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Pomace

Pomace is the solid residue remaining after the mechanical pressing of or to extract , , , or , typically comprising the skins, , seeds, stems, and any residual fragments left behind. This by-product is generated in large quantities by the industry, with examples including apple pomace from production, pomace from , and pomace from . Compositionally, pomace is rich in , polyphenols, proteins, , and minerals, varying by fruit type; for instance, pomace contains high levels of and seeds that yield valuable oils, while pomace includes 70–90% , 9–27% stones, and residual oil content around 2%. Apple pomace, similarly, is a source of , antioxidants, and bioactive components like , making it suitable for further valorization. Moisture content and vary by pomace type and processing method; for example, pomace has 45–70% moisture and 4.8–5.2. Despite its nutrient density, pomace is frequently underutilized and discarded, contributing to environmental challenges such as and water contamination from bacterial byproducts. However, it holds significant potential for sustainable applications, including , composting, production (e.g., bioethanol or ), and uses like fortifying baked goods, extracting for gelling agents, or recovering antioxidants for health-promoting products. In olive oil processing, pomace is further refined to produce olive-pomace oil, a blend of refined pomace oil and virgin suitable for consumption. Research continues to explore its role in enhancing food functionality, such as adding grape pomace extracts to products for and coloring effects.

Definition and Terminology

Definition

Pomace is the solid residue that remains after the pressing or crushing of , , or to extract , , or other liquids. This typically consists of skins, , stems, and , forming a fibrous, pulpy material with an initially high content, often up to 70%. The basic formation of pomace occurs through mechanical pressing or following the harvesting and initial processing of material. It is distinct from related terms such as "," which specifically denotes pomace, and "," the fibrous residue from crushing. Commonly obtained from sources like olives and s, pomace serves as a versatile agricultural byproduct.

Etymology

The term "pomace" originates from the Latin pomum, meaning "" or specifically "apple," which evolved through Medieval Latin pomācium (referring to ) and into Old French pomaz or pomace, denoting the dregs or lees of cider production. This linguistic path reflects the word's initial association with the pulpy residue left after pressing s for juice or cider in medieval . English adoption of "pomace" occurred in the , primarily describing the solid pressings from apples in cider-making, as documented in early modern texts on and . By the 17th and 18th centuries, the term underwent a shift, broadening from apple-specific usage to encompass the residue from other fruits like grapes and olives, aligning with expanding horticultural practices in . Distinct from broader terms like "lees," which refer to the liquid sediment or dregs (such as dead and fine particles settling in wine or ), "pomace" specifically denotes the coarse, solid remnants of skins, , , and stems after mechanical pressing. This differentiation highlights pomace's role as a fibrous versus lees' finer, suspended . Linguistic variations appear in other Romance languages, such as "orujo," which designates the pomace from grapes or olives before into spirits, rooted in regional pressing traditions. Similarly, "piquette" in describes a low-alcohol beverage produced by rehydrating pomace, derived from piquer ("to prick"), evoking its mild from secondary .

Types and Sources

Fruit Pomace

Fruit pomace refers to the solid residues remaining after the extraction of , oil, or other primary products from various , primarily consisting of skins, , , and sometimes stems. Among the most prominent types, pomace, also known as , is generated during and accounts for 20-25% of the original weight, comprising skins, , and residual that are particularly rich in and polyphenolic compounds concentrated in the . These components contribute to its properties and potential for secondary uses, with condensed making up 20-51% of the dry weight in some varieties. Apple pomace arises from and , representing a significant with high content, a soluble that constitutes up to 11-15% of its , making it a key commercial source for pectin extraction. Globally, the apple processing industry produces approximately 4 million tons of apple pomace annually, derived from over 87 million tons of apples processed for and . This pomace is characterized by its fibrous texture, including peels and core remnants, and retains substantial from the fruit's original composition. Olive pomace results from and exists in two primary forms: that obtained after mechanical pressing (first press), which retains higher moisture (25-45%), and exhausted pomace following to recover residual oil. The initial pomace after pressing contains 5-8% residual oil trapped in the , skins, and fragments, which is subsequently extracted using s like to produce pomace . This type of pomace is drier and more fragmented compared to or apple variants, with variations depending on methods such as traditional pressing, three-phase , or two-phase systems. Pomace from other fruits, such as (including and ), cherry, and , exhibits diverse traits based on the fruit's structure and processing. pomace, primarily peels and from , yields about 50% of the fruit's weight and is notable for its high fiber and content in the layer. Cherry pomace, a of or wine production, constitutes 15-28% of the fruit mass, featuring and skins rich in anthocyanins and organic acids. pomace, mainly peels (30-50% of fruit weight) with minor seed inclusion, is abundant in ellagitannins and fibers, often comprising 96% peels in processing residues. These fruit-specific pomaces highlight the variability in yield and bioactive profiles, influenced by the fruit's pulpy nature and intensity.

Non-Fruit Pomace

Non-fruit pomace refers to the solid residues obtained from the processing of , , and , distinct from fruit-derived materials due to variations in , retention, and profiles. These by-products arise primarily from in and or in , resulting in materials that are often drier and more meal-like compared to the pulpier consistency of pomace. and pomace typically exhibit a low content and a powdery or granular , making them suitable for diverse industrial applications, while pomace retains higher water levels, leading to a fibrous, moist residue. Seed and nut pomace is generated during the mechanical pressing of oilseeds such as sunflower and , where the residual oil content ranges from 0.5% to 8.9% in soybean cake and 1.0% to 23.6% in sunflower cake, depending on extraction efficiency. This pomace possesses a dry, meal-like consistency, with sunflower cake often containing 13–36% , contributing to its use as a protein- and fiber-rich . In contrast to pomace, which typically has levels ranging from 45% to 70%, seed pomace is drier, facilitating easier storage and processing. Vegetable pomace, derived from juicing processes, includes residues from and , characterized by high content—up to 53.97 g/100 g in tomato pomace and 37–55% in carrot pomace—and low oil levels, typically below 2%. pomace, a mixture of skins, seeds, and pulp, provides 48.62–53.97 g/100 g , enhancing its value as a functional . pomace similarly offers substantial fiber, with levels reaching 55% total , alongside minimal content. Specific examples illustrate the diversity of non-fruit pomace. Almond pomace, a fibrous byproduct from nut milk production, results from straining blended almonds and water, yielding a wet pulp that can be dried into a meal-like form rich in protein and fiber. Cocoa pomace, known as press cake from chocolate processing, retains 10–12% fat after butter extraction from cocoa liquor, providing a semi-solid residue with applications in powder production. Yields of vegetable pomace vary by crop but often constitute 20–50% of the input weight, attributed to the high (62–70%) in raw like tomatoes and s, which limits extraction efficiency. For tomatoes, pomace represents 5–30% of raw fruit weight, while carrot processing leaves up to 50% as pomace. These yields underscore the substantial volume of non-fruit pomace generated annually, promoting opportunities for valorization.

Historical Development

Ancient and Medieval Uses

In the ancient Mediterranean, particularly during the period, olive pomace—the solid residue left after —was valued for practical uses such as and animal . Olive pomace was employed as a , burning at a high and consistent temperature ideal for heating, cooking, and firing or lime kilns. Historical agricultural texts from the era also describe olive pomace being incorporated into cattle feed in , often as mixed with chopped and tree leaves to supplement diets during periods of . During the medieval period in , from the 12th to 15th centuries, apple pomace found widespread application in processes to produce and low-strength second-press beverages, often referred to as ciderkin or similar dépense. This method involved the crushed residues in to extract remaining sugars, yielding a modest or, upon further acetification, used for preservation, flavoring, and medicinal purposes among rural communities. Such practices maximized resource use in agrarian societies where fruit pressing was a seasonal staple, reflecting the era's emphasis on thrift in food production. Limited of pomace into spirits emerged in 14th-century , where residues from were processed to create rudimentary eaux-de-vie, primarily in northern regions like the and Trentino-Alto . This innovation, documented in early records and legends, allowed peasants to transform waste into a potent potable, marking an initial step toward modern pomace brandies like .

Industrial Era Advancements

The Industrial Era marked a significant shift in pomace utilization, transitioning from traditional manual methods to mechanized processes that enhanced efficiency and scalability. In the , the adoption of hydraulic presses in , particularly in regions like Puglia, revolutionized by applying greater pressure to olive paste, yielding higher volumes of oil and leaving behind pomace suitable for secondary processing. This innovation, emerging around the mid-1800s, allowed for more systematic handling of pomace residues, which were increasingly valued for further oil recovery or other uses. Concurrently, experienced a rise in pomace brandy production, known as marc, as distillation techniques industrialized amid expanding and the phylloxera crisis of the late , which prompted greater reliance on by-product spirits to sustain the wine industry. The brought further advancements, including the introduction of solvent extraction methods in the for recovering residual oils from pomace, a technique initially developed for seed oils but adapted to olive and fruit residues to maximize resource use. During and II shortages, pomace—such as castor and apple varieties—served as a critical alternative when synthetic and other organic options like cottonseed meal became scarce, supporting agricultural needs amid global disruptions. Post-1950, and mechanized amplified pomace surpluses from intensified and wine production, leading to its widespread incorporation into ; for instance, ensiled grape pomace became a staple in diets for its and energy content, reducing waste while enhancing feed . Annual grape pomace output in major EU producers like , , and was approximately 1.5 million tons as of the early . Environmental concerns in the late 1970s drove regulatory changes across , with EU waste directives such as 75/442/EEC and subsequent national policies in from the 1980s emphasizing pomace —through composting or —over open disposal to mitigate pollution from olive and processing effluents.

Production Methods

Extraction Processes

Pomace extraction primarily involves separation techniques to isolate the residue from components in materials such as fruits and s. In methods, the process begins with crushing or grinding the material to break down cellular structures, followed by pressing using or hydraulic presses to separate the fraction. This approach is commonly applied to s and s, achieving a separation of approximately 70-80% by weight, leaving behind the pomace as the byproduct. Centrifugation serves as a high-speed mechanical separation method, particularly in production, where a processes the crushed paste to isolate , , and solids. In two-phase centrifugation systems, this results in wet pomace with a content of 55-75%, typically around 60-70%, which facilitates efficient removal while retaining higher levels in the residue compared to traditional pressing. For recovering residual oils from dried pomace, solvent extraction employs chemical solvents such as hexane to dissolve and separate the remaining lipids from the solid matrix. This method is applied after initial mechanical dewatering and drying of the pomace to about 8% moisture, enabling up to 95% oil recovery efficiency by solubilizing the oil for subsequent distillation and separation. Extraction variations depend on the source material to optimize and . For apple pomace in juice production, cold-pressing at ambient temperatures preserves bioactive compounds, contrasting with hot-pressing methods used for seed pomace, where elevated temperatures enhance oil extraction efficiency from materials like grape or olive seeds. Modern processing plants often incorporate waste heat recovery systems, utilizing thermal energy from drying or centrifugation exhaust to reduce during pomace .

Composition and Properties

Pomace, the solid residue remaining after the of juices or oils from fruits and other sources, exhibits a diverse influenced by the and processing conditions. Macronutrients in fruit pomace typically include high levels of , ranging from 20% to 60% on a dry weight basis, with grape pomace often containing 26% to 70% , including exceptional levels of 18% to 55%. Protein content generally falls between 5% and 15%, as seen in grape pomace at approximately 8.5% and apple pomace around 4%. are present in lower amounts, typically 2% to 10%, with variations such as 2.6% in apple pomace and up to 13.8% in pomace. Polyphenols, particularly in grape pomace, can reach up to 50 g/kg dry weight, contributing to its bioactive profile. Micronutrients in pomace include antioxidants such as , predominantly found in pomace at levels up to 26.5 mg/g in extracts, alongside other polyphenols like flavanols and anthocyanins. Minerals, comprising 1% to 5% of dry weight as total ash, feature and calcium as major components, with often at 0.3% to 3.3% (3 to 33 g/kg) and calcium at 0.09% to 0.3% (0.9 to 3 g/kg) in apple and pomace. These elements, along with and magnesium, vary by source but provide essential nutritional value. Physical properties of fruit pomace include an acidic typically ranging from 3.5 to 5.0, such as 4.24 in grape pomace and 4.33 in apple pomace, which supports its stability but also promotes rapid microbial activity. Bulk density is generally 0.4 to 0.6 g/cm³, as observed in carrot and olive pomace at 0.45 to 0.56 g/cm³, facilitating handling in industrial applications. Pomace demonstrates high biodegradability, leading to quick due to its organic content and , enabling spontaneous processes that enhance valorization through microbial activity. Composition varies significantly by source; for instance, olive pomace contains higher levels, up to 30% to 42% dry weight, reflecting its lignocellulosic structure, while apple pomace has elevated residual sugars at 10% to 20% (or higher in some varieties, up to 30 g/100 g total sugars). pomace, in contrast, balances high fiber and polyphenols but lower sugars compared to apple, with red wine varieties at 4% to 9% versus white at 28% to 31%. These differences arise post-extraction and depend on fruit type, , and processing.

Applications

Beverage Production

Pomace brandy, also known as grappa in Italy or marc in France, is produced through the distillation of fermented pomace derived from grapes or other fruits after pressing. The process begins with the fermentation of the pomace, where residual sugars in the skins, seeds, and stems are converted to alcohol by yeast, typically yielding a low-alcohol wash of around 5-10% ABV before distillation. This wash is then double-distilled in copper pot stills or continuous column stills to concentrate the alcohol, resulting in a clear spirit with an alcohol by volume (ABV) typically ranging from 35% to 60%, though most commercial examples fall between 40% and 45%. The spirit is often aged in oak barrels to develop flavor complexity, imparting notes of fruit, nuts, and spice, and must meet regional standards for appellation, such as Italy's requirement for 100% Italian pomace in true grappa. In , pomace serves as an aid in secondary to produce piquette, a low-alcohol beverage traditionally made by rehydrating the pomace with water after primary wine pressing and allowing a second fermentation. This process extracts residual sugars and compounds from the pomace, resulting in a lightly effervescent wine with 4-7% ABV that gains enhanced color from anthocyanins and structure from released during extended of the skins and seeds. Piquette's production valorizes pomace that would otherwise be discarded, contributing to sustainable practices while providing a rustic, fruity profile distinct from standard wines. Apple pomace, obtained after pressing for , can be repurposed for second-run by soaking the residue in water to rehydrate and extract remaining juices, followed by a secondary pressing and to yield a lighter, lower-alcohol beverage often around 2-4% ABV. This second-run product, sometimes called "small ," captures additional flavors from the pomace's fibrous components. Alternatively, apple pomace undergoes acetic acid to produce , where the material is first enzymatically treated to break down fibers and release sugars, enabling alcoholic by yeast, followed by conversion to acetic acid by , achieving typical strengths of 4-6% acidity. This two-stage process transforms the pomace into a tangy, antioxidant-rich suitable for culinary uses. Modern innovations have expanded pomace's role in beverage , particularly through into craft beers and liqueurs to enhance and nutritional profiles. Fermented apple or pomace is added during to impart fruity esters, , and , creating beers with complex aromas and up to 150% higher content compared to standard varieties, as seen in experimental purple pomace-infused ales. Similarly, pomace extracts liqueurs by in , yielding spirits with elevated bioactive antioxidants. Globally, the wine industry generates 10.5 to 13.1 million tons of pomace annually, with a significant portion destined for , underscoring the scale of these applications.

Food and Feed Uses

Pomace serves as a valuable ingredient in products, particularly for enhancing nutritional profiles. Apple pomace, rich in , is commonly incorporated into baked goods such as muffins, cakes, and as a , with inclusion rates up to 20% maintaining acceptable and sensory qualities while boosting fiber content to levels that support digestive health. Similarly, , extracted from the residue of processing, is utilized in cooking applications like and due to its high and stability under heat, providing a cost-effective alternative to higher-grade oils without compromising in prepared dishes. In animal nutrition, pomace is widely used as a feed component, especially for . Grape pomace, a of , can be included in ruminant diets at 10-20% of , offering fiber and moderate protein levels (typically 3.5-14% by weight) that support and overall performance in such as , where it contributes to improved milk fatty acid profiles. Its protein content aids in maintaining balance, making it suitable for supplementing basal feeds in operations. The nutritional benefits of pomace in both and diets stem from its high and antioxidant content. from pomace promotes gut health by enhancing diversity and aiding digestion, while polyphenols act as antioxidants that reduce and immune function in supplements or fortified foods. Examples include pomace-based pet treats, such as those using apple pomace, which provide soluble for bowel regularity and gut in dogs. Processing pomace for food and feed applications typically involves drying to reduce moisture content to around 10%, preventing microbial spoilage and enabling long-term storage in powder or pellet form. The global market for pomace in animal feed exceeds $1 billion annually, driven by its role in sustainable nutrition across livestock sectors.

Industrial and Agricultural Applications

Pomace finds significant application in as a , leveraging its calorific value of 15-20 MJ/kg to serve as a source comparable to other materials. This property stems from its lignocellulosic composition, enabling or for heat and in facilities agricultural residues. In the cosmetics sector, polyphenols extracted from pomace are incorporated into for their potent effects, which help mitigate and support skin barrier function. These bioactive compounds, including , provide natural alternatives to synthetic preservatives and enhance product efficacy in dermatological formulations. Beyond energy and personal care, the fibrous structure of pomace supports paper production by substituting for conventional wood pulp in molded products and materials. This utilization repurposes the cellulose-rich residue into sustainable alternatives for absorbent papers and eco-friendly containers. Pomace also undergoes to produce , yielding approximately 200-300 m³ of per ton, which can be captured for while generating nutrient-rich . This process efficiently converts the into methane-rich gas, with yields enhanced by co-digestion strategies. Agriculturally, pomace functions as a and soil amendment, providing slow-release at levels of 1-2% over several months to support nutrition without rapid . Its application improves and microbial activity, fostering long-term fertility in amended fields. As a mulch, pomace layers suppress weed emergence by blocking light and retaining , reducing the need for herbicides in and management. This practice enhances water use efficiency and while minimizing on sloped terrains. In the , widespread adoption of pomace-based fertilizers promotes by decreasing dependence on synthetic inputs, thereby lowering environmental impacts from chemical production and application.

Regulations and Safety

International Standards

The Codex Alimentarius Commission establishes international food standards for olive-pomace oils, defining olive-pomace oil as a blend of refined olive-pomace oil and virgin olive oils with a free acidity, expressed as oleic acid, not exceeding 1 gram per 100 grams for edible use. Labeling requirements mandate compliance with the General Standard for the Labelling of Prepackaged Foods (CXS 1-1985), including the product name that accurately reflects its composition, such as "olive-pomace oil," without using the term "olive oil," and declaration of any additives when used in food products. No additives are permitted in virgin olive oils, but refined pomace oils may incorporate permitted processing aids under Codex guidelines for fats and oils. Revisions to the standard (CXS 33-1981) are ongoing as of 2024, including updates to sections on composition and contaminants. European Union regulations under the amended Waste Framework Directive (EU) 2018/851 classify olive pomace as bio-waste and promote its through separate collection, composting, or to achieve high and recovery rates, with targets of at least 55% of municipal by weight by 2025, 60% by 2030, and 65% by 2035; separate collection of bio-waste is mandatory, and new reduction targets include a 30% decrease at and levels by 2027. For pomace-derived oils, extraction solvent residues, such as , are limited to no more than 1 mg/kg in the final product to ensure safety, as specified in Directive 2009/32/EC on extraction solvents used in . The standard provides a for management systems applicable to organizations handling pomace within the global , from to distribution, emphasizing , , and prerequisite programs to ensure safe integration into food supply chains. Complementary ISO methods, such as ISO 12193 for lead determination, support testing for contaminants like in olive-pomace oils, with limits aligned to international thresholds to prevent health risks. World Trade Organization (WTO) rules under the Agreement on the Application of Sanitary and Phytosanitary Measures (SPS Agreement) govern pomace exports by requiring that import restrictions be science-based, transparent, and non-discriminatory, allowing measures to protect human, animal, or plant health while facilitating trade, as seen in resolved disputes over pomace olive oil imports. Global certification for organic pomace products follows standards like the USDA National Organic Program (NOP), which verifies organic integrity from farm to processing, ensuring no prohibited substances and traceability for international trade.

National Regulations

In the , national regulations for pomace often align with broader community standards but include localized implementations. In , a major olive producer, the use of as an extraction solvent in production is governed by EU Directive 2009/32/EC, which establishes a maximum residue limit of 1 mg/kg in the final fat or oil product to ensure safety. This limit applies directly to refined , helping to mitigate potential risks from solvent residues in a country where olive processing generates significant pomace volumes. , another key European producer, imposes strict (AOC) rules on , particularly for Marc de Bourgogne. Under these regulations, production must use pomace exclusively from grapes, with limited to a maximum alcohol strength of 72% by volume off the still, followed by aging for at least two years in oak barrels, and bottling at a minimum of 40% to preserve regional authenticity and quality. In the United States, the (FDA) affirms extracted from apple pomace as (GRAS) under 21 CFR 184.1585 for use in human applications, such as a source in baked goods, beverages, and supplements, based on its historical safe consumption. Apple pomace itself is used in based on similarity to this GRAS . For agricultural reuse, the Environmental Protection Agency (EPA) provides guidelines for applying pomace-based amendments as fertilizers, recommending rates not exceeding 20 tons per to avoid nutrient overload and maintain , in line with broader practices for composted materials. Canada's regulations, overseen by the Canadian Food Inspection Agency (CFIA), approve dehydrated apple pomace as a feed under the Feeds Regulations, 2024, with standards requiring guarantees for minimum crude protein (4%), maximum (12%), and maximum crude (20%), but cautioning against use in diets due to potential digestive issues; nutritional guidelines suggest a maximum inclusion rate of 15% in rations to optimize digestibility without nutritional imbalance. Imports of pomace are subject to CFIA restrictions on contaminated residues, prohibiting entry if or levels exceed established tolerances to protect animal health and the . In other nations, enforces stringent rules through the Department of , Fisheries and (DAFF), requiring permits and treatments (e.g., or ) for fruit pomace to mitigate risks from pests and diseases, with non-compliance leading to refusal or destruction at the border. In , the National Standard GB 2760-2024 permits the use of pomace-derived ingredients, such as apple fiber, in foods for functions like thickening or stabilization in categories like bakery products and beverages, subject to safety and labeling requirements.

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