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Vancomycin

Vancomycin is a tricyclic derived from the soil bacterium Amycolatopsis orientalis (formerly Streptomyces orientalis), primarily used to treat severe infections caused by , including methicillin-resistant Staphylococcus aureus (MRSA) and other multidrug-resistant strains. Discovered in 1952 from soil samples collected in the jungles of , it was introduced clinically in the late 1950s as a last-resort option for infections resistant to earlier antibiotics like penicillin. Vancomycin exerts its bactericidal effects by binding to the D-alanyl-D-alanine (D-Ala-D-Ala) terminus of precursors in the bacterial , inhibiting transpeptidation and transglycosylation steps essential for synthesis, which leads to bacterial . This narrow-spectrum activity targets aerobic and gram-positive organisms such as staphylococci, streptococci, enterococci, and , but it has no effect on due to their outer membrane barrier. Due to its poor oral for systemic use, vancomycin is typically administered intravenously to achieve therapeutic levels for serious conditions like , bacteremia, , and infections, and and infections. Orally, it is employed for non-systemic gastrointestinal infections, particularly Clostridium difficile-associated , where it remains active in the gut lumen without significant absorption. Alternative routes, such as intrathecal or topical, may be used for specific localized infections like or peritoneal dialysis-related . Despite its efficacy, vancomycin use is monitored closely due to risks of , , and the emergence of resistance mechanisms, such as vancomycin-resistant enterococci (VRE) and vancomycin-intermediate S. aureus ().

Medical uses

Indications

Vancomycin is primarily indicated for the treatment of serious or severe infections caused by susceptible , including methicillin-resistant Staphylococcus aureus (MRSA) and methicillin-resistant (MRSE). When administered intravenously, it is approved for conditions such as septicemia, , infections of the and joints, lower infections, and skin and infections due to these organisms. Orally, vancomycin is specifically indicated for the treatment of -associated diarrhea (CDAD) in both adults and pediatric patients. In clinical practice, vancomycin serves as a cornerstone therapy for various Gram-positive infections, including complicated skin and soft tissue infections, bacteremia, , , , and hospital-acquired or suspected to involve MRSA. It is particularly valuable for patients allergic to s or those with infections unresponsive to other agents. For surgical prophylaxis, guidelines recommend vancomycin in high-risk procedures such as cardiac, orthopedic, vascular, and neurosurgical interventions when there is known MRSA , allergy, or high institutional MRSA prevalence, typically as an alternative to . The Infectious Diseases Society of America (IDSA) guidelines endorse vancomycin as a first-line agent for serious MRSA infections, including bacteremia and (with or without prosthetic valves), complicated skin and soft tissue infections, , and bone and joint infections. For optimal efficacy, vancomycin therapy often targets an (AUC/MIC) ratio of ≥400. For CDI, the 2021 IDSA/SHEA guidelines suggest as the preferred initial therapy for nonsevere and severe episodes, with oral vancomycin (125 mg four times daily) as an acceptable alternative; for fulminant cases, oral (or nasogastric) vancomycin (500 mg four times daily) is recommended as first-line, with both and vancomycin outperforming in clinical outcomes. Off-label uses of vancomycin include treatment of susceptible enterococcal infections, such as caused by vancomycin-susceptible or , typically in combination with gentamicin or as an alternative for beta-lactam-intolerant patients. It may also be employed for other resistant Gram-positive infections where susceptibility is confirmed, though emerging patterns necessitate careful microbiological guidance.

Spectrum of activity

Vancomycin exhibits potent activity against a broad range of Gram-positive bacteria, including staphylococci (such as methicillin-resistant Staphylococcus aureus [MRSA]), streptococci, enterococci, and Gram-positive anaerobes like Clostridioides species (e.g., C. difficile) and other Clostridium species. This selectivity arises because vancomycin inhibits cell wall synthesis by binding to the D-Ala-D-Ala terminus of peptidoglycan precursors, a process accessible in Gram-positive organisms lacking an outer membrane. In vitro susceptibility testing demonstrates low minimum inhibitory concentrations (MICs) for most susceptible Gram-positive strains. For example, the MIC for S. aureus is typically ≤2 μg/mL, with MIC90 values of 2 μg/mL reported for MRSA isolates. Against streptococci, including Streptococcus pneumoniae, MICs range from 0.25 to 2 μg/mL, while for vancomycin-susceptible enterococci, they generally fall between 1 and 4 μg/mL. Vancomycin also shows strong anaerobic activity, particularly against Clostridioides difficile, with MICs for susceptible strains typically 0.5–2 μg/mL, supporting its efficacy in this context. Vancomycin is inherently ineffective against most due to its inability to penetrate the outer membrane, resulting in MICs exceeding 64 μg/mL for pathogens like . The accuracy of susceptibility testing for vancomycin can be influenced by factors such as inoculum size and testing . Higher inoculum levels may elevate MICs, particularly for staphylococci and enterococci, due to the inoculum , while cation concentrations in (e.g., calcium and magnesium) can alter results.
BacteriumTypical MIC Range for Susceptible Strains (μg/mL)
Staphylococcus aureus (including MRSA)0.5–2
Streptococci (e.g., S. pneumoniae)0.25–2
Vancomycin-susceptible enterococci1–4
Clostridioides difficile0.5–2

Adverse effects

Common side effects

Vancomycin's common side effects are typically mild and route-dependent, occurring in 5–10% of patients overall, though gastrointestinal issues with oral use can affect up to 20%. When given orally, primarily for treating Clostridioides difficile-associated diarrhea, vancomycin exhibits low systemic absorption, confining most effects to the gastrointestinal tract. Frequently reported reactions include nausea, vomiting, abdominal pain, and a bitter or unpleasant taste (dysgeusia). Clinical data indicate nausea and abdominal pain in ≥10% of patients receiving oral capsules, with these symptoms often resolving without intervention due to the drug's localized action. Intravenous administration, used for systemic infections, commonly leads to infusion-related reactions such as chills, fever, and phlebitis at the injection site. These effects, including histamine-mediated flushing (related to red man syndrome), have an incidence of 3.7–47%, influenced by infusion speed and dose. Phlebitis occurs in 1–10% of peripheral infusions, more frequently with rapid delivery. Management strategies focus on prevention and symptom relief. For intravenous reactions, infusing doses over at least reduces incidence significantly, with antihistamines like diphenhydramine used prophylactically in high-risk cases if needed. Oral gastrointestinal effects are managed symptomatically, such as with antiemetics for , and switching to liquid formulations may alleviate taste disturbances.

Serious side effects

Serious reactions to vancomycin are uncommon, occurring in less than 1% of patients, but can be life-threatening and include , Stevens-Johnson syndrome, and drug reaction with eosinophilia and systemic symptoms (). , an IgE-mediated type I reaction, may present with urticaria, , , and shortly after administration. Stevens-Johnson syndrome and represent severe cutaneous adverse reactions involving mucocutaneous lesions, fever, and multi-organ involvement, often requiring immediate discontinuation of the drug and supportive care. Hematologic adverse effects from vancomycin include , , and , which are immune-mediated and typically reversible upon drug cessation. Thrombocytopenia, characterized by a platelet count below 150,000/μL, has an incidence of approximately 3-5% and may lead to risks in vulnerable patients. , with an incidence of 2-8%, usually develops after prolonged (beyond 7-12 days) and increases susceptibility. often accompanies DRESS or other states but can occur independently. A prominent infusion-related reaction is red man syndrome (also known as vancomycin flushing syndrome), a non-IgE-mediated release causing flushing, pruritus, and sometimes or , primarily during rapid intravenous infusion. The incidence can reach 80-90% when vancomycin is infused at rates exceeding 10 mg/min (e.g., 1 g over 10 minutes), but it is largely preventable by extending infusion to 1-2 hours. This reaction typically resolves within 20 minutes to hours after slowing the infusion rate or pausing administration, and premedication with antihistamines may mitigate symptoms in recurrent cases. Risk factors for these serious effects include higher vancomycin doses (>4 g/day), rapid infusion rates, multiple prior exposures, and concurrent use of drugs like neuromuscular blockers or other nephrotoxic agents, which may exacerbate or hematologic issues. Patients with a history of or previous reactions warrant close monitoring, as these factors can heighten the likelihood of severe outcomes.

Nephrotoxicity and ototoxicity

Vancomycin is associated with , primarily manifesting as (AKI) through mechanisms involving and proximal tubular damage. This toxicity arises from high intracellular accumulation of the drug in renal tubular cells, leading to generation, mitochondrial dysfunction, and subsequent cellular injury. The incidence of vancomycin-induced nephrotoxicity varies from 5-35% depending on therapy duration and monitoring approach, with higher rates associated with area under the curve () values exceeding 650 mg·h/L. Ototoxicity from vancomycin is characterized by irreversible or vestibular dysfunction, though it remains a rare complication with an incidence of less than 1%. This is typically linked to elevated concentrations above 40 μg/mL or extended exposure durations, potentially involving direct damage to cochlear hair cells or synergistic effects with other ototoxic agents. Several risk factors heighten the likelihood of both and , including advanced age, , , and concurrent use of other nephrotoxic or ototoxic agents such as aminoglycosides and nonsteroidal anti-inflammatory drugs (NSAIDs). Pharmacokinetic interactions can exacerbate these risks; for instance, the combination of vancomycin with piperacillin-tazobactam has been shown to significantly increase the incidence of AKI compared to vancomycin monotherapy or with alternative beta-lactams. using AUC targets (400-600 mg·h/L) is preferred for mitigating these toxicities, as it better correlates with efficacy and safety compared to traditional trough monitoring.

Administration and dosing

Routes of administration

Vancomycin is primarily administered intravenously for the of systemic bacterial infections, as this route ensures effective throughout the body while minimizing local tissue irritation when delivered via a secure intravenous line with slow infusion to prevent and other infusion-related reactions. Orally, vancomycin is used specifically for Clostridioides difficile-associated , where its poor systemic allows it to achieve high concentrations directly in the without significant entry into the bloodstream. Off-label inhaled administration involves of the intravenous formulation via , primarily for targeting infections in the lower respiratory tract, such as in or , thereby providing high local lung concentrations with reduced systemic exposure. Rectal administration as retention enemas is employed off-label in cases of severe where oral intake is not feasible, such as with , to deliver the drug directly to the colon. In patients undergoing , intraperitoneal administration of vancomycin is utilized for managing , allowing direct delivery to the for optimal local efficacy.

Dosing considerations

Vancomycin dosing must account for patient-specific factors such as renal function, body weight, , and the severity of to optimize efficacy while minimizing . For adults with normal renal function, intravenous typically begins with a of 20 to 35 mg/kg actual body weight for serious infections, followed by maintenance doses of 15 to 20 mg/kg every 8 to 12 hours. This approach targets an to (AUC/MIC) ratio of 400 to 600 mg·h/L for invasive methicillin-resistant Staphylococcus aureus (MRSA) infections, which correlates with improved clinical outcomes. Oral vancomycin, primarily indicated for Clostridioides difficile-associated diarrhea, is dosed at 125 mg every 6 hours for 10 days in adults. Adjustments for renal impairment involve prolonging the dosing interval based on creatinine clearance (CrCl); for instance, patients with CrCl 50 to 80 mL/min may receive maintenance doses every 12 hours, while those with CrCl 10 to 50 mL/min require dosing every 24 to 48 hours. In obese patients, actual body weight should not exceed ideal body weight by more than 40% for calculations, or adjusted body weight can be used to prevent over-dosing and associated risks. Pediatric dosing for children over 1 month is generally 15 mg/kg intravenously every 6 hours, with total daily doses not exceeding 60 to 70 mg/kg in severe cases. For critically ill adults, higher loading doses of 25 to 35 mg/kg are recommended to account for increased and potential augmented renal clearance. Vancomycin is formulated as a intravenous powder for reconstitution in vials (typically 500 mg, 750 mg, or 1 g), administered by intermittent or continuous , and as oral capsules (125 mg or 250 mg) or an oral solution for gastrointestinal infections. Extended-infusion protocols, such as administering maintenance doses over 2 to 3 hours or via continuous , have been adopted to better achieve target values and enhance efficacy in serious infections.

Therapeutic drug monitoring

Therapeutic drug monitoring (TDM) of vancomycin is crucial for ensuring therapeutic efficacy against serious infections, such as methicillin-resistant Staphylococcus aureus (MRSA), while reducing the risk of adverse effects like . The 2020 consensus guidelines from the (ASHP), Infectious Diseases Society of America (IDSA), Pediatric Infectious Diseases Society (PIDS), and Society of Infectious Diseases Pharmacists (SIDP) emphasize TDM to guide dosing adjustments based on individual patient factors. Key monitoring parameters include trough concentrations and the area under the concentration-time curve (). For serious infections, trough levels are traditionally targeted at 10–20 μg/mL (measured just before the next dose), but the guidelines strongly recommend monitoring with a target of 400–600 mg·h/L, as it better predicts clinical outcomes and toxicity risk. calculation typically relies on Bayesian dosing software, which uses two levels (e.g., one shortly after and one midway) and patient-specific data like renal function to estimate exposure. concentrations are rarely monitored, as they offer limited value for or assessment. Measurements should be obtained early in therapy, preferably within the first 24 to 48 hours after initiation, without requiring steady-state conditions when using AUC monitoring with Bayesian estimation. For trough-based monitoring in intermittent dosing, levels are often drawn before the fourth dose, but early AUC assessment is preferred. TDM is indicated for all patients receiving vancomycin for serious infections, as well as those on prolonged therapy (>3–5 days), with renal dysfunction, or at high risk for toxicity. If monitored levels exceed targets (e.g., trough >20 μg/mL or >600 mg·h/L), doses should be reduced or intervals extended to mitigate risks, with rechecking after adjustments. The ASHP/IDSA guidelines specify —daily for unstable patients and every 1–2 days for stable ones—and stress early intervention to prevent .

Mechanism of action

Vancomycin exerts its bactericidal activity against by disrupting synthesis through specific binding to precursors. It targets the D-Ala-D-Ala terminus of these precursors, particularly lipid II, which is essential for assembly, thereby preventing the formation of the rigid structure required for bacterial survival. This inhibition leads to accumulation of uncross-linked units and eventual osmotic of the bacterial cell. The structural basis of this interaction lies in vancomycin's glycopeptide framework, where its rigid heptapeptide core forms a binding pocket that engages the via bonding. Specifically, five backbone-to-backbone bonds between the antibiotic's residues and the D-Ala-D-Ala provide high-affinity sequestration, with a in the nanomolar range. This precise molecular recognition sterically hinders the precursors from interacting with cell wall-synthesizing enzymes. By occupying the D-Ala-D-Ala terminus, vancomycin inhibits two key enzymatic steps in maturation: transglycosylation, which polymerizes chains from lipid II units, and transpeptidation, which cross-links adjacent stems to form a stable meshwork. These disruptions weaken the , rendering susceptible to , particularly during active growth phases. Vancomycin's activity is restricted to due to its inability to penetrate the outer membrane of Gram-negative organisms, a barrier that excludes large hydrophilic molecules like the (molecular weight approximately 1,450 ). This selectivity ensures targeted action against pathogens such as staphylococci and enterococci while sparing Gram-negative species.

Pharmacokinetics

Vancomycin exhibits negligible oral , typically less than 5%, necessitating intravenous administration for systemic infections, while oral dosing is reserved for gastrointestinal indications such as difficile-associated . Following intravenous administration, vancomycin distributes widely in body tissues with a ranging from 0.4 to 1 L/kg in adults with normal renal function. It achieves good penetration into bone and joint fluids, making it suitable for treating and , but cerebrospinal fluid penetration is poor (less than 1% of serum levels) unless the are inflamed. Protein binding is moderate, approximately 30–55%, primarily to . Vancomycin undergoes no significant in the body and is excreted primarily unchanged in the via glomerular , accounting for about 80–90% of the dose in patients with normal renal function. Its clearance is closely correlated with clearance (CrCl), with an approximate relationship of vancomycin clearance (mL/min) ≈ 0.695 × CrCl (mL/min) + 0.05. The elimination in individuals with normal renal function is 4–6 hours. In special populations, the of vancomycin is prolonged in neonates (up to 10–20 hours due to immature renal function), the elderly (often exceeding 6 hours owing to reduced ), and obese patients (where dosing adjustments based on ideal body weight are recommended to account for altered ). Renal impairment significantly extends the , reaching 7.5 days in anephric patients, underscoring the need for dose adjustments based on renal function assessments.

Antibiotic resistance

Vancomycin exhibits intrinsic resistance in primarily due to the impermeability of their outer membrane, which prevents the hydrophilic glycopeptide from accessing its intracellular target site on the precursors. Additionally, certain species of enterococci, such as and Enterococcus casseliflavus, display intrinsic low-level resistance to vancomycin through the expression of VanC clusters, which modify the terminus from D-Ala-D-Ala to D-Ala-D-Ser, resulting in a modest reduction in drug affinity. Acquired resistance to vancomycin is predominantly mediated by the VanA and VanB clusters in enterococci, leading to the production of vancomycin-resistant enterococci (VRE). These clusters encode enzymes that reprogram synthesis by replacing the D-Ala-D-Ala terminus with D-Ala-D-Lac, which decreases vancomycin's binding affinity by approximately 1,000-fold and thereby inhibits the drug's ability to block transpeptidation. In Staphylococcus aureus, acquired high-level manifests as vancomycin-resistant S. aureus (VRSA), typically arising from the horizontal transfer of the VanA from co-infecting VRE strains via plasmids, often in conjunction with the for . A related but distinct is vancomycin-intermediate S. aureus (VISA), characterized by heterogeneous with minimum inhibitory concentrations (MICs) of 4–8 μg/mL; this arises from metabolic adaptations, including thickened s that trap the drug and reduce its effective concentration at the target site. The prevalence of VRE among enterococcal isolates in U.S. hospitals is substantial, with approximately 30% of healthcare-associated enterococcal infections being due to VRE (as of 2021), while VRSA remains exceedingly rare, with about 16 cases reported in the as of 2023. These resistance patterns have significant clinical implications, contributing to higher rates of treatment failure in severe infections such as bacteremia and , and necessitating alternative therapies like , , or , though challenges persist due to emerging cross-resistance.

Chemistry and production

Chemical structure

Vancomycin is a complex glycopeptide consisting of a linear heptapeptide backbone composed of seven , five of which are non-proteinogenic and cross-linked via phenolic and biaryl ether bonds to form a rigid . This is substituted with two atoms at positions 2 and 6 on the aromatic rings, enhancing structural stability, and bears a moiety at the para position of one aromatic ring, comprising β-D-glucose linked to vancosamine, an unusual . The molecular formula of vancomycin is C66H75Cl2N9O24, with a molecular weight of 1449 Da. As a type I glycopeptide, vancomycin was originally isolated from the actinomycete bacterium Amycolatopsis orientalis (previously classified as Streptomyces orientalis), highlighting its natural origins through microbial biosynthesis. The compound exhibits amphoteric properties due to multiple ionizable groups, including amino and carboxylic acid functionalities, which influence its solubility profile. It is poorly soluble in water at neutral pH but readily dissolves in acidic or basic conditions, and it is most stable and commonly administered as the hydrochloride salt to improve aqueous solubility and prevent degradation. Vancomycin is sensitive to heat, with observed around 90°C, and to exposure, which can lead to over extended periods, necessitating protection during storage and handling.

Biosynthesis

Vancomycin is produced by the Gram-positive actinomycete bacterium Amycolatopsis orientalis, formerly classified as orientalis. This soil-dwelling microorganism synthesizes the as a to inhibit competing . The biosynthetic pathway is governed by a large spanning approximately 150 kb and containing over 40 genes, which encode the necessary enzymes and regulatory elements. The core of the pathway involves non-ribosomal peptide synthetases (NRPS) that assemble a linear heptapeptide backbone from seven modified building blocks, including non-proteinogenic residues such as 3,5-dihydroxyphenylglycine (DPG), 4-hydroxyphenylglycine (HPG), β-hydroxytyrosine (β-Hty), and L-asparagine. Three multifunctional NRPS enzymes—designated VpsA, VpsB, and VpsC—organize seven catalytic modules in a 3-3-1 configuration, where each module activates, modifies, and condenses one unit in an assembly-line fashion. Modules 2, 4, and 5 incorporate epimerization domains to generate D-configured residues, ensuring the correct for subsequent folding. Post-assembly modifications transform the linear heptapeptide into the mature vancomycin structure through a series of tailoring steps. Chlorination of rings in HPG and β-Hty residues is catalyzed by a flavin-dependent halogenase (VhaA), introducing two chlorine atoms essential for activity. Cyclization occurs via three monooxygenases—OxyA, OxyB, and OxyC—which form two aryl ether cross-links (between residues 2-4 and 4-6) and one biaryl linkage (between residues 5-7), creating the characteristic rigid, cup-shaped aglycone scaffold; OxyB initiates the process, followed sequentially by OxyA and OxyC. Additional oxidations, including formation of an ring on the seventh residue, are mediated by dedicated flavin-dependent oxidases. completes the maturation, with GtfD attaching an L-vancosamine sugar to the oxygen of the fourth residue's group, and GtfE subsequently adding a D-glucose moiety to the vancosamine via an α-1,2 linkage; these steps enhance and target binding. Industrial production of vancomycin relies on submerged fermentation of engineered A. orientalis strains in large-scale bioreactors, typically under oxygen-limited conditions to induce the biosynthetic pathway and optimize yields. Classical and selection, combined with modern —such as overexpression of precursor pathway genes (e.g., for shikimate-derived HPG) and pathway-specific regulators—have increased titers from early isolates (around 1-5 g/L) to over 10 g/L in optimized processes, enabling commercial viability.

Total synthesis

The total synthesis of vancomycin is a landmark achievement in , complicated by the molecule's intricate architecture, which features seven residues, six bonds, a , and three macrocyclic rings, including biaryl ether linkages prone to atropisomerism. The primary challenges involve controlling the complex at 21 chiral centers and managing in the atropisomeric biaryl units, where rotation barriers can lead to mixtures of diastereomers that compromise . These issues demand precise asymmetric synthesis and selective macrocyclization strategies to achieve the natural (3S,18S,32S,39S) configuration. The first of the vancomycin aglycon was accomplished by and coworkers in 1998, utilizing a convergent approach with asymmetric synthesis of the heptapeptide core, followed by sequential macrocyclizations via to form the AB and CD rings, and a final coupling to establish the DE ring. This route highlighted the use of s and conditions to favor kinetic control over formation, yielding the aglycon in 22 steps from derivatives. Independently, K. C. Nicolaou's group reported a of the full vancomycin molecule in 1999, building on the aglycon synthesis through a triazene-directed biaryl formation for the key atropisomeric linkages and enzymatic to attach the vancosamine and glucose units with high . Their strategy involved 47 linear steps, emphasizing Pd-catalyzed cross-couplings and protecting group orthogonality to assemble the structure. Subsequent efforts, including Dale L. Boger's 1999 synthesis, refined these methods but underscored the inefficiencies of full , prompting a shift to semi-synthetic approaches using the aglycon or early biosynthetic intermediates as precursors for derivative modification. Modern semi-syntheses, such as those modifying the backbone or moieties via selective functionalizations, streamline production while allowing targeted alterations like N-methylation or lipophilic extensions. This evolution has enabled the creation of resistance-evading analogs, such as those with enhanced binding to D-Ala-D-Lac precursors in vancomycin-resistant . Overall, these synthetic milestones not only validated vancomycin's but also facilitated analog to restore efficacy against evolving pathogens.

Other applications

Use in plant tissue culture

Vancomycin serves as a selective antibiotic in plant tissue culture, primarily to control bacterial contamination, particularly from Gram-positive bacteria during genetic transformation protocols, and in combination with other antibiotics to control Gram-negative bacteria such as Agrobacterium tumefaciens. It is added to culture media to inhibit bacterial growth while sparing plant cells, as vancomycin binds to the D-Ala-D-Ala terminus of peptidoglycan precursors, disrupting cell wall synthesis in bacteria—a process irrelevant to plant cells, which lack peptidoglycan and instead possess cellulose-based walls. Although ineffective alone against Gram-negative Agrobacterium, vancomycin is often combined with antibiotics like cefotaxime to fully eliminate it post-transformation while minimizing impact on plant cells. This selectivity makes it valuable in micropropagation and Agrobacterium-mediated transformation, where bacterial overgrowth can compromise explant regeneration. Typical concentrations range from 50 to 200 μg/mL in solid or liquid media, though effective levels can vary from 10 to 400 μg/mL depending on the plant species and bacterial strain; higher doses, such as 500–1000 μg/mL, have been used in early protocols for root explants but may reduce transformation efficiency. Its broad-spectrum activity against Gram-positive contaminants, combined with stability under standard culture conditions (pH 5.5–6.5, 25°C), positions it as a reliable agent for maintaining sterility without frequent medium changes. Vancomycin is often combined with cefotaxime (a β-lactam antibiotic effective against Gram-negatives) for enhanced control in transformation workflows, leveraging synergistic effects to eliminate Agrobacterium while promoting plant morphogenesis. Despite its advantages, vancomycin exhibits limitations, including potential at elevated concentrations, which can inhibit or reduce regeneration rates in sensitive species like and . For instance, exposures above 500 μg/mL have been linked to lower transformation success due to subtle deleterious effects on explant viability. In such cases, alternatives like alone or timentin may be preferred for their broader efficacy and reduced impact on plant growth. Historical applications of vancomycin in date to the late 1980s, with early adoption in Agrobacterium-mediated transformation of model plants like , where it effectively countered bacterial persistence post-infection without hindering root-to-shoot regeneration. By the 1990s and 2000s, it became a staple in protocols for crops and ornamentals, reflecting its integration into standard practices for contamination-free cultures.

Veterinary uses

Vancomycin is employed in veterinary medicine on an off-label basis for the treatment of serious infections caused by methicillin-resistant Staphylococcus aureus (MRSA) in companion animals, including dogs and cats, where parenteral administration is indicated for life-threatening systemic disease following culture and susceptibility testing. In equine medicine, oral vancomycin is used as a last-resort therapy for metronidazole-resistant Clostridioides difficile-associated enterocolitis, targeting enteric infections without systemic absorption. No formulations of vancomycin are approved for any veterinary species, limiting its application to cases where less critical antibiotics have failed. Due to the risk of fostering vancomycin-resistant enterococci (VRE) and compromising human treatment efficacy, vancomycin is prohibited for use in food-producing animals by the U.S. (FDA) and has been banned in the since as part of broader restrictions on glycopeptide antibiotics. These measures stem from the historical use of the related glycopeptide avoparcin as a growth promoter, which accelerated resistance emergence. In veterinary practice, alternatives to vancomycin for managing MRSA-like infections include for its activity against gram-positive pathogens or as another glycopeptide option, though both are similarly restricted to preserve their utility in human medicine. Research on vancomycin resistance in animal pathogens has documented VRE isolates from , companion animals, and zoo species, raising concerns about zoonotic transmission and the need for to mitigate spread to human populations. Studies emphasize that while vancomycin remains effective against many susceptible strains in animals, ongoing surveillance is essential to track resistance genes like vanA in enterococci from veterinary sources.

History

Discovery and development

Vancomycin was isolated in 1953 by organic chemist Edmund C. Kornfeld at from a soil sample collected in the interior jungles of , , by missionary William Bouw; the is produced by the actinomycete bacterium Amycolatopsis orientalis (originally classified as orientalis). The compound, initially known as 05865, was named vancomycin in reference to "vanquish," signifying its capacity to overcome resistant bacteria. Early laboratory testing revealed vancomycin's potent activity against , particularly penicillin-resistant strains of , positioning it as a promising agent amid rising staphylococcal resistance in the . Initial chemical characterization, published in , described it as a complex amphoteric tricyclic with basic properties, though its full structure would not be determined until later decades. Pre-clinical evaluations in animal models, including mice and dogs, confirmed vancomycin's against experimental staphylococcal infections, with effective doses protecting against lethal challenges; however, early impure raised significant concerns over , notably and observed at higher doses.

Clinical introduction and evolution

Vancomycin received approval from the U.S. (FDA) in 1958 for intravenous administration to treat severe staphylococcal infections, marking its entry as a critical for gram-positive bacterial infections resistant to other agents. This approval was based on open-label demonstrating against drug-resistant staphylococci, positioning vancomycin as a vital option in an era of emerging challenges. Initially reserved for life-threatening cases due to early concerns over and impurities in the , its use expanded cautiously in hospital settings. By the 1980s, vancomycin's clinical application surged in response to the rising prevalence of (MRSA) infections, which drove a dramatic increase in its prescription worldwide. This period saw vancomycin become a therapy for serious MRSA cases, with usage rising over 100-fold by the in many regions. Concurrently, oral vancomycin emerged as a preferred for difficile-associated (CDAD) following studies in 1978 that established its high efficacy against the pathogen, leading to its routine use for this indication despite poor systemic absorption. In the 1990s and 2000s, growing concerns over vancomycin-intermediate S. aureus () and heterogeneous strains prompted enhanced monitoring protocols to address resistance challenges. The FDA label warns of the risk of with vancomycin use, particularly with high doses or concurrent nephrotoxic agents. This led to the development of guidelines by the (ASHP), Infectious Diseases Society of America (IDSA), and Pediatric Infectious Diseases Society (PIDS) in 2009, recommending with trough levels of 15-20 mg/L for serious infections to optimize efficacy and minimize toxicity. In the 2020s, clinical practice evolved further with updated ASHP/IDSA guidelines in 2020 advocating area under the curve (AUC)-based monitoring over trough-only approaches to better balance efficacy against MRSA and toxicity risks, reflecting advances in pharmacokinetic modeling. These recommendations aim to target an AUC/MIC ratio of 400-600 mg·h/L for improved outcomes in resistant infections. Today, generic formulations dominate the vancomycin market, with multiple manufacturers supplying the majority of intravenous and oral products following the expiration of original patents, ensuring broad accessibility while maintaining quality standards.

Research directions

New formulations and analogs

To address limitations in the and delivery of vancomycin, researchers have developed advanced formulations such as liposomal and systems. These encapsulate the to enhance targeted delivery, reduce systemic toxicity, and improve , particularly for localized like ocular or bone-related conditions. For instance, liposomal vancomycin composed of and has demonstrated superior antibacterial efficacy in preclinical models by prolonging drug release and minimizing off-target effects. Similarly, surface-modified nanoliposomes loaded with vancomycin exhibit enhanced bone affinity, enabling better penetration into sites while maintaining stability in physiological conditions. Semisynthetic analogs of vancomycin, including , dalbavancin, and telavancin, represent significant advancements with structural modifications that extend and optimize tissue penetration. incorporates an additional sugar and a lipophilic , allowing for once-weekly dosing in acute bacterial . Dalbavancin features a lipophilic dimethylaminopropyl , supporting intravenous administration every 7-14 days with reduced frequency compared to standard vancomycin regimens. Telavancin includes a decylaminoethyl and a phosphono group, which contribute to its prolonged plasma exposure and activity against Gram-positive pathogens. All three have received FDA approval for treating and , leveraging these modifications for improved clinical utility. Halogenated derivatives of vancomycin focus on modifying the existing aryl moieties to strengthen interactions with bacterial precursors. Efforts involving selective dechlorination followed by cross-coupling at the position have yielded analogs with altered binding profiles, potentially increasing potency through precise introductions. These modifications, often enabled by approaches, aim to fine-tune the molecule's affinity without compromising its core structure. In terms of clinical progress, new oral formulations of vancomycin, such as FIRVANQ (vancomycin hydrochloride for oral solution), advanced through phase III trials for difficile-associated (CDAD) and were approved by the FDA in 2018. Liposomal nanocarriers for oral delivery of vancomycin derivatives like FU002 are under investigation, showing promise in preclinical studies for systemic absorption and reduced gastrointestinal side effects.

Strategies to combat resistance

One prominent strategy to restore vancomycin's efficacy involves chemical redesigns that enhance its penetration into bacterial cells, particularly against resistant strains. The vancomycin- conjugate (V-R), which attaches a single molecule to vancomycin, improves membrane permeability and targets cell-wall synthesis in like carbapenem-resistant , as well as vancomycin-resistant enterococci (VRE). This conjugate has demonstrated reduced minimum inhibitory concentrations (MICs) against actively growing resistant pathogens and , inducing morphological changes such as loss of rod shape in bacteria, thereby regaining activity where native vancomycin fails. Combination therapies pairing vancomycin with , such as ceftaroline, exploit synergistic effects to overcome vancomycin-intermediate Staphylococcus aureus (VISA) and vancomycin-resistant S. aureus (VRSA). In clinical case series, this combination resolved refractory MRSA bacteremia in patients unresponsive to vancomycin monotherapy, with in vitro studies showing against multiple VISA isolates by enhancing cell-wall disruption. Early administration of vancomycin plus ceftaroline has been associated with improved mortality outcomes in complicated MRSA infections compared to standard therapies. Similarly, pairings with or other agents have shown promise in salvage treatment for persistent VRE infections. Efforts to develop inhibitors focus on disrupting key mechanisms, such as the VanA that modifies precursors in VRE. D-alanine acts as a of VanA , reducing vancomycin by competing with D-alanine-D-lactate incorporation into cell walls, thereby lowering MICs in resistant enterococci. Chlorobiphenyl vancomycin , despite lacking -binding capacity, inhibit the transglycosylase activity of penicillin-binding protein 1b (PBP1b), a target in VanA-resistant strains, restoring without direct glycopeptide binding. Compounds targeting efflux pumps or VanA pathways are also under to block and expulsion. Global surveillance programs play a crucial role in tracking vancomycin resistance trends to inform targeted interventions. The World Health Organization's Global Antimicrobial Resistance and Use Surveillance System () collects standardized data on vancomycin-resistant like VRE and VRSA from national laboratories, enabling the monitoring of prevalence and guiding policy on . As of 2025, reports indicate rising antibiotic resistance globally between 2018 and 2023, with an average annual increase of 5-15% in over 40% of monitored antibiotics, and vancomycin-resistant Enterococcus faecium listed as a high-priority in the WHO Bacterial Priority Pathogens List 2024, underscoring the ongoing need for enhanced diagnostic and therapeutic strategies. Emerging future approaches include and CRISPR-based engineering to bolster vancomycin's utility. Bacteriophages combined with vancomycin eradicate VRE more effectively than either alone, as phages lyse resistant cells while the antibiotic prevents regrowth, with studies showing complete clearance in murine models of . For antibiotic production, CRISPR-Cas9 editing in vancomycin-producing Amycolatopsis orientalis enables rapid modification of biosynthetic clusters, potentially yielding variants with improved activity against resistant strains. Additionally, CRISPR systems targeting the vanA in resistant have cured plasmids carrying resistance determinants, sensitizing VRE to vancomycin in preclinical settings.

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