap water, enabling it to thicken up to approximately eight times its weight in liquid for medium-bodied consistencies. An alternative to is the slurry method, where flour or another is dispersed in a small amount of cold liquid (like or ) to form a smooth paste before being stirred into dishes, preventing lumps from forming. Cornstarch or slurries are often preferred over for their superior clarity and glossy finish in transparent sauces, as wheat flour tends to cloud the mixture due to its protein content. However, wheat flour slurries find use in classic preparations like , where the added opacity and subtle flavor complement milk-based liquids. Beyond Western techniques, flour serves as a thickener in diverse global cuisines, adapting to local grains for unique textures and flavors. In cooking, flour (besan) is dry-roasted or cooked with fats and spices to form a roux-like base, which thickens curries such as or senagapindi kura by releasing its starches into the gravy. In stir-fries, is commonly applied as a light coating (dredging) on proteins like or , enhancing crispiness during high-heat cooking without overpowering the dish's delicate flavors. Dredging with seasoned flour—often wheat flour mixed with salt, pepper, and herbs—prepares proteins for frying by creating a barrier that promotes even browning and helps seal the surface against moisture loss. This coating adheres during frying at temperatures around 175–190°C (350–375°F), where the flour's starches begin to set and the Maillard reaction develops flavor on the exterior.

Industrial and non-food uses

In the industry, flour serves as a key in processes, where pregelatinized or derivatives facilitate cohesion under high pressure and temperature, enabling the formation of uniform pasta shapes. Similarly, wheat flour acts as a in production, typically added at levels up to 5% of the weight in smoked products to enhance , reduce cooking losses, and improve without compromising sensory qualities. In pharmaceuticals, wheat starch derived from flour functions as a diluent and binder in tablet formulations, providing bulk, compressibility, and controlled disintegration while being compatible with active ingredients in various medicinal products such as capsules and ointments. Rice flour and its starch offer lactose-free alternatives as multifunctional excipients, serving as binders, disintegrants, and fillers in direct compression tablets, particularly beneficial for patients with dairy intolerances due to their hypoallergenic properties and ability to form stable matrices. Beyond food and pharmaceuticals, flour finds extensive non-food applications. In , extracted from or other flours is employed as a surface-sizing to enhance paper's resistance, printability, and strength by forming a protective on the sheet surface during . A significant portion of flour production—approximately 18% in major markets like the — is directed toward , where it supplements energy and protein needs for , often comprising feed flour with about 15.5% crude protein. Additionally, flour's content supports production through processes, as in dry milling where is ground into flour and then hydrolyzed to yield , contributing to renewable outputs from starchy feedstocks. In cosmetics, oat flour is incorporated into exfoliating scrubs for its gentle abrasive action, which removes dead skin cells while soothing irritation due to its anti-inflammatory beta-glucan content, making it suitable for sensitive skin formulations. Non-food uses account for a notable share of flour applications in markets like the UK, driven by demand in industrial sectors like adhesives, feeds, and renewables.

Safety and Regulations

Flammability risks

Flour poses significant flammability risks in and environments due to its ability to form suspensions in air. When dispersed, flour can create combustible mixtures if the concentration exceeds the minimum concentration (MEC), typically ranging from 30 to 50 g/m³ for , beyond which ignition can propagate a . The minimum ignition energy (MIE) required to initiate such an is relatively low, between 10 and 50 mJ, allowing even minor sparks from , mechanical friction, or electrical equipment to serve as ignition sources. These properties make flour a classic example of combustible , where rapid oxidation releases and pressure waves capable of causing structural damage. Historical incidents underscore the severity of these hazards. In 1878, the Washburn A explosion in , , triggered by accumulated flour ignition, killed 18 workers and destroyed the facility, marking one of the earliest recognized explosions. More recently, the 2008 Imperial Sugar refinery blast in , involving combustible sugar in a setting, resulted in 14 fatalities and 36 injuries, demonstrating how unchecked accumulation can lead to cascading explosions. In July 2025, a flour explosion at Panhandle Milling in Dawn, , killed one worker and injured three, highlighting persistent hazards in modern facilities. Prevention strategies focus on controlling dust dispersion and eliminating ignition sources. Effective ventilation systems are essential to maintain airborne dust levels below 10% of the lower explosive limit (LEL), preventing the formation of explosive atmospheres, while equipment grounding and bonding mitigate static discharge risks as outlined in NFPA , the standard for preventing fires and dust explosions in agricultural and facilities. Regular , explosion suppression systems, and deflagration venting further reduce hazards by limiting dust layers and containing potential blasts. Key factors influencing flammability include particle size, with finer wheat flour particles under 75 microns exhibiting greater volatility than coarser ones due to enhanced surface area for combustion and easier suspension in air. Moisture content and oxygen levels also play roles, as drier dusts ignite more readily, emphasizing the need for humidity controls in storage areas.

Pathogen and contaminant hazards

Flour, especially with its typical low moisture content of around 12-14%, can support the survival of bacterial pathogens such as * and Shiga toxin-producing (STEC), which exhibit remarkable resilience in dry environments with levels of approximately 0.44-0.60. These pathogens enter the supply chain primarily through contaminated raw during harvesting, milling, or storage, and their presence has led to notable outbreaks. For instance, in 2016, a multistate outbreak in the United States linked STEC serogroups O121 and O26 in flour to 56 confirmed cases across 24 states, resulting in 16 hospitalizations; the bacteria persisted in the low-moisture product until consumption in raw dough preparations. More recently, in 2023, a Infantis outbreak linked to contaminated flour resulted in 14 illnesses across 11 states, prompting a nationwide recall. Similarly, has been implicated in flour-related incidents, underscoring the need for vigilant microbial controls in low-moisture foods traditionally viewed as low-risk. Chemical contaminants, particularly mycotoxins produced by fungi like Aspergillus and Fusarium species, represent another significant hazard in flour, often arising from mold growth during prolonged or humid storage of grains. Aflatoxins, hepatotoxic and carcinogenic compounds, contaminate cereals including wheat and corn flours, with the European Union establishing a maximum limit of 4 μg/kg for the sum of aflatoxins B1, B2, G1, and G2 in unprocessed cereals, all cereals intended for direct human consumption, and cereal-based products like flour. In corn flour specifically, fumonisins—neurotoxic mycotoxins—pose risks, with EU regulations setting limits such as 1,000 μg/kg (sum of FB1 and FB2) for maize intended for direct human consumption and up to 1,400 μg/kg for processed maize-based foods, including flours, to safeguard public health. Allergens constitute an inherent biological hazard in flour, with gluten proteins (gliadins and glutenins) in , , and flours serving as the primary trigger for celiac disease and , affecting an estimated 1% of the global population. Beyond intrinsic content, cross-contamination risks arise in milling and processing facilities that handle multiple types or allergens, potentially introducing trace into otherwise low-gluten or gluten-free flours via shared equipment, airborne dust, or inadequate cleaning protocols. Studies indicate that while good manufacturing practices can minimize such cross-contact to below 20 ppm—the threshold for "gluten-free" labeling in many jurisdictions—residual risks persist in shared production environments without dedicated lines. Mitigation strategies for these and contaminant hazards focus on and physical interventions to achieve significant log s without compromising flour quality. Dry heat , applied post-milling, effectively inactivates STEC and by heating flour to a core temperature of 70°C for at least 5 minutes, yielding over a 5-log in viable cells under controlled conditions. Alternatively, ionizing using gamma rays, electron beams, or X-rays at doses up to 10 kGy provides a non- option, reducing bacterial pathogens by 4-6 logs in dry flour while also inhibiting mold growth and mycotoxin production precursors; the U.S. Food and Drug Administration permits such treatments for microbial control in certain low- foods. For mycotoxins and allergens, prevention emphasizes pre-harvest management, rapid to below 14% , and , with routine testing ensuring compliance with regulatory thresholds.

Adulteration and fraud prevention

In the , bakers commonly adulterated and by adding or to achieve a whiter appearance and improve texture, practices that posed risks due to the toxicity of alum and the indigestibility of chalk. These adulterations were widespread among working-class consumers, driven by economic incentives to cut costs and mimic higher-quality products. Such practices were progressively regulated through the Adulteration of Food and Drugs Acts, beginning with the 1860 legislation, and fully prohibited for alum in bread by the 1928 Food and Drugs Act, which strengthened enforcement and penalties in the 1920s. Modern instances of flour fraud continue to emerge globally, often motivated by profit through misrepresentation of quality or origin. In 2007, wheat gluten exported for use in pet foods was contaminated with , an industrial chemical added to artificially inflate protein content readings during testing, leading to the deaths of thousands of pets in the United States and prompting a massive . Similarly, in during the , surveys detected powder adulteration in atta () samples from markets, where it was mixed in to increase volume and weight at low cost, affecting staple foods for millions and raising concerns over nutritional dilution and health impacts like digestive issues. Detection methods have advanced significantly to combat these frauds, focusing on rapid, non-destructive analysis. Near-infrared (NIR) spectroscopy emerged in the 2010s as a key tool for identifying protein falsification in flour, as it measures molecular composition to detect anomalies like elevated nitrogen from melamine without sample preparation, enabling inline quality control in milling processes. Complementing this, DNA barcoding techniques, developed and applied since the early 2010s, allow for authentication of flour origin and adulteration by sequencing specific genetic markers (such as matK or ITS2 regions) from trace plant DNA, even in processed powders, to verify species purity and geographic sourcing. Regulatory frameworks emphasize prevention through enhanced to deter in flour supply chains. In the , the General Food Law Regulation (EC) No 178/2002 mandates one-step-back, one-step-forward for all businesses, including flour producers, requiring of sourcing, , and to facilitate rapid investigations and recalls. By the 2020s, pilot programs integrating technology have been tested in supply chains, including grains and flours, to create immutable digital ledgers for tracking from farm to mill, reducing opportunities for adulteration through transparent, tamper-proof records shared among stakeholders.

Regulatory standards and labeling

In the United States, the (FDA) established standards of identity for in 1941, requiring the addition of thiamin, , , and iron to restore nutrients lost during milling and combat deficiencies like . These standards define "" but do not mandate enrichment for all flour; however, it is widely practiced and required in many states. For labeling, U.S. regulations under the Labeling and Education Act require flour packages to declare protein content as a percentage of the serving size on the Facts panel, aiding consumers in selecting flours for specific needs. In the , flour classification relies on ash content—the mineral residue after —to indicate extraction rate and type, with "Type 550" denoting flour with 0.55% ash, suitable for general . , once used as a , has been prohibited in flour since 1990 due to carcinogenic risks identified in . flour certification falls under Regulation () 2018/848, which mandates strict rules on production, processing, and labeling to ensure no synthetic pesticides or GMOs are used, with the organic logo required on compliant products. Globally, the Commission's General Standard for the Labelling of Pre-packaged Foods (CXS 1-1985) requires declaration of major allergens, including "contains " for products with gluten-containing cereals, to protect sensitive consumers. For gluten-free labeling, Standard 118-1979 permits the claim only if gluten levels are below 20 parts per million (), harmonizing thresholds across adopting countries. The World Trade Organization's Agreement on the Application of Sanitary and Phytosanitary Measures (SPS Agreement) promotes harmonization of food standards, urging members to base national rules on international benchmarks like to facilitate trade while ensuring safety. For flour exports, this involves conformity assessments, including testing for contaminants such as mycotoxins, to meet importing countries' requirements and avoid trade barriers.

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