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Thorium dioxide

Thorium dioxide (ThO₂) is the chemical compound formed by thorium and oxygen, manifesting as a dense, white, crystalline powder with a high melting point of approximately 3390 °C, a density of 9.7 g/cm³, and insolubility in water.^[1]^[2] Its exceptional thermal and chemical stability, coupled with a high refractive index, have enabled applications in refractories, ceramics, and optical materials, while its role as a fertile nuclear material—convertible to fissile uranium-233 via neutron irradiation—positions it as a candidate for advanced reactor fuels with potential for efficient breeding and minimized transuranic waste.^[3]^[4] However, thorium dioxide's inherent radioactivity from the thorium-232 decay chain renders it hazardous, classified as toxic via ingestion, inhalation, or dermal contact, and a carcinogen capable of inducing organ damage and malignancies through prolonged alpha-particle exposure.^[5]^[6] A defining controversy arose from its medical deployment as Thorotrast, a colloidal suspension used as a radiographic contrast agent from the 1930s to 1950s, which bioaccumulated in the reticuloendothelial system and precipitated excess liver cancers and leukemias decades later due to inescapable internal irradiation.^[7]^[8] These risks, alongside proliferation-resistant attributes in the thorium fuel cycle, underscore ongoing debates over its viability versus established uranium technologies.^[9]

Chemical and physical properties

Crystal structure and lattice parameters

Thorium dioxide (ThO₂) crystallizes in the cubic fluorite structure with space group Fm\overline{3}m (No. 225).^[10] In this arrangement, Th⁴⁺ cations occupy the corners and face centers of the cubic unit cell, each coordinated by eight O²⁻ anions in a body-centered cubic geometry, while the anions form a simple cubic sublattice.^[10] The experimental lattice parameter a for single-crystal ThO₂ is 5.596(4) Å, reflecting the large ionic radius of Th⁴⁺ (approximately 1.05 Å) which expands the unit cell relative to lighter actinide or lanthanide dioxides.^[11] Defect structures in ThO₂, particularly oxygen vacancies, significantly influence its properties, including ionic conductivity. These vacancies arise intrinsically at high temperatures or through aliovalent doping (e.g., with Y₂O₃ or Ln₂O₃), creating charge-compensating anion sites that facilitate oxygen ion migration via a vacancy mechanism.^[12] First-principles calculations confirm that charged oxygen vacancies in ThO₂ have formation energies around 5-7 eV depending on Fermi level position, lower than in undoped perfect lattices, enabling applications in solid electrolytes when vacancy concentrations are optimized.^[13] ThO₂ shares its fluorite structure with cerium dioxide (CeO₂), both exhibiting face-centered cubic lattices but with ThO₂ possessing a larger a ≈ 5.60 Å versus CeO₂'s ≈ 5.41 Å due to the greater Th⁴⁺ radius.^[14] This structural isomorphism allows empirical parallels in defect engineering and doping behavior, though ThO₂ demonstrates superior thermal stability and resistance to radiation-induced amorphization compared to CeO₂, attributed to stronger Th-O bonds and higher melting point.^[15] Such similarities underpin ThO₂'s use as a surrogate for nuclear fuels in materials testing.^[15]

Thermal and mechanical properties

Thorium dioxide (ThO₂) possesses a low specific heat capacity of approximately 0.23 J/g·K at room temperature, as reported across multiple experimental determinations ranging from 0.223 to 0.269 J/g·K.^[16] This value, combined with its high melting point exceeding 3300 °C, enables efficient heat dissipation in high-temperature applications, though thermal conductivity decreases with temperature, measured at 20.8 W/m·K for bulk material at ambient conditions.^[17] ^[18] The material's linear thermal expansion coefficient is notably low, approximately 8–10 × 10⁻⁶ K⁻¹ over a wide temperature range up to 2100 °C, which minimizes dimensional changes under thermal cycling and confers superior thermal shock resistance compared to many other oxides.^[19] This property arises from its rigid fluorite crystal structure, empirically verified through high-temperature X-ray diffraction, making ThO₂ suitable for environments involving rapid temperature gradients without cracking.^[19] Mechanically, dense ThO₂ ceramics exhibit Vickers hardness values around 9–10 GPa, dependent on sintering conditions and density, with higher values achieved in vacuum or reducing atmospheres that limit oxygen vacancies.^[20] ^[21] Fracture toughness, assessed via indentation techniques on high-density samples, is typically 1–2 MPa·m¹/², reflecting brittle ceramic behavior but adequate for structural integrity under compressive loads in refractory uses.^[20] ^[22] Under neutron irradiation, ThO₂ demonstrates high radiation tolerance, with minimal lattice swelling—unit cell expansion limited to about 0.10% at room temperature—attributed to its chemical stability and lower fission gas retention compared to uranium dioxide (UO₂), which shows greater volumetric changes exceeding 0.15% under similar fluxes.^[23] ^[24] This reduced swelling, observed in surrogate irradiation studies, positions ThO₂ as resilient in nuclear-relevant high-stress thermal and radiation environments, with defect recovery upon annealing further preserving mechanical integrity.^[23] ^[24]

Chemical reactivity and stability

Thorium dioxide (ThO₂) demonstrates remarkable chemical inertness, primarily due to the stability of the Th⁴⁺ oxidation state and strong ionic Th-O bonds in its fluorite lattice. Unlike uranium dioxide, which can exhibit variable oxidation states leading to redox reactivity, ThO₂ lacks stable lower oxides, rendering it resistant to oxidation or reduction under ambient conditions. This fixed +4 valence for thorium precludes facile electron transfer, contributing to its use in high-temperature applications where chemical durability is paramount.^[25]^[26] The compound exhibits extremely low solubility in water, with a solubility product constant (K_{sp}) on the order of 10^{-50} to 10^{-53} at standard conditions, resulting in hydrolysis that is negligible even in aqueous environments. This insolubility persists across a wide pH range, with minimal dissolution in neutral or alkaline media and only slight reactivity in concentrated acids, underscoring its thermodynamic stability derived from high lattice energy.^[27]^[28] Reduction of ThO₂ to thorium metal proceeds via calciothermic or magnesiothermic processes at elevated temperatures above 1000°C, as exemplified by the reaction ThO₂ + 2Ca → Th + 2CaO, which leverages the high affinity of calcium for oxygen to overcome the refractory nature of ThO₂. Such pathways highlight the kinetic barriers to reduction, requiring both thermal activation and strong reductants due to the endothermic bond breaking in the stable Th-O framework.^[29]^[30] Raman spectroscopy further corroborates the bond strength, featuring a characteristic F_{2g} mode at approximately 465 cm⁻¹ corresponding to symmetric Th-O stretching vibrations, indicative of robust ionic-covalent character and high vibrational frequencies consistent with elevated bond dissociation energies exceeding those of analogous actinide oxides.^[31]^[32]

Occurrence and production

Natural abundance and mineral forms

Thorium dioxide occurs in nature as the rare mineral thorianite (ThO₂), a cubic oxide typically found as black to brownish-black crystals or grains with a submetallic luster and Mohs hardness of 6.5–7. Thorianite forms in granitic pegmatites, alkali-rich igneous rocks, and placer deposits derived from their weathering, often associated with other heavy minerals.^[33]^[34] The majority of terrestrial thorium, from which thorium dioxide can be concentrated, resides in accessory minerals such as monazite ((Ce,La,Nd,Th)PO₄), a phosphate that incorporates 3–12% ThO₂ by weight, with some varieties reaching up to 20–30%. Monazite occurs primarily in placer sands, vein deposits, and as a detrital component in granitic and metamorphic rocks, reflecting thorium's geochemical affinity for phosphate complexes during magmatic differentiation.^[35]^[36] Other thorium-bearing minerals include thorite (ThSiO₄), a metasilicate found in similar igneous and sedimentary contexts.^[35] Thorium exhibits a crustal abundance of approximately 6 parts per million by weight, rendering it about three to four times more prevalent than uranium and comparable to lead.^[37]^[38] Worldwide identified thorium resources total an estimated 6.4 million metric tons, predominantly in monazite-rich placer deposits; significant concentrations occur in India, Australia, Brazil, and the United States, with these nations accounting for a substantial share of recoverable resources.^[35] Naturally occurring thorium consists almost entirely of the isotope ²³²Th (>99.98%), whose long half-life (1.4 × 10¹⁰ years) contributes to its persistence in the geosphere without significant isotopic fractionation.^[4]^[38]

Extraction from monazite and other sources

Monazite sands, typically containing 3-12% thorium dioxide by weight along with rare earth elements (REEs), uranium, and phosphates, represent the principal commercial source for thorium extraction. The initial step involves acid digestion with concentrated sulfuric acid (93-98% H₂SO₄) at 220-250°C for 2-3 hours, employing an acid-to-monazite mass ratio of 1.5-2.0:1 to achieve near-complete decomposition of the mineral lattice into soluble thorium sulfate (Th(SO₄)₂), REE sulfates, and uranium sulfate, while leaving silica and other gangue insoluble.^[39]^[40] This process solubilizes over 95% of the thorium under optimized conditions, with mass balance indicating that 1 metric ton of monazite averaging 5% ThO₂ yields approximately 45-50 kg of thorium in solution after filtration and dilution of the leachate.^[41] The sulfate liquor is then processed for thorium separation, primarily via solvent extraction using 30% tributyl phosphate (TBP) in kerosene from a nitric acid-adjusted medium (1-3 M HNO₃), where thorium partitions preferentially into the organic phase with distribution coefficients exceeding 10, enabling >99% extraction in 2-3 counter-current stages while rejecting most REEs to the aqueous raffinate.^[42]^[43] Stripping of the loaded organic phase occurs with dilute acid or water, recovering thorium at concentrations suitable for downstream precipitation. Alternative extractants like primary amines (e.g., Primene JM-T) or D2EHPA have been tested for sulfate systems, offering comparable efficiencies but with selectivity tuned to matrix composition.^[44]^[45] Thorium recovery from the strip solution proceeds by precipitation as thorium oxalate (Th(C₂O₄)₂·2H₂O) using oxalic acid at pH 1-2 and temperatures of 40-70°C, yielding precipitates with initial purities of 90-92% ThO₂ equivalent after filtration and washing, as REE coprecipitation is minimized by prior extraction.^[46] Calcination of the dried oxalate at 600-800°C dehydrates and decomposes it to ThO₂, with overall process efficiencies from monazite to oxide reaching 90-95% thorium recovery.^[47] Alkali digestion with 40-50% NaOH at 140-160°C serves as an alternative for high-grade monazite (>6% ThO₂), producing insoluble thorium-REE hydroxides separable by dissolution in acid, though sulfuric acid methods predominate due to higher throughput and lower reagent costs.^[41] Global extraction remains limited, with annual ThO₂-equivalent production estimated at around 50 tons as of 2025, derived mainly as a byproduct of REE processing from monazite in India, Australia, and Brazil; other thorium-bearing minerals like thorianite (up to 70% ThO₂) are rarely exploited commercially due to low abundance and similar processing requirements.^[4] Mass balances in industrial flowsheets account for uranium coproduction (0.1-0.3% of monazite) via prior amine extraction and REE fractionation, enhancing economic viability despite thorium's niche demand.^[48]

Purification and synthesis methods

High-purity thorium dioxide (ThO₂) exceeding 99.9% is refined through solvent extraction techniques to separate thorium from contaminants like uranium, iron, and rare earths, followed by precipitation as thorium oxalate or hydroxide and subsequent calcination.^[45] ^[49] In industrial processes, thorium nitrate tetrahydrate (Th(NO₃)₄·4H₂O) is commonly calcined at approximately 600°C to decompose the precursor into crystalline ThO₂, yielding powders suitable for nuclear applications with controlled particle morphology.^[50] For nuclear-grade material, purification emphasizes reducing uranium impurities to levels below 10 ppm to limit neutron absorption and isotopic interference in breeding U-233 from Th-232.^[51] Other elemental impurities, such as rare earths and transition metals, are similarly constrained to parts-per-million thresholds via multi-stage extraction using agents like di-2-ethylhexyl phosphoric acid (D2EHPA).^[45] Laboratory-scale synthesis variants, such as sol-gel methods, employ thorium salts like Th(NO₃)₄ with complexing agents (e.g., 6-aminocaproic acid) to form gels that, upon calcination, produce nanostructured or macro-microporous ThO₂ nanoparticles with enhanced sinterability for advanced fuel fabrication.^[52] ^[53] Hydrothermal routes, involving aqueous reactions of thorium precursors at elevated temperatures and pressures, similarly yield high-surface-area nanoparticles, offering finer control over purity and morphology compared to bulk precipitation-calcination but at lower throughput.^[54] These methods prioritize homogeneity and minimal residual nitrates or oxalates, verified through techniques like X-ray diffraction and inductively coupled plasma analysis.^[50]

Historical development

Discovery and initial characterization

Jöns Jacob Berzelius discovered thorium in 1828 while analyzing a sample of a black mineral, later named thorite (ThSiO₄), collected by Norwegian mineralogist Morten Thrane Esmark from Løvøya Island. Berzelius identified the presence of a new element through chemical separation from associated rare earths and silica, naming it thorium after Thor, the Norse god of thunder, to reflect its powerful chemical properties.^[55]^[56]^[57] The initial isolation of thorium dioxide, termed thorina, involved dissolving the mineral in hydrochloric acid, precipitating thorium as a double sulfate or fluoride to separate it from impurities, and then igniting the resulting salt at high temperature to yield the pure white oxide. This ignition process exploited the thermal decomposition of thorium compounds into stable ThO₂, producing a heavy, infusible powder resistant to fusion under ordinary flames. Berzelius characterized the oxide as chemically similar to zirconia and yttria but distinct in its atomic weight and reactivity, establishing its identity through precipitation tests and solubility behaviors.^[58] In the 1850s, further empirical characterization included measurements of thorium dioxide's density, reported around 9.7–10 g/cm³ depending on preparation purity, reflecting its compact fluorite-like structure. Early attempts to determine its melting point confirmed an exceptionally high value exceeding 3000 °C, observed via resistance to fusion in oxyhydrogen flames, underscoring its refractory nature. The elemental status of thorium was corroborated in the mid-19th century through spectral analysis, revealing unique emission lines distinct from other rare earths, as demonstrated by early spectroscopists like Robert Bunsen.^[55]

Early commercial exploitation

The primary early commercial application of thorium dioxide (ThO₂) emerged in the production of incandescent gas lamp mantles, developed by Austrian chemist Carl Auer von Welsbach. Initially experimenting with rare earth oxides in 1884, Welsbach patented a thorium-inclusive mantle in 1889 (US Patent 399,174), refining the composition by 1891 to approximately 99% ThO₂ and 1% cerium dioxide for superior incandescence and structural integrity when heated. This innovation enabled brighter, more efficient gas lighting, supplanting earlier magnesium oxide versions and driving widespread adoption in households and streets across Europe and North America by the mid-1890s.^[59] Commercial production scaled rapidly, with ThO₂ accounting for nearly all thorium consumption at the turn of the century, comprising 92% of nonfuel uses by 1902. Derived from monazite sands processed into thorium nitrate then calcined to oxide, the material was primarily sourced from imports via India, a major monazite producer, alongside Brazil. (Note: USGS historical data confirms early reliance on Indian monazite for mantle-grade thorium.) Peak demand occurred in the 1920s, as electric lighting displaced gas but camping, industrial, and developing-market uses sustained output; U.S. firm Welsbach Gas Light Company alone manufactured up to 250,000 mantles daily at its height, contributing to global production in the billions of units over the era.^[60] Concurrently, by the early 1900s, ThO₂ found niche use in refractory crucibles owing to its exceptionally high melting point of 3,300°C and chemical inertness, enabling high-temperature laboratory and metallurgical applications where graphite or platinum failed. These crucibles, often pure ThO₂ or blended for density, represented a minor but specialized market segment predating broader ceramic adoption.^[61]

Post-WWII nuclear research involvement

Following World War II, thorium dioxide (ThO₂) emerged as a key material in U.S. state-sponsored nuclear research, particularly as a fertile oxide for breeding fissile uranium-233 (²³³U) in thermal-spectrum reactors. In the late 1940s and 1950s, the Atomic Energy Commission (AEC) initiated programs evaluating ThO₂ alongside uranium fuels, driven by its abundance and potential to extend fuel resources through breeding. Early tests focused on ThO₂-UO₂ mixtures in light-water designs, but uranium-plutonium cycles gained precedence due to established reprocessing infrastructure from wartime plutonium production, which favored fast-spectrum breeders over thorium's thermal breeding path.^[4]^[24] The Molten Salt Reactor Experiment (MSRE) at Oak Ridge National Laboratory (ORNL), conducted from 1965 to 1969, represented a pivotal state-sponsored effort to validate thorium-based molten-salt technology. This 7.4 MWth prototype used a lithium-beryllium fluoride salt incorporating thorium tetrafluoride (derived from ThO₂ processing) as the fertile component, achieving initial criticality with uranium-235 in 1965 before transitioning to bred ²³³U fuel in 1968. Over 13,000 hours of operation, it demonstrated stable thorium breeding, graphite compatibility, and a fuel burnup exceeding 7.4 GWd/MT, with no major corrosion issues in Hastelloy-N alloys, though tellurium-induced cracking required mitigation. These results affirmed ThO₂'s viability in liquid-fuel systems but highlighted challenges like salt chemistry control.^[62]^[63] In the 1970s, the Shippingport Atomic Power Station's Light Water Breeder Reactor (LWBR) core trials further tested ThO₂ in a seed-blanket configuration. Loaded in 1977 and operational until plant decommissioning in 1982, this 60 MWe core employed highly enriched ²³³U "seed" elements surrounded by ThO₂ blanket pellets to breed additional fissile material in pressurized light water. It achieved a net breeding ratio of approximately 1.01, producing over 2,300 MWd of thorium-burned energy and validating ThO₂'s neutronic performance, though fabrication costs and ²³³U handling complexities limited scalability. Outcomes indicated partial success in demonstrating closed thorium cycles but underscored integration hurdles with existing uranium-dominated infrastructure.^[64]^[4] Post-1970 deemphasis of thorium research stemmed from a strategic pivot to plutonium-fueled liquid metal fast breeder reactors (LMFBRs), as prioritized by the AEC and later Energy Research and Development Administration. This shift, formalized in the 1970s, aligned with abundant uranium-238 stocks and plutonium recycling from light-water reactors, rendering thorium's reprocessing demands uneconomical amid ample uranium supplies projected through the century. Consequently, ThO₂-focused programs like ORNL's molten-salt efforts were curtailed by 1976, subordinating thorium to uranium's entrenched fuel cycle dominance.^[24]^[4]

Nuclear applications

Role in thorium fuel cycle

In the thorium fuel cycle, thorium dioxide (ThO₂) functions as the primary fertile material, with its thorium-232 isotope (comprising virtually all natural thorium) capturing thermal neutrons to initiate the breeding process. The neutronics proceed as follows: Th-232 undergoes radiative capture to form Th-233, which beta-decays (half-life 22 minutes) to protactinium-233; Pa-233 then beta-decays (half-life 27 days) to fissile uranium-233. U-233 subsequently fissions upon absorbing another thermal neutron, releasing approximately 2.28 neutrons per absorption (η value), enabling chain reaction sustenance and excess neutron production for further breeding. This η exceeds that of plutonium-239 (~2.11 in thermal spectra), facilitating conversion ratios greater than 1 in thermal-spectrum systems without requiring fast neutrons.^[24]^[65] Experimental and design data from thorium molten-salt systems demonstrate breeding potential, with two-fluid configurations achieving conversion ratios of 1.07 to 1.08, as analyzed in Oak Ridge National Laboratory studies tied to the Molten Salt Reactor Experiment (MSRE) and subsequent Molten Salt Breeder Reactor (MSBR) concepts. These ratios indicate net fissile production, where more U-233 is generated than consumed per unit time, contrasting with uranium-plutonium cycles limited to ~0.6–0.7 in thermal reactors. Empirical measurements in zero-power thorium-uranium assemblies confirmed self-sustaining conversion under controlled conditions, supporting scalability to operational breeders.^[66]^[67]^[68] The cycle's waste profile features reduced transuranic production compared to uranium cycles, yielding primarily fission products and minimal plutonium or minor actinides like americium and curium, which dominate long-term radiotoxicity in plutonium-fueled systems. Actinide residues from thorium breeding, including U-232 (half-life 69 years) and its decay chain, exhibit shorter effective half-lives and lower alpha-emitter inventories, allowing radiotoxicity to decline more rapidly after initial decay (e.g., to levels manageable within centuries versus millennia for plutonium-actinide burdens). This stems from thorium's lighter nucleus producing fewer neutrons for higher-mass transuranic formation during fission.^[69]^[70]^[9] U-233 fission efficiency empirically supports ~1% higher energy yield per metric ton of thorium processed versus equivalent uranium cycles, attributable to superior neutron economy and near-complete fertile utilization in closed-loop reprocessing, as validated in burnup simulations and historical irradiations.^[71]^[72]

Use in experimental and prototype reactors

The AVR (Arbeitsgemeinschaft Versuchs-Reaktor), an experimental 46 MWth pebble-bed high-temperature gas-cooled reactor in Jülich, Germany, tested ThO₂-UO₂ mixed oxide fuels during operations from the 1970s to 1988. These trials involved fuel pebbles with thorium oxide blended with uranium oxide, demonstrating burn-up levels exceeding 100 GWd/t and operational stability under high-temperature conditions up to 950°C core outlet temperature.^[73]^[24] India's Advanced Heavy Water Reactor (AHWR) design, developed by the Bhabha Atomic Research Centre, incorporates ThO₂-PuO₂ mixed oxide fuel pins in a 300 MWe vertical pressure-tube configuration with boiling light-water cooling and heavy-water moderation. Optimized for thorium utilization, the prototype concept targets (Th,Pu)O₂ fuel achieving burn-ups of 30-60 GWd/t, with design completion reported in 2014 and emphasis on passive safety features like natural circulation.^[74]^[75] China's TMSR-LF1, a 2 MWt experimental molten salt reactor prototype operational since 2023, achieved online refueling of its thorium-based fluoride salt fuel in April 2025 without shutdown, marking a first for liquid thorium cycles derived from ThO₂ processing. This test validated continuous fuel addition and fission product removal in a thorium environment at temperatures around 650-700°C.^[76]^[77]

Comparative advantages over uranium fuels

Thorium dioxide (ThO₂) exhibits a higher melting point of approximately 3300°C compared to uranium dioxide (UO₂) at around 2860°C, which enhances fuel stability under extreme temperatures and reduces the risk of meltdown in reactor accidents by maintaining structural integrity longer during overheating events.^[78]^[79] This thermophysical advantage stems from ThO₂'s superior refractory properties, allowing it to withstand higher thermal loads without phase changes that could compromise cladding or core geometry in light-water or other reactor designs.^[24] Global thorium resources are estimated to be three to four times more abundant than uranium reserves on an identified basis, with thorium concentrations in the Earth's crust averaging 6 parts per million versus 2.7 parts per million for uranium, providing a more secure long-term fuel supply independent of enrichment bottlenecks associated with U-235 scarcity.^[71]^[80] The U.S. Geological Survey identifies substantial thorium potential in monazite sands and other deposits, often recoverable as byproducts from rare earth mining, contrasting with uranium's reliance on dedicated orebodies subject to geopolitical extraction constraints.^[80] In the thorium fuel cycle, neutron economy favors breeding uranium-233 from thorium-232 with minimal production of transuranic elements like plutonium and americium, resulting in spent fuel containing less than 1% long-lived actinides by mass compared to 5-10% in conventional uranium-plutonium cycles, thereby shortening radiological hazard durations from millennia to centuries.^[24]^[9] This reduction arises causally from U-233's fission yielding fewer neutrons captured by heavy nuclei, limiting higher-isotope buildup, as modeled in thermal spectrum reactors and validated through limited irradiations in prototypes like the Shippingport core experiments.^[24] Such waste characteristics challenge claims of equivalence by demonstrating empirically lower separation needs for minor actinides, though full-scale deployment data remains pending.^[24]

Non-nuclear applications

Gas lamp mantles and incandescent materials

Thorium dioxide served as the primary material in gas lamp mantles, enabling bright incandescence when heated by a gas flame to produce efficient white light for illumination. These mantles were fabricated by impregnating a knitted fabric, typically cotton or artificial silk, with a solution of thorium nitrate and cerium nitrate, then drying and shaping it into a conical form. Upon initial ignition, the organic binder and nitrates decomposed, leaving a brittle network of thorium dioxide (ThO₂) and cerium dioxide (CeO₂) that glowed intensely at temperatures exceeding 1700°C.^[81]^[59] The standard composition comprised approximately 99% ThO₂ and 1% CeO₂ by weight after calcination, a ratio optimized through empirical testing to maximize luminous efficacy. Pure ThO₂ emits a yellowish light due to its blackbody radiation spectrum favoring longer wavelengths, but CeO₂ doping forms a solid solution that modifies the electronic structure, enhancing visible emission (particularly in the blue-green range) while suppressing infrared output, resulting in whiter, more efficient luminescence with reduced fuel use. This incandescence arises from thermal excitation of electrons in the oxide lattice, not fluorescence, allowing sustained high-temperature operation without structural failure.^[82]^[83]^[84] Introduced commercially in 1885 by Austrian chemist Carl Auer von Welsbach, ThO₂-based mantles rapidly displaced flame-based lighting in urban and rural settings, powering street lamps, households, and industrial applications through the early 20th century. Usage peaked from the 1910s to 1940s amid widespread gas infrastructure, with U.S. thorium production reaching levels where 65% was allocated to mantles by 1952, supporting millions of units annually for both stationary and portable lanterns.^[81]^[59] The post-World War II rise of electric lighting grids diminished demand for gas mantles in permanent fixtures, as electrification provided superior convenience and reliability in developed regions. Residual applications persisted in off-grid contexts, such as camping and remote area lanterns, where the high light output per fuel volume remained advantageous until alternatives emerged.^[81]^[59]

Catalysts in chemical processes

Thorium dioxide (ThO₂) exhibits catalytic activity in heterogeneous processes due to its robust fluorite crystal structure, which provides a stable surface for adsorption and reaction intermediates under high-temperature conditions. Its melting point of approximately 3390°C enables operation at temperatures above 500°C without significant sintering or loss of activity, making it suitable for demanding industrial environments where other oxides degrade.^[85]^[86] In petroleum refining, ThO₂ has been utilized as a component in fluid catalytic cracking catalysts to facilitate the breakdown of heavy hydrocarbons into gasoline-range products, relying on acid-site surface chemistry for carbocation-mediated cracking pathways. This application exploits ThO₂'s ability to maintain porosity and dispersion in zeolite-supported systems at process temperatures around 500–550°C.^[87] Historical formulations incorporated ThO₂ to enhance thermal endurance, though modern zeolitic catalysts have largely supplanted it.^[88] ThO₂ also functions as a promoter in mixed-oxide catalysts for oxidation reactions, such as the aerobic selective oxidation of alcohols to aldehydes or ketones, where it stabilizes active metal sites (e.g., nickel-manganese oxides) and improves resistance to deactivation. In such systems, selectivity toward desired products can exceed 95% at conversions above 90%, attributed to ThO₂'s influence on oxygen vacancy formation and electron transfer at the surface.^[89] For instance, ThO₂-doped nickel-manganese catalysts calcined at 400°C demonstrate sustained performance in benzyl alcohol oxidation, with minimal byproduct formation over multiple cycles.^[89] Industrial-scale deployment of ThO₂ in catalysis remains minor, with global consumption estimated at less than 10 metric tons annually, primarily as dopants or minor additives rather than primary active phases, due to availability of non-radioactive alternatives and regulatory constraints on thorium handling.^[87]^[90]

Refractories, ceramics, and optics

Thorium dioxide (ThO₂) is utilized in refractories for its superior thermal stability and melting point exceeding 3,300°C, enabling the fabrication of crucibles capable of containing molten metals at temperatures up to 2,000°C or beyond without significant degradation.^[91]^[92] These crucibles, often produced by casting or sintering ThO₂ powder, exhibit minimal reactivity with aggressive melts such as those of titanium or uranium, outperforming alternatives like graphite or zirconia in extreme conditions.^[93] Historical production methods involved mixing ThO₂ with binders like cryolite to reduce shrinkage during firing, yielding dense vessels for laboratory and industrial melting operations.^[61] In ceramics, ThO₂ serves as a key component for high-temperature structural materials, leveraging its chemical inertness and resistance to corrosion by hot water vapor or molten alloys, which is critical for applications in nuclear and aerospace environments.^[94] Sintered ThO₂ ceramics demonstrate low thermal expansion and high density, making them suitable for components enduring prolonged exposure to oxidative or reductive atmospheres at elevated temperatures.^[95] Additives such as zirconium oxide can enhance sinterability while preserving refractoriness, as documented in early formulations for crucibles and linings.^[96] For optics, ThO₂ functions as a robust host material in ceramic lasers due to its fluorite crystal structure, wide optical band gap (~6 eV), and mechanical hardness, positioning it as an analog to yttrium aluminum garnet (YAG) for doping with rare-earth ions.^[97]^[98] Composites like yttria-thoria (Yttralox) have been developed for high-peak-power laser rods, offering improved thermal shock resistance over pure oxide hosts.^[99] Its potential in optical components stems from low phonon interactions in doped variants, though practical deployment remains limited by radiotoxicity concerns.^[100]

Health, safety, and environmental impacts

Radiotoxicity and human exposure effects

Thorium dioxide (ThO₂) exhibits significant radiotoxicity primarily due to its alpha-emitting decay products from thorium-232, posing a high internal radiation hazard upon inhalation, ingestion, or injection, as alpha particles deliver intense localized damage to tissues while having low penetration in external exposure.^[5] Human exposure effects are dominated by long-term accumulation in organs such as the liver, spleen, bone, and lungs, leading to elevated cancer risks through chronic irradiation.^[101] Historical medical use of Thorotrast, a colloidal suspension of ThO₂ injected for radiographic contrast from the 1930s to 1950s, resulted in estimated cumulative absorbed doses to the liver of 10–50 Gy over decades, correlating with a markedly increased incidence of primary liver cancers including cholangiocarcinoma, hemangiosarcoma, and hepatocellular carcinoma—up to a 100-fold relative risk in exposed cohorts compared to unexposed populations.^[102]^[103] These effects stem from the insoluble particles' retention in reticuloendothelial tissues, where alpha emissions from thorium progeny (e.g., radium-228, actinium-228, thorium-228) induce DNA damage and fibrosis, with risk estimates indicating approximately 40 excess liver cancer cases per 10,000 person-Sv when accounting for alpha radiation weighting factors.^[103] Inhalation of ThO₂ dust represents a primary occupational exposure route, with animal studies demonstrating dose-dependent pneumoconiosis and fibrosis; for instance, rats exposed to 100% ThO₂ aerosols developed lung sclerosis within 3–6 months, progressing to malignant transformations at intermediate durations, underscoring the compound's fibrogenic and carcinogenic potential via particle-laden alpha irradiation of bronchial epithelium.^[104] Human data from limited cohorts, including radium dial workers and thorium processors, link chronic low-level inhalation to increased lung and pancreatic cancer incidences, though confounding co-exposures to other radionuclides complicate attribution.^[101] Regulatory exposure limits mitigate risks, with the OSHA permissible exposure limit (PEL) for ThO₂ set at 0.1 mg/m³ as an 8-hour time-weighted average for insoluble thorium compounds, reflecting conservative thresholds to prevent bioaccumulation and stochastic effects based on animal dosimetry and epidemiological extrapolations.^[105]

Historical incidents and epidemiological data

Thorotrast, a colloidal dispersion of thorium dioxide used as an intravascular radiographic contrast medium from approximately 1928 to 1955, resulted in widespread alpha-particle exposure due to its long biological half-life and retention in organs such as the liver, spleen, and bone marrow.^[101] Epidemiological cohorts tracking over 10,000 exposed patients across Denmark, Germany, Japan, Portugal, and Sweden documented excess mortality from liver malignancies, including intrahepatic cholangiocarcinoma and hepatic angiosarcoma (a soft-tissue sarcoma), with sarcomas frequently confirmed via histopathological examination at autopsy.^[106]^[107] These effects manifested with latencies of 20–40 years, attributable to chronic low-dose alpha irradiation, and included elevated risks of leukemia and other extrahepatic cancers, with standardized mortality ratios for liver cancer exceeding 100 in some subgroups.^[108] Over 2,000 cases of Thorotrast-associated sarcomas and carcinomas have been reported globally, establishing clear causality through dose-response correlations in alpha-particle dosimetry models.^[109]^[8] In contrast, exposure from thorium dioxide-impregnated gas lantern mantles, which emit alpha radiation during use but primarily involve low-level inhalation of thorium particulates during manufacturing or breakage, has not been linked to widespread excess cancer in consumer cohorts.^[104] Limited epidemiological data on mantle users, often extrapolated from proxy studies of low-dose thorium handlers, indicate no significant elevation in respiratory or other malignancies, consistent with the dilute, intermittent nature of exposure compared to injected Thorotrast.^[5] Cohort analyses of thorium refinery workers (n=3,039) with cumulative exposures showed standardized mortality ratios for lung cancer near unity (SMR 1.05–1.10), with no attributable excess in non-smokers after adjusting for confounders.^[104] Occupational exposures in thorium processing facilities, including those at sites like Oak Ridge National Laboratory, involved handling thorium dioxide ores and compounds, primarily via inhalation of aerosols.^[110] A mortality study of workers in a dedicated thorium-processing plant categorized exposures into low (0.1–0.5 Bq mean thorium lung burden), moderate (0.9–2.0 Bq), and higher groups, revealing no statistically significant increases in leukemia or overall cancer mortality; leukemia incidence remained below 1% above expected rates, with relative risks under 1.5 even in higher-exposure cohorts followed for decades.^[111] These findings align with broader Oak Ridge radiation worker data, where low-level thorium-associated doses correlated with minimal (<1% per 10 mSv) elevations in hematologic cancers after latency periods exceeding 20 years, underscoring that causality requires sustained high burdens as in Thorotrast cases rather than occupational thresholds observed.^[112]^[113]

Waste generation and ecological considerations

Mining and processing of thorium-bearing ores for thorium dioxide production generate tailings with lower radiological impacts compared to uranium ore tailings. A comparative analysis of fuel cycles indicates that thorium mining and milling result in dose commitments of 6.1–14 person-rem (whole body) per reactor year, significantly less than the 660 person-rem for uranium, primarily due to the shorter half-life of thorium's radon isotope (220Rn, 55.6 seconds) versus uranium's 222Rn (3.82 days), reducing long-term radon emanation hazards.^[114] In the thorium fuel cycle utilizing thorium dioxide, spent fuel produces lower volumes of long-lived radioactive waste than uranium cycles, with minimal transuranic elements and actinides like neptunium, americium, and curium, leading to reduced radiotoxicity—up to 30 times lower in certain accelerator-driven designs over 30,000 years.^[24] Reprocessing challenges include the need for protactinium-233 separation or one-year cooling to prevent decay losses to uranium-233, potentially increasing vitrified waste glass volume by 50–70% relative to PUREX processes due to corrosion-mitigating additives, though overall effluent radiotoxicity remains lower absent plutonium production.^[24] Ecologically, thorium dioxide's insolubility in water (forming stable hydroxo complexes like Th(OH)₄ at neutral pH) restricts aquatic mobility and release from waste sites, with soluble fractions adsorbing strongly to sediments and soils, limiting groundwater transport.^[5] Bio-uptake shows high bioconcentration factors in lower aquatic trophic levels (e.g., algae up to 9.75 × 10⁶, zooplankton 2 × 10⁴), but decreases with trophic transfer, accumulating primarily in fish gastrointestinal tracts without biomagnification to predators, thereby constraining ecological propagation.^[5]

Controversies and debates

Technological and economic hurdles

Thorium dioxide (ThO₂) fuel fabrication presents significant engineering challenges due to its high thermal stability, requiring sintering temperatures typically exceeding 1700°C to achieve dense pellets, compared to approximately 1400°C for uranium dioxide (UO₂).^[115]^[116] This elevated temperature demands specialized high-temperature furnaces and additives like Nb₂O₅ to lower the threshold to around 1150°C, yet undoped processes remain energy-intensive and prone to incomplete densification, elevating production costs over established UO₂ methods.^[116] Additionally, ThO₂'s chemical inertness complicates powder processing and pelletization, contributing to higher defect rates and reduced scalability in manufacturing.^[24] In molten salt reactors (MSRs) proposed for thorium cycles, corrosion of structural materials emerges as a persistent barrier, with experimental rates for alloys like Hastelloy-N reaching 10–20 µm/year in FLiBe salts at 650°C—often exceeding early predictions due to chromium depletion and tellurium-induced cracking.^[117] Historical tests, such as those from the Molten Salt Reactor Experiment, demonstrated feasibility with modified alloys, but thorium-specific operations introduce protactinium handling and online reprocessing needs that accelerate impurity buildup and localized attack, necessitating advanced coatings or alternative materials unproven at scale.^[67]^[118] Economically, thorium-based systems face unverified levelized costs of electricity (LCOE) projected at $0.05–0.07/kWh in modeling studies, potentially competitive with coal but undermined by absent commercial prototypes and high initial R&D investments for fuel cycle closure.^[119] Front-end hurdles, including thorium purification and fabrication premiums, combined with backend reprocessing complexities for ThO₂'s radiation resistance, inflate capital expenditures by 20–50% over uranium cycles without offsetting infrastructure like enrichment facilities.^[24]^[120] These factors, absent empirical large-scale validation, deter investor confidence despite theoretical fuel efficiency gains.^[121]

Proliferation risks versus safeguards

The thorium fuel cycle produces uranium-233 (U-233) as the primary fissile material through neutron capture on thorium-232 (Th-232), but this U-233 is inherently contaminated with uranium-232 (U-232) at levels typically exceeding 100-200 parts per million in reactor-produced material.^[24] U-232, with a half-life of 69 years, decays via thorium-228 (half-life 1.9 years) to thallium-208, which emits high-energy gamma rays at 2.6 MeV, rendering the material highly detectable by radiation sensors from distances of several meters and complicating any attempts at isotopic separation or weaponization due to damage to electronics and severe handling hazards.^[122] This gamma signature enables near-complete (over 99% effective) monitoring and safeguards verification, as even small quantities of diverted U-233 would produce unmistakable radiation profiles distinguishable from weapons-grade plutonium or highly enriched uranium.^[122] In contrast to the uranium-plutonium cycle, which generates significant plutonium-239 suitable for weapons, the thorium cycle minimizes plutonium production—often by factors of 100 or more—while yielding far lower quantities of other transuranic elements like americium and curium, reducing the overall long-lived actinide burden in spent fuel by up to two orders of magnitude compared to light-water reactors using enriched uranium.^[9] Empirical evidence from India's three-stage nuclear program, which incorporates thorium breeding in advanced heavy-water and fast reactors, demonstrates no recorded diversions of thorium-derived fissile material for non-peaceful uses despite decades of operation and fuel reprocessing activities, supporting claims of intrinsic proliferation resistance under international safeguards.^[123] Proliferation concerns persist among some analysts, often amplified in environmental and arms-control advocacy circles emphasizing worst-case diversion scenarios, yet these are countered by isotopic data showing the thorium cycle's self-safeguarding properties and empirical track records that prioritize verifiable reductions in weapons-usable material over unsubstantiated fears of equivalence to plutonium pathways.^[4] While U-233 can theoretically sustain a nuclear chain reaction in weapons (as demonstrated in historical low-yield tests), the radiation barriers necessitate specialized facilities for purification, elevating technical hurdles beyond typical state-level proliferators and aligning with assessments that thorium fuels pose lower diversion risks than conventional cycles.^[24]

Policy suppression claims and regulatory biases

Claims of policy suppression in thorium development often center on the United States' nuclear research trajectory in the mid-20th century, where the Atomic Energy Commission prioritized uranium-plutonium fast breeder reactors after the 1960s to align with plutonium production for military applications, sidelining thorium-based alternatives despite empirical successes like the Molten Salt Reactor Experiment (MSRE). The MSRE, operational from 1965 to 1969 at Oak Ridge National Laboratory, achieved over 13,000 hours of critical operation using molten salt fuels, including a thorium-derived uranium-233 cycle phase starting in 1968, without meltdown risks or major corrosion issues under tested conditions.^[124] However, program funding ended in 1973 amid a broader pivot to liquid-metal fast breeders, which converted uranium-238 to plutonium-239 more efficiently for both energy and weapons, reflecting strategic imperatives during the Cold War era when uranium infrastructure was already entrenched.^[125] Proponents, including advocates like Kirk Sorensen, attribute this to deliberate deprioritization favoring weapons synergy over civilian thorium paths, though causal analysis points to path dependence: early momentum in plutonium programs from Manhattan Project legacies outcompeted thorium's nascent research, which lacked comparable institutional backing.^[126] Internationally, non-proliferation frameworks such as the Nuclear Non-Proliferation Treaty (1968) and IAEA safeguards have emphasized uranium enrichment and plutonium reprocessing, treating thorium cycles as non-standard or "exotic" fuels requiring case-by-case verification, which has imposed additional compliance burdens on developers.^[69] This uranium-centric structure, rooted in the dominant fuel cycles of the 1970s, has arguably biased regulatory environments against thorium by not providing streamlined pathways, as evidenced by ongoing IAEA analyses acknowledging thorium's potential but highlighting adaptation challenges in safeguards.^[127] Recent U.S. examples include Department of Energy plans, initiated under the George W. Bush administration, to downblend or dispose of uranium-233 stockpiles—key starter material for thorium breeders—by 2025 to free storage space, prompting bipartisan legislation like the Thorium Energy Security Act of 2022 (S.4242) to mandate preservation for research.^[128]^[129] Such policies reflect systemic regulatory inertia favoring legacy waste management over alternative fuel R&D, though without evidence of overt suppression. Counterarguments frame these developments as market and investment failures rather than conspiratorial biases, emphasizing underfunding of thorium R&D relative to uranium paths, which left technical hurdles like online reprocessing unresolved despite MSRE proofs-of-concept.^[130] Historical commercial ventures incorporating thorium, such as the U.S. Fort St. Vrain high-temperature gas reactor (operational 1976–1989), suffered frequent fuel and equipment failures leading to closure, attributable to engineering complexities rather than policy fiat.^[131] Mainstream analyses, including those from nuclear engineering bodies, attribute thorium's marginalization to economic path dependence—decades of sunk costs in uranium supply chains and breeder pursuits amid perceived uranium shortages—over intentional throttling, with no declassified records substantiating weapons-driven sabotage claims.^[132] This view aligns with causal realism: proliferation-aligned incentives influenced choices, but broader R&D allocation failures, not regulatory malice, explain stalled progress, as evidenced by parallel abandonments of other breeders post-1980s due to uranium abundance from discoveries like Australia's deposits.^[125] Sources promoting suppression narratives, often from advocacy sites, contrast with peer-reviewed histories underscoring pragmatic trade-offs in resource-constrained programs.

Recent research and prospects

Advances in molten salt and advanced reactors

China's TMSR-LF1, a 2 MWth thorium-fueled molten salt reactor prototype, achieved a breakthrough in April 2025 by successfully refueling its liquid fluoride thorium salt core without requiring a shutdown, enabling continuous operation and demonstrating practical feasibility for online fuel management in molten salt systems.^[133]^[76] This advancement addresses longstanding challenges in molten salt reactor technology, such as maintaining criticality during fuel addition and fission product removal, and supports scalability toward commercial thorium-based designs.^[134] Advancements in ThO₂ fuel fabrication include nanopowder synthesis methods that optimize powder properties for reactor applications. A 2025 study examined various synthesis routes, finding that hydrothermal decomposition of thorium hydroxide yields powders with specific surface areas exceeding 100 m²/g, which improves packing density, sinterability under conventional and spark plasma sintering, and overall fuel pellet integrity for molten salt and solid-fuel reactors.^[135]^[50] Hybrid ThO₂-based fuels in Generation IV fast reactor concepts leverage thorium's high melting point (over 3300°C) and radiation resistance to achieve burnups exceeding 20% in fast spectra, enhancing fuel efficiency and transuranic transmutation while minimizing waste generation compared to traditional UO₂ fuels.^[72]^[136] These designs, such as those incorporating ThO₂ with plutonium or minor actinides, benefit from thorium's chemical stability, reducing fission gas release and supporting deeper burnup in sodium- or lead-cooled fast reactors.^[137]

Market trends and commercialization efforts

The global market for thorium dioxide, primarily driven by its use in nuclear fuels and ceramics, is projected to expand at a compound annual growth rate (CAGR) of 13.9% from 2025 to 2032, fueled by rising demand for advanced nuclear materials amid energy transition needs.^[138] Commercial-grade thorium dioxide production emphasizes high-purity forms for reactor applications, with earlier estimates indicating a market value approaching USD 1.5 billion by 2024 at a 9.2% CAGR, reflecting steady pre-commercial scaling.^[139] Demand for thorium-based fuels, including thorium dioxide formulations, aligns with the broader nuclear renaissance, where geopolitical disruptions such as Russia's 2022 invasion of Ukraine have heightened emphasis on energy security and diversified fuel supplies, boosting uranium prices and interest in alternatives like thorium.^[140] Climate imperatives further propel this trend, positioning nuclear power—including thorium cycles—as a dispatchable, low-carbon baseload option to complement intermittent renewables, with thorium's abundance offering long-term supply resilience compared to uranium.^[141] Key commercialization players include Clean Core Thorium Energy (CCTE), which in February 2025 raised USD 15.5 million in seed funding to advance its ANEEL fuel—a thorium dioxide blended with high-assay low-enriched uranium (HALEU)—targeting deployment in existing CANDU reactors by late 2025.^[142] CCTE achieved irradiation testing milestones at Idaho National Laboratory in August 2025, surpassing burnup records, and secured U.S. export authorization for ANEEL to India in September 2025, enabling potential integration into India's infrastructure.^[143]^[144] India's three-stage nuclear program, designed to leverage domestic thorium reserves exceeding 12 million tonnes, shows progress across stages as of mid-2025, with Stage II fast breeder reactors operationalizing plutonium breeding for eventual Stage III thorium utilization in advanced heavy water reactors.^[145]^[146] Market projections for thorium reactor technologies, encompassing thorium dioxide fuels, indicate potential scaling to USD 50 billion by 2040 under optimistic deployment scenarios supported by policy and licensing advancements, though actual nuclear fuel market penetration remains contingent on regulatory approvals and infrastructure investments.^[147] India's program targets thorium as a cornerstone for expanding capacity to 100 GW by mid-century, potentially elevating thorium's role in global nuclear fuels if international collaborations like CCTE's exports materialize.^[148]

Barriers to widespread adoption

The U.S. Nuclear Regulatory Commission (NRC) regulatory framework is primarily designed for uranium-plutonium fuel cycles, necessitating extensive revisions and new licensing processes for thorium dioxide-based fuels, which lack standardized codes and precedents.^[68] Licensing a novel nuclear reactor design, including those incorporating thorium dioxide, typically requires 10 to 15 years and costs exceeding $1 billion due to rigorous safety analyses, environmental reviews, and demonstration of fuel performance under diverse accident scenarios.^[149] This uranium-centric approach stems from decades of operational data accumulation for light-water reactors, leaving thorium cycles with insufficient validated models for proliferation resistance, waste handling, and neutronics, thereby prolonging approval timelines and deterring investment.^[69] Thorium supply chains remain underdeveloped, as commercial mining focuses on rare earth elements (REE) from monazite sands, treating thorium dioxide as a low-value radioactive byproduct rather than a primary resource. In Australia, which holds significant monazite deposits, government assessments project no large-scale thorium production or trade before 2030 without prior commercialization of thorium fuel cycles, due to processing priorities for REE amid global supply chain diversification efforts.^[150] Regulatory restrictions on exporting unprocessed monazite—driven by radioactivity controls and REE strategic value—further constrain thorium availability, with stockpiles accumulating but lacking dedicated extraction infrastructure.^[151] Thorium-based reactors offer dispatchable baseload power with high capacity factors exceeding 90%, contrasting with the intermittency of solar and wind sources that require backup or storage for grid stability.^[4] However, energy policies in jurisdictions like the European Union and United States disproportionately subsidize renewables—such as through the Inflation Reduction Act's $369 billion allocation favoring intermittent technologies—while imposing stringent, cycle-specific barriers on nuclear innovation, including thorium, thereby skewing market incentives against firm-capacity options despite empirical evidence of renewables' higher system integration costs.^[152] This policy tilt, rooted in rapid deployment preferences over long-term reliability data, exacerbates adoption hurdles by limiting R&D funding and public procurement for alternative dispatchable fuels like thorium dioxide.^[153]

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May 14, 2025 · 1828 Thorium was discovered by Morten Thrane Esmark on Lovoya Island in Norway. He sent the black mineral he found (later called thorite) to his ...
[58]
Thorium Element Facts - Chemicool
(Thorium dioxide's very high melting point ensures it stays solid, glowing with an intense, bright white light at the temperature of the lantern's burning gas.).
[59]
Incandescent Gas Lantern Mantles | Museum of Radiation and ...
The thorium-containing incandescent mantle was invented in 1884 by Carl Auer von Welsbach, an Austrian chemist, and it is sometimes referred to as a “Welsbach ...Missing: 1890s | Show results with:1890s
[60]
[PDF] Health & Hazardous Waste - NJ.gov
The Welsbach Company was for a number of years the largest manufacturer of gas mantles in the world, at its peak making up to. 250,000 mantles per day. However, ...<|control11|><|separator|>
[61]
Thoria-crucible production - US1512801A - Google Patents
-Pure thorium oxide crucibles have high shrinkage and are conse uently of the greatest density.Missing: dioxide early
[62]
ORNL's Molten-Salt Reactor Program (1958-1976)
This reactor was built to test the types of fuels and materials that would be used in thorium reactors; it also provided operation and maintenance experience.Missing: details | Show results with:details
[63]
Molten Salt Reactor - Oak Ridge National Laboratory
Molten Salt Reactors are demonstrated technology. They're flexible in design and purpose, they can be used to help close the nuclear fuel cycle, and they allow ...
[64]
[PDF] Fuel Summary Report: Shippingport Light Water Breeder Reactor
The Shippingport Light Water Breeder Reactor (LWBR) was developed by Bettis Atomic Power Laboratory to demonstrate the potential of a water-cooled, thorium ...
[65]
Thorium Fuels - radioactivity.eu.com
Neutron captures by uranium-233 leading to fissions produce a higher number of secondary neutrons : 2.28 neutrons per neutron captures, against 2.07 for uranium ...
[66]
[PDF] WASH-1097 - the Molten Salt Energy Technologies Web Site
The MSBR offers the potential of a breeding ratio of 1.07, a specific inventory in the order of 1.0 kg ... Thus, one of the advantages inherent in the higher ...
[67]
[PDF] Status of Molten Salt Reactor Technology
MSR GROUP OF PROJECT-728, Thorium-Uranium Conversion Ratio Measurement. Experiments Summary Report of Molten Salt–Graphite Zero Power Reactor, Rep. D151-693 ...
[68]
[PDF] Safety and Regulatory Issues of the Thorium Fuel Cycle
” In a thermal reactor, the U-Pu cycle gives a conversion ratio of ~0.6 ̶0.7, and therefore a breeding cycle (conversion ratio greater than 1.0) is not possible.
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[PDF] Perspectives on the Use of Thorium in the Nuclear Fuel Cycle
Thorium, abundant, has potential as nuclear fuel, but lacks a fissionable isotope and needs prior fissile matter. It breeds 233U like 238U breeds 239Pu.Missing: deemphasis | Show results with:deemphasis
[70]
[PDF] Comparison of thorium and uranium fuel cycles - GOV.UK
Mar 5, 2012 · One of the benefits of the thorium fuel cycle is to reduce the inventories of plutonium and minor actinides, which control radiotoxicity between ...
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[PDF] Thorium based fuel options for the generation of electricity
Compared to the other fissile isotopes, 233U has the highest yield of neutrons per fission. This allows an increased breeding ratio (BR) of the thermal ...Missing: empirical | Show results with:empirical
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[PDF] IAEA Nuclear Energy Series Role of Thorium to Supplement Fuel ...
An major indicator of the efficiency of thermal and fast reactors for 233U production is the amount of. 233U produced per tonne of discharged heavy metal.Missing: empirical | Show results with:empirical
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[PDF] Final Report on the Power Operation of the AVR Experimental ...
of the 300 MW THTR reactor in Schmehausen. The minimum requirements on ... tested with Th-U mixed oxide as well as also uranium with low enrichment in.
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[PDF] AHWR300-LEU - BARC
The reactor physics design of AHWR300-LEU is optimised to achieve high burn-up with the LEU-Thorium based fuel along with inherent safety characteristics like ...
[75]
[PDF] Design and development of the AHWR—the Indian thorium fuelled ...
thorium-based technologies for the entire fuel cycle. The Advanced Heavy Water Reactor (AHWR) has been designed to fulfill this need. The. AHWR is a 300 MWe ...
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China Scientists Announce Breakthrough In Refuelling Thorium ...
May 4, 2025 · Scientists in China have refuelled a working thorium molten salt reactor (MSR) without causing a shutdown – a feat never achieved before.
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China's TMSR-LF1 Molten Salt Thorium Reactor Begins ... - Hackaday
Apr 19, 2025 · October 26, 2025. China's TMSR-LF1 Molten Salt Thorium Reactor Begins Live Refueling Operations. 33 Comments. by: Maya Posch · April 19, 2025.
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Thorium - Periodic Table of Elements: Los Alamos National Laboratory
Thorium oxide has a melting point of 3300°C, which is the highest of all oxides. Only a few elements, such as tungsten, and a few compounds, such as ...Missing: dioxide | Show results with:dioxide
[79]
[PDF] URANIUM OXIDE (UO2) - Department of Energy
Odor: N/A. Odor Threshold: N/A. pH: N/A. Molecular Weight: 270.03. Molecular Formula: UO2. Melting Point: 5176-5248°F (2858-2898°C). Specific Gravity: 10.96.
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Natural thorium resources and recovery: Options and impacts
Mar 27, 2017 · It may be possible to recover substantial quantities of thorium as a by-product from active titanium, uranium, tin, iron, and rare earth mines.<|separator|>
[81]
The Radioactivity of Thorium Incandescent Gas Lantern Mantles
Feb 1, 2021 · The use of thorium in providing the intense white luminescence emitted from gas mantles, has a history of some 130 years.Missing: dioxide | Show results with:dioxide
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US5071799A - Incandescent mantles - Google Patents
... mantle having a composition of about 99% thorium oxide and about 1% cerium oxide. This composition was determined by experimentation covering a wide range ...
[83]
Historical perspective on the physics of artificial lighting
The mantle reaches the flame temperature, hence high visible emission due to the Cerium with little gas consumption due to the weak infrared emission. Heated at ...
[84]
[PDF] E:\Advanced synthetic routes towards thorium dioxide doped with ...
This domain of chemistry, using mechanical impact on materials to alter their properties is called mechanochemistry. ... Hardness (Vickers). Fracture toughness ...
[85]
[PDF] Thorium dioxide - NJ.gov
Thorium Dioxide is a heavy, white, crystalline (sand-like) powder. It is used in ceramics, in nuclear fuels, as a catalyst, and in electrodes for arc welding.
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[PDF] THORIUM DIOXIDE: PROPERTIES AND NUCLEAR APPLICATIONS
This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States.
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[PDF] Thorium | 2018 Minerals Yearbook - USGS Publications Warehouse
in catalytic applications, tho2 is used in petroleum fluid catalytic cracking (converting crude oil into lighter fractions) and in the production of nitric and.
[88]
Oil and Gas Industry | Reporting Assistant for International Nuclear ...
Thorium oxide has been used as a catalyst to assist in cracking, the process of breaking complex organic molecules into simpler molecules. Thorium is nuclear ...
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Promoting effects of thoria on the nickel-manganese mixed oxide ...
Among all synthesized catalysts ThO2-(5%)-NiMnO catalyst calcined at 400 °C exhibited the highest catalytic performance and stability for the selective ...
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[PDF] thorium 2016 - AWS
in the united States, only minor amounts, estimated at about 1 t of thorium oxide (tho2), are typically used annually. Principal uses include catalysts ...Missing: dioxide | Show results with:dioxide
[91]
[PDF] Special refractories for use at high temperature
shapes from the oxides of thorium, magnesium, zirconium, and beryllium. Thorium oxide, with a melting point above 3,000° C, is the most refractoryof the four ...
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Small Cast Thorium Oxide Crucibles - ResearchGate
Aug 9, 2025 · Crucibles were made from thorium oxide by casting from a slip made according to ceramic practice. The presence of cryolite in the slip insured its successful ...Missing: 1900s | Show results with:1900s<|separator|>
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Thorium Nuclear Fuel Cycle
For nuclear applications, also important are thorium's radiation stability and thorium dioxide's higher thermal conductivity. These properties suggest thorium ...
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Properties of Thorium Oxide Ceramics
Resistance of thoria ceramics to hot water and molten metals is of interest in reactor applications. The few data concerning corrosion in the literature are ...Missing: applications | Show results with:applications
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Thorium Oxide | AMERICAN ELEMENTS ®
Thorium Oxide is a highly insoluble thermally stable Thorium source suitable for glass, optic and ceramic applications.
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5.2.6 Other Past Uses - Thorium Energy Alliance
Aug 11, 2020 · Thorium Ceramic is used in high temp Crucibles as described by Richardson (1935) whereby Thorium Oxide, with the addition of Zirconium Oxide, ...Missing: applications | Show results with:applications
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First-principles study of ground-state properties and high pressure ...
The mechanical properties, electronic structure and phonon dispersion of ground state ThO2 as well as the structure behavior up to 240 GPa are studied using ...
[98]
[PDF] arXiv:0908.3558v1 [cond-mat.mtrl-sci] 25 Aug 2009
Aug 25, 2009 · In particular, due to its prominent hardness, ThO2 has potential interests as an optical component material and laser host.
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Yttralox Ceramic Laser - DTIC
The long range goal of the current program is to develop the necessary technology for reproducibly fabricating a laser host material with both high peak and ...
[100]
[PDF] doped thorium dioxide due to phonon-spin interactions
) is investigated. ThO2 is an electronic insulator with a wide optical band-gap and no ... laser host materials, thermoelec- trics [3], and nuclear fuels [4]. In ...
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Thorium - Cancer-Causing Substances - NCI
Jun 11, 2024 · Minerals such as monazite, thorite, and thorianite are rich in thorium and may be mined for the metal. Thorium has coloring properties that ...<|separator|>
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Cancer risk following exposure to Thorotrast: overview in relation to ...
Hepatic tissue in USUR Case 1001 was estimated to have received an average lifetime absorbed dose of 16.2 Gy, based on radiochemical analyses, consistent with ...
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The german thorotrast study: recent results and assessment of risks
For liver cancer, the cumulative risk estimate was calculated to be 40 per 10(4) person Sv (radiation weighting factor = 20).
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HEALTH EFFECTS - Toxicological Profile for Thorium - NCBI - NIH
Hepatic effects have not been observed in studies of laboratory animals. Inhalation exposure to 0.55 nCi/m3 thorium dioxide for 1 year did not result in ...Missing: radiotoxicity | Show results with:radiotoxicity
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[PDF] Toxicological Profile for Thorium
Action Criteria; PEL = permissible exposure limit; REL = recommended exposure limit; RfC = inhalation reference concentration; RfD = oral reference dose ...
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Alpha-particle carcinogenesis in Thorotrast patients: epidemiology ...
The major causes of the death of Thorotrast patients are liver cancer, liver cirrhosis, leukemia, and other cancers. Three histologies of liver cancer are found ...Missing: sarcomas | Show results with:sarcomas
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Histological type of Thorotrast‐induced liver tumors associated with ...
Thorotrast is known to induce liver tumors, particularly intrahepatic cholangiocarcinoma (ICC) and angiosarcoma (AS), decades after injection.Missing: sarcomas | Show results with:sarcomas
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Mortality among Thorotrast-exposed patients and an unexposed ...
Mortality among Thorotrast-exposed patients and an unexposed comparison group in the German Thorotrast study. Eur J Cancer. 2008 Jun;44(9):1259-68. doi: 10.1016 ...
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Epidemiology of Thorotrast-induced hepatic angiosarcoma in the ...
An epidemiologic investigation of hepatic angiosarcoma (HAS) in the United States, directed primarily at the years 1964–1974, has identified 26 cases of ...
[110]
[PDF] Toxicological Profile for Thorium
Results: Thorotrast treatment was positively associated with all cancers and particularly with liver cancer. Cancer cause of death. Thorotrast-exposed. SIR.
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Mortality among workers in a thorium-processing plant - jstor
The range of the mean thorium exposure in this group was 0.9- 2.0 Bq. Group 3 (28 workers), which had the lowest thorium exposure (0.1. - 0.5 Bq) ...<|separator|>
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Mortality among workers at Oak Ridge National Laboratory ...
... exposure lag was related to all causes of death (2.68% increase per 10 mSv) primarily due to an association with cancer mortality (4.94% per 10 mSv).Missing: thorium | Show results with:thorium
[113]
Radiation and mortality of workers at Oak Ridge National Laboratory
These findings suggest increases in cancer mortality associated with low-level external exposure to ionizing radiation and potentially greater sensitivity to ...Missing: thorium | Show results with:thorium
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[PDF] .. Comparison of the Radiological Impacts of Thorium and Uranium ...
Mar 1, 2025 · The major difference between the impacts from the two fuel cycles is the larger dose commitments associated with current uranium mining and ...
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[PDF] improving the sintering behavior of thorium oxide | sck cen
ThO2 presents additional costs over UO2 both in the powder precipitation and pellet sintering stage. The higher thermal stability of ThO2, which increases ...Missing: hurdles | Show results with:hurdles
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ThO2 and (U,Th)O2 processing—A review
At Nuclear Fuel Complex, India, it was found that doping by Nb2O5 lowered the sintering temperature of ThO2 to 1150˚C [41,42]. Without the additive, the same ...
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[PDF] Corrosion of Containment Alloys in Molten Salt Reactors and the ...
Experiments on corrosion effects with molten salts date back to the Aircraft Reactor Experiment as early as. 1940 [1] and research on chemical compatibility ...
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[PDF] Molten Salt Reactor Technical and Safety Considerations Outside of ...
MSR technical issues affecting fuel cycle technology and high-level waste generation, transport, and storage have implications for policies that derive directly ...
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[PDF] Thorium Energy Cheaper Than Coal English Edition
According to recent modeling studies, the levelized cost of electricity (LCOE) for thorium-based nuclear power could fall below that of coal-fired plants ...
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A methodology for calculating the levelized cost of electricity in ...
In this paper we show how the traditional definition of the levelized cost of electricity (LCOE) can be extended to alternative nuclear fuel cycles in which ...
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[PDF] Does thorium have a place in the future U.S. electricity mix?
Dec 12, 2014 · ... reactor to market, there lies technical, political, and economic challenges. The following chapter will discuss what these challenges are.<|separator|>
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U-232 and the proliferation-resistance of U-233 in spent fuel
U-232 decays with a 69-year half-life through 1.9-year half-life Th-228 to T1-208, which emits a 2.6 MeV gamma ray upon decay. We find that pressurized light- ...
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New AHWR-LEU By India To Use Thorium
This non-proliferation feature becomes important in view of the proliferation concerns raised regarding India's civilian nuclear deals with the United States ...<|separator|>
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Molten salt reactors were trouble in the 1960s—and they remain ...
Jun 20, 2022 · After March 1968, the fuel was changed to one involving another weapons-usable material, uranium-233, which was derived from thorium. After this ...Missing: WWII 1940s-<|separator|>
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Kirk Sorensen – Why didn't molten salt thorium reactors succeed the ...
“The thorium-fueled fluoride reactor program was in competition with the plutonium fast breeder program, which got an early start and had copious government ...
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Thorium's Long-Term Potential in Nuclear Energy: New IAEA Analysis
Mar 13, 2023 · Another advantage is that thorium-fuelled reactors could be much more environmentally friendly than their uranium counterparts.
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Tuberville's legislation would stop destruction of thorium stockpiles
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S.4242 - 117th Congress (2021-2022): Thorium Energy Security Act ...
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Frequently Asked Questions - Energy From Thorium
... ignored. One path is thorium, the other path is the plutonium fast-breeder. The path that was taken, or at the very least, the path that the nuclear ...
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Thorium - PeakChoice.org
Vrain plant in Colorado, which closed in 1989 after 10 years and hundreds of equipment failures, leaks, and fuel failures. There were four failed commercial ...
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Thorium nuclear power was a commercial failure- nothing to do with ...
Feb 1, 2017 · Thorium nuclear power was a commercial failure- nothing to do with nuclear weapons, as pro nukers pretend · The existing major industrial and ...
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China refuels thorium reactor without shutdown
Apr 22, 2025 · Chinese scientists have refuelled an experimental thorium-fueled molten salt reactor continuously without shutting it down.
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Why China Is Building a Thorium Molten-Salt Reactor - IEEE Spectrum
China plans to build a thorium-based molten salt reactor in the Gobi Desert in 2025, marking a significant advancement in nuclear power research.
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Influence of thorium dioxide powder synthesis methods on ...
We investigated the influence of the synthesis method on the properties of ThO2 powders and on their sinterability in conventional and spark plasma ...
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[PDF] THE IMPORTANCE OF THORIUM IN THE CONTEXT OF ... - INIS-IAEA
Thorium dioxide is chemically more stable and has higher radiation resistance than uranium dioxide. The fission product release rate for ThO2–based fuels is ...
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The utilization of ThO2 fuel discharged from an ADS in the Multi ...
ThO2 fuel improves MASLWR performance, allowing longer cycles, higher burn-up, and less poison use. It also has lower temperature than UO2.
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Thorium dioxide Market Size and Industry Outlook - LinkedIn
Jun 19, 2025 · The "Thorium dioxide market" is anticipated to experience significant growth, with a projected CAGR of 13.9% from 2025 to 2032. This market ...
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Thorium Dioxide Market: A Comprehensive Analysis 2032
The global market for commercial grade thorium dioxide is expected to reach USD 1.5 billion by 2024, growing at a CAGR of 9.2%. Reactor Grade: Reactor grade ...
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[PDF] The Nuclear Renaissance - DBS Bank
Jun 2, 2025 · The urgency to tackle climate change is another powerful driver of nuclear energy demand. Nuclear energy is increasingly being viewed as the.
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Clean Core Thorium Energy Raises $15.5M in Series Seed
Feb 6, 2025 · Clean Core Thorium Energy (CCTE) has raised a $15.5M Series Seed round of financing to advance the ANEEL fuel - a patented blend of thorium & HALEU.
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US Firm Achieves Second Thorium Breakthrough at Idaho National ...
Aug 13, 2025 · CCTE's first-of-its-kind, thorium-based fuel continues to surpass burnup records, paving the way for safer and more sustainable nuclear ...
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Clean Core Gets Approval To Export Thorium Fuel Technology To ...
Sep 19, 2025 · US-based Clean Core Thorium Energy has received specific export authorisation for its advanced thorium-enriched uranium fuel technology, paving ...Missing: commercialization | Show results with:commercialization
[145]
Thorium-Powered Future: Key to India's 100 GW Nuclear Goal
Jun 10, 2025 · The third stage focuses on deploying reactors that run primarily on thorium-based fuels. The Advanced Heavy Water Reactor (AHWR), a 300 MWe ...
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Nuclear Power in India
See R&D section under IGCAR. Design of the first 300 MWe AHWR (920 MWt, 284 MWe net) was completed early in 2014 at BARC. It is mainly a thorium-fuelled ...
[147]
Thorium Reactor: Harnessing Emerging Innovations for Growth ...
Rating 4.8 (1,980) Apr 22, 2025 · By 2040, the market size is expected to reach upwards of $50 billion, driven by an increase in commercial deployments and government support.
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India's Most Sophisticated Atomic Reactor Set For Fuel Loading ...
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Safety and Regulatory Issues of the Thorium Fuel Cycle (NUREG ...
The primary objectives of this report are to summarize historical, current, and proposed uses of thorium in nuclear reactors; provide some important properties ...
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[PDF] Australian Energy Resource Assessment - Uranium and Thorium
Australian production and subsequent trade of thorium is not likely to occur on a large scale before 2030. • If commercialisation of a thorium fuel cycle occurs ...
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Rare earth elements (REE) - NSW Resources
The potential for monazite-hosted REEs in the province is actively being investigated by companies.
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Nuclear Power Versus Renewable Energy - Change Oracle
Jul 20, 2022 · Nuclear energy has advantages over renewables in terms of reliability, GHG emissions, land use and waste. Nuclear is far more reliable ( ...
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[PDF] Introduction of Thorium in the Nuclear Fuel Cycle | OECD
Notwithstanding, the fundamental driver of this renaissance, the decarbonising of the world's energy production to limit climate change, still remains valid.