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Spark gap

A spark gap is a passive electrical component consisting of two electrodes separated by a small gap filled with air or another gas, which acts as a voltage-controlled switch by allowing a high-voltage electrical discharge, or spark, to occur across the gap when the applied potential difference exceeds the dielectric breakdown voltage of the medium, typically ionizing the gas and forming a conductive plasma arc. This discharge can handle extremely high currents, often thousands of amperes, and serves to interrupt or divert electrical energy in various systems. Historically, spark gaps played a pivotal role in the development of communication, first demonstrated by in 1886–1888 to confirm the existence of electromagnetic waves through spark-generated oscillations, building on James Clerk Maxwell's theoretical predictions. advanced their practical application in spark gap transmitters for , achieving key milestones such as the first crossing in 1899 and transatlantic transmission in 1901, which revolutionized maritime and long-distance signaling until technology supplanted them in the 1920s due to their inefficiency and broadband interference. In contemporary , spark gaps are primarily utilized in surge protection devices, such as type 1 lightning arresters, to divert transient overvoltages from strikes or electromagnetic pulses away from sensitive equipment by shunting high currents—up to 40,000 amperes—to with low residual voltage under 1.5 and rapid response times. They also find use in high-voltage pulse generators, radar systems, and triggered switches for applications, offering advantages like no aging under repeated loads, high energy absorption exceeding standards (e.g., IEC 61643-11), and cost-effective in harsh environments such as infrastructure and wind turbines.

Fundamentals

Definition and Basic Operation

A spark gap is a physical space between two conductive electrodes across which an electric spark jumps when the applied voltage exceeds the breakdown strength of the medium, typically a gas such as air. It functions as a voltage-controlled switching without a solid , relying on the gaseous medium to insulate under normal conditions. The basic components consist of two electrodes, often shaped as rods, plates, or spheres, separated by a controllable gap distance, enclosed in a chamber filled with air or another gas at atmospheric or controlled pressure. Common electrode materials include tungsten or brass for their durability against erosion during discharges, ensuring repeated operation without significant degradation. In operation, a high-voltage source is applied across the electrodes, building an electric field that eventually ionizes the gas molecules, initiating an avalanche of electrons and ions to form a low-resistance plasma channel. This conductive path allows a brief, high-current discharge to flow until the voltage drops below the sustaining level, extinguishing the spark and restoring insulation. The process repeats with subsequent voltage applications, with performance influenced by key parameters such as gap distance, which determines the breakdown threshold; electrode material, affecting longevity; and ambient conditions like gas pressure and humidity, which alter ionization rates. A simple schematic illustrates two parallel electrodes connected to a , with the gap shown in an insulating state before and a luminous bridging the space afterward, highlighting the transition from open circuit to .

Electrical Breakdown Mechanism

The in a spark gap begins with the Townsend avalanche mechanism, where an initial in the gas accelerates under the applied , gaining sufficient energy to ionize neutral gas molecules through collisions. This process generates additional electrons and positive ions, leading to an exponential multiplication of charge carriers as the avalanche propagates across the gap. The growth is characterized by Townsend's first ionization coefficient α, which quantifies the number of ionizing collisions per unit length, resulting in a current increase proportional to e^{αd}, where d is the gap distance. As the avalanche intensifies, particularly in gaps on the order of millimeters or larger, it transitions into the streamer phase, where the space charge from accumulated ions distorts the electric field, enhancing local ionization at the avalanche head. This forms a self-propagating conductive plasma filament, or streamer, that bridges part or all of the gap at speeds around 10^7 cm/s, enabling rapid current rise without requiring the avalanche to span the entire distance uniformly. In longer gaps, such as those exceeding several centimeters, the streamer evolves into a leader phase, characterized by a hotter, more thermally ionized channel that fully connects the electrodes, sustaining higher currents through thermal runaway and further field enhancement. Photoionization plays a crucial role in augmenting these processes by producing through photons emitted during initial collisions in the ; these photons ionize gas molecules at a distance, initiating parallel that facilitate branching and propagation. Field emission from the surface contributes under high exceeding 10^7 V/m, where electrons tunnel through the potential barrier, providing seed electrons for the without relying solely on cosmic rays or surface emission. These mechanisms are particularly prominent in non-uniform fields typical of spark gaps. The gas medium, primarily air composed of and oxygen, influences breakdown through its molecular properties, with nitrogen's higher requiring stronger fields for initiation compared to more electronegative gases. introduces , which generally increases the breakdown voltage due to enhanced electron attachment that reduces the number of free s available for the , though effects can vary with , gap configuration, and presence of ; impurities like dust or pollutants similarly reduce the dielectric strength by providing sites for enhanced local fields or additional paths. Sustaining the discharge requires a minimum input to maintain conductivity, primarily through where the current through the partially ionized channel dissipates as heat, raising the gas temperature to thousands of and ensuring equilibrium. This balance, often on the order of millijoules for short sparks, prevents recombination from the prematurely.

Physical Properties

Breakdown Voltage

The breakdown voltage in a spark gap refers to the minimum voltage at which occurs, initiating a spark across the electrodes. This voltage is governed by , which posits that the breakdown voltage V_b depends solely on the product of gas pressure p and electrode gap distance d, expressed as V_b = f(pd). Developed by Friedrich Paschen through experiments on gas discharges in the late 19th century, the law holds for conditions of uniform and constant temperature, providing a foundational framework for predicting spark initiation in gases like air. The Paschen curve graphically depicts V_b versus pd, revealing a characteristic U-shape for air. The curve reaches a minimum at an optimal pd of approximately 0.55 ·, where V_b \approx 361 V under conditions; this minimum arises from the balance between sufficient ionizing collisions and efficient development. For low pd values (e.g., low pressure or small gaps), V_b rises sharply due to the extended of electrons, resulting in insufficient collisions for . At high pd (e.g., and larger gaps), V_b increases because the shortened requires greater overall voltage to sustain the Townsend leading to . An empirical approximation of for air is given by V_b = \frac{B (pd)}{\ln(A pd)}, where p is in Torr, d in cm, and the gas-specific constants are A \approx 11.25 (Torr·cm)^{-1} and B \approx 273 V·(Torr·cm)^{-1} . These parameters fit experimental data for dry air, though slight variations occur with humidity or impurities..pdf) Electrode geometry significantly modifies the effective breakdown voltage by altering field uniformity; blunt, parallel-plate electrodes yield the ideal Paschen behavior, while sharp or curved edges concentrate the electric field, reducing V_b through enhanced local ionization. Temperature influences V_b by affecting gas density at constant pressure—higher temperatures increase the electron mean free path, generally lowering V_b as fewer collisions are needed for breakdown, though the effect is modest (e.g., ~1-2% decrease per 10°C rise near room temperature). In direct current (DC) setups with non-uniform fields, electrode polarity matters: a positive anode (negative cathode) typically results in lower V_b due to greater secondary electron emission from the cathode surface. Breakdown voltage measurements distinguish between static (steady or low-frequency ) and dynamic (fast-rising transients) conditions, with the latter often requiring higher voltages due to reduced streamer propagation time. For uniform fields in air at (STP: 1 atm, 20°C), the field strength is approximately 3 kV/mm, implying V_b \approx 3 kV for a 1 mm gap, though this scales near-linearly only for gaps above ~0.5 mm where Paschen effects diminish. Deviations from ideal Paschen predictions are prominent in non-uniform fields, where initiates at voltages 20-50% below full spark , manifesting as localized partial ionization near high-curvature electrodes before complete gap bridging.

Spark Formation and Visibility

Once electrical breakdown occurs across a spark gap, the discharge evolves into distinct phases. The initial phase involves a bright leader stroke, where a conductive plasma channel rapidly propagates across the gap, ionizing the gas and establishing a low-resistance path for current flow. This leader is followed by an arc phase if the voltage is sustained, transitioning the spark into a more stable, high-conductivity column of plasma; however, for transient sparks typical in many applications, the entire process lasts on the order of microseconds before quenching. The visibility of a spark arises primarily from the and of gas atoms in the channel, particularly (N₂) and oxygen (O₂) in air, which emit across specific spectral bands. Excited molecules produce prominent emissions in the , , and regions, such as the second positive band at 337 , contributing to the characteristic bluish-purple glow observed. Additionally, thermal from the hot , with temperatures ranging from 10,000 to 30,000 , generates a broad-spectrum that enhances , though the discrete atomic lines dominate the color. Accompanying the optical effects are acoustic and electromagnetic phenomena inherent to spark formation. The rapid heating of air to extreme temperatures causes explosive expansion, producing a thunder-like sound wave as the channel's front propagates outward. Simultaneously, the abrupt surge during generates radiofrequency (RF) , as the fast-changing radiates across a wide . Several factors influence the spark's appearance and behavior. Higher discharge currents result in brighter and hotter sparks due to increased input, intensifying both lines and . Longer gap distances often lead to branched, lightning-like structures as the leader propagates through a more tortuous path in the nonuniform field. Variations in the surrounding atmosphere also alter the ; for instance, sparks in exhibit reddish hues from its atomic emissions, contrasting with air's violet tones. As byproducts, sparks produce ultraviolet radiation and through oxygen and recombination in the .

Types and Configurations

Open-Air and Simple Gaps

Open-air spark gaps represent the simplest form of spark gap devices, consisting of two conducting electrodes separated by a small in ambient atmospheric air, without any or additional enhancements. Typically, these electrodes are shaped as rods, plates, or spheres made from materials such as or , which provide good and durability under arcing conditions. For low-voltage applications, the gap is commonly set between 1 and 10 mm to achieve reliable at voltages in the kilovolt range, allowing the device to function as a basic electrical switch or voltage . The primary advantages of open-air and simple gaps lie in their straightforward construction, which requires minimal components and no specialized , resulting in low cost and ease of . These designs feature no moving parts in their basic static form, making them robust for initial testing and experimental setups, where they have been widely employed since the late to demonstrate electrical phenomena. However, open-air gaps exhibit significant limitations due to their exposure to environmental factors. Weather conditions, particularly , can substantially reduce the by 20–50% or more, as water droplets distort the and enhance across the , leading to premature arcing. Electrode is another critical drawback, caused by the intense and during , which progressively widens the and degrades performance over repeated use. Additionally, these gaps suffer from poor , where the tends to re-ignite easily after initial due to residual in the air, limiting their efficiency in applications requiring precise control. In terms of performance, the for open-air gaps in dry air is approximately 30 kV/cm, determined by the of air under uniform field conditions, which governs the onset of through and processes. This value provides a baseline for design but varies with geometry and . Representative examples include rotary spark gaps, where a rotating periodically closes the gap to enable controlled sparking for in early radio systems, improving repetition rates over static designs. A historical instance is Heinrich Hertz's apparatus for generating electromagnetic waves, which utilized ball-shaped electrodes in an open-air gap of about 3 mm to produce detectable sparks and demonstrate wave propagation.

Quenched and Pressurized Gaps

Quenched gaps represent an advanced configuration designed to enhance the speed and reliability of spark extinction compared to simple gaps, primarily through mechanisms that accelerate de-ionization of the channel. These devices employ multiple electrodes arranged in series, typically consisting of several short gaps—often two or more—stacked to divide the total voltage across smaller distances, which facilitates rapid and cooling of the . Electrodes in such setups are commonly constructed from plated with silver to leverage high conductivity, augmented by large cooling fins that increase surface area for air exposure, sometimes assisted by directed air blasts to further expedite . This multi-gap arrangement interrupts the conductive path quickly, typically within 3 to 4 cycles of high-frequency , thereby preventing re-striking and minimizing energy losses. A variant of quenched gaps incorporates rotary mechanisms, where segmented disks or wheels rotate to mechanically break the spark arc at high speeds, mimicking the action of a motor to segment and isolate the discharge path. These rotary quenchers use multiple electrodes on a spinning disk that align briefly with stationary counterparts, creating intermittent sparks while the segmentation ensures swift interruption and de-ionization. Another quenching approach utilizes intense applied across the gap, which accelerate plasma ions and generate shock waves to sweep residual out of the inter-electrode space, restoring rapidly. This magnetic quenching maintains a negative dynamic in the gap, enabling sustained operation at frequencies up to 0.5 MHz and quenching times as short as 1 . Pressurized spark gaps enclose the electrodes within a chamber filled with high-pressure insulating gas, such as , to improve and control breakdown characteristics under high-voltage conditions. At pressures ranging from 6 to 10 bars, SF6 significantly enhances reliability by increasing the gas density, which raises the , allowing the use of smaller gaps for equivalent insulation levels compared to atmospheric air gaps or handling higher voltages for the same gap size; for instance, tests have demonstrated stable performance up to 140 kV pulses with voltage rise rates of approximately 300 kV/ns across gaps up to 1.6 mm wide. This pressurization reduces the length of streamers during discharge initiation, promoting more uniform breakdown and minimizing the risk of partial discharges that could lead to insulation failure. Field modeling of these gaps confirms that pressure optimization distributes the more evenly, further bolstering high-voltage endurance. Hybrid designs combine pressurization or quenching with additional media for specialized performance, such as vacuum-enclosed spark gaps that achieve ultra-high voltage handling by eliminating gas molecules entirely, relying on surface conditions for control in applications exceeding hundreds of kilovolts. Oil-immersed variants immerse pressurized or quenched gaps in fluids like , which provide cooling and through thermal absorption and viscous damping of the . These enhancements collectively enable times below 1 and repetition rates up to the kilohertz range, far surpassing basic gaps by allowing precise, high-frequency switching without excessive wear or re-ignition. While solid-state switches have largely supplanted gaps in modern systems, quenched and pressurized designs remain relevant for rugged, high-power environments requiring robust .

Historical Development

Early Invention and Experiments

The study of , foundational to spark gaps, originated in early investigations of , with English physician William Gilbert conducting systematic experiments around 1600. In his seminal work , Gilbert described the attraction of light objects to rubbed and other substances, distinguishing electrical phenomena from and laying foundational observations for later electrical discharges. These efforts built on ancient anecdotal reports of from but marked the first rigorous documentation, using a versorium device to detect electric attractions without explicit spark generation. Advancements in the mid-18th century enabled visible sparks through the invention of the around 1745–1746, independently by Ewald Georg von Kleist and . This early stored substantial electric charge, producing brilliant sparks upon discharge that fascinated scientists and demonstrated high-voltage breakdown across air gaps. In the early 1700s, Francis Hauksbee's experiments with frictional electrical machines produced visible sparks, advancing understanding of electrical discharges in air. By the early 1800s, Michael Faraday's experiments with electrical discharges in rarefied gases within glass tubes further illuminated spark gap mechanisms, revealing how pressure and gas composition influenced conduction and luminous discharges in the 1830s. A pivotal milestone came in 1887 when employed spark gaps to generate and detect electromagnetic waves, experimentally confirming James Clerk Maxwell's theoretical predictions. Hertz's apparatus used an to create high-voltage sparks across adjustable gaps in resonators, producing waves detectable by a similar up to several meters away, thus establishing spark gaps as tools for production. In 1897, J.J. Thomson identified the through experiments with in discharge tubes, measuring their charge-to-mass ratio and providing key insights into processes in electrical discharges. Later, in 1899, Thomson collaborated with C.T.R. Wilson using early techniques to visualize ion tracks from photoelectrons and discharges, further elucidating spark-initiated paths. Concurrently, initial practical challenges arose in the 1850s with telegraph systems, where uncontrolled arcing from strikes damaged lines; Joseph Henry's 1847 proposal of a protective spark gap—allowing surges to jump to ground—pioneered early safeguards, formalized by 1860 patents.

Evolution in Early 20th-Century Technology

In the opening years of the , spark gaps underwent significant refinement as expanded, with key contributors enhancing their design for practical communication. British physicist advanced spark gap efficiency through syntonic tuning systems patented in 1897, which improved signal selectivity by matching transmitter and receiver frequencies in spark-based setups. Similarly, Russian physicist Alexander Popov refined gap configurations around 1895–1900, employing oil-immersed Righi-type spark gaps to generate more consistent and powerful discharges for detecting electromagnetic waves over distances up to 60 meters. These improvements laid groundwork for broader adoption in radio technology during the 1900–1920s. A landmark application came in 1901 when utilized a high-power to achieve the first transatlantic radio signal from Poldhu, , to St. John's, Newfoundland, spanning over 3,000 kilometers and demonstrating the scalability of spark technology for global messaging. As radio demands grew, innovations like the quenched spark gap—developed by German physicist Max Wien in 1906—emerged, featuring multiple small gaps in series to rapidly extinguish the arc and produce sharper, higher-frequency damped waves for clearer modulation in early transmitters. While alternator-based systems later enabled continuous-wave (CW) transmission for more efficient long-range signals, spark gaps remained essential for rudimentary until the mid-1920s. Parallel to radio advancements, spark gaps evolved in automotive ignition during the , transitioning from exposed air gaps to enclosed designs for reliability. The 1860 Lenoir engine, an early internal combustion prototype, ignited fuel-air mixtures via a high-voltage jumping spark across an open gap, setting a conceptual precedent despite its inefficiency. By 1902, patented the first practical , which insulated the gap electrodes within a body to prevent misfires and withstand , enabling widespread use in vehicles like the early . In power distribution, the 1910s saw spark gaps integrated into surge protection, particularly through horn gap arresters on high-voltage transmission lines. These devices featured diverging metal horns flanking an air gap, allowing lightning-induced overvoltages to arc across the gap and climb the horns, where the increasing distance self-extinguished the discharge to protect transformers and insulators. The dominance of spark gaps waned with the advent of vacuum tubes in the , which provided stable continuous-wave generation and , supplanting noisy, spark transmitters in radio. Transistors further accelerated this shift in the 1950s by enabling compact, , yet spark gaps endured in high-voltage domains such as ignition systems and arresters due to their simplicity and robustness under extreme conditions.

Applications

Ignition Systems

In internal combustion engines, particularly automotive and applications, spark gaps serve as the critical point for initiating combustion by generating a high-voltage electrical discharge that ignites the compressed fuel-air mixture within the engine cylinders. The produces a spark voltage typically ranging from 20 to 40 kV through an or magneto, which overcomes the of the air-fuel mixture across the gap, creating a channel that rapidly heats and ionizes the mixture to produce a flame kernel. Spark plugs, the primary devices incorporating these gaps, consist of a central electrode connected to the high-voltage source, a ground electrode (often in the form of a strap or prong) attached to the engine block, and a ceramic insulator that prevents premature discharge while withstanding high temperatures up to 1000°C. The gap between the electrodes is precisely set, usually between 0.7 and 1.1 mm, to optimize spark energy transfer and ensure reliable ignition under varying compression pressures and mixture densities; this size balances the required breakdown voltage with the need for a sufficiently large spark kernel to propagate combustion efficiently. Historically, early 20th-century ignition systems relied on magneto devices, which mechanically generated independent of a , as seen in engines from the 1900s onward, but these suffered from inconsistent timing and accelerated electrode wear due to mechanical contacts. The transition to electronic ignition systems in the 1970s, incorporating solid-state switches and controls, improved precision and reduced wear on the spark gap by eliminating points and allowing adaptive timing, thereby extending plug life and enhancing efficiency in high-mileage applications. Performance of spark gaps is limited by electrode erosion, where repeated discharges transfer material from the to , gradually widening the gap and increasing required voltage until misfires occur; conventional electrodes may endure up to 10^9 sparks before significant degradation, but this equates to roughly 30,000–50,000 miles in typical automotive use. Iridium-tipped electrodes, introduced for their high and low rate, extend longevity to 100,000 miles or more by minimizing material loss, particularly in the center , thus maintaining consistent gap dimensions over extended operation. Specialized variants adapt the gap for demanding conditions: racing spark plugs often feature smaller gaps around 0.4–0.6 mm to ensure reliable firing at high RPMs exceeding 8000, where pressures and demand lower voltages to prevent misfires. In , magneto-driven systems use even tighter gaps of 0.4–0.5 mm in massive-electrode plugs to accommodate high-altitude low-pressure environments and dual-magneto , prioritizing durability over spark volume.

Surge Protection Devices

Spark gaps serve as overvoltage protectors in power systems by providing a parallel path to divert transient surges, such as those caused by strikes, away from sensitive equipment. When the voltage across the gap exceeds the normal operating level—typically set to break down at about 1.5 to 2 times the maximum continuous operating voltage—the air or gas in the gap ionizes, forming a conductive channel that shunts the surge current to ground with low impedance. Common types include horn gaps and rod gaps. Horn gaps feature diverging, horn-shaped electrodes that allow the arc formed during breakdown to travel upward along the increasing separation, promoting self-extinction of the arc after the surge passes and preventing power follow current. Rod gaps, consisting of straight or bent rods with an adjustable air gap, are widely used on transmission lines up to 500 kV to protect insulators and equipment by sparking over during severe overvoltages. Design of these gaps requires coordination with other protective devices like surge arresters to ensure the sparkover voltage aligns with the system's basic level, avoiding premature operation under normal conditions while providing timely . Gap settings follow standards such as IEEE Std 516, which specifies rod-to-rod sparkover distances; for example, gaps of 1 to 2 meters are typical for 345 kV lines to achieve the required withstand voltage. Despite their high energy-handling capacity, spark gaps have limitations, including a relatively slow response time on the order of microseconds for certain transients, which may allow initial overvoltages to stress equipment before full diversion. They are also susceptible to pollution-induced , where contaminants like or reduce the , leading to unintended operation. To mitigate these issues, modern hybrid designs combine spark gaps with metal oxide varistors (MOVs) for faster response and improved reliability across a broader range of conditions. Spark gaps became widespread for lightning protection on electrical grids in the 1920s, as AC transmission networks expanded and early arresters evolved from simple air gaps to more refined configurations integrated with power lines and substations.

Radio Transmitters

Spark gaps played a central role in the first practical radio transmitters, known as spark-gap transmitters, which generated radio frequency signals through electrical discharges across the gap. These devices produced damped sinusoidal oscillations by rapidly discharging a high-voltage capacitor through an inductive-capacitive (LC) resonant circuit connected to an antenna, creating broadband radio frequency sparks typically in the range of 100–500 kHz for early long-wave applications. The spark acted as a simple switch, ionizing the air to conduct current and initiate the oscillations, which decayed quickly due to the resistance in the circuit and the gap itself. In operation, a high-voltage source, such as an or , charged the to several kilovolts until the spark gap broke down, dumping the stored energy into the and radiating electromagnetic waves from the . To achieve transmission, the spark rate was controlled mechanically; stationary gaps produced single sparks per key press, while rotary spark gaps—consisting of rotating electrodes—enabled repetition rates up to 1000 Hz for more continuous signaling and higher average power output. These transmitters powered early from the to the , with commercial systems reaching up to 200 kW for transoceanic links, enabling the first global communications like Marconi's 1901 signal. Despite their pioneering success, spark-gap transmitters suffered from inefficient use, as each generated a wide of harmonics and noise, interfering with other signals and limiting in crowded airwaves. This broadband emission, often spanning tens of kilohertz per , made precise difficult and contributed to widespread , leading to international regulations; the (ITU) prohibited new spark transmitter licenses in 1929 and banned them entirely in 1934, except for emergencies, in favor of more efficient continuous-wave alternatives. The legacy of spark-gap transmitters endures in the foundations of , where early experimenters adopted and refined the technology, fostering innovations in that influenced modern radio . Today, replicas and educational demonstrations recreate these systems to illustrate fundamental radio principles, highlighting their historical impact without practical use due to regulatory bans.

Voltage Measurement Tools

Spark gaps serve as precise tools for measuring high voltages by correlating the gap distance at which occurs with the applied voltage value. The sphere gap, a uniform-field configuration, consists of two polished metal spheres of equal diameter, typically ranging from 15 cm to 150 cm, positioned horizontally or vertically with one sphere earthed. This setup, standardized in IEC 60052:2002, enables accurate of voltages for (AC), (DC), and impulse waveforms up to 1 MV, with an overall of ±3% under controlled conditions. In operation, the voltage is determined by adjusting the gap spacing until a spark occurs, at which point the V_b corresponds to the predefined value for that spacing as tabulated in the standard. Environmental factors such as air , , and influence the , necessitating corrections; for instance, the disruptive discharge voltage increases by approximately 0.2% per g/m³ of absolute above a of 11 g/m³, applied via a correction factor formula. These tables and formulas ensure reproducibility, with often required for gaps below 50 kV to initiate consistent sparking. The method aligns with principles for uniform fields, where depends on pressure-distance product, though practical implementations prioritize empirical calibrations over theoretical derivations. Beyond sphere gaps, needle-plane configurations are employed in settings for characterizing voltages, particularly or switching surges, due to their ability to simulate non-uniform fields encountered in power systems. In these setups, a sharp needle faces a flat plane, with voltages measured under controlled s to assess performance, though they lack the standardization of sphere gaps and exhibit higher variability from geometry. These tools have been integral to high-voltage testing since the , initially developed for calibrating early systems and later standardized for modern applications such as verifying and ratings in labs. Sphere gaps provide a reference for calibrating other measuring devices like voltage dividers, ensuring in insulation coordination tests. Despite their reliability, spark gaps have limitations: the destructive nature of the spark erodes electrodes over time and requires manual resetting of the gap after each measurement, limiting throughput in repetitive testing. In contemporary practice, they have been partially supplanted by non-contact methods, such as optical and capacitive sensors, for higher precision and automation in routine calibrations.

Power Switching Devices

Spark gaps serve as high-voltage switches in systems, enabling the controlled interruption or initiation of current in or high-power circuits. In these applications, they function by rapidly breaking down the insulating gas between upon triggering, allowing the of stored energy from capacitors into a load. This capability is particularly valuable in systems requiring voltages exceeding 100 kV, where switches are limited by voltage handling and . Triggered spark gaps, such as trigatrons, incorporate a third to initiate the precisely, often using methods like over-voltage pulsing or UV illumination to ensure reliable firing with low . Designs for power switching emphasize durability and controllability, with trigatron configurations featuring a main gap (typically 0.4–60 cm spacing) and a trigger pin embedded in one to distort the and promote streamer formation. Electrodes are often made from erosion-resistant materials like copper-tungsten to withstand repetitive discharges, and the assembly may be hermetically sealed with low-permeability materials such as KEL-F for operation under pressurized gases (e.g., at 300 psi or ), which enhances and strength compared to open-air gaps. For repetitive operation, some designs integrate gas circulation systems to flush ionized byproducts, reducing recovery time between pulses. Performance metrics highlight their suitability for fast, high-energy switching: rise times as low as 10 ns, jitter below 10 ns in optimized setups, and the ability to handle peak currents of 10 or more and voltages from several to 1 per stage. Recovery times can be as short as milliseconds with gas flow, enabling repetition rates up to 100 Hz or higher (e.g., >600 Hz in sealed designs), though multiple-shot operation is constrained by cumulative wear. These characteristics support efficient energy transfer in pulse-forming networks. In applications, spark gaps are integral to Marx generators, which erect voltages to 1–10 MV for delivering megajoule pulses in research and military contexts, such as driving high-power lasers, electromagnetic railguns, and experiments. For instance, multi-stage Marx banks use synchronized trigatron switches to generate uniform pulses for transient electromagnetic testing or acceleration. Despite these strengths, challenges persist, including electrode that limits lifespan in high-repetition scenarios and the need for specialized triggering to avoid self-breakdown, restricting modern adoption to extreme environments beyond capabilities.

Specialized and Emerging Uses

Spark gaps have found specialized applications in , where they serve as intense, short-duration light sources or triggers for capturing ultra-fast events. In the 1940s, Harold Edgerton at developed setups using spark gaps to produce microsecond-duration flashes, enabling stroboscopic imaging of phenomena like bullet impacts or liquid splashes that were previously impossible to . These air-gap strobes generated high-voltage arcs between electrodes, displacing air and producing a brilliant burst of lasting on the order of microseconds, which froze motion for in scientific studies. In control devices such as bug zappers and electric fences, spark gaps facilitate the creation of lethal electrical s to electrocute pests. These systems employ high-voltage transformers to charge capacitors, which then discharge across small gaps in a or wire when an bridges the electrodes, typically at voltages ranging from 2 to 5 kV. The resulting delivers a brief, high-energy pulse that kills the without sustaining , minimizing power consumption while ensuring effectiveness against flying like mosquitoes. Other niche uses include initiation in processes and pollution control in electrostatic precipitators. In (TIG), spark gaps generate high-frequency pulses to ionize the air gap between the and workpiece, establishing a stable without direct contact and reducing contamination. Similarly, in electrostatic precipitators, the inter-electrode gaps—typically between discharge wires and collection plates—produce corona discharges that charge airborne particles for removal from exhaust gases, with controlled sparking helping to optimize particle collection efficiency in industrial pollution control. Emerging applications leverage spark gaps in plasma research for medical and aerospace purposes, as well as nanomaterials synthesis. In medicine, post-2010 developments have utilized spark gaps to generate cold atmospheric jets for sterilization, where adjustable gaps in setups produce non-thermal that inactivates bacteria and spores on surfaces without damaging heat-sensitive materials like medical implants. In aerospace, pressurized spark gaps in (EMP) simulators replicate nuclear EMP effects on and missiles, allowing testing of resilience through controlled high-voltage discharges. Additionally, since the early 2000s, spark discharge generators have enabled the scalable synthesis of , such as metal nanoparticles, by evaporating materials in inert gases to form aerosols with narrow size distributions (5–50 nm), offering a clean, solvent-free method for applications in and .

References

  1. [1]
    None
    ### Summary of Spark Gaps from the Document
  2. [2]
    Spark Gap Transmitter: History Timeline - Electronics Notes
    The spark gap transmitter was one of the very first forms of radio transmitter. It was the form of transmitter that Hertz used when he confirmed the presence of ...
  3. [3]
    Spark gap technology | Phoenix Contact
    Discover the technology behind our new triggered multi-carbon spark gap in detail and take a look at the history of our spark gaps.Missing: definition | Show results with:definition
  4. [4]
  5. [5]
    [PDF] Spark-gap flashover measurements for steeply rising voltage impulses
    They were used in making up dividers for measuring linearly rising chopped impulses with peak voltages up to 300 kilovolts and times to spark over from 0.03 to ...
  6. [6]
    [PDF] Triggered Switching Spark Gaps - TDK Electronics
    In the conducting state, the electric breakdown will establish a conductive path between the electrodes, and the two electrodes are connected by a high- ...
  7. [7]
    [PDF] HIGH-PERFORMANCE COMPACT GAS FILLED SPARK SWITCHES
    A gas filled spark switch at its simplest is two electrodes, separated by a gaseous dielectric. When a sufficiently high voltage is applied to the HV electrode ...
  8. [8]
    [PDF] 10.3.1.3 Electrical sparks (spark discharges) - iupac
    discontinuous electrical discharges across a gap between at least two electrodes ... The voltage control may be achieved by the defined breakdown voltage of a ...
  9. [9]
    Electrical Breakdown - an overview | ScienceDirect Topics
    The electrons do not gain enough energy from the electric field to ionize the gas atoms or molecules due to their frequent collisions with the gas molecules.
  10. [10]
    [PDF] The breakdown mechanisms in electrical discharges
    The processes that are primarily responsible for the breakdown of a gas are ionization by charged particle collisions, photo-ionization and the secondary ...Missing: leader | Show results with:leader
  11. [11]
    The physics of streamer discharge phenomena - IOPscience
    Streamers are propagating ionization fronts with self-organized field enhancement at their tips that can appear in atmospheric air, or more generally in gases ...
  12. [12]
    Dynamics of streamer‐to‐leader transition at reduced air densities ...
    Nov 8, 2013 · Streamer-to-leader transition is the name given to a sequence of events occurring in a thin plasma channel through which a relatively strong ...
  13. [13]
    Photo-ionization and the electrical breakdown of gases - Journals
    A quantitative theoretical investigation is made of the role of photo-ionization of the gas in the development of ionization currents in gases under uniform ...
  14. [14]
    The humidity effect on the breakdown voltage characteristics and the ...
    Oct 28, 2025 · It has been observed experimentally that humidity increases the breakdown voltage of discharges, mainly due to the increased electron attachment ...
  15. [15]
    High-Voltage Electrodes in Moist Air Accumulate Charge That is ...
    Nov 30, 2023 · Considering humidity, studies have shown that the breakdown voltage of air increases with increasing relative humidity, (33−38) suggesting that ...
  16. [16]
    Energy loss in spark gap switches - AIP Publishing
    Apr 28, 2014 · The paper reports on numerical study of the energy loss in spark gap switches. The operation of the switches is analyzed using the Braginsky ...Missing: considerations | Show results with:considerations
  17. [17]
    Free and Wire-Guided Spark Discharges in Water: Pre-Breakdown ...
    Jun 25, 2023 · Thus, it can be stated that the main energy loss during the pre-breakdown process in the case of free path discharges is joule heating due to ...Missing: considerations | Show results with:considerations
  18. [18]
    [PDF] Paschen's law studies in cold gases - Los Alamos National Laboratory
    Paschen's law describes electric discharge based on gap distance and gas pressure. This study found deviations in cold gases, and a significant shift in colder ...
  19. [19]
    [PDF] CHARACTERIZATION OF PASCHEN CURVE ANOMOLIES ... - DTIC
    Paschen's law estimates breakdown voltage based on pressure and distance (pd). However, at high pd values, the voltage deviates from the theoretical curve.
  20. [20]
    [PDF] Surge voltage breakdown of air in a nonuniform field
    The discharge and breakdown phenomena in air when a surge voltage is applied to sphere-plane electrodes were investigated. A steeply rising surge of 145 ...
  21. [21]
    [PDF] The mechanism of the long spark formation - HAL
    Feb 4, 2008 · - The aim of this paper is to present the state of the art of the research on the physics of long sparks. The reference configuration is a non ...
  22. [22]
    Theoretical modelling of the development of the positive spark in ...
    The main purpose of this paper is to present a physical model of the positive discharge in long air gaps. A large number of previous experimental and ...
  23. [23]
    Optical Signatures Associated With Streamers and Leaders of ...
    Oct 13, 2021 · This work investigates the strongest optical emissions associated with long laboratory sparks (at the wavelengths of 337 and 777 nm)
  24. [24]
    Generated Plasma - an overview | ScienceDirect Topics
    The average temperature and electron density of the thermal plasma is in the range of 10,000–30,000 K and 1021–1026 m−3 respectively. ... The thermal plasma can ...
  25. [25]
    Transient Spark Discharge and Ozone-Driven Nitrogen Fixation to ...
    Oct 14, 2025 · This study investigates reaction pathways that enhance nitrogen fixation by combining air treated with transient spark discharge, containing NO ...Ftir Absorption Spectroscopy... · In-Situ Uv/vis Absorption... · Ts Discharge In Dry...
  26. [26]
    Chapter 15 Thunder - ScienceDirect.com
    A thunder refers to the acoustic radiation associated with lightning. It is the most common of loud natural noises and can be divided into two categories.
  27. [27]
    Characteristics of acoustic response from simulated impulsive ...
    Jul 4, 2019 · Thunder is the result of acoustic energy emission associated with lightning discharge which forms shock waves and attenuates into a sound ...
  28. [28]
    The Mechanism of Spark Discharge in Air at Atmospheric Pressure. I
    This mechanism enables one to discuss the breakdown potentials of unsymmetrical gaps showing the difference in sparking potential between positive and negative ...
  29. [29]
    A Theory of Spark Discharge | Phys. Rev.
    The theory proposes spark discharge occurs when an electron avalanche transitions into a self-propagating streamer, forming a conducting filament via electron ...
  30. [30]
    Ozone production from Corona Discharge - Oxidation Technologies
    Any electrical discharge, or spark will create ozone. The spark will split the oxygen molecule (O2) found in ambient air into elemental oxygen (O).
  31. [31]
    [PDF] Two-Electrode Spark Gap Preamble - AEP International
    A two-electrode spark gap is an insulator at low voltages, but as voltage increases, it ionizes gas, leading to an arc discharge. It is used for voltage surge ...
  32. [32]
    Optimization Of The Three-electrode Spark Gap Characteristics
    The electrode material were: copper, tungsten and steel. We varied thevoltage from 30% to 90% of the spontaneous breakdown voltage. We determined and designed ...
  33. [33]
    Study on the influence of rainfall on the electric field distribution and ...
    Dec 17, 2018 · Rainfall significantly distorts the electric field, causing a dramatic decrease in discharge voltage, especially with water columns forming. ...
  34. [34]
    [PDF] electrode erosion in a high energy spark gap - DTIC
    The ratio of cathode to anode erosion varied from 1.5 in stainless steel (304) to 16 in copper-graphite for those materials which had significant anode erosion.
  35. [35]
    Breakdown Voltage - an overview | ScienceDirect Topics
    An approximate rule for uniform fields at all frequencies up to at least 300 megahertz is that the breakdown gradient of air is 30 peak kilovolts/centimeter or ...
  36. [36]
    [PDF] Electric Waves
    of the experiments the spark-gap was reduced to 3 mm. Here, again, the small sparks induced in a secondary conductor were the means used for detecting the ...
  37. [37]
    [PDF] SECTION "A." THE SPARK TRANSMITTER.
    In the quenched gap, the spark gap is broken up into a number of very short gaps in serie with each other. The electrodes are made of copper, plated with silver ...
  38. [38]
    [PDF] authority this page is unclassified - DTIC
    A serious problem in using transmission lines to connect the ring to a central spark gap is the transmission-line losses. The ring trans- mitter is a low- ...
  39. [39]
    Measurement of breakdown characteristics of SF6 insulated spark ...
    First experiments were done with maximum pulse voltages of 140 kV and slopes of approximately 300 kV/ns. The gas pressure varied between 6 and 8 bar and the gap ...
  40. [40]
    Breakdown strength criteria of a spark gap switch in high pressure ...
    Breakdown voltage tests have demonstrated the functioning of the spark gap switch as intended up to 9bars of SF6. In parallel, Field modeling has been performed ...Missing: pressurized | Show results with:pressurized
  41. [41]
    [PDF] Spark Gap Impedance Collapse and Current Rise Times in Modern ...
    Jun 9, 2024 · It took twice as long for the voltage across the gap to collapse for SF6 than C4F7N. At pressure below 1.5 atm, C4F7N demonstrates comparable ...
  42. [42]
  43. [43]
  44. [44]
    Leyden Jar Battery - Science History Institute
    May 19, 2012 · To entertain a king, Jean-Antoine Nollet made 180 French soldiers jump into the air as electricity from his Leyden jars coursed through them.
  45. [45]
    Rays and Particles - Galileo
    In 1897, J. J. Thomson announced at the Royal Institution that they were ... Wilson, in a cloud chamber experiment. They introduced photoelectrons into ...
  46. [46]
    [PDF] History of Arresters on Power Systems 1750 - 1890
    By 1890, Elihu Thomson patented an arrester to be used to protect power lines for electric rails. His system also included a lightning rod on the pole, and a ...Missing: spark | Show results with:spark
  47. [47]
    NIHF Inductee Oliver Joseph Lodge Invented Wireless Telegraphy
    Physicist Oliver Lodge made several important technological contributions, most notably his advancement of wireless telegraphy.
  48. [48]
    [PDF] Popov versus Marconi: the Centenary of Radio - TrevorWright.com
    The transmitter had a similar aerial and earth' connected to a Righi-type spark gap (a gap immersed in oil, thought to produce a more vigorous spark), energized ...
  49. [49]
    The Quenched Spark System (1916) - Early Radio History
    The quenched spark system is one of the most important and successful systems of wireless telegraphy, as can be gauged from the fact that upwards of 1250 ...
  50. [50]
    Patent Page: The Humble Spark Plug - Gas Engine Magazine
    Dec 9, 2020 · Etienne Lenoir, the inventor of one of the very first internal combustion engines in 1858, patented an electric ignition in 1860 and is ...Missing: gap | Show results with:gap
  51. [51]
    Lightning and Fault Suppression - Edison Tech Center
    Horn gaps used to be a rudimentary protection for transformers as seen in the photo from the 1910s below. Learn more detail about Flashovers Here. Above: ...
  52. [52]
    Wireless_Spark_Gap_Ham_Gear - Western Historic Radio Museum
    By 1921, Spark was on the way out being replaced by vacuum tube oscillators. *It was possible to use DC line voltage and "key" the transformer through an ...
  53. [53]
    Ignition Coil Output - Tomorrow's Technician.
    Rating 5.0 (2) Kilovolts or kV is the unit used to measure the output of an ignition coil. Some coils can output 20kV to 40 kV.
  54. [54]
    Spark and Ignition | Basic Knowledge | SPARK PLUG - DENSO Global
    If the plug gap is wide, the flame core is larger and the quenching effect is smaller, so reliable ignition can be expected, but if the gap is too wide, a large ...
  55. [55]
    Ignition coil – checking, measuring, faults - forvia hella
    The opening induction voltage of the primary winding is between 300 and 400 V. The high voltage on the secondary coil can be up to 40 kV, depending on the ...<|separator|>
  56. [56]
    What are the Parts of a Spark Plug? | Champion Auto Parts
    A ceramic insulator separates the electrode from the rest of the spark plug. The plug is screwed into the cylinder head and protrudes into the combustion ...Missing: 0.7-1.1 mm
  57. [57]
    DENSO explains spark plug technology
    Dec 6, 2022 · The ceramic-based insulator (item 3) provides electrical insulation between the terminal, centre shaft, housing and centre electrode. With spark ...<|separator|>
  58. [58]
    Spark plug gap settings
    What are the conventional spark plug gap settings? · Racing Plugs 0.016" 0.4mm · Coil (Standard) 0.025" 0.6mm · Coil (Sports) 0.028" / 0.032" 0.7/0.8mm · Magneto ...
  59. [59]
    The Evolution of Ignition Systems in Automotive Engineering
    Early in the 20th century, the hightension magneto ignition system was introduced, marking a major improvement in performance and dependability. Magneto ...
  60. [60]
    Clemson Vehicular Electronics Laboratory: Electronic Ignition
    Ignition systems have evolved over the years from magneto systems to digital electronic systems. Magneto ignition systems are the simplest form of ignition ...
  61. [61]
    The Evolution Of Ignition - Road & Track
    May 31, 2013 · In the early days, magnetos were used to provide the pulses of electricity for the spark because they didn't require a battery or other ...
  62. [62]
    Characterization of erosion and failure processes of spark plugs ...
    Current spark plug lifetimes are on the order of only 1000–4000 h, which results in loss of performance and necessitates frequent costly downtime for the plug ...Missing: sparks | Show results with:sparks
  63. [63]
    How Long Will My Iridium Spark Plugs Last? - NGK.com
    Therefore, NGK gives them a life expectancy of 40-50k miles and Denso assigns a recommended replacement interval of 30k miles. OE Iridium Long Life Plugs NGK ...
  64. [64]
    Spark Plug replacement - All you need to know from the experts at ...
    Dec 11, 2014 · The estimated mileage of standard nickel spark plugs is between 30,000 and 45,000 km, platinum spark plugs around 70,000 km, and double platinum ...
  65. [65]
    Gapping and Indexing - NGK Spark Plugs
    The voltage requirement is directly proportional to the gap size. The larger the gap, the more voltage is needed to jump the gap. Most experienced tuners know ...
  66. [66]
    Racing Spark Plugs - Engine Builder Magazine
    Mar 27, 2017 · One spark plug manufacturer said a good way to determine the ideal plug gap for an engine is to start out with a modest gap of around .035˝and ...
  67. [67]
    Mind the Gap: Spark Plug Preventive Maintenance
    A spark plug with a 0.020-inch gap must be able to handle around 14,000 volts and fire reliably during its lifespan.
  68. [68]
    How SPDs work | NEMA Surge protection Institute
    SPDs limit overvoltages by diverting surge currents, reducing transients to prevent damage to equipment, similar to a pressure relief valve.
  69. [69]
    Complete overview of lightning arresters (part 3)
    Jul 2, 2018 · Types of Lightning Arresters for outdoor application · (1) Rod gap arrester · (2) Horn gap arrester · (3) Multigap arrester · (4) Expulsion type ...
  70. [70]
  71. [71]
  72. [72]
    Response Time of Surge Protective Devices With Spark Gap ...
    Response time of spark gap SPDs is ~70ns for lightning, but can be ~3000ns for switching transients, exceeding the declared 100ns.
  73. [73]
    [PDF] Surge Arresters and Switching Spark Gaps - TDK Electronics
    Surge arresters are gas-filled devices that act as voltage-dependent switches, used for surge protection in telecom and power lines.
  74. [74]
    Citel's VG Technology - CITEL Surge Protection
    Several technologies exist on the market for AC or DC power surge protection: • Metal Oxide Varistor (MOV) • Triggered Spark Gap • MOV + Gas-filled Spark Gap ( ...
  75. [75]
    A brief history of AC surge arresters | IEEE Journals & Magazine
    Since the beginning of AC transmission, approximately 100 years ago, lightning protection of transmission equipment has been provided by gaps and by nonlinear
  76. [76]
    How Does Spark Gap Transmitter Work: Operation - Electronics Notes
    A spark gap acts within a transmitter as an electronic switch. When it has not fired, it forms an open circuit with a very high resistance.
  77. [77]
    Spark Transmitter - Engineering and Technology History Wiki
    Sep 28, 2015 · One characteristic of the spark tramitter was its ability to produce a lot of unwanted interference (in todays crowded bands where spectrum ...
  78. [78]
    Early Radio Tech - Flying the Beams
    By the late 1960's the transistor had displaced the vacuum tube for most electronic applications, the same way the latter had banished spark gaps and crystals a ...<|control11|><|separator|>
  79. [79]
    Sounds of a Spark Transmitter - Hammond Museum of Radio
    Dec 22, 1994 · The first wireless transmissions (1888-1905) employed spark technology. Marconi systems were based on spark technology. Fessenden recognised ...
  80. [80]
    [PDF] How spark-gap transmitters worked - UVARC Shack
    In 1906, German physicist Max Wien devised a new kind of spark gap that suppressed the signal from the primary transmission, called the quenched gap, made from ...
  81. [81]
    [PDF] IS 1876 (2005): Voltage Measurement by Means of standard air gap
    The sphere-gap shall be connected in accordance with the requirements specified in. IEC 60060-2. 4.3.1. Earthing. (1'te sphere normally shall be connected.
  82. [82]
  83. [83]
  84. [84]
    [PDF] measurement of air breakdown voltage and electric field using ...
    Air breakdown voltage changes for a given humidity change increase with gap ... This work investigates the influence of humidity on the AC breakdown voltage and.
  85. [85]
    Trigatron Spark Gaps | Semantic Scholar
    Triggered gas switches increase the reliability of pulsed power systems. In particular, the performance of high power, repetitively rated impulse generators ...
  86. [86]
    [PDF] development of a hermetically sealed, high energy trigatron switch ...
    The principal advantages of spark gaps are their fast tum on time, good current handling capability, wide operating voltage range, and acceptable pulse ...
  87. [87]
    Triggered Spark Gap Switch with Gas Circulation for Repetitively ...
    A column type set of spark gap switches for 12-stage 5 kJ Marx generator repetitively operated with rep-rate of up to 10 pps was designed and constructed.
  88. [88]
    [PDF] Dissecting Time... A review of the development of ultra high-speed ...
    The famous milk drop picture by Harold Edgerton ... Total time window. 2 microseconds with 100 um slit. Triggered spark gap at 50 Mfps with 10ns exposures.
  89. [89]
    Air-gap strobe | MIT Museum
    Very high-speed photographs, like those of bullets in flight, are made with a microflash. A high-voltage spark sent into the flash tube causes an arc of ...
  90. [90]
    How Bug Zappers Work | HowStuffWorks - Home and Garden
    May 2, 2024 · The makers of this product say that blocking the insect's ability to "smell" carbon dioxide reduces the number of mosquito landings and bites.<|separator|>
  91. [91]
    Why Don't Bug Zappers and Fly Swatter Bats Kill Humans?
    The high voltage charge instantly flows through it causing it to burst with a spark. Mosquito Killer Racket Circuit Diagram.
  92. [92]
    Welding system toroidal spark gap method and system - Illinois Tool ...
    Nov 22, 2011 · A spark gap device is described such as for use in welding systems. The device receives a high voltage, low current input signal and ...<|separator|>
  93. [93]
    Methods of Arc Initiation and Maintenance | Welding
    When the electrode is withdrawn it results in sparking and ionisation of the gap between the electrode and the workpiece. If the arc is not initiated at the ...
  94. [94]
    [PDF] Section 6 Particulate Matter Controls
    An electrostatic precipitator (ESP) is a particle control device that uses electrical forces to move the particles out of the flowing gas stream and onto ...
  95. [95]
    Electrostatic Precipitation (ESP) Factors - PPC AIR
    Sparking is a normal phenomena where the current of the high voltage areas rushes to a grounded surface. Normal spark rates are less than 100 sparks per minute.
  96. [96]
    Cold plasma sterilization devices and associated methods
    Adjustable spark gaps provide the opportunity to adjust the output of the unipolar high voltage power supply and the intensity of the cold plasma device to ...
  97. [97]
    Cold atmospheric argon plasma jet source and its application for ...
    Apr 26, 2019 · The bactericidal properties of low-current spark discharge plasma jets were studied for their effects on the E. coli strains. Figure 2 shows a ...
  98. [98]
    [PDF] EMP Simulators for Missiles and Airplanes - DTIC
    Feb 4, 2025 · The simulator was modified to eliminate as much of the lower bicone as possible. Ideally, the feed-point, which is a pressurized spark gap,.
  99. [99]
    Full article: Review of Spark Discharge Generators for Production of ...
    The process provides continuous synthesis of nanoparticles with controlled size, a narrow size distribution, high crystallinity, and good stoichiometry (Okuyama ...
  100. [100]
    Synthesis of Nanoparticles by Spark Discharge as a Facile ... - NIH
    Jan 18, 2021 · Spark discharge synthesis is a simple and versatile method for producing nanoparticles, since it requires only gas, electrodes, and electricity.Missing: post- | Show results with:post-